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SAFETY DATA SHEET

Issue Date 02-Mar-2018 Revision Date 02-Mar-2018 Version 1.1 Page 1 / 14

1. IDENTIFICATION
Product identifier
Product Name Hydrolab. pH 10 Buffer Kit

Other means of identification


Product Code(s) 000534HY

Safety data sheet number M02186

Recommended use of the chemical and restrictions on use


Recommended Use Buffer.
Uses advised against None.
Restrictions on use None.

Details of the supplier of the safety data sheet

Manufacturer Address
Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050

Emergency telephone number


+1(303) 623-5716 - 24 Hour Service +1(515)232-2533 - 8am - 4pm CST

2. HAZARDS IDENTIFICATION
Classification

Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute toxicity - Inhalation (Dusts/Mists) Category 4


Serious eye damage/eye irritation Category 2A

Hazards not otherwise classified (HNOC)


Not applicable

Label elements

Signal word - Warning

Hazard statements

H319 - Causes serious eye irritation

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
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H332 - Harmful if inhaled

Precautionary statements
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P271 - Use only outdoors or in a well-ventilated area
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical advice/attention

Other Hazards Known


May be harmful if swallowed
May be harmful in contact with skin
Causes mild skin irritation

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable

Mixture

Percent ranges are used where confidential product information is applicable.

Chemical name CAS No. Percent HMRIC #


Range
Disodium carbonate 497-19-8 60 - 70% -

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018
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4. FIRST AID MEASURES


Description of first aid measures

General advice Show this safety data sheet to the doctor in attendance.

Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical
attention immediately. If symptoms persist, call a physician.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention if irritation develops and
persists.

Skin contact Wash skin with soap and water.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Get medical attention.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination.

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Coughing and/ or wheezing. Difficulty in breathing.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.

Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.

Specific hazards arising from the No information available.


chemical

Hazardous combustion products Sodium monoxide. Carbon monoxide, Carbon dioxide.

Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear.

6. ACCIDENTAL RELEASE MEASURES


U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous
substances may respond to a spill according to federal regulations (OSHA 29 CFR
1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance.
Outside of the US, only persons properly qualified according to state or local regulations
should respond to a spill involving chemicals.

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Ensure adequate ventilation. Avoid generation of dust. Do not breathe dust.

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
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Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Environmental precautions See Section 12 for additional ecological information.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

Reference to other sections See section 8 for more information. See section 13 for more information.

7. HANDLING AND STORAGE


Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Avoid breathing
dust/fume/gas/mist/vapors/spray. Avoid generation of dust. Ensure adequate ventilation.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children.

Flammability class Not applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies

Appropriate engineering controls


Engineering Controls Showers
Eyewash stations
Ventilation systems.

Individual protection measures, such as personal protective equipment


Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

Hand Protection Wear suitable gloves.

Eye/face protection If splashes are likely to occur, wear safety glasses with side-shields.

Skin and body protection Wear suitable protective clothing.

General Hygiene Considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Avoid breathing
dust/fume/gas/mist/vapors/spray.

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
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Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not
allow into any sewer, on the ground or into any body of water.

Thermal hazards None under normal processing.

9. PHYSICAL AND CHEMICAL PROPERTIES


Information on basic physical and chemical properties

Physical state Solid


Appearance powder Color white
Odor None Odor threshold No data available

Property Values Remar


ks •Met
hod

Molecular weight No data available

pH 10.0

Melting point/freezing point No data available

Boiling point / boiling range No data available

Evaporation rate Not applicable

Vapor pressure Not applicable

Vapor density (air = 1) Not applicable

Specific gravity (water = 1 / air = 1) No data available

Partition Coefficient (n-octanol/water) log Kow ~ 0

Soil Organic Carbon-Water Partition log Koc ~ 0


Coefficient
Autoignition temperature No data available

Decomposition temperature No data available

Dynamic viscosity Not applicable

Kinematic viscosity Not applicable

Solubility(ies)

