Safety Data Sheet: 1. Identification

SAFETY DATA SHEET
Issue Date 01-Oct-2019 Revision Date 07-Oct-2019 Version 7.6 Page 1 / 15
1. IDENTIFICATION
Product identifier
Product Name Molybdate 3 Reagent for Silica
Other means of identification

Product Code(s) 199532
Safety data sheet number M00187
UN/ID no UN3264
Recommended use of the chemical and restrictions on use

Recommended Use Laboratory reagent. Silica determination.
Uses advised against Consumer use.
Restrictions on use For Laboratory Use Only.
Details of the supplier of the safety data sheet
Manufacturer Address
Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050
Emergency telephone number

+1(303) 623-5716 - 24 Hour Service
2. HAZARDS IDENTIFICATION
Classification
Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Corrosive to metals Category 1

Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
Specific target organ toxicity (repeated exposure) Category 1
Hazards not otherwise classified (HNOC)

Not applicable
Label elements
Signal word
Danger
EN / AGHS Page 1 / 15
Product Code(s) 199532 Product Name Molybdate 3 Reagent for Silica
Issue Date 01-Oct-2019 Revision Date 07-Oct-2019
Version 7.6 Page 2 / 15
Hazard statements
H290 - May be corrosive to metals
H314 - Causes severe skin burns and eye damage
H372 - Causes damage to organs through prolonged or repeated exposure
Precautionary statements
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P363 - Wash contaminated clothing before reuse
P405 - Store locked up
P501 - Dispose of contents/ container to an approved waste disposal plant
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P270 - Do not eat, drink or smoke when using this product
P234 - Keep only in original container
P390 - Absorb spillage to prevent material damage
Other Hazards Known

Toxic to aquatic life
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable
Mixture
Chemical Family Mixture.

Chemical nature Aqueous solution of inorganic acids and salts.
Percent ranges are used where confidential product information is applicable.
Chemical name CAS No. Percent HMRIC #

Range
Sulfuric acid 7664-93-9 7 - 13% -
Sulfuric acid, sodium salt (1:1) 7681-38-1 7 - 13% -
Molybdate (MoO42-), dihydrogen, (T-4)- 7782-91-4 5 - 10% -
4. FIRST AID MEASURES
Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical
attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. If breathing is difficult, (trained personnel
should) give oxygen. Delayed pulmonary edema may occur. Get immediate medical
advice/attention.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get immediate medical advice/attention.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Get immediate medical advice/attention.
Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Get immediate medical
advice/attention.
Self-protection of the first aider Avoid contact with skin, eyes or clothing. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination. Avoid direct contact with skin. Use barrier to give mouth-to-mouth
resuscitation.
Most important symptoms and effects, both acute and delayed
Symptoms Burning sensation.
Indication of any immediate medical attention and special treatment needed
Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the The product causes burns of eyes, skin and mucous membranes. Thermal decomposition
chemical can lead to release of irritating gases and vapors.
Hazardous combustion products Sulfur oxides. Sodium oxides.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.
6. ACCIDENTAL RELEASE MEASURES

U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous
substances may respond to a spill according to federal regulations (OSHA 29 CFR

1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance.
Outside of the US, only persons properly qualified according to state or local regulations
should respond to a spill involving chemicals.
Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required. Attention! Corrosive material. Evacuate personnel to
safe areas. Keep people away from and upwind of spill/leak.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Reference to other sections See section 8 for more information. See section 13 for more information.
7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. Handle product only in closed system or provide appropriate exhaust
ventilation. Do not eat, drink or smoke when using this product. Take off contaminated
clothing and wash before reuse.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture. Store locked up. Keep out of the reach of children. Store away from other
materials.
Flammability class Class IIIB
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical name ACGIH TLV OSHA PEL NIOSH

Sulfuric acid TWA: 0.2 mg/m3 thoracic TWA: 1 mg/m3 IDLH: 15 mg/m3
CAS#: 7664-93-9 particulate matter (vacated) TWA: 1 mg/m3 TWA: 1 mg/m3
Molybdate (MoO42-), dihydrogen, TWA: 0.5 mg/m3 Mo TWA: 5 mg/m3 IDLH: 1000 mg/m3 Mo
(T-4)- respirable particulate matter (vacated) TWA: 5 mg/m3

