Physics of Cavitation: GAS CONTENT and Nuclei: 3.1 Cohesive Forces
Physics of Cavitation: GAS CONTENT and Nuclei: 3.1 Cohesive Forces
Physics of Cavitation: GAS CONTENT and Nuclei: 3.1 Cohesive Forces
9
10 G.Kuiper, Cavitation in Ship Propulsion, January 15, 2010
In practice the main mechanism of inception in which µ is the dynamic viscosity of water
is the growth of small gas bubbles called nu- (related to the kinematic viscosity ν by ν = µρ .
clei,which are present in the water. These nu- The rise velocity of a bubble can then simply
clei are small bubbles, filled with air (or other be written by equating the rise force FD with
gases) and vapor. The diameter can vary from the bubble drag, which results in Stokes’ law:
a few microns to nearly visible bubbles of the
order of 1 mm. That seems queer, because g ∗ D2
Vb = (3.1)
in standing water at atmospheric conditions 18 ∗ ν
gas bubbles will generally disappear due to two This equation is useful to estimate the time
mechanisms: bubble rise and dissolution. To needed for a bubble to rise out of the measure-
understand the behavior of nuclei it is useful ment volume. Consider e.g. a nucleus of 100
to describe these two phenomena first. microns (100 ∗ 10− 6 m)in diameter. As we will
see later in chapter 4, such a nucleus is suf-
ficient in many cases to bring the cavitation
3.2 Rising bubbles inception pressure close to the vapor pressure.
In standing water a bubble will rise to the sur- Such a nucleus reaches a rising speed (from
face due to the difference between the weight eq. 3.1of
of the bubble and the weight of the displaced 9.81 ∗ 10− 8
water. This difference causes a buoyancy force = 0.55 ∗ 10− 2m/sec
18 ∗ 10− 6
on the bubble. Neglecting the weight of the
air in the bubble this force F is equal to the or approximately 5 mm/sec. In a towing tank
weight of water displaced by the bubble: the upper layer of 1 meter depth will be free
of such nuclei after a few minutes. Nuclei of
ρw ∗ π ∗ Db3 ∗ g 10 microns take 100 times as much time, so a
F = few hours.
6
At sea the turbulent motions in the upper
, in which ρw is the specific mass of water and layer of the water are often in sufficient
Db is the bubble diameter. motion to keep nuclei mixed up forever. But
The subsequent rise velocity is determined by after a storm the nuclei content of the upper
the drag Db of the bubble. That is a compli- layer of the sea can contain much more larger
cated matter, but the simplest solution is a so- nuclei. The storm itself creates these nuclei
lution of the Navier-Stokes equation in which by breaking waves and the increased wave
the kinematic forces are negligible relative to motions prevent the rise to the surface or at
the viscous forces. The drag of the bubble least delay it considerably. However, over
is thus completely due to friction along the time they will rise to the surface.
bubble wall wilt a laminar boundary layer and
this condition is expressed in non-dimensional
terms as a low Reynolds number Reb = VbνDb ,
in which nu is the kinematic viscosity of wa- 3.3 Dissolving bubbles
ter and Vb is the bubble velocity. In this equa-
tion it is also assumed that the bubble remains Another mechanism for gas bubbles to disap-
spherical, which is applicable for small bubbles pear is dissolution. In that case the gas bub-
at low velocities. The drag of a bubble can bles disappear because the air dissolves in the
then be written as surrounding water due to diffusion and the va-
por in the bubble condensates because of the
Db = 3πµDb Vb surface tension.
January 15, 2010, Nuclei11
Water can absorb a lot of air and it is very pressure of that gas in equilibrium with
important to distinguish between dissolved that liquid. The coefficient is called Henry’s
air and free air. Free air is present in the form constant, but this ”constant” is temperature
of bubbles. The majority of the air in water is dependent.
dissolved and dissolved air has no significant When the water is not saturated, there will
effect on the cohesive forces in the water. be a mass flow through the bubble wall and
At 15 degrees Celcius in atmospheric condi- the bubble will disappear because the free
tions the amount of air that can be dissolved air goes into solution. Even when the water
in one cubic meter of water is about 25-30g is saturated, small bubble will disappear
(25-30 liters in atmospheric conditions). because the pressure inside a bubble is higher
This is expressed as the gas concentration than in the surrounding fluid due to the
C = 3 ∗ 10− 2kg/m3 . In that case the water surface tension, as will be discussed later.