Water solubility

Water solubility classification Water solubility Water Solubility Temperature


Soluble > 1000 mg/L 25 °C / 77 °F

Solubility in other solvents

Chemical Name Solubility classification Solubility Solubility Temperature


None reported No information available No data available No information available

Other Information

Metal Corrosivity

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
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Steel Corrosion Rate Not applicable


Aluminum Corrosion Rate Not applicable

Volatile Organic Compounds (VOC) Content


Not applicable

Chemical name CAS No. Volatile organic CAA (Clean Air Act)
compounds (VOC) content
Disodium carbonate 497-19-8 No data available -

Explosive properties

Upper explosion limit No data available


Lower explosion limit No data available

Flammable properties

Flash point Not applicable

Flammability Limit in Air


Upper flammability limit: No data available
Lower flammability limit: No data available

Oxidizing properties No data available.

Bulk density No data available

Particle Size No information available

Particle Size Distribution No information available

10. STABILITY AND REACTIVITY


Reactivity
Not applicable.

Chemical stability
Stability Stable under normal conditions.

Explosion data
Sensitivity to Mechanical Impact None
Sensitivity to Static Discharge None.

Possibility of Hazardous Reactions


Possibility of Hazardous Reactions None under normal processing.

Hazardous polymerization
None under normal processing.

Conditions to avoid
Conditions to avoid Excessive heat.

Incompatible materials
Incompatible materials Strong oxidizing agents, strong acids, and strong bases.

Hazardous Decomposition Products


Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
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11. TOXICOLOGICAL INFORMATION


Information on Likely Routes of Exposure
Product Information

Inhalation May cause irritation of respiratory tract. Harmful by inhalation.

Eye contact Causes serious eye irritation. May cause redness, itching, and pain.

Skin contact May cause irritation. Prolonged contact may cause redness and irritation.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Symptoms May cause redness and tearing of the eyes. Coughing and/ or wheezing.

Aggravated Medical Conditions Skin disorders. Eye disorders.


Toxicologically synergistic None known.
products
Toxicokinetics, metabolism and No information available.
distribution

Product Acute Toxicity Data


Oral Exposure Route No data available
Dermal Exposure Route No data available
Inhalation (Dust/Mist) Exposure Route No data available
Inhalation (Vapor) Exposure Route No data available
Inhalation (Gas) Exposure Route No data available

Unknown Acute Toxicity


0% of the mixture consists of ingredient(s) of unknown toxicity.

Acute Toxicity Estimations (ATE)

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral) 4,141.00 mg/kg


ATEmix (dermal) 3,683.00 mg/kg
ATEmix (inhalation-dust/mist) 1.92 mg/L
ATEmix (inhalation-vapor) No information available
ATEmix (inhalation-gas) No information available

Ingredient Acute Toxicity Data


Oral Exposure Route If available, see data below
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Disodium carbonate Rat 4090 mg/kg None None reported IUCLID (The International
(60 - 70%) LD50 reported Uniform Chemical Information
CAS#: 497-19-8 Database)
Dermal Exposure Route If available, see data below
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Disodium carbonate Mouse 2210 mg/kg None None reported No information available
(60 - 70%) LD50 reported
CAS#: 497-19-8
Inhalation (Dust/Mist) Exposure Route If available, see data below
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Disodium carbonate Rat 1.15 mg/L 4 hours None reported IUCLID (The International
(60 - 70%) LC50 Uniform Chemical Information

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018
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CAS#: 497-19-8 Database)


Inhalation (Vapor) Exposure Route If available, see data below
Inhalation (Gas) Exposure Route If available, see data below

Product Specific Target Organ Toxicity Single Exposure Data


Oral Exposure Route No data available
Dermal Exposure Route No data available
Inhalation (Dust/Mist) Exposure Route No data available
Inhalation (Vapor) Exposure Route No data available
Inhalation (Gas) Exposure Route No data available

Ingredient Specific Target Organ Toxicity Single Exposure Data


Oral Exposure Route If available, see data below
Dermal Exposure Route If available, see data below
Inhalation (Dust/Mist) Exposure Route If available, see data below
Inhalation (Vapor) Exposure Route If available, see data below
Inhalation (Gas) Exposure Route If available, see data below

Aspiration toxicity
If available, see data below
Kinematic viscosity Not applicable

Product Skin Corrosion/Irritation Data


No data available.

