This document discusses four colligative properties of solutions:
1. Vapor pressure lowering and boiling point elevation - Adding a solute lowers vapor pressure and raises the boiling point of a solvent. The higher the solute concentration, the greater the effect.
2. Freezing point depression - Adding a solute lowers the freezing point of a solvent. The higher the solute concentration, the greater the freezing point depression.
3. Osmotic pressure - The pressure required to prevent osmosis, or diffusion of solvent into the solution. Higher solute concentrations yield higher osmotic pressures.
4. A sample problem calculates the boiling point and freezing point of a sucrose solution using the concepts of boiling
This document discusses four colligative properties of solutions:
1. Vapor pressure lowering and boiling point elevation - Adding a solute lowers vapor pressure and raises the boiling point of a solvent. The higher the solute concentration, the greater the effect.
2. Freezing point depression - Adding a solute lowers the freezing point of a solvent. The higher the solute concentration, the greater the freezing point depression.
3. Osmotic pressure - The pressure required to prevent osmosis, or diffusion of solvent into the solution. Higher solute concentrations yield higher osmotic pressures.
4. A sample problem calculates the boiling point and freezing point of a sucrose solution using the concepts of boiling
This document discusses four colligative properties of solutions:
1. Vapor pressure lowering and boiling point elevation - Adding a solute lowers vapor pressure and raises the boiling point of a solvent. The higher the solute concentration, the greater the effect.
2. Freezing point depression - Adding a solute lowers the freezing point of a solvent. The higher the solute concentration, the greater the freezing point depression.
3. Osmotic pressure - The pressure required to prevent osmosis, or diffusion of solvent into the solution. Higher solute concentrations yield higher osmotic pressures.
4. A sample problem calculates the boiling point and freezing point of a sucrose solution using the concepts of boiling
This document discusses four colligative properties of solutions:
1. Vapor pressure lowering and boiling point elevation - Adding a solute lowers vapor pressure and raises the boiling point of a solvent. The higher the solute concentration, the greater the effect.
2. Freezing point depression - Adding a solute lowers the freezing point of a solvent. The higher the solute concentration, the greater the freezing point depression.
3. Osmotic pressure - The pressure required to prevent osmosis, or diffusion of solvent into the solution. Higher solute concentrations yield higher osmotic pressures.
4. A sample problem calculates the boiling point and freezing point of a sucrose solution using the concepts of boiling
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Colligative Properties Tb = Kbm b.
Calculate the boiling point The higher the concentration of
Properties of solutions elevation the solution the higher is the They are dependent on the Tb = boiling point elevation Tb = Kbm osmotic pressure number of solute particles that = (0.52oC/m) (0.058m) Osmosis are dissolved in a given quantity Kb = boiling point elevation constant = 0.03oC A Greek word meaning “push” of the solvent and not in their (0.512oC/m) A process in which the solvent identity. c. Calculate the boiling point moves through a semipermeable m = molal concentration Tb = boiling point of water + Tb membrane into the solution 1. Vapor Pressure Lowering = 100oC + 0.03oC The presence of a solute lowers 3. Freezing point depression = 100.03oC Semipermeable membrane the vapor pressure of the solvent The presence of solute Allows certain types of molecules The presence of the solute with lowers the freezing point of Freezing point elevation to pass through while preventing exert attraction on the solvent the solvent a. Calculate the molality the passage of other species in molecules, thus decreasing their mole of solute solution. m= rate of escape Tf = Kfm kg of solvent Higher concentration of the solute added, the greater is Tf = freezing point elevation 4g m= decrease of vapor pressure 0.2 kg Kf = freezing point constant m = 0.058 m 2. Boiling Point Elevation (1.86oC/m) The boiling point of the solution b. Calculate the freezing point is higher than the boiling point of m = molal concentration elevation a pure solvent Tf = Kfm The addition of a solute Sample Problem for boiling point = (1.86oC/m) (0.058m) increases the boiling point of the elevation and freezing point depression = 0.11oC solution To bring the solution to its Find the boiling point and freezing point c. Calculate the freezing point boiling point more heat is of a solution containing 4 g sucrose Tf = freezing point of water + Tf o o needed (C12H22O11) dissolved in 200 g of H2O. = 0 C + 0.11 C = -0.11oC Boiling point of a liquid Boiling point elevation Is the temperature at which the a. Calculate the molality 4. Osmotic pressure vapor pressure of the liquid and mole of solute The pressure needed to prevent m= its atmospheric pressure are kg of solvent osmosis from the pure solvent to equal the solution Boling point is directly 4g Related to the molar concentration m= proportional to the amount of 0.2 kg of the solution solute added m = 0.058 m