000534hy Aghs en

SAFETY DATA SHEET
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018 Version 1.1 Page 1 / 14
1. IDENTIFICATION
Product identifier
Product Name Hydrolab. pH 10 Buffer Kit
Other means of identification

Product Code(s) 000534HY
Safety data sheet number M02186
Recommended use of the chemical and restrictions on use

Recommended Use Buffer.
Uses advised against None.
Restrictions on use None.
Details of the supplier of the safety data sheet
Manufacturer Address
Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050
Emergency telephone number

+1(303) 623-5716 - 24 Hour Service +1(515)232-2533 - 8am - 4pm CST
2. HAZARDS IDENTIFICATION
Classification
Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Inhalation (Dusts/Mists) Category 4

Serious eye damage/eye irritation Category 2A
Hazards not otherwise classified (HNOC)

Not applicable
Label elements
Signal word - Warning
Hazard statements
H319 - Causes serious eye irritation
EN / AGHS Page 1 / 14
Product Code(s) 000534HY Product Name Hydrolab. pH 10 Buffer Kit
Issue Date 02-Mar-2018 Revision Date 02-Mar-2018
Version 1.1 Page 2 / 14
H332 - Harmful if inhaled
Precautionary statements
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P271 - Use only outdoors or in a well-ventilated area
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical advice/attention
Other Hazards Known

May be harmful if swallowed
May be harmful in contact with skin
Causes mild skin irritation
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Not applicable
Mixture
Percent ranges are used where confidential product information is applicable.
Chemical name CAS No. Percent HMRIC #

Range
Disodium carbonate 497-19-8 60 - 70% -
4. FIRST AID MEASURES

Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance.
Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical
attention immediately. If symptoms persist, call a physician.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention if irritation develops and
persists.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Get medical attention.
Self-protection of the first aider Avoid contact with skin, eyes or clothing. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination.
Most important symptoms and effects, both acute and delayed
Symptoms Burning sensation. Coughing and/ or wheezing. Difficulty in breathing.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the No information available.

chemical
Hazardous combustion products Sodium monoxide. Carbon monoxide, Carbon dioxide.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear.
6. ACCIDENTAL RELEASE MEASURES

U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous
substances may respond to a spill according to federal regulations (OSHA 29 CFR
1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance.
Outside of the US, only persons properly qualified according to state or local regulations
should respond to a spill involving chemicals.
Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Ensure adequate ventilation. Avoid generation of dust. Do not breathe dust.
Other Information Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental precautions See Section 12 for additional ecological information.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Reference to other sections See section 8 for more information. See section 13 for more information.
7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Avoid breathing
dust/fume/gas/mist/vapors/spray. Avoid generation of dust. Ensure adequate ventilation.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children.
Flammability class Not applicable
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies
Appropriate engineering controls

Engineering Controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hand Protection Wear suitable gloves.
Eye/face protection If splashes are likely to occur, wear safety glasses with side-shields.
Skin and body protection Wear suitable protective clothing.
General Hygiene Considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Avoid breathing
dust/fume/gas/mist/vapors/spray.
Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not
allow into any sewer, on the ground or into any body of water.
Thermal hazards None under normal processing.
9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical state Solid

Appearance powder Color white
Odor None Odor threshold No data available
Property Values Remar

ks •Met
hod
Molecular weight No data available
pH 10.0
Melting point/freezing point No data available
Boiling point / boiling range No data available
Evaporation rate Not applicable
Vapor pressure Not applicable
Vapor density (air = 1) Not applicable
Specific gravity (water = 1 / air = 1) No data available
Partition Coefficient (n-octanol/water) log Kow ~ 0
Soil Organic Carbon-Water Partition log Koc ~ 0

Coefficient
Autoignition temperature No data available
Decomposition temperature No data available
Dynamic viscosity Not applicable
Kinematic viscosity Not applicable
Solubility(ies)
Water solubility
Water solubility classification Water solubility Water Solubility Temperature

Soluble > 1000 mg/L 25 °C / 77 °F
Solubility in other solvents
Chemical Name Solubility classification Solubility Solubility Temperature

None reported No information available No data available No information available
Other Information
Metal Corrosivity
Steel Corrosion Rate Not applicable

Aluminum Corrosion Rate Not applicable
Volatile Organic Compounds (VOC) Content

Not applicable
Chemical name CAS No. Volatile organic CAA (Clean Air Act)
compounds (VOC) content
Disodium carbonate 497-19-8 No data available -
Explosive properties
Upper explosion limit No data available

Lower explosion limit No data available
Flammable properties
Flash point Not applicable
Flammability Limit in Air

Upper flammability limit: No data available
Lower flammability limit: No data available
Oxidizing properties No data available.
Bulk density No data available
Particle Size No information available
Particle Size Distribution No information available
10. STABILITY AND REACTIVITY

Reactivity
Not applicable.
Chemical stability
Stability Stable under normal conditions.
Explosion data
Sensitivity to Mechanical Impact None
Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions

Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization
None under normal processing.
Conditions to avoid
Conditions to avoid Excessive heat.
Incompatible materials
Incompatible materials Strong oxidizing agents, strong acids, and strong bases.
Hazardous Decomposition Products

Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.
11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure
Product Information
Inhalation May cause irritation of respiratory tract. Harmful by inhalation.
Eye contact Causes serious eye irritation. May cause redness, itching, and pain.
Skin contact May cause irritation. Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Symptoms May cause redness and tearing of the eyes. Coughing and/ or wheezing.
Aggravated Medical Conditions Skin disorders. Eye disorders.

Toxicologically synergistic None known.
products
Toxicokinetics, metabolism and No information available.
distribution
Product Acute Toxicity Data

Oral Exposure Route No data available
Dermal Exposure Route No data available
Inhalation (Dust/Mist) Exposure Route No data available
Inhalation (Vapor) Exposure Route No data available
Inhalation (Gas) Exposure Route No data available
Unknown Acute Toxicity

0% of the mixture consists of ingredient(s) of unknown toxicity.
Acute Toxicity Estimations (ATE)
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 4,141.00 mg/kg

ATEmix (dermal) 3,683.00 mg/kg
ATEmix (inhalation-dust/mist) 1.92 mg/L
ATEmix (inhalation-vapor) No information available
ATEmix (inhalation-gas) No information available
Ingredient Acute Toxicity Data

Oral Exposure Route If available, see data below
Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Disodium carbonate Rat 4090 mg/kg None None reported IUCLID (The International
(60 - 70%) LD50 reported Uniform Chemical Information
CAS#: 497-19-8 Database)
Dermal Exposure Route If available, see data below
Disodium carbonate Mouse 2210 mg/kg None None reported No information available
(60 - 70%) LD50 reported
CAS#: 497-19-8
Inhalation (Dust/Mist) Exposure Route If available, see data below
Disodium carbonate Rat 1.15 mg/L 4 hours None reported IUCLID (The International
(60 - 70%) LC50 Uniform Chemical Information

Inhalation (Vapor) Exposure Route If available, see data below
Inhalation (Gas) Exposure Route If available, see data below
Product Specific Target Organ Toxicity Single Exposure Data

Ingredient Specific Target Organ Toxicity Single Exposure Data

Aspiration toxicity
If available, see data below
Kinematic viscosity Not applicable
Product Skin Corrosion/Irritation Data

No data available.
Ingredient Skin Corrosion/Irritation Data

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Disodium carbonate Standard Draize Rabbit 500 mg 24 hours Mild skin irritant ECHA (The European
(60 - 70%) Test Chemicals Agency)
CAS#: 497-19-8 HSDB (Hazardous
Substances Data
Bank)
Product Serious Eye Damage/Eye Irritation Data

No data available.
Ingredient Eye Damage/Eye Irritation Data

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Disodium carbonate Standard Draize Rabbit 100 mg 24 hours Eye irritant HSDB (Hazardous
(60 - 70%) Test Substances Data
CAS#: 497-19-8 Bank)
Sensitization Information
Product Sensitization Data

Skin Sensitization Exposure Route No data available.
Respiratory Sensitization Exposure Route No data available.
Ingredient Sensitization Data

Skin Sensitization Exposure Route If available, see data below.
Respiratory Sensitization Exposure Route If available, see data below.
Chronic Toxicity Information
Product Specific Target Organ Toxicity Repeat Dose Data
Oral Exposure Route No data available.

Dermal Exposure Route No data available.
Inhalation (Dust/Mist) Exposure Route No data available.
Inhalation (Vapor) Exposure Route No data available.
Inhalation (Gas) Exposure Route No data available.
Ingredient Specific Target Organ Toxicity Repeat Exposure Data

Product Carcinogenicity Data

Ingredient Carcinogenicity Data

Chemical name CAS No. ACGIH IARC NTP OSHA
Disodium carbonate 497-19-8 - - - -
Legend
ACGIH (American Conference of Governmental Industrial Hygienists) Does not apply

IARC (International Agency for Research on Cancer) Does not apply
NTP (National Toxicology Program) Does not apply
OSHA (Occupational Safety and Health Administration of the US Department of Does not apply
Labor)

Product Germ Cell Mutagenicity invitro Data

No data available.
Ingredient Germ Cell Mutagenicity invitro Data

No data available
Product Germ Cell Mutagenicity invivo Data

Ingredient Germ Cell Mutagenicity invivo Data

Product Reproductive Toxicity Data


Ingredient Reproductive Toxicity Data

12. ECOLOGICAL INFORMATION
Ecotoxicity
Product Ecological Data
Aquatic toxicity
Fish No data available

Crustacea No data available
Algae No data available
Ingredient Ecological Data
Aquatic toxicity
Fish If available, see ingredient data below

Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Disodium carbonate 96 hours Lepomis macrochirus LC50 300 mg/L IUCLID (The International
(60 - 70%) Uniform Chemical Information
Crustacea If available, see ingredient data below
Chemical name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Disodium carbonate 48 Hours Daphnia magna EC50 265 mg/L IUCLID (The International
(60 - 70%) Uniform Chemical Information
Algae No data available
Other Information
Persistence and degradability
Product Biodegradability Data

No data available.
Ingredient Biodegradability Data
Chemical name Test method Biodegradation Exposure Results

time
Disodium carbonate None reported None reported None Readily
(60 - 70%) reported biodegradable
CAS#: 497-19-8
Sodium bicarbonate None reported None reported None Readily
(40 - 50%) reported biodegradable
CAS#: 144-55-8
Bioaccumulation
Product Bioaccumulation Data

No data available.
Partition Coefficient (n-octanol/water) log Kow ~ 0
Ingredient Bioaccumulation Data
Chemical name Test method Exposure Species Bioconcentrat Results

time ion factor
(BCF)
Disodium carbonate None reported None None reported None reported Does not
(60 - 70%) reported have the
CAS#: 497-19-8 potential to
bioaccumula
te
Mobility
Soil Organic Carbon-Water Partition Coefficient log Koc ~ 0
Water solubility
Water solubility classification Water solubility Water Solubility Temperature
Soluble > 1000 mg/L 25 °C / 77 °F
Other adverse effects

No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.
Contaminated packaging Do not reuse empty containers.
Special instructions for disposal Dilute material with excess water making a weaker than 5% solution. Adjust to a pH
between 6 and 9 with an acid, such as sulfuric or citric. Open cold water tap completely,
slowly pour the reacted material to the drain. Allow cold water to run for 5 minutes to
completely flush the system.
14. TRANSPORT INFORMATION

U.S. DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG Not regulated
Additional information
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.
15. REGULATORY INFORMATION

National Inventories
TSCA Complies
DSL/NDSL Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
International Inventories
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
TCSI Complies
AICS Complies
NZIoC Complies
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories

Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
U.S. EPA Label Information
Chemical name FIFRA FDA

Disodium carbonate 180.1234 21 CFR 184.1742
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

Special Comments
None
Additional information
Global Automotive Declarable Substance List (GADSL)

Not applicable
NFPA and HMIS Classifications
NFPA Health hazards - 2 Flammability - 0 Instability - 0 Physical and Chemical

Properties -
HMIS Health hazards - 1 Flammability - 0 Physical Hazards - 0 Personal protection - X
- See section 8 for more
information
Key or legend to abbreviations and acronyms used in the safety data sheet
NIOSH IDLH Immediately Dangerous to Life or Health

ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)
NDF no data
Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value
X Listed Vacated These values have no official status. The only

binding levels of contaminants are those
listed in the final OSHA PEL. These lists are
for reference purposes only. Please note that
some reference state regulations of these
"liberated" exposure limits in their state
regulations.
SKN* Skin designation SKN+ Skin sensitization

RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen
Prepared By Hach Product Compliance Department
Issue Date 02-Mar-2018
Revision Date 02-Mar-2018
Revision Note None
Disclaimer
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO

WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.
HACH COMPANYÓ2018
End of Safety Data Sheet

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SAFETY DATA SHEET

Issue Date 02-Mar-2018 Revision Date 02-Mar-2018 Version 1.1 Page 1 / 14

Other means of identification

Safety data sheet number M02186

Recommended use of the chemical and restrictions on use

Details of the supplier of the safety data sheet

Emergency telephone number

Acute toxicity - Inhalation (Dusts/Mists) Category 4

Hazards not otherwise classified (HNOC)

Signal word - Warning

H319 - Causes serious eye irritation

H332 - Harmful if inhaled

Other Hazards Known

Percent ranges are used where confidential product information is applicable.

Chemical name CAS No. Percent HMRIC #

4. FIRST AID MEASURES

Skin contact Wash skin with soap and water.

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Coughing and/ or wheezing. Difficulty in breathing.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

Specific hazards arising from the No information available.

Hazardous combustion products Sodium monoxide. Carbon monoxide, Carbon dioxide.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions See Section 12 for additional ecological information.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities

Flammability class Not applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Appropriate engineering controls

Individual protection measures, such as personal protective equipment

Hand Protection Wear suitable gloves.

Skin and body protection Wear suitable protective clothing.

Thermal hazards None under normal processing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state Solid

Property Values Remar

Molecular weight No data available

Melting point/freezing point No data available

Boiling point / boiling range No data available

Evaporation rate Not applicable

Vapor pressure Not applicable

Vapor density (air = 1) Not applicable

Specific gravity (water = 1 / air = 1) No data available

Partition Coefficient (n-octanol/water) log Kow ~ 0

Soil Organic Carbon-Water Partition log Koc ~ 0

Decomposition temperature No data available

Dynamic viscosity Not applicable

Kinematic viscosity Not applicable

Water solubility classification Water solubility Water Solubility Temperature

Solubility in other solvents

Chemical Name Solubility classification Solubility Solubility Temperature

Steel Corrosion Rate Not applicable