Safety Data Sheet: 1. Identification of The Substance/Preparation and of The Company/Undertaking

SAFETY DATA SHEET
Issue Date 20-Jun-2016 Revision Date 18-Aug-2016 Version 2 Page 1 / 15
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier
Product Name Citric Acid
Safety data sheet number M00072
Other means of identification

Product Code(s)
1454999
Component of Kits or Sets 1455400; 1455400RGT; 2350500; 2350500RGT; 2350700; 2350700RGT; 2462300
Manufacturer Address
Hach Company
P.O.Box 389 Loveland, CO 80539 USA
(970) 669-3050
Emergency Telephone
(303) 623-5716 - 24 Hour Service (515)232-2533 - 8am - 4pm CST
Product Information
Chemical Name Not applicable
Formula C6H8O7
CAS No 77-92-9
Alternate CAS Number 5949-29-1 - Monohydrate
NIOSH (RTECS) Number GE7350000
2. HAZARDS IDENTIFICATION
GHS - Classification
Acute toxicity - Oral Category 5
Acute toxicity - Dermal Category 5
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Label elements
Signal word - Warning
Hazard statements
Product Code(s) 1454999 Product Name Citric Acid
Issue Date 20-Jun-2016 Revision Date 18-Aug-2016
Version 2 Page 2 / 15
H303 - May be harmful if swallowed

H313 - May be harmful in contact with skin
H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary statements
P264 - Wash face, hands and any exposed skin thoroughly after handling
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical advice/attention
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P312 - Call a POISON CENTER or doctor if you feel unwell
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Chemical Name CAS No EC No Percent Range

Citric acid 77-92-9 201-069-1 100
4. FIRST AID MEASURES

Description of first aid measures
General advice In case of accident or unwellness, seek medical advice immediately (show directions for
use or safety data sheet if possible).
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If symptoms persist, call a physician.
Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower. If symptoms persist, call a physician.
Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. If symptoms
persist, call a physician.
Ingestion IF SWALLOWED: Rinse Mouth. If symptoms persist, call a physician.
Self-protection of the first aider Use personal protective equipment as required. Ensure that medical personnel are aware
of the material(s) involved and take precautions to protect themselves.
Most important symptoms and effects, both acute and delayed
Symptoms See Section 11: TOXICOLOGICAL INFORMATION.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Fire-fighting Measures
Flammable properties
Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHS criteria.
Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media

Caution: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical

The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating and toxic
gases and vapors. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefighters

Wear self-contained breathing apparatus and protective suit.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions Evacuate personnel to safe areas. Do not touch or walk through spilled material. Ventilate
affected area. Use personal protective equipment as required.
Environmental precautions Avoid release to the environment. See Section 12 for additional ecological information.
Methods for containment Prevent further leakage or spillage if safe to do so. Cover with plastic sheet to prevent
spreading.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal. Clean contaminated
surface thoroughly. Dispose of in accordance with local, state and federal regulations or
laws.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
Do not breathe dust/fume/gas/mist/vapors/spray.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep in properly labeled containers. Keep containers tightly closed in a dry, cool and
well-ventilated place. Keep out of the reach of children.
Flammability class Not applicable
Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies
Chemical Name India Thailand Russia Israel South Africa

Citric acid NDF NDF MAC: 1 mg/m3 NDF NDF
(100)
CAS#: 77-92-9
Legend See section 16 for terms and abbreviations
Engineering Controls Showers. Eyewash stations. Ventilation systems.
Personal Protective Equipment

