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Boiling Point Elevation
Boiling Point Elevation
Therefore if:
Vapor Pressure increases, Boiling Point decreases.
Clues:
1. Write the formula that you will use.
Tb = iKbCm
= 1 x K b x Cm
= 1 x 2.61C/m x 0.100m
= 0.261C increase
= 80.461C
Tb = iKbCm
First calculate the molality.
89.75g NaCl = 1.54“X” mol
1.54 mol
= 6.16m
Therefore:
0.250 Kg
Tb = iKbCm
= 2 x K b x Cm
= 2 x 0.512C/m x 6.16m
= 6.31C increase
= 106.31C
Tb = iKbCm
= 1 x K b x Cm
= 1 x 0.512C/m x 0.0222m
= 0.0114C increase
= 100.0114C
Clues:
= 1 x 0.512C/m x 0.0825m
= 0.0422C increase
= 100.0422C
B.P. Elevation example #5:
Clues:
1. Determine the molality of the solution.
Tb = iKbCm
0.78C = 1 x Kb x Cm
And if…
218.33“X”
g
9.75g =
0.0447 mol 1 mol
Freezing point depression -
Tf equals the freezing point of the pure solvent
minus the freezing point of the solution.
Tf = iKfCm where
i = The number of ions if solute is ionic.
Kf = freezing point depression constant
(depends on the solvent)
Cm = molal concentration
(m = #mol solute/Kg solvent)
Freezing point depression example #1:
Kf H2O = 1.858C/m
Determination of molar mass from F.P. depression.
Example #2:
Safrole is contained in oil of sassafras and was
once used to flavor root beer. A 2.39mg sample of
safrole was dissolved in 103.0mg of Diphenyl ether.
The solution had a melting point of 25.70C .
Calculate the molecular weight of Safrole.
F.P. pure Diphenyl ether = 26.84C
Kf = 8.00C/m
Clues:
1. Write the formula that you will use.
Tf = iKfCm
You must calculate the following to solve:
Tf = 1.14C
Cm = 0.1425m