Safety data sheet

Issue Date 22-Dec-2015 Revision Date 15-Dec-2015 Version 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product Name Formalin LM 30, 44, 51 - NL
Chemical Name CAS No EC No REACH registration number
Formaldehyde 50-00-0 200-001-8 01-2119488953-20-0023

Pure substance/mixture Substance

1.2. Relevant identified uses of the substance or mixture and uses advised against
Industrial Manufacture of substances and Formaldehyde in water solution. Formulation of
preparations (mixtures). Use for application of adhesives and coatings, for impregnation
of textiles, and of formaldehyde based products. Manufacture: of rubber, of fertilizers, of
firelighters, of foams, of leather, of paper, of bonded fibres or fiber mats, of bonded
particulates (abrasive, casting and moulding), of impregnated paper, of woodbased
materials (panels, bricks etc), of resins and of polymers,
Professional Use: of formaldehyde based products, of resins in wood applications, for application of
adhesives and coatings and Laboratory chemicals. Manufacture: of foams.
Consumer Not applicable

Uses advised against Not identified.

1.3. Details of the supplier of the safety data sheet

Manufacturer

Perstorp Specialty Chemicals BV

Schoolstraat 1
2912CP Nieuwerkerk aan den IJssel
Netherlands
Tel. +31 180 323714

E-mail address productinfo@perstorp.com

1.4. Emergency telephone number

Europe (+)1 760 476 3961 (contract no: 334101)

United Kingdom (+)44 8 08 189 0979 (contract no: 334101)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity - Oral Category 3 - (H301)
Acute toxicity - Dermal Category 3 - (H311)
Acute toxicity - Inhalation (Gases) Category 3 - (H331)
Skin corrosion/irritation Category 1 Sub-category B - (H314)
Serious eye damage/eye irritation Category 1 - (H318)
Skin sensitisation Category 1A - (H317)
Germ cell mutagenicity Category 2 - (H341)
Carcinogenicity Category 1B - (H350)
Specific target organ toxicity (single exposure) Category 3 - (H335)

2.2. Label elements

Symbols/Pictograms

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Page 1 / 54 EUGB - BE
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Signal word
Danger

Hazard statements
H331 - Toxic if inhaled
H311 - Toxic in contact with skin
H301 - Toxic if swallowed
H350 - May cause cancer
H314 - Causes severe skin burns and eye damage
H341 - Suspected of causing genetic defects
H317 - May cause an allergic skin reaction
H335 - May cause respiratory irritation

Precautionary Statements
P201 - Obtain special instructions before use
P260 - Do not breathe mist/vapours/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Contains: Formaldehyde 30-52%, Methanol =<1%

2.3. Other hazards

Toxic to aquatic life. Combustible liquid.

SECTION 3: Composition/information on ingredients

3.1 Substances
Chemical Name EC No CAS No REACH registration Weight-% Classification according to
number Regulation (EC) No. 1272/2008
[CLP]
Formaldehyde 200-001-8 50-00-0 01-2119488953-20-0023 30-52 Acute Tox. 2 (H330) Tox. 3 (H301)
Acute Tox. 3 (H311)
Carc. 1B (H350)
Muta. 2 (H341)
Skin Corr. 1B (H314)
Eye Dam. 1 (H318)
Skin Sens. 1A (H317)
STOT SE 3 (H335)

Methanol 200-659-6 67-56-1 01-2119433307-44-0057 =<1 Acute Tox. 3 (H301)

Acute Tox. 3 (H311)
Acute Tox. 3 (H331)
STOT SE 1 (H370)
Flam. Liq. 2 (H225)

Full text of H- and EUH-phrases: see section 16

Additional information
This safety data sheet covers different concentrations of formaldehyde. The figure in the trade name represents the different
concentrations.

