Safety Data Sheet: Section 1: Product and Company Identification
Safety Data Sheet: Section 1: Product and Company Identification
Safety Data Sheet: Section 1: Product and Company Identification
Manufacturer Address
Hach Company
P.O.Box 389 Loveland, CO 80539 USA
(970) 669-3050
Label elements
Hazard statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary statements
P264 - Wash face, hands and any exposed skin thoroughly after handling
P280 - Wear protective gloves/protective clothing/eye protection/face protection
Product Code(s) 2105569 Product Name DPD Free Chlorine Reagent
Issue Date 09-Aug-2016 Revision Date 18-Mar-2017
Version 5 Page 2 / 15
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical advice/attention
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
Other Information
Mixture
General advice IF IN EYES: Flush eyes for at least 15 minutes. May cause skin irritation.
Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. If symptoms
persist, call a physician.
Skin contact For minor skin contact, avoid spreading material on unaffected skin. IF ON SKIN (or hair):
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Wash contaminated clothing before reuse. Remove and isolate contaminated clothing and
shoes. Call a POISON CENTER or doctor if you feel unwell. If skin irritation persists, call a
physician.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Self-protection of the first aider Use personal protective equipment as required. Ensure that medical personnel are aware
of the material(s) involved and take precautions to protect themselves. See section 8 for
more information.
Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient.
Hazardous combustion products Carbon monoxide, Carbon dioxide. Phosphorus oxides. Nitrogen
oxides.
Personal precautions Evacuate personnel to safe areas. Do not touch or walk through spilled material. Ventilate
affected area. Use personal protective equipment as required.
Environmental precautions
Methods for containment Prevent further leakage or spillage if safe to do so. Cover with plastic sheet to prevent
spreading.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal. Clean contaminated
surface thoroughly. Dispose of in accordance with local, state and federal regulations or
laws.
Advice on safe handling Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
Do not breathe dust/fume/gas/mist/vapors/spray.
General Hygiene Considerations Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Wear suitable gloves and eye/face protection. Wash face, hands and any exposed skin
thoroughly after handling. Regular cleaning of equipment, work area and clothing is
recommended. Handle in accordance with good industrial hygiene and safety practice.
Avoid prolonged or repeated contact with skin. Take off all contaminated clothing and wash
it before reuse. Do not eat, drink or smoke when using this product. Keep away from food,
drink and animal feeding stuffs.
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Product Code(s) 2105569 Product Name DPD Free Chlorine Reagent
Issue Date 09-Aug-2016 Revision Date 18-Mar-2017
Version 5 Page 4 / 15
Skin and body protection Wear protective gloves and protective clothing.
pH 6.3 ; 1% Solution
Coefficient
Solubility(ies)
Water solubility
Other Information
Chemical stability
Stable under normal conditions.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
None known.
Explosive properties
Autoignition temperature
No data available
The following values are calculated based on chapter 3.1 of the GHS document
Chemical Name Test method Species Reported Exposure Results Key literature
Product Code(s) 2105569 Product Name DPD Free Chlorine Reagent
Issue Date 09-Aug-2016 Revision Date 18-Mar-2017
Version 5 Page 8 / 15
Chemical Name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Sodium phosphate Standard Draize Rabbit 500 mg 24 hours Eye irritant RTECS (Registry of
dibasic Test Toxic Effects of
(30 - 40%) Chemical Substances)
CAS#: 7558-79-4
Disodium EDTA Standard Draize Rabbit 50 mg None Mild eye irritant ECHA (The European
(1 - 5%) Test reported Chemicals Agency)
CAS#: 139-33-3
Sensitization Information
Legend
Ingredient Germ Cell Mutagenicity invitro Data If available, see data below
Chemical Name Test Cell Strain Reported Exposure Results Key literature
dose time references and
sources for data
Disodium EDTA Cytogenetic Hamster lung 200 mg/L None Positive test result for RTECS (Registry
(1 - 5%) analysis reported mutagenicity of Toxic Effects of
CAS#: 139-33-3 Chemical
Substances)
Aquatic toxicity
Terrestrial toxicity
Product Code(s) 2105569 Product Name DPD Free Chlorine Reagent
Issue Date 09-Aug-2016 Revision Date 18-Mar-2017
Version 5 Page 11 / 15
Aquatic toxicity
Terrestrial toxicity
Other Information
Bioaccumulation
None known.
Additional information
Ingredient Information
Mobility
Mobility in soil: Moderate to high mobility. If available, see ingredient data below.
Ingredient Information
Additional information
Water solubility
Product Information
Ingredient Information
Chemical Name Water solubility Water solubility Water solubility Water solubility
classification temperature C temperature F
Sodium phosphate dibasic Completely soluble 118000 mg/L 20 C 68 F
(30 - 40%)
CAS#: 7558-79-4
Salt of N,N-Diethyl-p-Phenylenediamine Completely soluble > 10000 mg/L 25 C 77 F
(1 - 5%)
CAS#: -
Disodium EDTA Completely soluble 100000 mg/L 20 C 68 F
(1 - 5%)
CAS#: 139-33-3
Contaminated packaging Dispose of in accordance with federal, state and local regulations. Improper disposal or
reuse of this container may be dangerous and illegal.
Additional information
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
Country Regulations
Brazil
Federal Decree No. 2.657, July 3, 1998
Standard ABNT NBR 14725-3
Ordinance No. 229, May 24, 2011 - Changes to Regulatory Standard No. 26
Standard ABNT NBR 14725-4
Resolution no. 420/2004 - ANTT
Resolution no. 5.232 / 2016 - ANTT
NR 15 Ministry of Labor and Employment
Ordinance no. 1274 / 2003
Federal Decree 3.665 / 2000
Product Code(s) 2105569 Product Name DPD Free Chlorine Reagent
Issue Date 09-Aug-2016 Revision Date 18-Mar-2017
Version 5 Page 14 / 15
Argentina
SRT 3359/2015
Resolution 801/2015
Law of Health and Safety and Work (Law 19,587)
Decree 351/79
Regulatory Law 19587
Columbia
Law 253, 1996: Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal.
Resolution 2400/1979: Ministry of Labour and Social Security, ACGIH Exposure Limits.
Decision 602, Andean Regulation for the Control of chemical substances used in the illegal manufacture of narcotic drugs and
psychotropic substances.
Law 29/1992: Montreal Protocol on Substances that Deplete the Ozone Layer and its Amendments.
Law 55/1993: Recommendation No. 177 on the International Work Conference on Safety in the Use of Chemical Products at Work.
Law 30/1990: Vienna Convention for the Protection of the Ozone Layer.
Law 55/1993: Convention No. 170 on the General Conference of the ILO.
Uruguay
Law 16.157: Approval of the Montreal Protocol on Substances that Deplete the Ozone Layer.
Law 17.283: Regarding environmental protection and management of hazardous wastes.
Presidential Decree 346/11: Implementation of GHS for all manufactured or distributed products.
Presidential Decree 519/984: Regulates the activities relating to the use of radioactive materials and ionizing radiation throughout
the country.
Ecuador
Law No. 37 - Environmental Management Act
NTE INEN 2266:2013 - Requirements for Transport, Storage and Handling of Hazardous Materials
Unified Text of Secondary Legislation of the Environment Ministry: Book VI
Key or legend to abbreviations and acronyms used in the safety data sheet
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
This material safety data sheet has been prepared according to Brazilian legislation and ABNT NBR 14725:2009
Disclaimer
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.
HACH COMPANY2017