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3 Fire and Heat

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3 Fire and Heat

• Introduction to fire behaviour, fire load


and rate of heat release
• Fire growth
• Flashover
• Post-flashover fires
• Design “natural” fire behaviour

The fire triangle


Heat

Fuel + Oxidant = Combustion products


CH4 + O2 = CO2 + 2H20

Reaction
occurs when
Oxygen/fuel
mixture hot
enough

Fuel Oxygen

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Fuels
• All fuels are hydrocarbons consisting
mainly carbon and hydrogen atoms with
addition of oxygen, nitrogen and others in
some cases
e.g., combustion of propane
C3H8 + 5O2 = 3CO2 + 4H2O

Calorific Value ΔHc


• The amount of heat release from a complete
combustion of a unit mass of fuel
• Unit = MJ/kg

• Energy released due to combustion is


E = m ΔHc

Mass of fuel (kg) Calorific value (MJ/kg)

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Fire Load
• Fire load is often expressed as Fire Load
Density per floor area, Af
qf = E/Af
• European code expresses it as Fire Load
Density per total room surface area, At
qf = E/At
At is the bounding surfaces include floor,
ceiling, walls including window openings.

Fire Load Density Per Unit Floor Area (ECCS)

TYPE OF FIRE COMPARTMENT FIRE LOAD


DENSITY qf
MJ/m2

DWELLINGS: Bedroom 630


Living room 510
OFFICES: Technical 720
Administrative 640
SCHOOLS: Junior level 370
Middle level 400
Senior level 260
HOSPITALS: Bedroom 80

HOTELS: Bedroom 420

1 kg wood = 17.3 MJ

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Rate of Heat Release (RHR) Q
 = E/t
Q (MW)

E = total energy contained in the fuel (MJ)


t = duration of the burning (second)

 = (m ΔHc)/t
Q

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Oxygen Consumption Calorimeter
By sampling the oxygen concentration in the fuel gas

1 kg O2 = 13100 kJ=
13MJ


Q

ΔHc can be determined


We know m and t
Hence we can determine
m 
Q = (m ΔHc)/t

Oxygen Calorimetry (1)

Oxygen Consumption Calorimetry

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Oxygen Calorimetry (2)

Oxygen Consumption Calorimetry


- Room Calorimetry

Example: Mattress

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Sources of RHR
• Babrouskas, V. Greyson, S. (ed.): Heat
Release in Fires, E & FN Spon, 1992
• SFPE Handbook of Fire Protection
Engineering, 2rd ed., National Fire
Protection Association, Quincy, MA., 2000

Single Burning Item


Q = αt2, α = fire intensity coefficient (MW/s2)

T-square fire

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Two Burning Items

Item 2

Item 1

T-Square Fire
.
Q = αt 2
Fire density coefficient
Growth Rate α (kW/s2)

Ultra Fast (e.g. Shopping centres, entertainment centres) 0.19

Fast (e.g. Schools, offices, Hotels, Nursing homes) 0.047

Medium (e.g. Dwellings) 0.012

Slow (e.g Gallery) 0.003

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The time t1 to reach the maximum heat release rate Qmax is

. Q max Qmax
Q = αt 2 t1 =
α

Energy released is area under the curve, Qm


which is one-third the rectangular area E2
E1
1t
1 1
E1 = ∫ αt 2 dt = αt 31 = Q max t 1
3 3 t m t1 t2
0 tb
Total energy that has not been in time t1 will be released in the steady burning
phase E2 given as E2 = E – E1
And the duration of the steady burning phase is
tb = t2 – t1 = E2/Qmax

If the fuel has insufficient time to reach its maximum release rate, all the fuel
will be consumed in time tm where tm = 3E/Q and Q = αtm2, we have
tm = (3E/α)1/3

Example
Calculate the heat release rate for 160kg office furniture with an
average calorific value of 20MJ/kg. It burns as a “fast” t2 fire with
a peak heat release rate of 9.0MW
Mass of Fuel M = 160 kg Calorific value ΔHc = 20 MJ/kg
Energy contained in fuel = E = M ΔHc = 160x20 = 3200 MJ
Fire intensity coefficient for a fast fire α = 0.047 (kW/s2)
Maximum heat release rate Q max = 9.0MW
Time to reach the maximum heat release t = (Q max/ α)0.5 =
(9000/0.047)0.5=438s
Energy released in time t1 E1 = t1Qmax/3 = 438 x 9/3 = 1314 MJ
Since E1 < E so there is a steady burning

Energy released in steady burning E2 = E – E1 = 3200 -1314 = 1886


Duration of steady burning tb = E2/Qmax = 1886/9 = 210s

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Qmax = 9MW

E2 = 1886 MJ

E1= 1314 MJ

T1=438s T2 = 648 s

Tb = 210 s

Additional Homework
• Repeat the example assuming low t-square
fire (e.g., residential building)

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