SECTION 4: First aid measures

4.1. Description of first aid measures
Formalin LM 30, 44, 51 - NL Revision Date 15-Dec-2015
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General advice First aid personnel should pay attention to their own safety. If unconscious place in
recovery position and seek medical advice. Remove/Take off immediately all
contaminated clothing. Remove breathing equipment only after contaminated clothing
have been completely removed. If breathing is irregular or stopped, administer artificial
respiration. Emergency shower and eye wash facilities must exist on work place.

Inhalation Remove to fresh air. Call a doctor or poison control centre immediately. Oxygen or
artificial respiration if needed. If unconscious place in recovery position and seek medical
advice.

Skin contact Important! Immediately flush skin with water for at least 15 minutes. Use lukewarm water
if possible. Remove contaminated clothing and shoes. Get medical attention
immediately. Cover wound with a sterile dressing.

Eye contact Important! Immediately flush eyes, also under eyelids, with water for at least 15 minutes.
Use lukewarm water if possible. Get medical attention immediately.

Ingestion Rinse mouth then drink plenty of water. Do NOT induce vomiting. Seek immediate
medical attention/advice.

Self-protection of the first aider

Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required.

4.2. Most important symptoms and effects, both acute and delayed
Exposure may cause watery eyes, nausea, coughing, chest tightness, wheezing, skin rashes, allergenic reactions, and burning
sensations in the eyes, nose, and throat. Formaldehyde is corrosive on skin and may cause permanent clouding of the cornea
after only one exposure. Subsequent exposures can produce symptoms more quickly and at lower concentrations. Symptoms
of exposure may include coughing, eye or skin irritation, allergic reactions, vomiting, and diarrhoea. Formaldehyde has been
shown to cause cancer in laboratory animals and may cause cancer in humans. It is toxic if swallowed, inhaled, or absorbed
though skin or mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed
Note: Contains: =<1% Methanol

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Carbon dioxide (CO2). Extinguishing powder. Water spray (fog).

Unsuitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Vapours may form explosive mixtures with air. Thermal decomposition can lead to release of irritating and toxic gases and
vapours. In the event of fire and/or explosion do not breathe fumes.

5.3. Advice for firefighters

Wear self-contained breathing apparatus and protective suit.

Additional information
Cool containers with flooding quantities of water until well after fire is out. Prevent fire extinguishing water from contaminating
surface water or the ground water system.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Keep unprotected persons away. Wear full protective clothing and self contained breathing apparatus. Remove all sources of
ignition. Ensure adequate ventilation, especially in confined areas.

6.2. Environmental precautions

Do not allow into any sewer, on the ground or into any body of water. Local authorities should be advised if significant spillages
cannot be contained. See Section 12 for additional ecological information.

6.3. Methods and material for containment and cleaning up

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Methods for containment

Prevent further leakage or spillage if safe to do so.
Small spill Dilute with water and wipe up or absorb with inert material.
Large spill Contact the rescue service.

Methods for cleaning up

Clean contaminated surface thoroughly. Flush area with flooding quantities of water.

6.4. Reference to other sections

See Section 7,8,13 for more information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Use only with adequate ventilation and in closed systems. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Not to be
used by pregnant workers and workers who have recently given birth or who are breastfeeding.

General Hygiene Considerations

When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.

7.2. Conditions for safe storage, including any incompatibilities

Store in a locked area. Storage at low temperatures (below 20°C) will lead to the formation of a paraformaldehyde as a white
precipitate, and this polymerization reaction is enhanced as the temperature reduces. Storage facilities should be equipped
with ventilation at high level.

Suitable container/equipment material: Stainless steel 1.4301 (V2), High density polyethylene (HDPE), Low density
polyethylene (LDPE), Stainless steel 1.4401, aluminum.

Unsuitable container/equipment material: Paper, Board, Glass.

7.3. Specific end use(s)

For details, see the separate exposure scenario(s).

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure Limits
Keep personal exposure levels below Derived No Effect Level (DNEL) and national exposure limit values (if existing).
Chemical Name European Union United Kingdom
Formaldehyde Not available TWA: 2 ppm
50-00-0 TWA: 2.5 mg/m3
STEL: 2 ppm
STEL: 2.5 mg/m3
Methanol TWA: 200 ppm TWA: 200 ppm
67-56-1 TWA: 260 mg/m3 TWA: 266 mg/m3
Skin STEL: 250 ppm
STEL: 333 mg/m3
Sk*

Derived No Effect Level (DNEL) - worker

Formaldehyde (50-00-0)
Type Exposure route DNEL Remarks
Acute effects, local Inhalation 0.75 mg/m3
Chronic effects, local Inhalation 0.375 mg/m3
Chronic effects, systemic Inhalation 9 mg/m3
Chronic effects, local Dermal 37 µg/cm2
Chronic effects, systemic Dermal 240 mg/kg bw/d

Methanol (67-56-1)
Type Exposure route DNEL Remarks
Acute effects, local Inhalation 260 mg/m3
Acute effects, systemic Inhalation 260 mg/m3
Chronic effects, local Inhalation 260 mg/m3
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Chronic effects, systemic Inhalation 260 mg/m3

Acute effects, systemic Dermal 40 mg/kg bw/d
Chronic effects, systemic Dermal 40 mg/kg bw/d

Derived No Effect Level (DNEL) - Consumer

Formaldehyde (50-00-0)
Type Exposure route DNEL Remarks
Chronic effects, systemic Oral 4.1 mg/kg bw/d
Chronic effects, local Dermal 12 µg/cm2
Chronic effects, systemic Dermal 102 mg/kg bw/d
Chronic effects, local Inhalation 0.1 mg/m3
Chronic effects, systemic Inhalation 3.2 mg/m3

Methanol (67-56-1)
Type Exposure route DNEL Remarks
Acute effects, local Inhalation 50 mg/m3
Acute effects, systemic Inhalation 50 mg/m3
Chronic effects, local Inhalation 50 mg/m3
Chronic effects, systemic Inhalation 50 mg/kg bw/d
Acute effects, systemic Dermal 8 mg/kg bw/d
Chronic effects, systemic Dermal 8 mg/kg bw/d

Formaldehyde (50-00-0)
Environmental compartment Predicted No Effect Concentration Remarks
(PNEC)
Freshwater 0.44 mg/l
Intermittent 4.44 mg/l
Freshwater sediment 2.3 mg/kg dry weight
Marine water 0.44 mg/l
Marine sediment 2.3 mg/kg dry weight
Impact on Sewage Treatment 0.19 mg/l
Soil 0.2 mg/kg dry weight

Methanol (67-56-1)
Environmental compartment Predicted No Effect Concentration Remarks
(PNEC)
Freshwater 20.8 mg/l
Intermittent 1540 mg/l
Freshwater sediment 77 mg/kg dry weight
Marine water 2.08 mg/l
Marine sediment 7.7 mg/kg dry weight
Impact on Sewage Treatment 100 mg/l
Soil 3.18 mg/kg dry weight

8.2. Exposure controls

Appropriate engineering controls
Ensure adequate ventilation, especially in confined areas.

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles, Face protection shield.
Hand Protection Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove
supplier for information on breakthrough time for specific gloves.
Duration of contact Glove material Glove thickness Break through time Remarks
Suitable materials also with Nitrile rubber, NBR 0.4 mm >480 min Gloves must conform to
prolonged, direct contact standard EN 374
(protective index 6,
corresponding > 480 minutes of
permeation time according to EN
374):
Suitable materials also with Butyl rubber 0.7 mm > 480 min Gloves must conform to
prolonged, direct contact standard EN 374
(protective index 6,
corresponding > 480 minutes of
permeation time according to EN
374):
Skin and body protection Body protection must be chosen depending on activity and possible exposure, e.g.
apron, protecting boots, chemical-protection suit (according to EN 14605 in case of
Formalin LM 30, 44, 51 - NL Revision Date 15-Dec-2015
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splashes). Whenever risk of direct contact use full protective suit (e.g. according to EN
14605).

