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SDS Isopropyl Alcohol

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MATERIAL SAFETY DATA SHEET

SECTION I : IDENTIFICATION OF PRODUCT AND THE COMPANY

Trade Name : JM 141 SL ; IPA

Supplier :
PT. JM MUTU UTAMA Emergency contact :
Kawasan Industri Modern Cikande Tel. : +62 254 403844 - 46
Jl.Modern Industri III No. 5, Cikande Fax. : +62 254 403847
Serang, Indonesia

SECTION II : COMPOSITION / INFORMATION ON INGREDIENTS

Name % by weight
Isopropyl alcohol 99.9 % Min

SECTION III : HAZARD IDENTIFICATION

Classification according to Regulation (EC) No 1272/2008


Flammable liquids (Category 2), H225
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
F Highly flammable R11
Xi Irritant R36
R67
Labelling according Regulation (EC) No. 1272/2008

Pictogram :
Signal Word : Danger
Hazard statement(s)
H225 : Highly flammable liquid and vapour
H319 : Causes serious eye irritation
H336 : May cause drowsiness or dizziness

Precautionary statement(s)
P210 : Keep away from heat/sparks/open flames/hot surfaces. – No smoking
P261 : Avoid breathing vapours

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P305 + P351 + P338 : IF IN EYES : Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.

Potential Acute Health Effects : Hazardous in case of eye contact (irritant), of ingestion, of inhalation.
Slightly hazardous in case of skin contact (irritant, sensitizer, permeator).
Potential Chronic Health Effects : Slightly hazardous in case of skin contact (sensitizer).
CARCINOGENIC EFFECTS : A4 (Not classifiable for human or animal) by ACGIH, 3 (Not
classifiable for human), by IARC. MUTAGENIC EFFECTS : Not available. TERATOGENIC
EFFECTS : Not available. DEVELOPMENTAL TOXICITY : classified reproductive
system/toxin/female, Developmental toxin [POSSIBLE]. The substance may be toxic to kidneys, liver,
skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce
target organs damage.

SECTION IV : FIRST AID MEASURES

Eye Contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes
with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
Skin Contact : Wash with soap and water. Cover the irritated skin with an emollient. Get medical
attention if irritation develops. Cold water may be used.
Serious Skin Contact : Not available.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention if symptoms appear.
Serious Inhalation : Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such
as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or
waistband. Get medical attention if symptoms appear.

SECTION V : FIRE FIGHTING MEASURES

Flammability of the Product : Flammable.


Auto-Ignition Temperature : 399 °C (750.2 °F)
Flash Points : CLOSED CUP : 11.667 °C (53 °F) - 12.778 deg. C (55 deg. F) (TAG)
Flammable Limits : LOWER : 2% UPPER: 12.7%
Products of Combustion : These products are carbon oxides (CO, C)
Fire Hazards in Presence of Various Substances : Highly flammable in presence of open flames and
sparks, of heat. Flammable in presence of oxidizing materials. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances : Risks of explosion of the product in presence
of mechanical impact: Not available. Explosive in presence of open flames and sparks, of heat.
Fire Fighting Media and Instructions : Flammable liquid, soluble or dispersed in water. SMALL

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FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog.
Special Remarks on Fire Hazards : Vapor may travel considerable distance to source of ignition and
flash back. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME. Hydrogen peroxide sharply
reduces the autoignition temperature of Isopropyl alcohol. After a delay, Isopropyl alcohol ignites on
contact with dioxgenyl tetrafluorborate, chromium trioxide, and potassium tert-butoxide. When heated
to decomposition it emits acrid smoke and fumes.
Special Remarks on Explosion Hazards : Secondary alcohols are readily autooxidized in contact with
oxygen or air, forming ketones and hydrogen peroxide. It can become potentially explosive. It reacts
with oxygen to form dangerously unstable peroxides which can concentrate and explode during
distillation or evaporation. The presence of 2-butanone increases the reaction rate for peroxide
formation. Explosive in the form of vapor when exposed to heat or flame. May form explosive mixtures
with air. Isopropyl alcohol + phosgene forms isopropyl chloroformate and hydrogen chloride. In the
presence of iron salts, thermal decompositon can occur, whicn in some cases can become explosive. A
homogeneous mixture of concentrated peroxides + isopropyl alcohol are capable of detonation by
shock or heat. Barium perchlorate + isopropyl alcohol gives the highly explosive alkyl perchlorates. It
forms explosive mixtures with trinitormethane and hydrogen peroxide. It produces a violent explosive
reaction when heated with aluminum isopropoxide + crotonaldehyde. Mixtures of isopropyl alcohol +
nitroform are explosive.