is saturated. In that condition there is no
net transfer of air molecules through the free Contrary to evaporation, diffusion is a
surface. The air content of water is often relatively slow process. Evaporation takes
expressed as the fraction of the maximum place at the surface of a bubble only, but
amount of gas that can be absorbed: the diffusion extends over a much thicker layer
saturation rate. For the calculation of the of fluid around the bubble. At the bubble
air content in in various units see Appendix wall the saturation rate of the water will
A. Note that the saturation rate can be immediately be such that the partial pressure
exceeded considerably without gas coming of the dissolved air is equal to the partial
out of solution immediately. In that case the pressure of the air in the bubble. When the
water is oversaturated or supersaturated and saturation rate of the bulk of the water is
this can amount to two or three times the different, air molecules will migrate to or
saturation rate. from the bubble. Over a certain distance a
concentration gradient will form.
As mentioned bubbles in water contain air
The mass flow m in kg/m3 through the wall
and vapor. Dalton’s law states that the total
of a bubble with radius R can be written as
pressure exerted by a gaseous mixture is equal
to the sum of the partial pressures of each
individual component in a gas mixture. This dm dCg
= 4πR2 Dg ( )R (3.2)
empirical law was observed by John Dalton in dt dr
1801. So the pressure inside of a bubble is the in which Dg is a diffusion coefficient
sum of the partial pressures of air and vapor. (m2 /sec) and Cg is the gas concentration in
The partial pressure of vapor is the equi- (kg/m3 ). The gradient ( ∂C g
∂r R
) is the gradient
librium vapor pressure. In many conditions of the gas concentration at the bubble wall.
the vapor pressure can be neglected and a When the vapor is neglected and the gas den-
bubble can be considered as a pure gas bubble. sity remains the same the mass change is
dm d(4/3πR3 )
Transport of gas through the bubble wall = ρg
dt dt
is governed by Henry’s law (formulated by
and from eq.3.2 the bubble radius changes as
William Henry in 1803), which states that
at a constant temperature, the amount of a
given gas dissolved in a given type and volume dR Dg dCg
= ( )R (3.3)
of liquid is directly proportional to the partial dt ρg dr
12 G.Kuiper, Cavitation in Ship Propulsion, January 15, 2010
Eppstein and Plesset [9] gave an approxi- (πDt)1/2 is 5 ∗ 10− 4, which is still an orders
mate solution for the concentration gradient: of magnitude larger than the initial radius
R0 = 5−5 . It is therefore justified to neglect
this term in eq.3.4.
dCg 1 1
( )R = ( + )(Cg∞ − CgR )
dr R (πDg t)1/2
Surface tension will reduce this time for a
(3.4) bubble to dissolve, but these approximations
can be used to determine a time scale. It fol-
in which the length (πDg t)1/2 can be re- lows that the diffusion rate is low when com-
garded as a diffusion boundary layer thickness. pared to the time scale of bubble dynamics in
For small bubbles this thickness is much larger a flow. However, when the existence of gas
than the radius R, so eq. 3.4 can be written bubbles in a fluid is considered, small bubbles
as will tend to go into solution.
dCg (Cg∞ − CgR )
( )R = (
dr R
and eq.3.3 can be integrated and written as 3.4 Mechanisms to sustain
nuclei
2Dg (Cg∞ − CgR )
R2 = R0 2 + t (3.5) From the foregoing it is still unexplained
ρg why there are so many nuclei in water.
The time to go completely into solution is One mechanism that can keep nuclei in the
when R=0 in eq.3.5 and when Cg∞ − CgR is water without rising to the surface is the
negative: combination of gas and solid particles. For
that mechanism we have to consider the
surface tension of a fluid. The difference in
R0 2 ρg bond between cohesion between the water
t= (3.6)
2D(CgR − Cg∞ ) molecules and adhesion between water and
air molecules causes surface tension. The
The diffraction coefficient Dg is close to cohesion attracts the molecules at a free sur-
2 ∗ 10−9 m2 /sec. face and prevent these molecules to mix with
the air. The result is also a tension on the
An example can give a rough idea about surface molecules, which curves the surface in
time scales. Consider a bubble with a diame- the neighborhood of a solid wall. The surface
ter of 100 microns (R = 0.5 ∗ 10− 5m) in water tension makes that a small gas bubble tends
at atmospheric pressure with a saturation to be spherical. The surface tension increases
rate of 50%. The saturation rate of the the pressure inside a spherical gas bubble
water at the bubble wall will be 100 %. The with an amount of 2s/Rb Pa, in which s is
concentration gradient is then estimated as the surface tension and Rb the bubble radius.