Respiratory protection Suitable respiratory protection for lower concentrations or short-term exposure:
Gas filter for gases/vapours of organic compounds (boiling point >65°C, e. g. Type
ABEK)
Suitable respiratory protection for higher concentrations or long-term exposure:
Self-contained breathing apparatus.

Environmental exposure controls

Further information concerning special risk management measures: see annex of this safety data sheet (exposure scenarios).

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
liquid
colourless
Odour Pungent
Odour threshold 0.2-1 ppm

Property Value 5HPDUNV‡0HWKRG

pH 3 - 4 @ 20°C (68 °F)
Melting point / freezing point Not determined
Boiling point / boiling range 99 °C
Flash point 75-85 °C ASTM D 7094-04
Evaporation rate Not determined
Flammability (solid, gas) Not applicable
Explosive limits
Upper explosive limits 73 Vol-% (100% FA)
Lower explosive limits 7 Vol-% (100% FA)
Vapour pressure 1520 Pa @ 55°C (49% FA)

Vapour density Not applicable

Relative density No information available
Water solubility 550 g/L @ 20 °C
Solubility(ies) No information available
Partition coefficient -1 log POW
Autoignition temperature ca 430 °C
Decomposition temperature Not determined
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties Not explosive.
Oxidising properties Not oxidising.
Density 1.1 g/cm3
Bulk density No information available

9.2. Other information

The physical data apply to 37% concentration.

SECTION 10: Stability and reactivity

10.1. Reactivity
The substance is a strong reducing agent, especially in the presence of alkalis. The substance reacts violently with nitrous
oxides at about 180°C, performic acid, nitromethane, manganese carbonate and hydrogen peroxide. The substance reacts
with strong oxidizers and acids.

10.2. Chemical stability

The product is stable under normal conditions of use and storage. However, it is normal for formaldehyde solutions to form
paraformaldehyde (white precipitate or cloudy solutions) at temperatures below 20°C. Formaldehyde will sIowly oxidize in
contact with air to give formic acid.

10.3. Possibility of hazardous reactions

The substance reacts violently with nitrous oxides at about 180°C, performic acid, nitromethane, manganese carbonate and
hydrogen peroxide. Risk of run-away reactions between formaldehyde and phenol. Reaction with hydrochloric acid may form
bis-chloromethyl ether (carcinogenic).
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10.4. Conditions to avoid

Keep away from heat and sources of ignition.

10.5. Incompatible materials

See above.

10.6. Hazardous decomposition products

Thermal decomposition may release noxious, toxic or corrosive gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Inhalation. Dermal.

Symptoms related to the physical, chemical and toxicological characteristics

See Section 4 for more information.

Numerical measures of toxicity

Acute toxicity
Toxic by inhalation, in contact with skin and if swallowed.

Formaldehyde (50-00-0)
Method Species Exposure route Effective dose Remarks
OECD Test No. 401: Acute Rat Oral 460 LD50 (lethal dose)
Oral Toxicity mg/kg
OECD Test No. 403: Acute Rat Inhalation 1000 LC50 mg/m3
Inhalation Toxicity
Unknown Rat Inhalation 490 LC50 ppm

Methanol (67-56-1)
Method Species Exposure route Effective dose Remarks
Not defined Rat Oral 7000-9000 LD50 (lethal dose)
mg/kg
Not defined Rabbit Dermal 17100 LD50 (lethal dose)
mg/kg
Not defined Rat Inhalation 128.2 LC50 4h mg/l

Skin corrosion/irritation
Causes burns.

Formaldehyde (50-00-0)
Method Species Exposure route Results:
OECD Test No. 404: Acute Dermal Rabbit Dermal Corrosive
Irritation/Corrosion

Methanol (67-56-1)
Method Species Exposure route Results:
Not defined Rabbit Dermal Non-irritant

Serious eye damage/eye irritation

Causes burns. Risk of serious damage to eyes.

Formaldehyde (50-00-0)
Method Species Exposure route Results:
Unknown Rat Eye Corrosive

Methanol (67-56-1)
Method Species Exposure route Results:
Not defined Rabbit Eye Non-irritant
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Respiratory or skin sensitisation

May cause sensitisation by skin contact.