CAS#: 7782-91-4
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hand Protection Wear suitable gloves. Impervious gloves.
Eye/face protection Face protection shield.
Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
General Hygiene Considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this
product. Regular cleaning of equipment, work area and clothing is recommended. Avoid
contact with skin, eyes or clothing. Remove and wash contaminated clothing and gloves,
including the inside, before re-use. Contaminated work clothing should not be allowed out
of the workplace. Wash hands before breaks and immediately after handling the product.
Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not
allow into any sewer, on the ground or into any body of water.
Thermal hazards None under normal processing.
9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical state Liquid

Appearance clear Color Colorless to light yellow
Odor Odorless Odor threshold Not applicable
Property Values Remarks • Method
Molecular weight Not applicable
pH <2
Melting point/freezing point ~ -13 °C / 8.6 °F
Boiling point / boiling range ~ 100 °C / 212 °F
Evaporation rate 1.17 (water = 1)
Vapor pressure 22.127 mm Hg / 2.95 kPa at 25 °C / 77 °F
Vapor density (air = 1) 0.62 (Air = 1)
Specific gravity (water = 1 / air = 1) 1.2
Partition Coefficient (n-octanol/water) Not applicable
Soil Organic Carbon-Water Partition Not applicable

Coefficient
Autoignition temperature No data available
Decomposition temperature No data available

Dynamic viscosity No data available
Kinematic viscosity No data available
Solubility(ies)
Water solubility
Water solubility classification Water solubility Water Solubility Temperature

Soluble > 1000 mg/L 25 °C / 77 °F
Solubility in other solvents
Chemical Name Solubility classification Solubility Solubility Temperature

Acid Soluble > 1000 mg/L 25 °C / 77 °F
Other Information
Metal Corrosivity
Classified as corrosive to metal according to GHS criteria
Steel Corrosion Rate 151.6 mm/yr / 5.97 in/yr
Aluminum Corrosion Rate No data available /
Volatile Organic Compounds (VOC) Content
Chemical name CAS No. Volatile organic CAA (Clean Air Act)
compounds (VOC) content
Sulfuric acid 7664-93-9 No data available -
Sulfuric acid, sodium salt (1:1) 7681-38-1 No data available -
Molybdate (MoO42-), dihydrogen, 7782-91-4 Not applicable -
(T-4)-
Explosive properties
Upper explosion limit No data available

Lower explosion limit No data available
Flammable properties
Flash point > 100 °C / 212 °F

Method CC (closed cup)
Flammability Limit in Air

Upper flammability limit No data available
Lower flammability limit No data available
Oxidizing properties Not classified according to GHS criteria.
Bulk density No data available
10. STABILITY AND REACTIVITY

Reactivity
Not applicable.
Chemical stability
Stable under normal conditions.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions

None under normal processing.
Hazardous polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Exposure to air or moisture over prolonged periods.
Incompatible materials
Oxidizing agent. Acids. Bases.
Hazardous Decomposition Products

Thermal decomposition can lead to release of irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure
Product Information
Inhalation Corrosive by inhalation. Inhalation of corrosive fumes/gases may cause coughing, choking,
headache, dizziness, and weakness for several hours. Pulmonary edema may occur with
tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and
increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs.
Pulmonary edema can be fatal.
Eye contact Causes burns. Corrosive to the eyes and may cause severe damage including blindness.
Causes serious eye damage. May cause irreversible damage to eyes.
Skin contact May cause irritation.
Ingestion Causes burns. Ingestion causes burns of the upper digestive and respiratory tracts. May
cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark
blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the
mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung
damage if swallowed. May be fatal if swallowed and enters airways.
Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing.
Acute toxicity
Based on available data, the classification criteria are not met
Product Acute Toxicity Data

Test data reported below.
Oral Exposure Route
Endpoint type Reported dose Exposure time Toxicological effects Key literature references
Rat 7099 mg/kg None reported None reported and sources for data
LD50 Outside testing
Inhalation (Gas) Exposure Route
Ingredient Acute Toxicity Data

