Safety Data Sheet TGX-2209: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

SDS identifier:
Safety Data Sheet TGX-2209: (Rev. 2.0)

according to Regulation (EC) No. 1907/2006 (REACH)
TGX-2209
Version number: 2.0 Revision: 2017-09-12
Replaces version of: 2014-03-19 (1)
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name TGX-2209 (electrode for Gas Tungsten Arc Welding)
Registration number (REACH) not relevant (mixture)
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Welding and soldering product
The product is intended for professional use
Specific process or activity welding (welding process)
1.3 Details of the supplier of the safety data sheet

Kobelco Welding of Europe B.V.
Eisterweg 8
6422 PN Heerlen
Netherlands

Telephone: +31(0)45-5471111
Telefax: +31(0)45-5471100
e-mail: info@kobelcowelding.nl
e-mail (competent person) info@kobelcowelding.nl
1.4 Emergency telephone number

Emergency information service +31(0)45-5471111
This number is only available during the following office hours: Mon-
Fri 09:00 - 17:00
Poison centre
Country Name Telephone
United Kingdom National Poisons Information Service (NPIS) 0344-8920111

(medical professionals only)
United Kingdom NHS non-emergency: 111 or a doctor;
(general public) emergency: 999
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Category Hazard class and Hazard state-

category ment
3.3 serious eye damage/eye irritation 2 Eye Irrit. 2 H319
3.4S skin sensitisation 1 Skin Sens. 1 H317
3.6 carcinogenicity 2 Carc. 2 H351
3.9 specific target organ toxicity - repeated exposure 1 STOT RE 1 H372
United Kingdom: en Page: 1 / 16

SDS identifier:
TGX-2209
For full text of abbreviations: see SECTION 16.
The most important adverse physicochemical, human health and environmental effects
Delayed or immediate effects can be expected after short or long-term exposure.
2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
- signal word danger
- pictograms
GHS07, GHS08
- hazard statements
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
- precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
- hazardous ingredients for labelling Nickel
2.3 Other hazards

Avoid breathing dust. Avoid contact with eyes. Avoid skin contact.
When this product is used in a welding process, the most significant hazards are electric shock, fumes, gases, radiation, spatter,
slag and heat.
Shock: electric shock can kill.
Fumes: Overexposure to welding fumes may result in symptoms like dizziness, nausea, dryness or irritation of the nose, throat or
eyes. Chronic overexposure to welding fumes may affect pulmonary function.
Gases: gases may cause gas poisoning.
Radiation: arc rays can severely damage eyes or skin.
Spatter, slag and heat: spatter and slag can damage eyes. Spatter, slag, melting material, arc rays and hot welds can cause
burn injuries and start fires.
Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
SECTION 3: Composition/information on ingredients

3.1 Substances
Not relevant (mixture)
3.2 Mixtures
The product does not contain any (other) ingredients which are classified according to present knowledge of the supplier and
contribute to the classification of the substance and hence require reporting in this section.

SDS identifier:
TGX-2209
Name of sub- Identifier Wt% Classification Picto- Notes Specific M-Factors

stance acc. to GHS grams Conc. Limits
Chromium CAS No 13 – 33 IOELV

7440-47-3
EC No
231-157-5
REACH Reg.
No
01-
2119485652
-31-xxxx
Nickel CAS No 3 – 13 Skin Sens. 1 / IARC:
7440-02-0 H317 2B
Carc. 2 / H351
EC No STOT RE 1 / H372
231-111-4 Aquatic Chronic 3 /
H412
REACH Reg.
No
01-
2119438727
-29-xxxx
calcium oxide CAS No ≤ 1 Skin Irrit. 2 / H315

1305-78-8 Eye Dam. 1 / H318
STOT SE 3 / H335
EC No
215-138-9
REACH Reg.
No
01-
2119475325
-36-xxxx
Notes
IARC: IARC group 2B: possibly carcinogenic to humans (International Agency for Research on Cancer)
2B:
IOELV: Substance with a community indicative occupational exposure limit value
Remarks
For full text of H-phrases: see SECTION 16. All the percentages given are percentages by weight unless stated otherwise.
SECTION 4: First aid measures

4.1 Description of first aid measures
General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered.
Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case
of unconsciousness place person in the recovery position. Never give anything by mouth. Disconnect and turn off the power. If
the victim is semi- or unconscious, open the airway. If the victim cannot breath, give artificial respiration. If there is no pulse, mas-
sage the chest and apply artificial respiration.
Electrical shock
Disconnect and turn off the power. If the victim is semi- or unconscious, open the airway. If the victim cannot breath, give artifi-
cial respiration. If there is no pulse, massage the chest and apply artificial respiration.

SDS identifier:
TGX-2209
Following inhalation
Provide fresh air. If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. If experien-
cing respiratory symptoms: Call a doctor.
Following skin contact

Rinse skin with water/shower.
Following eye contact

Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 15
minutes, holding the eyelids apart.
Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting. Call a POISON CENTER or doctor if you feel
unwell.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
For specialist advice physicians should contact the poison centre.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
Alcohol resistant foam, Dry extinguishing powder, Carbon dioxide (CO2), Water spray
5.2 Special hazards arising from the substance or mixture

Hazardous combustion products

During fire hazardous fumes/smoke could be produced.
5.3 Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Do not allow
firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal pre-
cautions from a reasonable distance.
Special protective equipment for firefighters

Self-contained breathing apparatus (EN 133). Standard protective clothing for firefighters.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Remove persons to safety.
For emergency responders

Wear breathing apparatus if exposed to vapours/dust/spray/gases. Use personal protective equipment as required.
6.2 Environmental precautions

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

SDS identifier:
TGX-2209
6.3 Methods and material for containment and cleaning up

Advices on how to contain a spill
Covering of drains. Take up mechanically.
Advices on how to clean up a spill

Take up mechanically.
Other information relating to spills and releases

Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections

Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see sec-
tion 10. Disposal considerations: see section 13.
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Keep away from fire.
Recommendations
- measures to prevent fire as well as aerosol and dust generation
No special measures are necessary.
Advice on general occupational hygiene

Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment be-
fore entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are
normally used for food or drink. Keep away from food, drink and animal feedingstuffs.
7.2 Conditions for safe storage, including any incompatibilities

Managing of associated risks
- explosive atmospheres
Removal of dust deposits.
- flammability hazards
Keep away from fire. Keep away from combustible material.
- incompatible substances or mixtures

Acids, Alkalis, Oxidisers
Control of effects
Protect against external exposure, such as
High temperatures, Humidity
Consideration of other advice

Store in a well-ventilated place. Keep container tightly closed.
- general rule
Store welding consumables inside a room without humidity. Do not store welding consumables directly on the ground or beside a
wall. Keep welding consumables away from chemical substances like acids which could cause chemical reactions.
- ventilation requirements
Use local and general ventilation.

SDS identifier:
TGX-2209
7.3 Specific end use(s)

Welding (welding process).
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Cou Name of agent CAS No Nota- Identi- TWA TWA STEL STEL Source
ntry tion fier [ppm] [mg/m³] [ppm] [mg/m³]
EU calcium oxide 1305-78-8 r IOELV 1 4 2017/164/E

U
EU manganese 7439-96-5 i IOELV 0.2 2017/164/E
U
EU chromium 7440-47-3 IOELV 2 2017/164/E

U
GB dust i WEL 10 EH40/2005
GB dust r WEL 4 EH40/2005

GB calcium oxide 1305-78-8 WEL 2 EH40/2005
GB aluminium oxides 1344-28-1 i WEL 10 EH40/2005

GB aluminium oxides 1344-28-1 r WEL 4 EH40/2005
GB titanium dioxide 13463-67-7 i WEL 10 EH40/2005

GB titanium dioxide 13463-67-7 r WEL 4 EH40/2005
GB manganese 7439-96-5 WEL 0.5 EH40/2005

GB nickel 7440-02-0 WEL 0.1 EH40/2005
GB silicon 7440-21-3 i WEL 10 EH40/2005

GB silicon 7440-21-3 r WEL 4 EH40/2005
GB chromium 7440-47-3 WEL 0.5 EH40/2005

GB silica, amorphous 7631-86-9 i WEL 6 EH40/2005
GB silica, amorphous 7631-86-9 r WEL 2.4 EH40/2005

Notation
i inhalable fraction
r respirable fraction
STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period unless oth-
erwise specified
TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted
average
Relevant DNELs/DMELs/PNECs and other threshold levels
Relevant DNELs of components of the mixture
Name of substance CAS No End- Threshold Protection goal, Used in Exposure time
point level route of exposure
Chromium 7440-47-3 DNEL 0.5 mg/m³ human, inhalatory worker (industry) chronic - local ef-
fects
Nickel 7440-02-0 DNEL 0.05 mg/m³ human, inhalatory worker (industry) chronic - local ef-
fects

SDS identifier:
TGX-2209
Relevant DNELs of components of the mixture
Name of substance CAS No End- Threshold Protection goal, Used in Exposure time
point level route of exposure
Nickel 7440-02-0 DNEL 0.05 mg/m³ human, inhalatory worker (industry) chronic - systemic
effects
Nickel 7440-02-0 DNEL 0.05 mg/m³ human, inhalatory worker (industry) acute - systemic
effects
Nickel 7440-02-0 DNEL 4 mg/m³ human, inhalatory worker (industry) acute - local ef-
fects
calcium oxide 1305-78-8 DNEL 4 mg/m³ human, inhalatory worker (industry) acute - local ef-
fects
calcium oxide 1305-78-8 DNEL 1 mg/m³ human, inhalatory worker (industry) chronic - local ef-
fects
Relevant PNECs of components of the mixture
Name of substance CAS No End- Threshold Organism Environmental Exposure time

point level compartment
Chromium 7440-47-3 PNEC 6.5 µg/l aquatic organisms freshwater short-term (single
instance)
Chromium 7440-47-3 PNEC 205.7 mg/kg aquatic organisms freshwater sedi- short-term (single
ment instance)
Chromium 7440-47-3 PNEC 21.1 mg/kg terrestrial organisms soil short-term (single
instance)
calcium oxide 1305-78-8 PNEC 0.37 mg/l aquatic organisms freshwater short-term (single
instance)
calcium oxide 1305-78-8 PNEC 0.24 mg/l aquatic organisms marine water short-term (single
instance)
calcium oxide 1305-78-8 PNEC 2.27 mg/l aquatic organisms sewage treatment short-term (single
plant (STP) instance)
calcium oxide 1305-78-8 PNEC 817.4 mg/kg terrestrial organisms soil short-term (single
instance)
calcium oxide 1305-78-8 PNEC 0.37 mg/l aquatic organisms water intermittent re-
lease
8.2 Exposure controls

Appropriate engineering controls
Use enough ventilation, local exhaust at the arc, or both, to keep the fumes and gases below the TLVs in the worker’s breathing
zone and the general area. Use extra ventilation when welding galvanized plate or coated plate.
Individual protection measures (personal protective equipment)

Eye/face protection
Wear helmet or use face shield with filter lens. As a rule of thumb, start with a shade which is too dark to see the weld zone. Then
go to the next lighter shade which gives sufficient view of the weld zone. Provide protective screens and flash goggles, if neces-
sary, to shield others.

SDS identifier:
TGX-2209
Skin protection
Protective clothing (EN 340).
- hand protection
Welding gloves according to EN12477:2001 and A1:2005 in case of arc welding. For special purposes, it is recommended to
check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The ex-
act break through time should be requested at the protective glove manufacturer and must be observed.
- breakthrough times of the glove material

>480 minutes (permeation: level 6).
- other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash
hands thoroughly after handling. Wear head, hand and bodyprotection which help to prevent injury form radiation, sparks and
electric shock. At a m inimum this includes welder's gloves and protective face shield and may include arm protectors, aprons,
hats, shoulder protection as well as dark substantial clothing.
Train the welder not to touch live electrical parts and to insulate himself from work and ground.
Respiratory protection
Use respirable fume respirator or air supplied respirator when welding in confined space or where local exhaust or ventilation
does not keep exposure below TLV. Keep head out of the fumes and gases.
Ear protection
Wear earplugs or earmuffs when using engine driven arc welding machine or pulsed arc welding machine that generates high-
level noise.
Environmental exposure controls

Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state solid (electrode)
Colour grey
Odour odourless
Other safety parameters
pH (value) not applicable
Melting point/freezing point not determined
Initial boiling point and boiling range not determined
Flash point not applicable
Evaporation rate not determined
Flammability (solid, gas) non-combustible

SDS identifier:
TGX-2209
Explosion limits of dust clouds not determined
Vapour pressure not determined
Density not determined
Vapour density this information is not available
Relative density information on this property is not available
Solubility(ies) not determined
Partition coefficient
- n-octanol/water (log KOW) this information is not available
Auto-ignition temperature information on this property is not available
Viscosity not relevant (solid matter)
Explosive properties none
Oxidising properties none
9.2 Other information

Of no significance.
SECTION 10: Stability and reactivity

10.1 Reactivity
Contact with chemical substances could cause generation of gas.
10.2 Chemical stability

See below "Conditions to avoid".
10.3 Possibility of hazardous reactions

Reacts with:. Acids. Alkalis. Oxidising substances.
10.4 Conditions to avoid

Keep away from heat.
10.5 Incompatible materials

Oxidisers, Acids, Alkalis
10.6 Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not
known. Hazardous decomposition products includes those from the volatilization, reaction or oxidation of the material listed in
section 3 and those from the base metal and coating. Manganese has a low exposure limit, in some countries, that may be eas-
ily exceeded. Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Reasonably ex-
pected fume constituents of this product would include oxides of metals

SDS identifier:
TGX-2209
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Inhalation of welding fumes and gases can be dangerous to your health. The composition and quantity of both are dependent
upon the material being worked, the process, procedures and consumables used.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Classification according to GHS (1272/2008/EC, CLP)

Acute toxicity
Overexposure to gases, fumes and dusts may inclide irritation of the eyes, lungs, nose and throat. Some toxic gases (associ-
ated with welding) may cause pulmonary edema, asphyxiation and death. Acute overexposure may include signs and symp-
toms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty in breathing, frequent coughing or chest pain.
Exposure to the fluoride ion may cause hypocalcaemia-calcium deficiency in the blood that can result in muscle cramps and in-
flammation and necrosis of mucous membranes.
- acute toxicity of components of the mixture
Acute toxicity of components of the mixture
Name of substance CAS No Exposure Endpoint Value Species

route
Nickel 7440-02-0 oral LD50 >9,000 mg/kg rat

calcium oxide 1305-78-8 oral LD50 >2,000 mg/ rat
kg
Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation

Causes serious eye irritation.
Respiratory or skin sensitisation

May cause an allergic skin reaction.
Germ cell mutagenicity

Shall not be classified as germ cell mutagenic.
Carcinogenicity
Suspected of causing cancer.
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
Name of substance CAS No Wt% Classification Remarks Number Date indica-

tion
nickel powder (particle dia- 7440-02-0 13 2B Volume 49 1990

meter < 1mm)
Chromium 7440-47-3 33 3 Volume 49 1990
Legend
2B Possibly carcinogenic to humans
3 Not classifiable as to carcinogenicity in humans

SDS identifier:
TGX-2209
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Summary of evaluation of the CMR properties

Nickel is considered carcinogenic. Long term overexplosure to nickel fumes may also cause pulmonary fibrosis and oedema.
Welding fumes (not otherwise specified) are possibly carcinogenic to humans.
Specific target organ toxicity - repeated exposure

Causes damage to organs through prolonged or repeated exposure. Nickel is considered carcinogenic. Long term overexplos-
ure to nickel fumes may also cause pulmonary fibrosis and oedema. Overexposure to air contaminants may lead to their accu-
mulation in the lungs, a condition which may be seen as dense areas on chest X-rays. The severity of the change is proportional
to the length of the exposure. The changes may be caused by non-work factors such as smoking, etc. Long term exposure to
welding and allied processes gasses, dusts and fumes may contribute to pulmonary irritation or pneumoconiosis. Overexposure
to manganese compounds may affect the central nervous system, symptoms of which are languor, sleepiness, muscular weak-
ness, emotional disturbances and spastic gait. The effect of manganese on the nervous systeem is irreversible. Inhalation of to
much iron oxide fume over a long time can cause siderosis, sometimes called "iron pigmentation"of the lung, which can be seen
on a cest x-ray but causes little or no disability. Chronic overexposure to iron (>50-100 mg Fe per day) can result in pathological
deposition of iron in body tissues of which are firbrosis of the pancreas, diabetes mellitus and lever cirrhosis. Chronic fluoride ab-
sorption can result in osseous fluor sis, increased radiographic density of the bones and mottling of the teeth. Chromium (in
some forms) is considered carcinogenic. Chromium compounds have a corrosive action on the skin and mucous membranes
and forms lesions on exposed skin and the nasal septum. Liver damage and allergic skin rash have also been reported.
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposure

time
Nickel 7440-02-0 LC50 15.3 mg/l fish 96 h

Nickel 7440-02-0 EC50 561.3 µg/l aquatic invertebrates 96 h
Nickel 7440-02-0 ErC50 <148 µg/l algae 72 h
Aquatic toxicity (chronic) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposure

time
Nickel 7440-02-0 ErC50 8,363 µg/l fish 40 d

Nickel 7440-02-0 LC50 204 µg/ aquatic invertebrates 21 d
l
Nickel 7440-02-0 EbC50 6.2 µg/l aquatic invertebrates 30 d

Nickel 7440-02-0 EC50 406 µg/ aquatic invertebrates 24 h
l
12.2 Persistence and degradability


SDS identifier:
TGX-2209
12.3 Bioaccumulative potential

12.4 Mobility in soil

Not mobile.
12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Other adverse effects

Endocrine disrupting potential

None of the ingredients are listed.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment.
Waste treatment of containers/packagings

Handle contaminated packages in the same way as the substance itself.
Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled
separately by the local or national waste management facilities.
SECTION 14: Transport information

14.1 UN number not subject to transport regulations
14.2 UN proper shipping name not relevant
14.3 Transport hazard class(es) none
14.4 Packing group not relevant
14.5 Environmental hazards non-environmentally hazardous acc. to the dangerous goods regu-
lations
14.6 Special precautions for user

There is no additional information.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No data available.
Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)
Not subject to ADR, RID and ADN.
International Maritime Dangerous Goods Code (IMDG)

Not subject to IMDG.

SDS identifier:
TGX-2209
International Civil Aviation Organization (ICAO-IATA/DGR)

Not subject to ICAO-IATA.
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII
Dangerous substances with restrictions (REACH, Annex XVII)
Name of substance Name acc. to inventory CAS No Type of registra- Restriction No

tion
nickel powder (particle diameter nickel 7440-02- 1907/2006/EC annex R27 27

< 1mm) 0 XVII
Legend
R27 1. Shall not be used:
(a) in any post assemblies which are inserted into pierced ears and other pierced parts of the human body unless the rate of nickel re-
lease from such post assemblies is less than 0,2 μg/cm2/week (migration limit);
(b) in articles intended to come into direct and prolonged contact with the skin such as:
- earrings,
- necklaces, bracelets and chains, anklets, finger rings,
- wrist-watch cases, watch straps and tighteners,
- rivet buttons, tighteners, rivets, zippers and metal marks, when these are used in garments,
if the rate of nickel release from the parts of these articles coming into direct and prolonged contact with the skin is greater than 0,5
μg/cm2/week.
(c) in articles referred to in point (b) where these have a non-nickel coating unless such coating is sufficient to ensure that the rate of
nickel release from those parts of such articles coming into direct and prolonged contact with the skin will not exceed 0,5 μg/cm2/week
for a period of at least two years of normal use of the article.
2. Articles which are the subject of paragraph 1 shall not be placed on the market unless they conform to the requirements set out in that
paragraph.
3. The standards adopted by the European Committee for Standardisation (CEN) shall be used as the test methods for demonstrating
the conformity of articles to paragraphs 1 and 2.
List of substances subject to authorisation (REACH, Annex XIV)

Regulation 166/2006/EC concerning the establishment of a European Pollutant Release and

Transfer Register (PRTR)
Pollutant release and transfer registers (PRTR)
Name of substance CAS No Remarks Threshold for releases to air

(kg/year)
nickel powder (particle diameter < 1mm) 7440-02-0 (8) 50

Chromium 7440-47-3 (8) 100
Legend
(8) All metals shall be reported as the total mass of the element in all chemical forms present in the release
Directive 2000/60/EC establishing a framework for Community action in the field of water policy
(WFD)
Water Framework Directive (WFD)
Name of substance CAS No Listed in Remarks
nickel powder (particle diameter < 1mm) 7440-02-0 Annex X

Legend
annex X List of priority substances in the field of water policy

SDS identifier:
TGX-2209
Regulation 98/2013/EU on the marketing and use of explosives precursors

15.2 Chemical Safety Assessment

No chemical safety assessment has been carried out for this mixture.
SECTION 16: Other information

Indication of changes (revised safety data sheet)
Complete revised version.
Abbreviations and acronyms
Abbr. Descriptions of used abbreviations
2017/164/EU Comission Directive establishing a fourth list of indicative occupational exposure limit values pursuant to Council
Directive 98/24/EC, and amending Commission Directives 91/322/EEC, 2000/39/EC and 2009/161/EU
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation
intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways)
ADR Accord européen relatif au transport international des marchandises dangereuses par route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
Aquatic Chronic Hazardous to the aquatic environment - chronic hazard
Carc. Carcinogenicity
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
DGR Dangerous Goods Regulations (see IATA/DGR)

DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identifier of
substances commercially available within the EU (European Union)
EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-licence/)

EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances

Eye Dam. Seriously damaging to the eye
Eye Irrit. Irritant to the eye

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
IARC International Agency for Research on Cancer

IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation (EC) No
1272/2008
IOELV Indicative occupational exposure limit value

MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")
NLP No-Longer Polymer

SDS identifier:
TGX-2209
Abbr. Descriptions of used abbreviations
PBT Persistent, Bioaccumulative and Toxic
PNEC Predicted No-Effect Concentration

ppm Parts per million
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations concern-
ing the International carriage of Dangerous goods by Rail)
Skin Corr. Corrosive to skin

Skin Irrit. Irritant to skin
Skin Sens. Skin sensitisation

STEL Short-term exposure limit
STOT RE Specific target organ toxicity - repeated exposure

STOT SE Specific target organ toxicity - single exposure
TWA Time-weighted average

vPvB Very Persistent and very Bioaccumulative
WEL Workplace exposure limit
Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures. Regulation (EC) No.
1907/2006 (REACH), amended by 2015/830/EU.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Maritime Dangerous Goods
Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).
Classification procedure
Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mixture (ad-
ditivity formula).
List of relevant phrases (code and full text as stated in chapter 2 and 3)
Code Text
H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.

H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

H351 Suspected of causing cancer.
H372 Causes damage to organs through prolonged or repeated exposure.

H412 Harmful to aquatic life with long lasting effects.
Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this
product.

SDS identifier:
TGX-2209
Warning text on the label

WARNING: PROTECT yourself and others. Read and understand this information.
FUMES AND GASES can be hazardous to your health.
ARC RAYS can injure eyes and burn skin.
ELECTRIC SHOCK can KILL.
・Before use, read and understand the manufacturer's instructions, Material Safety Data Sheets (MSDSs), and your employer's
safety practices.
・Keep your head out of the fumes.
・Use adequate ventilation, exhaust at the arc, or both, to keep fumes and gases from your breathing zone and the general area.
・Wear correct eye, ear, and body protection.
・Do not touch free electrical parts.

Safety Data Sheet TGX-2209: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

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Safety Data Sheet TGX-2209: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

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SDS identifier:

Safety Data Sheet TGX-2209: (Rev. 2.0)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone number

Country Name Telephone

United Kingdom National Poisons Information Service (NPIS) 0344-8920111

SECTION 2: Hazards identification

Section Hazard class Category Hazard class and Hazard state-

3.3 serious eye damage/eye irritation 2 Eye Irrit. 2 H319

3.4S skin sensitisation 1 Skin Sens. 1 H317

3.6 carcinogenicity 2 Carc. 2 H351

3.9 specific target organ toxicity - repeated exposure 1 STOT RE 1 H372

United Kingdom: en Page: 1 / 16

For full text of abbreviations: see SECTION 16.

2.2 Label elements

- hazardous ingredients for labelling Nickel

2.3 Other hazards

Results of PBT and vPvB assessment

SECTION 3: Composition/information on ingredients

United Kingdom: en Page: 2 / 16

Name of sub- Identifier Wt% Classification Picto- Notes Specific M-Factors

Chromium CAS No 13 – 33 IOELV

calcium oxide CAS No ≤ 1 Skin Irrit. 2 / H315

SECTION 4: First aid measures

United Kingdom: en Page: 3 / 16

Following skin contact

Following eye contact

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

Hazardous combustion products

5.3 Advice for firefighters

Special protective equipment for firefighters

SECTION 6: Accidental release measures

For emergency responders

6.2 Environmental precautions

United Kingdom: en Page: 4 / 16

6.3 Methods and material for containment and cleaning up

Advices on how to clean up a spill

Other information relating to spills and releases

6.4 Reference to other sections

SECTION 7: Handling and storage

Advice on general occupational hygiene

7.2 Conditions for safe storage, including any incompatibilities

- incompatible substances or mixtures

Consideration of other advice

United Kingdom: en Page: 5 / 16

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

Occupational exposure limit values (Workplace Exposure Limits)

EU calcium oxide 1305-78-8 r IOELV 1 4 2017/164/E

EU chromium 7440-47-3 IOELV 2 2017/164/E

GB dust r WEL 4 EH40/2005

GB aluminium oxides 1344-28-1 i WEL 10 EH40/2005

GB titanium dioxide 13463-67-7 i WEL 10 EH40/2005

GB manganese 7439-96-5 WEL 0.5 EH40/2005

GB silicon 7440-21-3 i WEL 10 EH40/2005

GB chromium 7440-47-3 WEL 0.5 EH40/2005

GB silica, amorphous 7631-86-9 r WEL 2.4 EH40/2005

Chromium CAS No 13 – 33 IOELV

calcium oxide CAS No ≤ 1 Skin Irrit. 2 / H315