Eye/face protection Wear tight sealing safety goggles and/or face protection shield.
Skin and body protection Wear protective gloves and protective clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Take
off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling. Regular cleaning of equipment, work
area and clothing is recommended.
Environmental exposure controls Avoid creating dust.
9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical state Solid
Gas Under Pressure Not classified according to GHS criteria
Appearance crystalline Color white
Odor Odorless Odor threshold No data available
Property Values Remar

ks •Met
hod
Molecular weight 192.12 g/mole
pH 2 ; 1% Solution
Melting point/freezing point 153 °C / 307 °F
Boiling point / boiling range No data available
Evaporation rate Not applicable
Vapor pressure Not applicable
Vapor density (air = 1) Not applicable
Specific gravity (water = 1 / air = 1) 1.67
Partition Coefficient (n-octanol/water) log Kow = -1.64
Soil Organic Carbon-Water Partition log Koc = -1.16

Coefficient
Autoignition temperature 540 °C / 1004 °F
Decomposition temperature 175 °C
Dynamic viscosity Not applicable
Kinematic viscosity Not applicable
Solubility(ies)
Water solubility
Water solubility classification Water solubility Water Solubility Temperature

Completely soluble 750000 mg/L 25 °C / 77 °F
Solubility in other solvents
Chemical Name Solubility classification Solubility Solubility Temperature

Acids Soluble > 1000 mg/L 25 °C / 77 °F
Ethyl alcohol Soluble > 1000 mg/L 25 °C / 77 °F
Methanol Soluble > 1000 mg/L 25 °C / 77 °F
Benzene Insoluble < 0.1 mg/L 25 °C / 77 °F
Chloroform Insoluble < 0.1 mg/L 25 °C / 77 °F
Other Information
Metal Corrosivity Not classified as corrosive to metal according to GHS criteria
Steel Corrosion Rate Not applicable
Aluminum Corrosion Rate Not applicable
Volatile Organic Compounds (VOC) Content Not applicable.
Bulk density No data available
Explosive properties Not classified according to GHS criteria.
Explosion data No data available
Upper explosion limit 64%
Lower explosion limit 18%
Flammable properties Can burn in fire, releasing toxic vapors. Material is not classified
as flammable according to GHS criteria.
Flammability Limit in Air
Upper flammability limit: No data available
Lower flammability limit: No data available
Flash point Not applicable
Oxidizing properties Not classified according to GHS criteria.
Reactivity propeties Not classified as self-reactive, pyrophoric, self-heating or emitting

flammable gases in contact with water according to GHS criteria.
10. STABILITY AND REACTIVITY

Reactivity propeties Not classified as self-reactive, pyrophoric, self-heating or emitting flammable gases in
contact with water according to GHS criteria.
Stability Stable under normal conditions.
Special dangers of the product None reported.
Conditions to avoid Exposure to air or moisture over prolonged periods.

Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents.
Hazardous Decomposition Products Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Possibility of Hazardous Reactions None under normal processing.
Explosive properties
Not classified according to GHS criteria.
Upper explosion limit 64%
Lower explosion limit 18%
Autoignition temperature
540 °C / 1004 °F
Sensitivity to Static Discharge

None reported.
Sensitivity to Mechanical Impact

None reported.
11. TOXICOLOGICAL INFORMATION
Information on Likely Routes of Exposure
Product Information Causes skin irritation. Causes eye irritation. May be harmful if
swallowed. MAY BE HARMFUL IF ABSORBED THROUGH
SKIN. May be harmful in contact with skin. Causes serious eye
irritation.
Inhalation No known effect based on information supplied.
Eye contact Contact with eyes may cause irritation. Severely irritating to
eyes.
Skin contact Causes skin irritation. May be harmful in contact with skin.
Ingestion May be harmful if swallowed. Ingestion may cause irritation to
mucous membranes.
Aggravated Medical Conditions Skin disorders. Eye disorders.
Toxicologically synergistic products None known.
Toxicokinetics, metabolism and distribution This Product is by Weight 100% an Individual Pure Chemical
Substance.
Product Acute Toxicity Data This Product is by Weight 100% an Individual Pure Chemical
Substance
Oral Exposure Route If available, see ingredient data below
Dermal Exposure Route If available, see ingredient data below
Inhalation (Dust/Mist) Exposure Route If available, see ingredient data below
Inhalation (Vapor) Exposure Route If available, see ingredient data below
Inhalation (Gas) Exposure Route If available, see ingredient data below
Acute Toxicity Estimations (ATE) Not applicable
Ingredient Acute Toxicity Data

Oral Exposure Route

Chemical Name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Citric acid Rat 3000 mg/kg None None reported IUCLID (The International
(100) LD50 reported Uniform Chemical Information
CAS#: 77-92-9 Database)
Dermal Exposure Route

Citric acid Rat > 2000 mg/kg None None reported IUCLID (The International
(100) LD50 reported Uniform Chemical Information
Inhalation (Dust/Mist) Exposure Route Toxicological data for ingredients is not indicative of likely harm.
Citric acid Rat 0.180 mg/L None Lungs, Thorax, or Respiration RTECS (Registry of Toxic
(100) TDLo reported Other changes Effects of Chemical
CAS#: 77-92-9 Liver Substances)
Impaired liver function tests
Biochemical
Enzyme inhibition, induction, or
change in blood or tissue levels
(dehydrogenases)
Inhalation (Vapor) Exposure Route No data available
Inhalation (Gas) Exposure Route No data available
Product Skin Corrosion/Irritation Data

This Product is by Weight 100% an Individual Pure Chemical Substance. If available, see ingredient data below.
Ingredient Skin Corrosion/Irritation Data
Chemical Name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Citric acid Standard Draize Rabbit 500 mg 24 hours Mild skin irritant RTECS (Registry of
(100) Test Toxic Effects of
CAS#: 77-92-9 Chemical Substances)
Product Serious Eye Damage/Eye Irritation Data

Ingredient Eye Damage/Eye Irritation Data
Chemical Name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Citric acid Standard Draize Rabbit 0.750 mg 24 hours Eye irritant RTECS (Registry of
(100) Test Toxic Effects of
CAS#: 77-92-9 Chemical Substances)
Sensitization Information
Product Sensitization Data

Skin Sensitization Exposure Route This Product is by Weight 100% an Individual Pure Chemical
Substance. If available, see ingredient data below.
Respiratory Sensitization Exposure Route This Product is by Weight 100% an Individual Pure Chemical
Substance. If available, see ingredient data below.
Ingredient Sensitization Data
Skin Sensitization Exposure Route No data available.
Respiratory Sensitization Exposure Route No data available.
Chronic Toxicity Information
Product Repeat Dose Toxicity Data
Oral Exposure Route If available, see ingredient data below.
Dermal Exposure Route If available, see ingredient data below.
Inhalation (Dust/Mist) Exposure Route If available, see ingredient data below.
Inhalation (Vapor) Exposure Route If available, see ingredient data below.
Inhalation (Gas) Exposure Route If available, see ingredient data below.
Ingredient Repeat Dose Toxicity Data
Oral Exposure Route Toxicological data for ingredients is not indicative of likely harm.
Citric acid Rat 930 mg/kg 15 days Biochemical RTECS (Registry of Toxic
(100) TDLo Enzyme inhibition, induction, or Effects of Chemical
CAS#: 77-92-9 change in blood or tissue levels Substances)
(dehydrogenases)
Blood
Changes in serum composition
(e.g. TP, bilirubin, cholesterol)
Dermal Exposure Route No data available
Inhalation (Dust/Mist) Exposure Route Toxicological data for ingredients is not indicative of likely harm.
Citric acid Rat 0.180 mg/L None Lungs, Thorax, or Respiration RTECS (Registry of Toxic
(100) TDLo reported Other changes Effects of Chemical
CAS#: 77-92-9 Liver Substances)
Impaired liver function tests
Biochemical
Enzyme inhibition, induction, or
change in blood or tissue levels
(dehydrogenases)
Chemical Name CAS No ACGIH IARC NTP OSHA

Citric acid 77-92-9 - - - -
Legend
ACGIH (American Conference of Governmental Industrial Hygienists) Does not apply

