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KENDRIYA VIDYALAYA SANGATHAN GURUGRAM REGION

1ST PREBOARD EXAMINATION


2024-25
CLASS XII MAX MARKS 70
SUBJECT: CHEMISTRY TIME : 3 HRS

Marking Scheme

Section - A
Q. 1 c 1
Q. 2 c 1
Q. 3 a 1
Q. 4 a 1
Q. 5 a 1
Q. 6 b 1
Q. 7 c 1
Q. 8 a 1
Q. 9 a 1
Q.10 c 1
Q.11 d 1
Q.12 d 1
Q.13 a 1
Q.14 b 1
Q.15 a 1
Q.16 d 1
Section - B
Q.17 As ΔTb= iKbm 2 (0.5+1+0.5)
(x – 100) °C = 0.35 × 0.512 K kg mol-1 × 2 m
(x – 100) = 0.35 × 0.512 × 2
x = 100.36 °C
Q.18 It represent actual dependence of rate on concentration of 2(1+0.5+0.5)
reactants and it is represented by
Rate = k[A]x [B]y

(i) 1.5 (ii) 3


Q.19 Suggestive answer: 2 (1+1)
(a) As compared to O- and m- isomers p-isomer is
comparatively more symmetrical and causes close packing,
thus require more heat to break these strong forces of
attraction.
(b) (±)-2-Chlorobutane is optically inactive because it is a
racemic mixture which contains 50% d and 50% l isomer.
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Q.20 2C2H5CHO NaOH/∆ CH3CH2CH=C(CH3)CHO 2 (1+1)

2C6H5CHO NaOH/∆ C6H5CH2OH + C6H5COOH


OR

(a) CH3CHO Zn-Hg/HCl CH3CH2OH (Any other example


of Ald. or ketone)

(b) C6H5COCl H2/ Pd-BaSO4 C6H5CHO

Q.21 (a) Phosphodiester linkage 2(1+1)


(b) Increased blood clotting time
Section - C

Q.22 Ecell = EoCell-0.0591/n log [Cu2+]/[Ag+]2 3 (0.5 + 2+0.5)


EoCell = EoCathode - Eoanode
EoCell= 0.80-0.34 = 0.46 V
Ecell = 0.46 - 0.0591/2 log [101-]/[103-]2
Ecell = 0.46 – 0.1477 = 0.31 V
∆G = - nFEoCell = - 2 x 96500 x 0.31 = -59830 Joule/mole
Q.23 (a) It is the time in which concentration of reactants becomes 3
half. (1+0.5+1+0.5+)
(b) k = 2.303/t log [R]/[R]0
k = 2.303/20 log 100/50
k = 2.303/20 log 2
k = 2.303/20 (0.3010)
k = 0.0346
t = 2.303/k log [R]/[R]0
t = 2.303/0.0346 log 100/60
t = 2.303/0.0346 (0.22)
t = 2.303/0.0346 (0.22)
t ≈ 14.64 Min

Q.24 (a) [Cr(H2O)6]Cl3 6(0.5)=3


Hexaaquachromium(III) chloride
Hydrate isomerism
(b) [Fe(C2O4)3]3-
Due to chelate effect
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Q.25 (a)CH2=CH2CH2CH3HBr/peroxide BrCH2CH2CH2CH3NaI/Acetone 3 (1+1+1)
ICH2CH2CH2CH3

(b)CH3CH(Br)CH2CH3HBr/peroxide CH2=CHCH2CH3HBr
BrCH2CH2CH2CH3

(c) CH3CH2Cl KCN CH3CH2CN H2O/H+CH3CH2COOH

Q.26 (a) Formation of hydrogen bond with water 3(1+1+1)


