SAFETY DATA SHEET

According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY

1.1 Product name : DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

1.2 Identified uses : Adhesive, binding agents

Electrical and electronic applications

Uses advised against : None known.

1.3 Company : Dow Corning Europe S.A.

rue Jules Bordet - Parc Industriel - Zone C
B-7180 Seneffe
Belgium

E-mail address (Safety : sdseu@dowcorning.com

Data Sheet)

Customer Service : English Tel: +49 611237507

Deutsch Tel: +49 611237500
Français Tel: +32 64511149
Italiano Tel: +32 64511170
Español Tel: +32 64511163

Fax: +32 64888683

1.4 Emergency Phone : Dow Corning (Barry U.K. 24h) Tel: +44 1446732350
Number Dow Corning (Wiesbaden 24h) Tel: +49 61122158
Dow Corning (Seneffe 24h) Tel: +32 64 888240

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

According to EU Directives 67/548/EEC or 1999/45/EC:

R43 May cause sensitization by skin contact.

2.2 Label elements

Labelling according to EEC Directive

Contains : Trimethoxy(methyl)silane

Symbols : Xi Irritant.

R-phrases : R43 May cause sensitization by skin contact.

S-phrases : S24 Avoid contact with skin.

S37 Wear suitable gloves.
S51 Use only in well-ventilated areas.

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 SAFETY DATA SHEET
According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical characterization: Silicone elastomer

According to EU Directives 67/548/EEC or 1999/45/EC:

Name CAS-No. EINECS/ REACH Conc. Classification

ELINCS Registration (% w/w)
No. Number
Trimethylated silica 68909-20-6 272-697-1 - 23.0 R66

Trimethoxy(methyl)sila 1185-55-3 214-685-0 01-21195174 6.7 R43

ne 36-40 F R11

Methanol 67-56-1 200-659-6 01-21194333 0.14 F R11

07-44 T R23/24/25
R39/23/24/25

According to Regulation (EC) No. 1272/2008:

Name CAS-No. EINECS/ REACH Conc. Classification

ELINCS Registration (% w/w)
No. Number
Trimethylated silica 68909-20-6 272-697-1 - 23.0 Substance with a Community workplace exposure
limit
Trimethoxy(methyl)sila 1185-55-3 214-685-0 01-21195174 6.7 Flammable liquid: Category 2 - H225
Skin sensitization: Category 1 - H317
ne 36-40

Methanol 67-56-1 200-659-6 01-21194333 0.14 Flammable liquid: Category 2 - H225

Acute toxicity (Oral): Category 3 - H301
07-44
Acute toxicity (Dermal): Category 3 - H311
Acute toxicity (Inhalation - vapour): Category 3 -
H331
Specific target organ toxicity - single exposure
(Dermal): Category 1 (eye - retina, central nervous
system) - H370
Specific target organ toxicity - single exposure
(Inhalation - vapour): Category 1 (eye - retina,
central nervous system) - H370
Specific target organ toxicity - single exposure
(Oral): Category 1 (eye - retina, central nervous
system) - H370

For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
CLP classifications are based on all current available data including from known international organizations. These classifications are subject to revision as
more information becomes available.

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 SAFETY DATA SHEET
According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

4. FIRST AID MEASURES

4.1 Description of First Aid Measures:

On contact with eyes : Flush with water.

On skin contact : Flush with water. Wipe off. Obtain medical attention.

If inhaled : Remove to fresh air.

On ingestion : Obtain medical attention.

4.2 Most important : May cause sensitization by skin contact.

symptoms/effects, acute
and delayed

5. FIRE-FIGHTING MEASURES

5.1 Suitable extinguishing : On small fires use carbon dioxide (CO2), dry chemical or water spray. On large fires use
media dry chemical, foam or water spray (fog). Water can be used to cool fire exposed
containers.

