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The Millennium School: Subject: Chemistry (043) Class: Xii Unit Test

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THE MILLENNIUM SCHOOL

SUBJECT: CHEMISTRY(043)
CLASS: XII
UNIT TEST
Q1. Why formaldehyde cannot give aldol condensation? (1mark)
Q2. What are Chelates? (1mark)
Q3. Write the name of an hexadentate ligand. (1 mark)
Q4. Define Ambident ligand. (1 mark)
Q5. Why Nickel does not form low spin octahedral complexes.
(1 mark)
Q6. Arrange the following compounds in an increasing order of their reactivity in
nucleophilic addition reactions :
ethanal, propanal, propanone, butanone.
(1 mark)
Q7. Give a chemical test to distinguish between Benzoic acid and Phenol. (1 mark)
Q8. Write the structures of the following compounds: (2 marks)
α-Methoxypropionaldehyde
3-Hydroxybutanal
OR
Although phenoxide ion has more number of resonating structures than
carboxylate ion, carboxylic acid is a stronger acid than on phenol. Why?
Q9. Write the names of the following compounds :
(i) [Co(en)3]Cl3
(ii) [Pt(NH3)2Cl2].
(2 marks)
Q10. DEFINE. ( 2 marks)
Peptisation
Coagulation
Q11.Write the reactions involved in the following reactions:
(i) Clemmensen reduction
(ii) Cannizzaro reaction (2 marks)
Q12.Why is Tyndall effect shown by colloidal solutions? (2 marks)
Q13.Give one example each of sol and gel. (2 marks)
Q14. Give two differences between adsorption and absorption. ( 2 marks)
OR
Give two differences between chemisorption and physisorption.
Q15.A. Predict the product of the following reaction: (3 marks)
OR

B . How will you bring about the following conversions in not more than two steps?
(i) Propanone to Propene
(ii) Benzoic acid to Benzaldehyde
(iii) Ethanol to 3-Hydroxybutanal
Q16.Using Valence bond theory explain the geometry and magnetic behaviour by
[Cr(NH3)6]3+
Also write the name of the compound . (At. no. Cr = 24). (3 marks)
Q17.Using IUPAC norms write the formulae for the following: (3 marks)

(a) Tris(ethane-1,2-diamine) chromium (III) chloride


(b) Potassium tetrahydroxozincate(II)
( c) Sodium dicyanidoaurate (I)

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