1.5 ∗ 10−2 kg/m3 and with ρg = 1 this means The surface tension of water in contact with
(C −C )
that g∞ρg gR = −1.5 ∗ 10−2. From eq.3.6 air at 15 degrees Celcius is 0.075 Nm and
it follows that the time for the bubble to the sensitivity to the temperature is not very
dissolve is 41 seconds. When submerged at strong.
1 m below the surface, such a bubble will
not reach the surface (at 5mm/sec), but go Consider again a nucleus of 0.1mm diame-
into solution. At a time t = 41 the term ter in a fluid of 1 bar (105 P a). The pressure
January 15, 2010, Nuclei13
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Appendix A
The amount of air dissolved in water α can with saturated water therefore contain 36 per-
be expressed in many ways. The most common cent oxygen. But nuclei which are generated
ways in literature are from the air above the water contain 21 per-
cent oxygen. Since the ratio between oxygen
• the gas fraction in weight ratio αw and nitrogen is not fixed, it is difficult to re-
late measurements of dissolved oxygen (by os-
• the gas fraction in volume ratio αv
mose) to measurements of dissolved air (from
• the molecule ratio e.g a van Slijke apparatus).
The amount of oxygen dissolved in water at
• the saturation rate
atmospheric pressure at 15 degrees Celcius is
• the partial pressure of air approximately 10 ∗ 10− 6kg/kg. For nitrogen
this value is about 15 ∗ 10− 6, so the solubility
of air in water is the sum of both: 25 ∗ 10− 6.
A.1 Solubility Here the dissolved gas contents are expressed
as a weigth ratio αw .Air is very light relative
Air is a mixture of 21 percent oxygen, 78 per- to water and the weight ratio is very small.
cent nitrogen and one percent of many other This ratio is therefore often expressed as parts
gases, which are often treated as nitrogen. The per million (in weight), which is 106 ∗ αw .
specific mass of gases involved in air are:
69
70 G.Kuiper, Cavitation in Ship Propulsion, January 15, 2010
M( water)
αw = αm (A.4)
M( gas)
in which M is the molar weight, which is 18
for water, 16 for oxygen(O2 ) and 28 for Nitro-
gen (N2 ). For air a virtual molar weigth can
Appendix B
Standard Cavitators
71
72 G.Kuiper, Cavitation in Ship Propulsion, January 15, 2010
Tables
T pv
Celcius N/m2
0 608.012
2 706.078
4 813.951
6 932
8 1069
10 1226
12 1402
14 1598
15 1706
16 1814
18 2059
20 2334
22 2638
24 2981
26 3364
28 3785
30 4236
32 4756
34 5315
36 5943
38 6619
40 7375
75
76 G.Kuiper, Cavitation on Ship Propellers, January 15, 2010
Rn Cf × 103
1 × 105 8.333
2 6.882
3 6.203
4 5.780
5 5.482
6 5.254
7 5.073
8 4.923
9 4.797
1 × 106 4.688
2 4.054
3 3.741
4 3.541
5 3.397
6 3.285
7 3.195
8 3.120
9 3.056
1 × 107 3.000
2 2.669
4 2.390
6 2.246
8 2.162
1 × 108 2.083
2 1.889
4 1.721
6 1.632
8 1.574
1 × 109 1.531
2 1.407
4 1.298
6 1.240
8 1.201
1 × 1010 1.17x
Nomenclature
kg
ρ density of water m3
See TableC.4
3
Cg gas concentration kg/m see Appendix A
Dg diffusion coefficient m2 /sec representative value 2 ∗ 109
D diameter m
Fd drag N
m
g acceleration due to gravity sec2
Taken as 9.81
−
N d number density of nuclei m 4
pg gas pressure f racN m2
f racN m2
pv equilibrium vapor pressure
R radius m
kg
µ dynamic viscosity of water m∗sec
m2
ν kinematic viscosity of water sec
(ν = µρ )See Table C.2
s surface tension Nm for water 0.075
79