IARC (International Agency for Research on Cancer) Does not apply
NTP (National Toxicology Program) Does not apply
OSHA (Occupational Safety and Health Administration of the US Department of X - Present
Labor)
Product Carcinogenicity Data This Product is by Weight 100% an Individual Pure Chemical
Substance
Ingredient Carcinogenicity Data
Oral Exposure Route No data available
Inhalation (Dust/Mist) Exposure Route No data available
Product Germ Cell Mutagenicity invitro Data

Ingredient Germ Cell Mutagenicity invitro Data No data available
Product Germ Cell Mutagenicity invivo Data

This Product is by Weight 100% an Individual Pure Chemical Substance.
Ingredient Germ Cell Mutagenicity invivo Data

Product Reproductive Toxicity Data

This Product is by Weight 100% an Individual Pure Chemical Substance.
Ingredient Reproductive Toxicity Data
12. ECOLOGICAL INFORMATION
Ecotoxicity Based on the classification principles, not classified as hazardous

to the environment
Product Ecological Data This Product is by Weight 100% an Individual Pure Chemical
Substance
Aquatic toxicity
Fish If available, see ingredient data below
Crustacea If available, see ingredient data below
Algae If available, see ingredient data below
Terrestrial toxicity
Soil If available, see ingredient data below
Vertebrates If available, see ingredient data below
Invertebrates If available, see ingredient data below
Ingredient Ecological Data
Aquatic toxicity
Fish Toxicological data for ingredients is not indicative of likely harm.

Chemical Name Exposure Species Endpoint Reported Key literature references and
time type dose sources for data
Citric acid 96 hours Lepomis macrochirus LC50 1516 mg/L IUCLID (The International
(100) Uniform Chemical Information

Citric acid 48 hours Leuciscus idus Melanotus LC50 440 mg/L IUCLID (The International
Crustacea Toxicological data for ingredients is not indicative of likely harm.

Citric acid 72 hours Daphina magna EC50 120 mg/L IUCLID (The International
Algae No data available
Terrestrial toxicity
Soil No data available
Vertebrates No data available
Invertebrates No data available
Other Information
Persistence and degradability

Readily biodegradable according the GHS criteria.
Product Biodegradability Data

Ingredient Biodegradability Data

Test data reported below
Chemical Name Test method Biodegradation Exposure Results

time
Citric acid None reported None reported None Readily
(100) reported biodegradable
CAS#: 77-92-9
Bioaccumulation
Does not have the potential to bioaccumulate according to GHS criteria.
Product Bioaccumulation Data If available, see ingredient data below.
Ingredient Bioaccumulation Data
Chemical Name Test method Exposure Species Bioconcentrat Results

time ion factor
(BCF)
Citric acid None reported None None reported None reported Does not
(100) reported have the
CAS#: 77-92-9 potential to
bioaccumula
te
Additional information
Product Information
Partition Coefficient (n-octanol/water) log Kow = -1.64
Ingredient Information
Chemical Name Partition Coefficient Method

(n-octanol/water)
Citric acid log Kow = -1.64 No information available
(100)
CAS#: 77-92-9
Mobility
Mobility in soil: High mobility. If available, see ingredient data below.
Product Information
Soil Organic Carbon-Water Partition Coefficient log Koc = -1.16
Chemical Name Soil Organic Carbon-Water Partition Method

Coefficient
Citric acid log Koc = -1.16 No information available
(100)
CAS#: 77-92-9
Water solubility
Product Information
Water solubility classification Water solubility Water Solubility Temperature
Completely soluble 750000 mg/L 25 °C / 77 °F
Chemical Name Water solubility Water solubility Water solubility Water solubility
classification temperature °C temperature °F
Citric acid Completely soluble 750000 mg/L 25 °C 77 °F
(100)
CAS#: 77-92-9
Other adverse effects

No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Do not reuse container.