Formaldehyde (50-00-0)
Method Species Exposure route Results:
OECD Test No. 429: Skin Mouse Skin Sensitising
Sensitisation: Local Lymph Node
Assay
Unknown Mouse Inhalation Not sensitising.
Not defined human data Inhalation Not sensitising.

Methanol (67-56-1)
Method Species Exposure route Results:
OECD Test No. 406: Skin Guinea pig Skin Not sensitising.
Sensitisation

Germ cell mutagenicity

May cause heritable genetic damage.

Formaldehyde (50-00-0)
Method Species Results:
OECD Test No. 471: Bacterial Reverse in vitro Positive
Mutation Test
OECD Test No. 476: In vitro Mammalian Cell in vitro Positive
Gene Mutation Test
OECD Test No. 479: Genetic Toxicology: In in vitro Positive
vitro Sister Chromatid Exchange Assay in
Mammalian Cells
OECD Test No. 484: Genetic Toxicology: in vivo Negative
Mouse Spot Test
OECD Test No. 474: Mammalian Erythrocyte in vivo Negative
Micronucleus Test
Other in vivo Positive

Methanol (67-56-1)
Method Species Results:
OECD Test No. 471: Bacterial Reverse in vitro Negative
Mutation Test
OECD Test No. 476: In vitro Mammalian Cell in vitro Negative
Gene Mutation Test
OECD Test No. 474: Mammalian Erythrocyte in vivo Negative
Micronucleus Test

Carcinogenicity
The International Agency for Research on Cancer (IARC) has classified formaldehyde as a Group 1 human carcinogen (June
2004). The classification is based on epidemiological evidence linking nasopharyngeal cancer with long-term exposure to high
concentrations of formaldehyde.

Formaldehyde (50-00-0)
Method Species Exposure route Effective dose Remarks
OECD Test No. 453: Mouse Inhalation 15 NOAEC ppm May
Combined Chronic cause cancer by
Toxicity/Carcinogenicity inhalation
Studies
OECD Test No. 453: Rat Oral 82-109 NOAEL mg/kg bw/d No
Combined Chronic carcinogenic effects
Toxicity/Carcinogenicity have been observed.
Studies
OECD Test No. 451: Rat Oral - No carcinogenic effects
Carcinogenicity Studies have been observed.

Methanol (67-56-1)
Method Species Exposure route Effective dose Remarks
OECD Test No. 453: Mouse Inhalation >1.3 NOAEC mg/l Not
Combined Chronic considered to be
Toxicity/Carcinogenicity carcinogen.
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Studies

Reproductive toxicity
This product does not contain any known or suspected reproductive hazards.

Formaldehyde (50-00-0)
Method Species Exposure route Effective dose Remarks
Effects on fertility Not applicable
Toxicokinetics,
metabolism and
distribution To Formic
acid
OECD Test No. 414: Mouse Oral 185 NOAEL mg/kg bw/d
Pre-natal Development Developmental Toxicity
Toxicity Study
OECD Test No. 414: Rat Inhalation 10 NOAEC ppm
Pre-natal Development Developmental Toxicity
Toxicity Study

Methanol (67-56-1)
Method Species Exposure route Effective dose Remarks
OECD Test No. 416: Rat Inhalation 1.3 NOAEC mg/l P
Two-Generation
Reproduction Toxicity
OECD Test No. 416: Rat Inhalation 0.13 NOAEC mg/l F1
Two-Generation
Reproduction Toxicity
OECD Test No. 416: Rat Inhalation 0.13 NOAEC mg/l F2
Two-Generation
Reproduction Toxicity

STOT - single exposure Irritating to respiratory system.