Ingredient Skin Corrosion/Irritation Data


If available, see data below
Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Disodium carbonate Standard Draize Rabbit 500 mg 24 hours Mild skin irritant ECHA (The European
(60 - 70%) Test Chemicals Agency)
CAS#: 497-19-8 HSDB (Hazardous
Substances Data
Bank)

Product Serious Eye Damage/Eye Irritation Data


No data available.

Ingredient Eye Damage/Eye Irritation Data


If available, see data below
Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Disodium carbonate Standard Draize Rabbit 100 mg 24 hours Eye irritant HSDB (Hazardous
(60 - 70%) Test Substances Data
CAS#: 497-19-8 Bank)

Sensitization Information

Product Sensitization Data


Skin Sensitization Exposure Route No data available.
Respiratory Sensitization Exposure Route No data available.

Ingredient Sensitization Data


Skin Sensitization Exposure Route If available, see data below.
Respiratory Sensitization Exposure Route If available, see data below.

Chronic Toxicity Information

Product Specific Target Organ Toxicity Repeat Dose Data

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018
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Oral Exposure Route No data available.


Dermal Exposure Route No data available.
Inhalation (Dust/Mist) Exposure Route No data available.
Inhalation (Vapor) Exposure Route No data available.
Inhalation (Gas) Exposure Route No data available.

Ingredient Specific Target Organ Toxicity Repeat Exposure Data


Oral Exposure Route If available, see data below
Dermal Exposure Route If available, see data below
Inhalation (Dust/Mist) Exposure Route If available, see data below
Inhalation (Vapor) Exposure Route If available, see data below
Inhalation (Gas) Exposure Route If available, see data below

Product Carcinogenicity Data


Oral Exposure Route No data available
Dermal Exposure Route No data available
Inhalation (Dust/Mist) Exposure Route No data available
Inhalation (Vapor) Exposure Route No data available
Inhalation (Gas) Exposure Route No data available

Ingredient Carcinogenicity Data


Chemical name CAS No. ACGIH IARC NTP OSHA
Disodium carbonate 497-19-8 - - - -

Legend

ACGIH (American Conference of Governmental Industrial Hygienists) Does not apply


IARC (International Agency for Research on Cancer) Does not apply
NTP (National Toxicology Program) Does not apply
OSHA (Occupational Safety and Health Administration of the US Department of Does not apply
Labor)

Oral Exposure Route If available, see data below


Dermal Exposure Route If available, see data below
Inhalation (Dust/Mist) Exposure Route If available, see data below
Inhalation (Vapor) Exposure Route If available, see data below
Inhalation (Gas) Exposure Route If available, see data below

Product Germ Cell Mutagenicity invitro Data


No data available.

Ingredient Germ Cell Mutagenicity invitro Data


No data available

Product Germ Cell Mutagenicity invivo Data


Oral Exposure Route No data available
Dermal Exposure Route No data available
Inhalation (Dust/Mist) Exposure Route No data available
Inhalation (Vapor) Exposure Route No data available
Inhalation (Gas) Exposure Route No data available

Ingredient Germ Cell Mutagenicity invivo Data


Oral Exposure Route If available, see data below
Dermal Exposure Route If available, see data below
Inhalation (Dust/Mist) Exposure Route If available, see data below
Inhalation (Vapor) Exposure Route If available, see data below
Inhalation (Gas) Exposure Route If available, see data below

Product Reproductive Toxicity Data


Oral Exposure Route No data available
Dermal Exposure Route No data available

EN / AGHS Page 9 / 14
Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018
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Inhalation (Dust/Mist) Exposure Route No data available


Inhalation (Vapor) Exposure Route No data available
Inhalation (Gas) Exposure Route No data available

Ingredient Reproductive Toxicity Data


Oral Exposure Route If available, see data below
Inhalation (Dust/Mist) Exposure Route If available, see data below
Inhalation (Vapor) Exposure Route If available, see data below
Inhalation (Gas) Exposure Route If available, see data below

