के न्द्रीय विद्यालय संगठन, गुरुग्राम संभाग

KENDRIYA VIDYALAYA SANGATHAN GURUGRAM REGION

कक्षा- XII Class-XII
2022-23

PRACTICE PAPER-III

CLASS : XII CHEMISTRY THEORY (043)

MM:- 70 Time: 3hours
MARKING SCHEME

Q.NO. Answer Marks

SECTION-A
1 d. 1
2 c. 1
3 b. 1
4 a. 1
5 a. 1
6 a) 1

7 b) 1
8 c) 1
9 b) 1
10 b) 1
11 b. 1
12 a. 1
13 c. 1
14 a 1
15 a. 1
16 d. 1
17 a. 1
18 d. 1
SECTION-B
19 a. For tetrahedral complexes, the crystal field stabilisation 1+1
energy is lower the pairing energy.
b.cis-Platin
20 0.05M Al2SO4 1
because gives a lower depression in freezing point. Hence it
will freeze at high temperature. 1
21
I. First order reaction ½
 II. time-1 or min-1 ½
III. t1/2 is independent of [R]0 ½
IV. ½

22
a) Cr3+ ½
b) Mn3+ ½
c) Ti4+ ½
d) Mn3+ ½

23 a)[Co(NH3)4Cl2]Cl 1
b) Tetraamminechloridocobalt (III)chloride. 1
OR
a) Geometrical isomerism 1
b) In [NiCl4]2- , Nickel undergo sp3 hybridisation and have two 1
unpaired electrons because chloride ion (Weak field ligand)
does not cause pairing of electron, hence paramagnetic.
In [NI(CO)4] , Nickel undergo sp3 hybridisation and have two
unpaired electron because CO (Strong field ligand)
cause pairing of electron, Hence diamagnetic.
24 a) Protein are polymers of amino acid connected to each other 1
by peptide linkage (-CO-NH-)
b) Twomonosaccharide units are joined together by an oxide 1
linkage formed by the loss of water molecule.
OR
Sucrose is dextrorotatory. On hydrolysis, it produces a mixture
of glucose and fructose having specific rotation
+ 52 5°. and -92.4°. Thus, the respectively net resultant
mixture become laevorotatory. Hence, the mixture is
laevorotatory and product is known as invert sugar.
25 i) CH3I
Iodine is better leaving group because of larger size than
Bromine
ii) CH3Cl
Because primary halides have lesser steric hindrance.
SECTION-C
26 Tb= i x Kb x m ½
For MgSO4 i=2 ½
 Molality of solution=4/120 x 10 =1/3m 1
Tb= 2 x 0.52 x 1/3 = 0.347 ½
Boiling point of solution= 100+0.347=100.3470C ½

27
a) Mercury cell is used in hearing aids. ½
b) Fuel cell was used in Apollo Space Programme. ½
c) Lead storage cell is used in automobiles and invertors. ½
d) Dry cell does not have long life.
(ii) Specific conductivity decreases because the number of ions ½
per unit volume decrease. 1

28 a) Any two correct difference. 2

b) t=2.302/k log [A]0/[A]=2.032/1.15x10-3 log 5/3 ½
=2 x 10-3 x 0.2219 =443.8 s ½

29 a) diamminesilver(I)dicyanoargentate(I) 1
b) dicloridobis(ethane-1,2-diamine) cobalt (III)chloride 1
c)Potassiumtrioxalatoaluminate (III) 1

30 i)Reimer-Tiemann reaction 1

ii) Kolbe’s reaction

b) Phenol and Benzyl Chloride

OR
1
I. On adding NaOH/I2 and heating Isopropyl alcohol form
a yellow ppt. of iodoform but n-Propyl alcohol does not
 give this test. 1
II. On adding neutral FeCl3solution, Phenol form red-violet
complexbut alcohol does not gives this test 1
b) NaBH4(Sodium borohydride)

SECTION-D
31 i. b) C12H22O11 1
II. d) NaHSO3 1
III. d) Rhamnose 1
iv. c) Lactose 1
OR
v. The carbohydrates are optically active polyhydroxy
aldehyde or ketone
32 i) c
ii) d
iii) a
iv) b
OR
v) a
SECTION-E
33 a) 2Al(s) + 3Cd (0.1M) 3Cd(s) +2Al3+(0.01M)
2+

n=6 ½
Ecell=E0cell – 0.059/n log [Al3+]2/ [Cd2+]3 ½
= 1.26 – 0.059/6 log (0.01)2/(0.1)3 1
= 1.26 – 0.059/6 x (-1) ½
= 1.26 + 0.009
½
= 1.269 V
b) Given that k= 0.025 S cm-1
Molarity = 0.2 M 1
m = k /Molarity x 1000 ½
= 0.025/0.2 x 1000 ½
= 125 S cm2 mol-1
OR
a) 1
i. Cu (s)/ Cu2+(aq.)  Ag+(aq.) / Ag (s) 1
ii. Current will flow from sliver to copper electrode in the
½
external circuit.
½
iii. At Cathode : 2 Ag+(aq.) + 2 e-2 Ag (s)
At Anode : Cu (s) Cu2+(aq.) + + 2 e- 1
½
 b) H2-O2 Fuel Cell ½
At Cathode : O2(g) + 2H2O(l) + 4 e-4OH-(aq.)
At Anode : 2H2(g) + 4OH-(aq.) +4H2O(l) + 4 e-

34 a) CuF2is coloured due to presence of unpaired electron 1

(Cu2+ion)
b) Explain:
1
i. Cr in CrO42-has oxidation state +6. It can reduce its
oxidation to +3 (in Cr3+ ,t2g3 stable state) and act as
strong oxidising agent while Mn in MnO42- has oxidation
state +6.But its most stable state is +7,Hence it does not
act as oxidising agent. 1
ii. Due to lanthanoid contraction. 1
iii. Because higher oxide are ionic in nature but lower oxide
1
are covalent in nature
iv. Because it have maximum five unpaired electron.
OR
a) Complete the following chemical equations:
i) 8MnO2 +(s) +6SO42-(aq.) + 2OH-(aq.)
ii) 2Cr3+(aq.) + 6Fe3+(aq.) + 7H2O(l)
b) 4FeCrO4+8Na2CO3+7O28Na2CrO4+2Fe2O3+ 8CO2
4Na2CrO4+ 2H+Na2Cr2O7+2Na+ +H2O
Na2Cr2O7+ KCl  K2Cr2O7 + NaCl
35 a) Write the structure of A, B, C and D in the following 4+1
reactions:
i. A = CH3COCl
ii. B = CH3CHO
iii. C= CH3CH(OH)CH3 and D= CH3CH2OH
b) Due to absence of alpha hydrogen.
OR
a) Write down the equations involved in the following 3+2
reactions:
 i.

b) How do you convert the following: