Set-2 MS
Set-2 MS
Set-2 MS
Marking Scheme
Section - A
Q. 1 c 1
Q. 2 c 1
Q. 3 a 1
Q. 4 a 1
Q. 5 a 1
Q. 6 b 1
Q. 7 c 1
Q. 8 a 1
Q. 9 a 1
Q.10 c 1
Q.11 d 1
Q.12 d 1
Q.13 a 1
Q.14 b 1
Q.15 a 1
Q.16 d 1
Section - B
Q.17 As ΔTb= iKbm 2 (0.5+1+0.5)
(x – 100) °C = 0.35 × 0.512 K kg mol-1 × 2 m
(x – 100) = 0.35 × 0.512 × 2
x = 100.36 °C
Q.18 It represent actual dependence of rate on concentration of 2(1+0.5+0.5)
reactants and it is represented by
Rate = k[A]x [B]y
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Q.25 (a)CH2=CH2CH2CH3HBr/peroxide BrCH2CH2CH2CH3NaI/Acetone 3 (1+1+1)
ICH2CH2CH2CH3
(b)CH3CH(Br)CH2CH3HBr/peroxide CH2=CHCH2CH3HBr
BrCH2CH2CH2CH3
Q.29 (a) Complexes which contains same type of ligands. Ex. 4(1+1+2)
K4[Fe(CN)6].
(b)
OR
(i) Due to presence of 5 unpaired electrons in [Fe(H2O)6]3+ and 1
unpaired electron in [Fe(CN)6]3–.
(ii) Correct answer
Q.30 4(1+1+2)
(a)
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(b) Zn is more reactive metal than iron so it get oxidized instead
of iron
868500 C
Section - E
Q.31 (a) Given: wb = 2.56 g wa = 100 g = 0.1 kg ΔTf = 0.383 K Kf= 3.83 5(3+1+1)
K kg mol-1 Atomic mass of sulphur = 32 g mol-1 Mb = ?
Using formula,
∆Tf =iKf m
m = w2x 1000/M2 x w1
M2= i x Kf x w2 x 1000/∆Tfx w1
M2= 1 x 3.83 x 2.56 x 1000/0.383 x 100
M2 = 256 g mol-1
(b) Water present inside the cells moves into the NaCl solution
which results in shrinkage of RBCs.
OR
(a) ∆Tb =i Kb m
i =2
m = w2x 1000/M2 x w1= 0.33
∆Tb =2 x 0.52 x 0.33 = 0.346
Tb= ∆Tb + Tbo
Tb= 0.346 + 373.15 = 373.496 K
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Q.32 (a) Cr2O7−2(aq)+ H+(aq) + I-(aq) 2Cr3+(aq) + 7H2O + 3I2 (s 5(1+1+1+1+1)
OR
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