US EPA Waste Number D002
Waste from residues/unused Disposal should be in accordance with applicable regional, national and local laws and
products regulations.
Contaminated packaging Do not reuse container.
Basel Convention Codes

Chemical Name ANNEX I ANNEX III
Citric acid Y34 (solid or solution, listed under Acidic solutions -
77-92-9 or acids in solid form)
14. TRANSPORT INFORMATION

IMDG
Proper shipping name Not Currently Regulated
IATA
DOT
TDG
ADR
There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods.
If the item is not in a reagent set or kit, the classification given above applies.
If the item is part of a reagent set or kit the classification would change to the following:
UN3316 Chemical Kit, Hazard Class 9, Packing Group II or III.
If the item is not regulated, the Chemical Kit classification does not apply.
15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
TCSI Complies
AICS Complies
NZIoC Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances

IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
Wastes Management Dispose of in accordance with federal, state and local regulations
Basel Convention Codes

Chemical Name CAS No ANNEX I ANNEX III
Citric acid 77-92-9 Y34 (solid or solution, listed -
under Acidic solutions or
acids in solid form)
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
16. OTHER INFORMATION
Key or legend to abbreviations and acronyms used in the safety data sheet
NIOSH IDLH Immediately Dangerous to Life or Health

ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)
NDF no data
Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value
X Listed Vacated These values have no official status. The only

binding levels of contaminants are those
listed in the final OSHA PEL. These lists are
for reference purposes only. Please note that
some reference state regulations of these
"liberated" exposure limits in their state
regulations.
SKN* Skin designation SKN+ Skin sensitization

RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen
Prepared By Hach Product Compliance Department
Issue Date 20-Jun-2016
Revision Date 18-Aug-2016
Revision Note None.

Disclaimer
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO

WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.
HACH COMPANY Ó2015
End of Safety Data Sheet

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SAFETY DATA SHEET

Issue Date 20-Jun-2016 Revision Date 18-Aug-2016 Version 2 Page 1 / 15

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Other means of identification

Signal word - Warning

H303 - May be harmful if swallowed

Chemical Name CAS No EC No Percent Range

4. FIRST AID MEASURES

Ingestion IF SWALLOWED: Rinse Mouth. If symptoms persist, call a physician.

Most important symptoms and effects, both acute and delayed

Symptoms See Section 11: TOXICOLOGICAL INFORMATION.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

Suitable Extinguishing Media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Protective equipment and precautions for firefighters

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities

Flammability class Not applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical Name India Thailand Russia Israel South Africa

Legend See section 16 for terms and abbreviations

Engineering Controls Showers. Eyewash stations. Ventilation systems.

Personal Protective Equipment

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

General Hygiene Considerations

Environmental exposure controls Avoid creating dust.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state Solid

Gas Under Pressure Not classified according to GHS criteria

Appearance crystalline Color white

Odor Odorless Odor threshold No data available

Property Values Remar

Molecular weight 192.12 g/mole

Melting point/freezing point 153 °C / 307 °F

Boiling point / boiling range No data available

Evaporation rate Not applicable

Vapor pressure Not applicable

Vapor density (air = 1) Not applicable

Specific gravity (water = 1 / air = 1) 1.67

Partition Coefficient (n-octanol/water) log Kow = -1.64

Soil Organic Carbon-Water Partition log Koc = -1.16

Decomposition temperature 175 °C

Dynamic viscosity Not applicable

Kinematic viscosity Not applicable

Water solubility classification Water solubility Water Solubility Temperature

Solubility in other solvents

Chemical Name Solubility classification Solubility Solubility Temperature

Metal Corrosivity Not classified as corrosive to metal according to GHS criteria

Steel Corrosion Rate Not applicable

Aluminum Corrosion Rate Not applicable

Volatile Organic Compounds (VOC) Content Not applicable.

Bulk density No data available

Explosive properties Not classified according to GHS criteria.

Explosion data No data available

Upper explosion limit 64%