(b) Phenol is not enough strong to evolve CO2 from NaHCO3
(c) In p-NitrophenolNO2 group contributes in resonance but not
when present on m-position in m-Nitrophenol
(d) As carbocation is formed as intermediate in this reaction
and Order of stability of carbocation is 3o>2o>1o
Q.27 (a) (I) Iodoform test (with chemical equation involved) 3(1+1+1)
(II) Tollen’s test (with chemical equation involved)
(b) Butanone < Propanone <Propanal<Ethanal

Q.28 (a) A=T, C≡G 3(1+1+1)


(b) (i) Saccharic acid
(ii) n-Hexane
Section - D

Q.29 (a) Complexes which contains same type of ligands. Ex. 4(1+1+2)
K4[Fe(CN)6].
(b)

(c) In a coordination compound, the electronic configuration of


the central metal ion is t2g3eg2
(i) Outer orbital complex
(ii) Paramagnetic

OR
(i) Due to presence of 5 unpaired electrons in [Fe(H2O)6]3+ and 1
unpaired electron in [Fe(CN)6]3–.
(ii) Correct answer
Q.30 4(1+1+2)
(a)

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(b) Zn is more reactive metal than iron so it get oxidized instead
of iron

(C)The amount of chemical reaction which occurs at any


electrode during electrolysis by a current is proportional to the
quantity of electricity passed through the electrolyte (solution
or melt).

868500 C

Section - E

Q.31 (a) Given: wb = 2.56 g wa = 100 g = 0.1 kg ΔTf = 0.383 K Kf= 3.83 5(3+1+1)
K kg mol-1 Atomic mass of sulphur = 32 g mol-1 Mb = ?
Using formula,
∆Tf =iKf m
m = w2x 1000/M2 x w1
M2= i x Kf x w2 x 1000/∆Tfx w1
M2= 1 x 3.83 x 2.56 x 1000/0.383 x 100
M2 = 256 g mol-1

(b) Water present inside the cells moves into the NaCl solution
which results in shrinkage of RBCs.

(c) Minimum boiling azeotropes are solutions which show a


large positive deviation from Raoult’s law at a specific
composition
Ex. 95% Ethanol-water mixture

OR
(a) ∆Tb =i Kb m
i =2
m = w2x 1000/M2 x w1= 0.33
∆Tb =2 x 0.52 x 0.33 = 0.346
Tb= ∆Tb + Tbo
Tb= 0.346 + 373.15 = 373.496 K

(b) Properties which depends on number of solute particles


present in solutionirrespective of their nature

(c) Because molarity changes with temperature

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Q.32 (a) Cr2O7−2(aq)+ H+(aq) + I-(aq) 2Cr3+(aq) + 7H2O + 3I2 (s 5(1+1+1+1+1)

(b) 8MnO4(aq) + 3S2O32-(aq) + H2O (l) 8MnO2(s) + 6 SO42-(aq) + 2OH-(aq)

(c) Due to presence of unpaired electrons in d-orbital, which


undergoes d-d transition by absorption of energy from visible
region and then the emitted light shows complementary
colours.

(d) Mn3+ is less stable than Cr3+

(e) Due to lanthanoid contraction in second series after


lanthanum

(f) This is due to comparable energies of 5f 6d and 7s orbitals in


actinoids.

(g) The catalytic properties of the transition elements are due to


the presence of unpaired electrons in their incomplete d-orbitals
and variable oxidation states.

Q.33 (a) A = CH3 CH2CN ( Propane nitrile ) 5 (3+1+1)

B = CH3 CH2 CH2NH2 ( Propanamine)

C = CH3 CH2 CH2NHOC CH3( N-Propylethanamide )

(b) Due to formation of anilinium ion

(c) C2H5NH2< C6H5CH2NH2<NH3<C6H5NH2

OR

(a) A = CH3NH2 ( Propane nitrile )

B = CH3 NC ( Methane isonitile)

C = CH3 NH CH3( N-Metylmethanamine )


(b) due to formation of salt with aluminium chloride, the Lewis
acid.
(c)C6H5NH2< (C2H5)2NH < C2H5NH
-:The End:-

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