Unsuitable extinguishing : None known.

media

5.2 Hazards during fire : None known.

fighting

Hazardous Combustion : Thermal breakdown of this product during fire or very high heat conditions may evolve
Products the following decomposition products: Silica. Carbon oxides and traces of incompletely
burned carbon compounds. Formaldehyde.
5.3 Special protective : A self-contained respirator and protective clothing should be worn. Determine the need to
equipment/procedures evacuate or isolate the area according to your local emergency plan. Use water spray to
keep fire exposed containers cool.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, : Wear proper protective equipment.

protective equipment and
emergency procedures

6.2 Environmental : Do not allow large quantities to enter drains or surface waters.
precautions

6.3 Methods and materials for : Scrape up and place in a container fitted with a lid. The spilled product produces an
containment and cleaning extremely slippery surface.
up

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 SAFETY DATA SHEET
According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

7. HANDLING AND STORAGE

7.1 Advice on safe handling : General ventilation is required. Avoid skin and eye contact. Local ventilation is
recommended. Do not breathe vapour. Do not ingest. Do not empty into drains.

7.2 Advice on storage : Do not store with oxidizing agents. Keep container closed and store away from water or
moisture.
Storage temperature: maximum 32 °C

7.3 Specific uses : Refer to technical data sheet available on request.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

Name CAS-No. Exposure Limits

Trimethoxy(methyl)silane 1185-55-3 50 ppm (8h TWA) - Dow Corning recommendation.

Methanol 67-56-1 200 ppm TWA

250 ppm STEL
266 mg/m3 TWA
333 mg/m3 STEL

8.2 Exposure controls

Engineering Controls : Ventilation : Refer to Section 7.1

Personal protection equipment

Respiratory protection : Contact with water or humid air will form methanol. Please take into account any
occupational exposure limits for methanol which are applicable in your country.
-
Suitable respiratory protection should be worn if the product is used in large quantities,
confined spaces or in other circumstances where the OEL may be approached or
exceeded.
Depending on the working conditions, wear a respiratory mask with filter(s) AX or use
a self-contained respirator.
The choice of a filter type depends on the amount and type of chemical being handled in
the workplace. Regarding filter characteristics, contact your respiratory protection
supplier.

Hand protection : Chemical protective gloves or gauntlets should be worn and removed correctly to avoid
skin contamination: Silver shield(TM). 4H(TM). Regarding glove's breakthrough
time,contact your chemical protective glove supplier.

Eye/face protection : Safety glasses should be worn.

Skin protection : Wear impervious overalls in circumstances where significant skin contact can occur.

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 SAFETY DATA SHEET
According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

Hygiene measures : Exercise good industrial hygiene practice. Wash after handling, especially before eating,
drinking or smoking. Remove contaminated clothing immediately.

Additional information : These precautions are for room temperature handling. Use at elevated temperature or
aerosol/spray applications may require added precautions.

Environmental exposure : Refer to section 6 and 12.

controls

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : Paste

Colour : Gray

Odour : Slight

Explosive properties : No

Specific Gravity : 1.12

Oxidizing properties : No

The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.

10. STABILITY AND REACTIVITY

10.1 Reactivity : This product releases methanol.

10.2 Stability : Stable under normal usage conditions.

10.3 Possibility of hazardous : None known.

reactions

10.4 Conditions to avoid : None established.

10.5 Materials to avoid : Can react with strong oxidising agents. Keep from any possible contact with water.
Protect from moisture

10.6 Hazardous decomposition : Thermal breakdown of this product during fire or very high heat conditions may evolve
products the following decomposition products: Silica. Carbon oxides and traces of incompletely
burned carbon compounds. Formaldehyde.

11. TOXICOLOGICAL INFORMATION

Acute toxicity:

On contact with eyes : May cause temporary discomfort.

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 SAFETY DATA SHEET
According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

On skin contact : Large amount in contact with significant skin surface areas may cause systemic adverse
effects.

If inhaled : May cause dizziness, drowsiness, confusion, headaches, nausea, and at high
concentrations, unconsciousness.

On ingestion : Forms methanol. Swallowing large amounts may cause systemic adverse effects and
blindness.

Chronic toxicity:

On skin contact : Prolonged or repeated dermal contact may cause systemic adverse effect. Repeated
contact can cause sensitisation and allergic dermatitis.

If inhaled : Prolonged or repeated inhalation may cause systemic adverse effects.

On ingestion : Repeated swallowing may cause systemic adverse effects.

Toxicokinetics, metabolism : Dangerous amounts can be absorbed through the skin.

and distribution

Other Health Hazard : This product contains (a) powder(s) hazardous by inhalation. This is not relevant to the
Information current physical form of the product, which is not in a respirable form.
Product may emit formaldehyde vapour at temperatures above 180ºC in the presence of
air. Formaldehyde vapour is a suspected carcinogen, toxic byinhalation and irritating to
eyes and the respiratory system. Exposure limits should be strictly respected.

1
Based on product test data.
2
Based on test data from similar products.

12. ECOLOGICAL INFORMATION

12.1 Ecotoxicity effects

No adverse effects on aquatic organisms are predicted.

12.2 Persistence and degradability

Solid material, insoluble in water. No adverse effects are predicted.

12.3 Bioaccumulation

No bioaccumulation potential.

12.4 Release to waters / Mobility in soil

Fate and effects in waste water treatment plants:

No adverse effects on bacteria are predicted.

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 SAFETY DATA SHEET
According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

13. DISPOSAL CONSIDERATIONS

Product and packaging : Dispose of in accordance with local regulations. According to the European Waste
disposal Catalogue, Waste Codes are not product specific, but application specific. Waste codes
should be assigned by the user, preferably in discussion with the waste disposal
authorities.

14. TRANSPORT INFORMATION

Road / Rail (ADR/RID)

Not subject to ADR/RID.

Sea transport (IMDG)

Not subject to IMDG code.

Air transport (IATA)

Not subject to IATA regulations.

15. REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Status

EINECS : All ingredients listed, exempt or notified (ELINCS).

TSCA : All chemical substances in this material are included on or exempted from listing on the
TSCA Inventory of Chemical Substances.

AICS : All ingredients listed, exempt or notified.

IECSC : All ingredients listed or exempt.

ENCS/ISHL : All ingredients listed, exempt or notified.

KECL : All ingredients listed, exempt or notified.

PICCS : All ingredients listed, exempt or notified.

DSL : All ingredients listed or exempt.

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 SAFETY DATA SHEET
According to article 31 and Annex II of the EU REACH Regulation

Version: 4.0
Revision Date: 13.01.2014
Superseded date: 21.12.2011
DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-GRAY

16. OTHER INFORMATION

This product safety data sheet was prepared in compliance with article 31 and Annex II of the EU REACH Regulation as well as
its relevant amendements, on the approximation of laws, regulations and administrative provisions relative to the classification,
packaging and labelling of dangerous substances and preparations.

It is the responsibility of persons in receipt of this Product Safety Data Sheet to ensure that the information contained herein is
properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the
recipient subsequently produces a formulation containing the Dow Corning product, it is the recipient's sole responsibility to
ensure the transfer of all relevant information from the Dow Corning Product Safety Data Sheet to their own Product Safety
Data Sheet in compliance with article 31 and Annex II of the EU REACH Regulation.

All information and instructions provided in this Safety Data Sheet (SDS) are based on the current state of scientific and
technical knowledge at the date indicated on the present SDS. Dow Corning shall not be held responsible for any defect in the
product covered by this SDS , should the existence of such defect not be detectable considering the current state of scientific
and technical knowledge.

As stated above, this Safety Data Sheet has been prepared in compliance with applicable European law. If you purchase this
material outside Europe, where compliance laws may differ, you should receive from your local Dow Corning supplier a SDS
applicable to the country in which the product is sold and intended to be used. Please note that the appearance and content of the
SDS may vary - even for the same product - between different countries, reflecting the different compliance requirements.
Should you have any question, please refer to your local Dow Corning supplier.

Source of information: Internal data and publically available information

R11 Highly flammable., R23/24/25 Toxic by inhalation, in contact with skin and if swallowed., R39/23/24/25 Toxic: danger of
very serious irreversible effects through inhalation, in contact with skin and if swallowed., R43 May cause sensitization by skin
contact., R66 Repeated exposure may cause skin dryness or cracking.

H225 Highly flammable liquid and vapour., H301 Toxic if swallowed., H311 Toxic in contact with skin., H317 May cause an
allergic skin reaction., H331 Toxic if inhaled.

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