12. ECOLOGICAL INFORMATION

Ecotoxicity

Product Ecological Data

Aquatic toxicity

Fish No data available


Crustacea No data available
Algae No data available

Ingredient Ecological Data

Aquatic toxicity

Fish If available, see ingredient data below


Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Disodium carbonate 96 hours Lepomis macrochirus LC50 300 mg/L IUCLID (The International
(60 - 70%) Uniform Chemical Information
CAS#: 497-19-8 Database)
Crustacea If available, see ingredient data below
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Disodium carbonate 48 Hours Daphnia magna EC50 265 mg/L IUCLID (The International
(60 - 70%) Uniform Chemical Information
CAS#: 497-19-8 Database)
Algae No data available

Other Information

Persistence and degradability

Product Biodegradability Data


No data available.

Ingredient Biodegradability Data

Chemical name Test method Biodegradation Exposure Results


time
Disodium carbonate None reported None reported None Readily
(60 - 70%) reported biodegradable
CAS#: 497-19-8
Sodium bicarbonate None reported None reported None Readily
(40 - 50%) reported biodegradable
CAS#: 144-55-8

Bioaccumulation

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
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Product Bioaccumulation Data


No data available.

Partition Coefficient (n-octanol/water) log Kow ~ 0

Ingredient Bioaccumulation Data

Chemical name Test method Exposure Species Bioconcentrat Results


time ion factor
(BCF)
Disodium carbonate None reported None None reported None reported Does not
(60 - 70%) reported have the
CAS#: 497-19-8 potential to
bioaccumula
te

Mobility

Soil Organic Carbon-Water Partition Coefficient log Koc ~ 0

Water solubility

Water solubility classification Water solubility Water Solubility Temperature

Soluble > 1000 mg/L 25 °C / 77 °F

Other adverse effects


No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.

Contaminated packaging Do not reuse empty containers.

Special instructions for disposal Dilute material with excess water making a weaker than 5% solution. Adjust to a pH
between 6 and 9 with an acid, such as sulfuric or citric. Open cold water tap completely,
slowly pour the reacted material to the drain. Allow cold water to run for 5 minutes to
completely flush the system.

14. TRANSPORT INFORMATION


U.S. DOT Not regulated

TDG Not regulated

IATA Not regulated

IMDG Not regulated

Additional information
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.

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Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
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If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.

15. REGULATORY INFORMATION


National Inventories
TSCA Complies
DSL/NDSL Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

International Inventories
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
TCSI Complies
AICS Complies
NZIoC Complies

EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories


Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)


This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material

EN / AGHS Page 12 / 14
Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018
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US State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals

U.S. State Right-to-Know Regulations

U.S. EPA Label Information

Chemical name FIFRA FDA


Disodium carbonate 180.1234 21 CFR 184.1742

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION


Special Comments
None

Additional information

Global Automotive Declarable Substance List (GADSL)


Not applicable

NFPA and HMIS Classifications

NFPA Health hazards - 2 Flammability - 0 Instability - 0 Physical and Chemical


Properties -
HMIS Health hazards - 1 Flammability - 0 Physical Hazards - 0 Personal protection - X
- See section 8 for more
information

Key or legend to abbreviations and acronyms used in the safety data sheet

NIOSH IDLH Immediately Dangerous to Life or Health


ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)
NDF no data

Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)

MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value

X Listed Vacated These values have no official status. The only


binding levels of contaminants are those
listed in the final OSHA PEL. These lists are
for reference purposes only. Please note that
some reference state regulations of these
"liberated" exposure limits in their state
regulations.

SKN* Skin designation SKN+ Skin sensitization


RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen

EN / AGHS Page 13 / 14
Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018
Version 1.1 Page 14 / 14

Prepared By Hach Product Compliance Department

Issue Date 02-Mar-2018

Revision Date 02-Mar-2018

Revision Note None

Disclaimer

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO


WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.

HACH COMPANYÓ2018

End of Safety Data Sheet

EN / AGHS Page 14 / 14

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