Formaldehyde (50-00-0)
Method Species Exposure route Effective dose Remarks
Unknown Inhalation - Irritating to respiratory
system

Methanol (67-56-1)
Method Species Exposure route Effective dose Remarks
Unknown human data Oral - Causes damage to the
following organs if
swallowed: Eyes
central nervous system

STOT - repeated exposure

Formaldehyde (50-00-0)
Method Species Exposure route Effective dose Remarks
OECD Test No. 453: Rat Oral 15 NOAEL mg/kg bw/d
Combined Chronic
Toxicity/Carcinogenicity
Studies

Methanol (67-56-1)
Method Species Exposure route Effective dose Remarks
Unknown Monkey Oral 2340 LOAEL mg/kg bw/d
3d
OECD Test No. 412: Rat Inhalation 6.66 NOAEC mg/l
Sub-acute Inhalation Toxicity:
28-Day Study
OECD Test No. 453: Mouse Inhalation 1.3 NOAEC mg/l
Combined Chronic
Toxicity/Carcinogenicity
Studies

Aspiration hazard
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No hazard from product as supplied.

SECTION 12: Ecological information

12.1. Toxicity
Toxic to aquatic life.

Formaldehyde (50-00-0)
Method Species Exposure route Effective dose Exposure time Remarks
Unknown Morone saxatilis Freshwater 6.7 96h LC50 (lethal
concentration) mg/l
OECD Test No. 202: Daphnia pulex Freshwater 5.8 48h EC50 (effective
Daphnia sp. Acute concentration) mg/l
Immobilization Test
OECD Test No. 201: Scenedesmus Freshwater 4.9 72h EC50 (effective
Freshwater Algae and subspicatus concentration) mg/l
Cyanobacteria, Growth
Inhibition Test
OECD Test No. 215: Fish, Oryzias latipes Freshwater >48 28d NOEC mg/l
Juvenile Growth Test (Ricefish)
OECD Test No. 212: Fish, Brachydanio rerio Freshwater 6.9 144h LC50 (lethal
Short-term Toxicity Test concentration) mg/l
on Embryo and Sac-Fry
Stages
OECD Test No. 209: Freshwater 19 3h EC50 (effective
Activated Sludge, concentration) mg/l
Respiration Inhibition Test
(Carbon and Ammonium
Oxidation)

Methanol (67-56-1)
Method Species Exposure route Effective dose Exposure time Remarks
EPA-660/3-75-009 Lepomis Freshwater 15400 96h LC50 (lethal
macrochirus concentration) mg/l
OECD Test No. 202: Daphnia magna Freshwater 18260 96h EC50 (effective
Daphnia sp. Acute concentration) mg/l
Immobilization Test
OECD Test No. 201: Pseudokirchneriell Freshwater 22000 96h EC50 (effective
Freshwater Algae and a subcapitata concentration) mg/l
Cyanobacteria, Growth
Inhibition Test
OECD Test No. 209: Bacteria toxicity Freshwater >1000 3h IC50 mg/l
Activated Sludge,
Respiration Inhibition Test
(Carbon and Ammonium
Oxidation)
OECD Test No. 207: Eisenia fetida >1 48h LC50 (lethal
Earthworm, Acute Toxicity concentration)
Tests

12.2. Persistence and degradability

Readily biodegradable.

Formaldehyde (50-00-0)
Method Value Exposure time Results:
OECD Test No. 301D: Ready 90% 28d Readily biodegradable
Biodegradability: Closed Bottle Test
(TG 301 D)

Methanol (67-56-1)
Method Value Exposure time Results:
Unknown 95% 20d Readily biodegradable
Unknown 97% 20d Readily biodegradable

12.3. Bioaccumulative potential

No bioaccumulation potential.
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Chemical Name Partition coefficient Bioconcentration factor (BCF)

Formaldehyde 0.35
Methanol -0.77

12.4. Mobility in soil

The product is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Koc which
indicates a moderate to high mobility in soil.

Chemical Name Log Koc

Formaldehyde 1.202

12.5. Results of PBT and vPvB assessment

This substance does not meet the criteria for classification as PBT or vPvB.