SECTION VI : ACCIDENTAL RELEASE MEASURES

Small Spill : Dilute with water and mop up, or absorb with an inert dry material and place in an
appropriate waste disposal container.
Large Spill : Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if
without risk. Absorb with DRY earth, sand or other non-combustible material. Do not touch spilled
material. Prevent entry into sewers, basements or confined areas; dike if needed. Be careful that the
product is not present at a concentration level above TLV. Check TLV on the MSDS and with local
authorities.

SECTION VII : HANDLING AND STORAGE

Storage : Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep
container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or
flame).
Precautions : Keep away from heat. Keep away from sources of ignition. Ground all equipment
containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes.
Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Keep
away from incompatibles such as oxidizing agents, acids.
SECTION VIII : EXPOSURE CONTROLS AND PERSONAL PROTECTION

Engineering Controls : Provide exhaust ventilation or other engineering controls to keep the airborne

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concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
Personal Protection : Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.
Exposure Limits : TWA : 983 STEL : 1230 (mg/m3) [Australia] TWA : 200 STEL : 400 (ppm) from
ACGIH (TLV) [United States] [1999] TWA : 980 STEL : 1225 (mg/m3) from NIOSH TWA : 400
STEL : 500 (ppm) from NIOSH TWA : 400 STEL : 500 (ppm) [United Kingdom (UK)] TWA : 999
STEL : 1259 (mg/m3) [United Kingdom (UK)] TWA : 400 STEL : 500 (ppm) from OSHA (PEL)
[United States] TWA : 980 STEL : 1225 (mg/m3) from OSHA (PEL) [United States]Consult local
authorities for acceptable exposure limits.
Personal Protection in Case of a Large Spill : Splash goggles. Full suit. Vapor respirator. Boots.
Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.

SECTION IX : PHYSICAL AND CHEMICAL PROPERTIES

Physical state : liquid


Form : liquid
Colour : Clear colorless
Odour : alcohol-like
Odour Threshold : 100 ppm
pH : no data available
Melting point/range : -90 °C
Boiling point/boiling range : 83 °C
Flash point : 11.7 °C
Test Method : closed cup
Auto-ignition temperature : 456 °C
Lower explosion limit : 2 % (V) (in air)
Upper explosion limit : 12 % (V) (in air)
Vapour pressure : 4.4 kPa ( 20 °C)
Relative vapour density : 2.1 (Air = 1.0)
Relative density : 0.786 – 0.787
Water solubility : Miscible in water.
Partition coefficient : log Pow : 0.05
n-octanol/water
Decomposition temperature : no data available
Viscosity, kinematic : ca.1.6 mm2/s

SECTION X : STABILITY AND REACTIVITY

Stability : The product is stable.

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Instability Temperature : Not available.
Conditions of Instability : Heat, Ignition sources, incompatible materials
Incompatibility with various substances : Reactive with oxidizing agents, acids, alkalis.
Corrosivity : Non-corrosive in presence of glass.
Polymerization : Will not occur.
Special Remarks on Corrosivity : May attack some forms of plastic, rubber and coating
Special Remarks on Reactivity : Reacts violently with hydrogen + palladium combination, nitroform,
oleum, COCl2, aluminum triisopropoxide, oxidants Incompatible with acetaldehyde, chlorine, ethylene
oxide, isocyanates, acids, alkaline earth, alkali metals, caustics, amines, crotonaldehyde, phosgene,
ammonia. Isopropyl alcohol reacts with metallic aluminum at high temperatures. Isopropyl alcohol
attacks some plastics, rubber, and coatings. Vigorous reaction with sodium dichromate + sulfuric acid

SECTION XI : TOXICOLOGICAL INFORMATION

Routes of Entry : Absorbed through skin. Dermal contact. Eye contact. Inhalation.
Toxicity to Animals : WARNING : THE LC50 VALUES HEREUNDER ARE ESTIMATED ON
THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD 50) : 3600 mg/kg [Mouse]. Acute
dermal toxicity (LD50) : 12800 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50) : 16000 8 hours [Rat].
Chronic Effects on Humans : CARCINOGENIC EFFECTS : A4 (Not classifiable for human or
animal.) by ACGIH, 3 (Not classifiable for human.) by IARC. DEVELOPMENTAL TOXICITY :
Classified Reproductive system/toxin/female, Development toxin [POSSIBLE]. May cause damage to
the following organs: kidneys, liver, skin, central nervous system (CNS).
Other Toxic Effects on Humans : Hazardous in case of ingestion, of inhalation. Slightly hazardous in
case of skin contact (irritant, sensitizer, permeator).
Special Remarks on Toxicity to Animals : Not available
Special Remarks on Chronic Effects on Humans : May cause adverse reproductive/teratogenic effects
(fertility, fetoxicity, developmental abnormalities (developmental toxin) based on animal studies.
Detected in maternal milk in human.
Special Remarks on other Toxic Effects on Humans : Acute Potential Health Effects: Skin: May cause
mild skin irritation, and sensitization. Eyes: Can cause eye irritation. Inhalation: Breathing in small
amounts of this material during normal handling is not likely to cause harmful effects. However,
breathing large amounts may be harmful and may affect the respiratory system and mucous membranes
(irritation), behavior and brain (Central nervous system depression - headache, dizziness, drowsiness,
stupor, in coordination, unconsciousness, coma and possible death), peripheral nerve and sensation,
blood, urinary system, and liver. Ingestion: Swallowing small amounts during normal handling is not
likely to cause harmful effects. Swallowing large amounts may be harmful. Swallowing large amounts
may cause gastrointestinal tract irritation with nausea, vomiting and diarrhea, abdominal pain. It also
may affect the urinary system, cardiovascular system, sense organs, behavior or central nervous system
(somnolence, generally depressed activity, irritability, headache, dizziness, drowsiness), liver, and
respiratory system (breathing difficulty). Chronic Potential Health Effects: May cause defatting of the
skin and dermatitis and allergic reaction. May cause adverse reproductive effects based on animal data
(studies).

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SECTION XII : ECOLOGICAL INFORMATION

Ecotoxicity : Ecotoxicity in water (LC50): 100000 mg/l 96 hours [Fathead Minnow]. 64000 mg/l 96
hours [Fathead Minnow].
BOD5 and COD : Not available.
Products of Biodegradation : Possibly hazardous short term degradation products are not likely.
However, long term degradation products may arise.
Toxicity of the Products of Biodegradation : The product itself and its products of degradation are not
toxic
Special Remarks on the Products of Biodegradation : Not available.

SECTION XIII : DISPOSAL CONSIDERATION

Waste Disposal : Waste must be disposed of in accordance with federal, state and local environmental
control regulations.

SECTION XIV : TRANSPORT INFORMATION

DOT Classification : CLASS 3 : Flammable liquid.


Identification : Isopropyl Alcohol UNNA : 1219 PG : II
Special Provisions for Transport : Not available.

SECTION XV : REGULATION INFORMATION

NFPA Rating :
Health : 1 Flammability : 3 Reactivity : 0 Specific Hazard : None
PPE : H (safety goggles, gloves, apron, vapor respirator)

SECTION XVI : OTHER INFORMATION

The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided
without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or
disposal of the product are beyond our control. For this, we do not assume responsibility and expressly disclaim liability for loss,
damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This
MSDS was prepared and is to be used only for this product.

Prepared by : R&D
Date : 10/06/2021
Approved by : BDM

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