No data available.
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Sulfuric acid, sodium Rat 2490 mg/kg None None reported IUCLID (The International
salt (1:1) LD50 reported Uniform Chemical Information
(7 - 13%) Database)
CAS#: 7681-38-1
Molybdate (MoO42-), Rat 2689 mg/kg None None reported Vendor SDS
dihydrogen, (T-4)- LD50 reported
(5 - 10%)
CAS#: 7782-91-4
Unknown Acute Toxicity
8.33% of the mixture consists of ingredient(s) of unknown toxicity.
Acute Toxicity Estimations (ATE)
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) No information available

ATEmix (dermal) 30,012.00 mg/kg
ATEmix (inhalation-dust/mist) No information available
ATEmix (inhalation-vapor) No information available
ATEmix (inhalation-gas) No information available
Skin corrosion/irritation
Causes severe burns.
Product Skin Corrosion/Irritation Data

Test data reported below.
Test method Species Reported dose Exposure Results Key literature references and
United States Rabbit 0.5 mL time Not corrosive sources for data
Department of 4 hours to skin Internal Data
Transportation (DOT) Outside testing
Skin Corrosion Test
Ingredient Skin Corrosion/Irritation Data

No data available.
Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sulfuric acid Existing human Human None None Corrosive to skin HSDB (Hazardous
(7 - 13%) experience reported reported Substances Data
CAS#: 7664-93-9 Bank)
Sulfuric acid, sodium Standard Draize Rabbit 500 mg 4 hours Not corrosive or ECHA (The European
salt (1:1) Test irritating to skin Chemicals Agency)
(7 - 13%)
CAS#: 7681-38-1
Serious eye damage/irritation
Classification based on data available for ingredients. Causes burns. Risk of serious damage to eyes.
Product Serious Eye Damage/Eye Irritation Data

No data available.
Ingredient Eye Damage/Eye Irritation Data

No data available.
Chemical name Test method Species Reported Exposure Results Key literature
sources for data
Sulfuric acid Existing human Human None None Corrosive to eyes HSDB (Hazardous
(7 - 13%) experience reported reported Substances Data
CAS#: 7664-93-9 Bank)
Sulfuric acid, sodium Standard Draize Rabbit 100 mg None Eye irritant ECHA (The European
salt (1:1) Test reported Chemicals Agency)
(7 - 13%)
CAS#: 7681-38-1
Respiratory or skin sensitization
Based on available data, the classification criteria are not met.
Product Sensitization Data

No data available.
Ingredient Sensitization Data

No data available.
STOT - single exposure

Product Specific Target Organ Toxicity Single Exposure Data

No data available.
Ingredient Specific Target Organ Toxicity Single Exposure Data

No data available.
Sulfuric acid Human 0.144 mg/L 5 minutes Lungs, Thorax, or RTECS (Registry of Toxic
(7 - 13%) TDLo Respiration Effects of Chemical
CAS#: 7664-93-9 Dyspnea Substances)
STOT - repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Product Specific Target Organ Toxicity Repeat Dose Data

No data available.
Ingredient Specific Target Organ Toxicity Repeat Exposure Data

No data available.
Sulfuric acid Human 0.003 mg/L 168 days Musculoskeletal RTECS (Registry of Toxic
(7 - 13%) TCLo Changes in teeth and Effects of Chemical
CAS#: 7664-93-9 supporting structures Substances)
Carcinogenicity
Product Carcinogenicity Data

No data available.
Ingredient Carcinogenicity Data

No data available.
Chemical name CAS No. ACGIH IARC NTP OSHA
Sulfuric acid 7664-93-9 A2 Group 1 Known X

Sulfuric acid, sodium salt 7681-38-1 - - - -
(1:1)
Molybdate (MoO42-), 7782-91-4 A3 - - -
dihydrogen, (T-4)-
Legend
ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen

A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program) Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of X - Present
Labor)
Germ cell mutagenicity

Product Germ Cell Mutagenicity invitro Data

No data available.
Ingredient Germ Cell Mutagenicity invitro Data

No data available.
Chemical name Test Cell Strain Reported Exposure Results Key literature
sources for data
Sulfuric acid Cytogenetic Hamster ovary 4 mmol/L None Positive test result for No information
(7 - 13%) analysis reported mutagenicity available
CAS#: 7664-93-9
Product Germ Cell Mutagenicity invivo Data
No data available.
Ingredient Germ Cell Mutagenicity invivo Data

No data available.
Reproductive toxicity
Product Reproductive Toxicity Data

No data available.
Ingredient Reproductive Toxicity Data

No data available.
Sulfuric acid Rabbit 0.02 mg/L 7 hours Specific Developmental RTECS (Registry of Toxic
(7 - 13%) TCLo Abnormalities Effects of Chemical
CAS#: 7664-93-9 Musculoskeletal system Substances)
Aspiration hazard
12. ECOLOGICAL INFORMATION
Ecotoxicity .
Unknown aquatic toxicity 8.33% of the mixture consists of components(s) of unknown hazards to the aquatic
environment.
Product Ecological Data
Aquatic Acute Toxicity

No data available.
Aquatic Chronic Toxicity

No data available.
Ingredient Ecological Data
Aquatic Acute Toxicity

No data available.
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Sulfuric acid, sodium 48 Hours Daphnia magna EC50 190 mg/L IUCLID (The International
salt (1:1) Uniform Chemical Information
(7 - 13%) Database)
CAS#: 7681-38-1
Aquatic Chronic Toxicity
No data available.
Persistence and degradability
Product Biodegradability Data

No data available.
Bioaccumulation
Product Bioaccumulation Data

No data available.
Partition Coefficient (n-octanol/water) Not applicable
Mobility
Soil Organic Carbon-Water Partition Coefficient Not applicable
Other adverse effects

No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.
Contaminated packaging Do not reuse empty containers.
US EPA Waste Number D002
Special instructions for disposal Dilute to 3 to 5 times the volume with cold water. Adjust to a pH between 6 and 9 with an
alkali, such as soda ash or sodium bicarbonate. If permitted by regulation. Open cold water
tap completely, slowly pour the reacted material to the drain. Allow cold water to run for 5
minutes to completely flush the system. Check with local municipal and state authorities
and waste contractors for pertinent local information regarding the proper disposal of
chemicals.
14. TRANSPORT INFORMATION

DOT
UN/ID no UN3264
Proper shipping name Corrosive Liquid, Acidic, Inorganic, N.O.S.
DOT Technical Name Sulfuric acid
Hazard Class 8
Packing Group III
Reportable Quantity (RQ) Sulfuric acid: RQ kg= 3588.42
Description UN3264, Corrosive liquid, acidic, inorganic, n.o.s. (Sulfuric acid), 8, III, RQ
Emergency Response Guide 154
Number
TDG
UN/ID no UN3264
Proper shipping name Corrosive Liquid, Acidic, Inorganic, N.O.S.
TDG Technical Name Sulfuric acid
Hazard Class 8
Packing Group III
Description UN3264, Corrosive liquid, acidic, inorganic, n.o.s. (Sulfuric acid), 8, III
IATA
UN/ID no UN3264
Proper shipping name Corrosive liquid, acidic, inorganic, n.o.s.
IATA Technical Name Sulfuric acid
Hazard Class 8
Packing Group III
ERG Code 8L
Special precautions for user A3, A803
IMDG
UN/ID no UN3264
Proper shipping name Corrosive liquid, acidic, inorganic, n.o.s.
IMDG Technical Name Sulfuric acid
Hazard Class 8
Packing Group III
EmS-No F-A, S-B
Special precautions for user 223, 274
Marine pollutant No
Additional information
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.
15. REGULATORY INFORMATION

National Inventories
TSCA Complies
DSL/NDSL Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
International Inventories
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
TCSI Complies
AICS Complies
NZIoC Complies
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical name SARA 313 - Threshold Values %

Sulfuric acid (CAS #: 7664-93-9) 1.0
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical name CWA - Reportable CWA - Toxic Pollutants CWA - Priority CWA - Hazardous
Quantities Pollutants Substances
Sulfuric acid 1000 lb - - X
7664-93-9
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

Sulfuric acid 1000 lb 1000 lb RQ 1000 lb final RQ
7664-93-9 RQ 454 kg final RQ
U.S. - DEA (Drug Enforcement Administration) List I & List II
Chemical name U.S. - DEA (Drug Enforcement U.S. - DEA (Drug Enforcement
Administration) - List I or Precursor Administration) - List II or Essential
Chemicals Chemicals
Sulfuric acid Not Listed 50 gallon Export Volume (exports,
(7 - 13%) transshipments and international
CAS#: 7664-93-9 transactions to designated countries)
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical name California Proposition 65