12.6. Other adverse effects

Emissions to water lowers the pH. This may cause local damage to fish and aquatic organisms in the discharge area.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste from residues/unused products
This material and its container must be disposed of as hazardous waste.

Contaminated packaging
Not applicable.

Waste codes / waste designations according to EWC / AVV

Waste from residues/unused products: 16 03 05*.

Other Information
Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14: Transport information

ADR Road transport

14.1 UN number UN2209
14.2 UN proper shipping name Formaldehyde solution
Proper Shipping Description UN2209, Formaldehyde solution, 8, III, (E)
14.3 Transport hazard class(es) 8
Subsidiary hazard class 8
14.4 Packing Group III
14.5 Environmental hazard Not applicable
14.6 Special precautions for user 533
Tunnel restriction code (E)
Limited quantity (LQ) 5L
ADR Hazard Id (Kemmler 80
Number)

RID Rail transport

14.1 UN number UN2209
14.2 UN proper shipping name Formaldehyde solution
Proper Shipping Description UN2209, Formaldehyde solution, 8, III
14.3 Transport hazard class(es) 8
14.4 Packing Group III
14.5 Environmental hazard Not applicable
14.6 Special precautions for user None

IMDG Sea transport

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14.1 UN number UN2209

14.2 UN proper shipping name Formaldehyde solution
Proper Shipping Description UN2209, Formaldehyde solution, 8, III
14.3 Transport hazard class(es) 8
14.4 Packing Group III
14.5 Marine pollutant Not applicable
14.6 Special precautions for user None
EmS-No F-A, S-B
Limited quantity (LQ) 5L
14.7 Transport in bulk according No information available
to Annex II of MARPOL 73/78 and
the IBC Code

IATA Air transport

14.1 UN number UN2209
14.2 UN proper shipping name Formaldehyde solution
14.3 Transport hazard class(es) 8
14.4 Packing Group III
Proper Shipping Description UN2209, Formaldehyde solution, 8, III
14.5 Environmental hazard Not applicable
14.6 Special precautions for user A803
Limited quantity (LQ) 1L
ERG Code 8i

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
International Regulations
IARC (International Agency for Research on Cancer): Group 1 - Carcinogenic to Humans.

European Union
Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work
Take note of Directive 94/33/EC on the protection of young people at work
This product contains one or more substance(s) subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Named dangerous substances per Seveso Directive (2012/18/EU)

Chemical Name Upper-tier requirements (tons) Lower-tier requirements (tons)
Formaldehyde - 50-00-0 50 5
Methanol - 67-56-1 5000 500
France
Occupational Illnesses (R-463-3, France)

Chemical Name French RG number

Formaldehyde RG 43
50-00-0
Methanol RG 84
67-56-1
Germany
Water hazard class (WGK) Hazardous to water (WGK 2)
TA Luft (German Air Pollution Control Regulation)
Chemical Name Type Class
Formaldehyde - 50-00-0 5.2.5 0.10 kg/h Mass flow (Class I); 20 mg/m3
Mass concentration (Class I)
I

15.2. Chemical safety assessment

A Chemical Safety Assessment has been carried out for this substance.

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3

H330 - Fatal if inhaled
H301 - Toxic if swallowed
H311 - Toxic in contact with skin
Formalin LM 30, 44, 51 - NL Revision Date 15-Dec-2015
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H350 - May cause cancer if swallowed

H341 - Suspected of causing genetic defects if inhaled
H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
H317 - May cause an allergic skin reaction
H335 - May cause respiratory irritation
H226 - Flammable liquid and vapour
H331 - Toxic if inhaled
H302 - Harmful if swallowed
H370 - Causes damage to organs if inhaled
H225 - Highly flammable liquid and vapour
EUH071 - Corrosive to the respiratory tract

Issue Date 22-Dec-2015

Revision Date 15-Dec-2015

Revision Note Not applicable.

This safety data sheet complies with the requirements of: Regulation (EC) No. 1907/2006, COMMISSION REGULATION
(EU) No. 453/2010 of 20 May 2010.

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.
The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet