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Taller Ciencia M

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1.

Estimate the number of oxygen molecules that can fit in the CC “portal el Prado”
(Barranquilla).
Answer 1.
nat∗pm
ρ=
vcell∗Nav
ρ=density
pm= molecular weight
Nav= Avogadro number = 6.022∗10 23 atosmos /mol

molecular weight of oxygen= 15.999 g/mol


Surface area of the Portal del Prado shopping center in cubic meters = 11.252,40
Surface area of the Portal del Prado shopping center in cubic centimeters= 11252400
Estimation of cubic centimeters= 8.4 g /cm3
( 6.022∗10¿¿ 23 atomos /mol)
8.4 g O/cm3 =3.1617∗10 23 atomos /cm3 ¿
15.999 g O/mol

3.1617∗1023 atomos
3
∗11252400 cm3
cm
3
=3.5576∗1030 atomos/m3
(1 m)

2. Calculate the volume occupied by a piece of pure copper with a mass of 7.4 kg and a
density of 8.96 g/cm3.
Answer 2.

m
ρ=
v
ρ
v=
m
m= 7.4 kg

1kg 1000 g
7.4 x
ρ=8.96 g /cm˄ 3
7400 g
v= =825.89 cm˄ 3
8.96 g /cm˄ 3

3. According to the following table, calculate the grade average for the classroom.

Student Grade
Maria Perez 3.5
Juan Acosta 4.2
Helen Martinez 2.9
Carlos Peña 3.8
Pedro Caña 4.5
Carmen Villalobos 1.7
Total 20.6

Answer 3. The class average is 3.43.


20.6
m= =3.43
6

4. Calculate the molecular weight of the following compounds.


a.[Ni(CO)4]
NI= 58.71 * 1 g/mol = 58.71 g/mol
C 4= 12.011 *4 g/mol = 48.044 g/mol

O 4 = 15.999 * 4 g/mol = 63.996 g/mol

58.71 g/mol + 48.044 g/mol + 63.996 g/mol = 170 g/mol.


The molecular weight of [Ni(CO)4] is 170 g/mol.

b.K2Zn3[Fe(CN)6]2
K 2 = 39.102 * 2 g/mol = 78.204 g/mol

Zn3 = 65.37 * 3 g/mol = 196.11 g/mol

Fe2 = 55.942 * 2 g/mol = 111.884 g/mol

C 12 = 12.011 * 12 g/mol = 144.132 g/mol

N 12 = 14.006 * 12 g/mol = 168.072 g/mol

78.204 g/mol +196.11 g/mol +111.884 g/mol +144.132 g/mol +168.072 g/mol = 698.402
g/mol
The molecular weight of K2Zn3[Fe(CN)6]2 is 698.402 g/mol.

c. [Ag(NH3)2]Cl
Ag = 107.87 * 1 g/mol = 107.87 g/mol
N 2= 14.006 * 2 g/mol = 28.012 g/mol

H 6 = 1.0079 * 6 g/mol = 6.0474 g/mol

Cl= 35.453 * 1 g7mol = 35.453 g/mol


107.87 g/mol + 28.012 g/mol + 6.0474 g/mol + 35.453 g/mol = 177.3824 g/mol
The molecular weight of [Ag(NH3)2]Cl is 177.3824 g/mol.

d. [Pt(NH3)2Cl(NO2)]
Pt = 195.09 * 1 g/mol = 195.09 g/mol
N 2= 14.006 * 2 g/mol = 28.012 g/mol

H 6 = 1.0079 * 6 g/mol = 6.0474 g/mol

Cl = 35.453 * 1 g/mol = 35.453 g/mol


N = 14.006 * 1 g/mol = 14.006 g/mol
O2 = 15.999 * 2 g/mol = 31.998 g/mol

195.09 g/mol + 28.012 g/mol + 6.0474 g/mol + 35.453 g/mol + 14.006 g/mol + 31.998
g/mol = 310.6064 g/mol
The molecular weight of [Pt(NH3)2Cl(NO2)] is 310.6064 g/mol.
5. According to the following expression:

A=B exp −C
DE ( )
Where:
A = 1; B = 2.5; D = 10.85; E = 0,57
Calculate the value of C.

−c
1=2.5 e ( 10.85∗0.57 )
−c
2.5 e( 10.85∗0.57 )=1
−c
2.5 e (
10.85∗0.57 ) 1
=
2.5 2.5

−c
e ( 10.85∗0.57 )=0.4
−c
( 10.85∗0.57 )
=ln(0.4)

c=−6.1845 ln ⁡(0.4)
c=5.66
6. Describe the fundamental state electronic configuration |of the following
compounds:
a. Oxygen = 1 S 2 2 S 2 2 P4

b. Nitrogen = 1 S 2 2 S 2 2 P3

c. Sulfur = 1 S 2 2 S 2 2 P6 3 S 2 3 P4

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