Sulfuric acid (CAS #: 7664-93-9) Carcinogen
WARNING: This product can expose you to chemicals including Sulfuric acid, which is known to the State of California to
cause cancer.
For more information, go to http://www.P65Warnings.ca.gov
IMERC: Not applicable
U.S. State Right-to-Know Regulations
Chemical name New Jersey Massachusetts Pennsylvania

Sulfuric acid X X X
7664-93-9
U.S. EPA Label Information
Chemical name FIFRA FDA

Sulfuric acid 180.0910 21 CFR 184.1095
Sulfuric acid, sodium salt (1:1) 180.0920 -
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

Special Comments
None
Additional information
Global Automotive Declarable Substance List (GADSL)

Not applicable
NFPA and HMIS Classifications
NFPA Health hazards - 3 Flammability - 1 Instability - 0 Physical and chemical

properties -
HMIS Health hazards - 3 Flammability - 1 Physical hazards - 0 Personal protection -
-* X
Key or legend to abbreviations and acronyms used in the safety data sheet
NIOSH IDLH Immediately Dangerous to Life or Health

ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)
NDF no data
Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value
X Listed Vacated These values have no official status. The only

binding levels of contaminants are those
listed in the final OSHA PEL. These lists are
for reference purposes only. Please note that

some reference state regulations of these
"liberated" exposure limits in their state
regulations.
SKN* Skin designation SKN+ Skin sensitization

RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen
Prepared By Hach Product Compliance Department
Issue Date 01-Oct-2019
Revision Date 07-Oct-2019
Revision Note None
Disclaimer
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO

WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.
Ó2019
HACH COMPANYÓ
End of Safety Data Sheet

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SAFETY DATA SHEET

Issue Date 01-Oct-2019 Revision Date 07-Oct-2019 Version 7.6 Page 1 / 15

Other means of identification

Safety data sheet number M00187

Recommended use of the chemical and restrictions on use

Details of the supplier of the safety data sheet

Emergency telephone number

Corrosive to metals Category 1

Hazards not otherwise classified (HNOC)

Other Hazards Known

Chemical Family Mixture.

Percent ranges are used where confidential product information is applicable.

Chemical name CAS No. Percent HMRIC #

4. FIRST AID MEASURES

Description of first aid measures

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation.

Indication of any immediate medical attention and special treatment needed

Hazardous combustion products Sulfur oxides. Sodium oxides.

6. ACCIDENTAL RELEASE MEASURES

substances may respond to a spill according to federal regulations (OSHA 29 CFR

Personal precautions, protective equipment and emergency procedures

Other Information Refer to protective measures listed in Sections 7 and 8.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities

Flammability class Class IIIB

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical name ACGIH TLV OSHA PEL NIOSH

(T-4)- respirable particulate matter (vacated) TWA: 5 mg/m3

Individual protection measures, such as personal protective equipment

Hand Protection Wear suitable gloves. Impervious gloves.

Eye/face protection Face protection shield.

Thermal hazards None under normal processing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid

Property Values Remarks • Method

Molecular weight Not applicable

Melting point/freezing point ~ -13 °C / 8.6 °F

Boiling point / boiling range ~ 100 °C / 212 °F

Evaporation rate 1.17 (water = 1)

Vapor pressure 22.127 mm Hg / 2.95 kPa at 25 °C / 77 °F

Vapor density (air = 1) 0.62 (Air = 1)

Specific gravity (water = 1 / air = 1) 1.2

Partition Coefficient (n-octanol/water) Not applicable

Soil Organic Carbon-Water Partition Not applicable

Decomposition temperature No data available

Kinematic viscosity No data available

Water solubility classification Water solubility Water Solubility Temperature

Solubility in other solvents

Chemical Name Solubility classification Solubility Solubility Temperature

Volatile Organic Compounds (VOC) Content

Upper explosion limit No data available

Flash point > 100 °C / 212 °F

Flammability Limit in Air

Oxidizing properties Not classified according to GHS criteria.

Bulk density No data available