3 Fire and Heat
3 Fire and Heat
3 Fire and Heat
Reaction
occurs when
Oxygen/fuel
mixture hot
enough
Fuel Oxygen
1
Fuels
• All fuels are hydrocarbons consisting
mainly carbon and hydrogen atoms with
addition of oxygen, nitrogen and others in
some cases
e.g., combustion of propane
C3H8 + 5O2 = 3CO2 + 4H2O
2
Fire Load
• Fire load is often expressed as Fire Load
Density per floor area, Af
qf = E/Af
• European code expresses it as Fire Load
Density per total room surface area, At
qf = E/At
At is the bounding surfaces include floor,
ceiling, walls including window openings.
1 kg wood = 17.3 MJ
3
Rate of Heat Release (RHR) Q
= E/t
Q (MW)
= (m ΔHc)/t
Q
4
Oxygen Consumption Calorimeter
By sampling the oxygen concentration in the fuel gas
1 kg O2 = 13100 kJ=
13MJ
Q
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Oxygen Calorimetry (2)
Example: Mattress
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Sources of RHR
• Babrouskas, V. Greyson, S. (ed.): Heat
Release in Fires, E & FN Spon, 1992
• SFPE Handbook of Fire Protection
Engineering, 2rd ed., National Fire
Protection Association, Quincy, MA., 2000
T-square fire
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Two Burning Items
Item 2
Item 1
T-Square Fire
.
Q = αt 2
Fire density coefficient
Growth Rate α (kW/s2)
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The time t1 to reach the maximum heat release rate Qmax is
. Q max Qmax
Q = αt 2 t1 =
α
If the fuel has insufficient time to reach its maximum release rate, all the fuel
will be consumed in time tm where tm = 3E/Q and Q = αtm2, we have
tm = (3E/α)1/3
Example
Calculate the heat release rate for 160kg office furniture with an
average calorific value of 20MJ/kg. It burns as a “fast” t2 fire with
a peak heat release rate of 9.0MW
Mass of Fuel M = 160 kg Calorific value ΔHc = 20 MJ/kg
Energy contained in fuel = E = M ΔHc = 160x20 = 3200 MJ
Fire intensity coefficient for a fast fire α = 0.047 (kW/s2)
Maximum heat release rate Q max = 9.0MW
Time to reach the maximum heat release t = (Q max/ α)0.5 =
(9000/0.047)0.5=438s
Energy released in time t1 E1 = t1Qmax/3 = 438 x 9/3 = 1314 MJ
Since E1 < E so there is a steady burning
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Qmax = 9MW
E2 = 1886 MJ
E1= 1314 MJ
T1=438s T2 = 648 s
Tb = 210 s
Additional Homework
• Repeat the example assuming low t-square
fire (e.g., residential building)
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