SAFETY DATA SHEET

Section 1. Identification of the material and the supplier

Product: Alteco Superglue

Product Use: Adhesive
Restriction of Use: Refer to Section 15

New Zealand Supplier: Hobeca Trading Co Ltd

Address: 25 Andrew Baxter Drive
Auckland, 2022
New Zealand

Telephone: +64 9 249 0499

Emergency No: 0800 764 766 (National Poison Centre)

Manufacturer: Alteco Chemical Pte Ltd

19 Tuas Avenue 11
Singapore 639084 SINGAPORE
Telephone: +65 6862 0377

Date of SDS Preparation: 6 October 2020

Section 2. Hazards Identification

This substance is hazardous according to the EPA Hazardous Substances

(Classification) Notice 2017

EPA Approval No: Surface Coatings and Colourants (subsidiary) - HSR002670

Pictograms

Irritant

Signal Word: Warning

HSNO
Hazard Code Hazard Statement GHS Category
Classification
6.1E (Resp) H335 May cause respiratory irritation. STOT SE 3
6.3A H315 Causes skin irritation. Skin Irrit. 2
6.4A H319 Causes serious eye irritation. Eye Irrit. 2A
9.1D H401 Toxic to aquatic life. Aquatic Acute 2

Prevention Code Prevention Statement

P103 Read label before use.
P261 Avoid breathing fumes, vapours or spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
Product Name: SG SDS Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 6 October 2020 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 1
 P273 Avoid release to the environment.
P280 Wear protective clothing as detailed in Section 8.

Response Code Response Statement

P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P362 Take off contaminated clothing and wash before re-use.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position
comfortable for breathing.
P305 + IF IN EYES: Rinse cautiously with water for several minutes. Remove
P351+P338 contact lenses, if present and easy to do. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.

Storage Code Storage Statement

P405 Store locked up.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal Code Disposal Statement

P501 Triple rinse container before disposal or crush or puncture to prevent
reuse.

Section 3. Composition / Information on Ingredients

Ingredients Wt% CAS NUMBER.

Ethyl 2-Cyanoacrylate 85-95 7085-85-0
Polymethyl methacrylate 1-15 9011-14-7
Hydroquinone 0.1-0.9 123-31-9

Section 4. First Aid Measures

Routes of Exposure:

If in Eyes Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice.

If on Skin Take off contaminated clothing and wash before re-use. Rinse with soap
and water. Wash off hardened remains with warm water. If skin irritation
occurs: Get medical advice/ attention.

If Swallowed If product is swallowed or gets in mouth, do NOT induce vomiting; wash

mouth with water. Seek medical advice if needed.

If Inhaled Remove person to fresh air. Remove contaminated clothing and loosen
remaining clothing. Allow person to assume most comfortable position
and keep warm. Keep at rest until fully recovered. Get medical advice if
breathing becomes difficult.

Most important symptoms and effects, both acute and delayed

Symptoms:
Swallowed: Not applicable.
Inhaled: May cause respiratory irritation. Cough.
Skin: Causes skin irritation and redness.
Eye: Causes severe eye irritation.

Product Name: SG SDS Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 6 October 2020 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 2
Section 5. Fire Fighting Measures

Hazard Type Non Flammable.

Hazards from Carbon oxides. Nitrogen oxide, Organic vapor.
products
Suitable Carbon dioxide. Sand. Do not use water.
Extinguishing
media
Precautions for Firefighters should wear positive pressure for Firefighter self-contained
firefighters and breathing apparatus.
special protective
clothing
HAZCHEM CODE None allocated

Section 6. Accidental Release Measures

Wear protective protection as detailed in Section 8. Evacuate all non-essential personnel.

Ensure adequate ventilation. Don’t let product enter drains.

Don’t use clothes. Pick up with absorbent materials. Dispose of according to Section 13.

Section 7. Handling and Storage

Precautions for Handling:

• Read label before use.
• Avoid breathing fumes, vapours or spray.
• Avoid spillage.
• Wash hands thoroughly after handling.
• Use only outdoors or in a well-ventilated area.
• Avoid release to the environment.
• Wear protective clothing as detailed in Section 8.

Precautions for Storage:

• Store away from incompatible materials listed in Section 10.
• Store locked up.
• Store in a well-ventilated place. Keep container tightly closed.
• Keep container closed at 2 - 30°C.

Section 8 Exposure Controls / Personal Protection

WORKPLACE EXPOSURE STANDARDS (provided for guidance only)

TWA STEL
Substance Cas No ppm mg/m3 ppm mg/m3

Hydroquinone [123-31-9] - 2 - -

Workplace Exposure Standard – Time Weighted Average (WES-TWA). The time-weighted average exposure standard
designed to protect the worker from the effects of long-term exposure. Workplace Exposure Standard – Short-Term
Exposure Limit (WESSTEL). The 15-minute average exposure standard. Applies to any 15- Minute period in the working
day and is designed to protect the worker against adverse effects of irritation, chronic or irreversible tissue change, or
narcosis that may increase the likelihood of accidents. The WES-STEL is not an alternative to the WES-TWA; both the
short-term and time-weighted average exposures apply. Workplace Exposure Standards and Biological Exposure
Indices NOV 2019 11TH EDITION.

Engineering Controls
Ensure adequate ventilation is available.

Personal Protection Equipment:

Product Name: SG SDS Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 6 October 2020 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 3
Eyes Wear safety goggles.
Hands and Wear waterproof gloves and protective clothes. Polyethylene, polypropylene
Skin and nitrile rubber gloves are recommended. Natural rubber, cotton and
nylon gloves are not recommended.
Respiratory General (mechanical) room ventilation is expected to be satisfactory.

Section 9 Physical and Chemical Properties

Appearance Clear to Slight Yellowish Liquid

Odour Irritating.
Odour Threshold Not applicable
pH 6-7 at 25°C
Boiling Point 54°C (3 mmHg)
Melting Point Not available
Freezing Point Not applicable
Flash Point 92°C
Flammability Non Flammable
Upper and Lower Not available
Exposure Limits
Vapour Pressure 186 mmHg at 125°C
Vapour Density Not applicable
Density 1.06 ± 0.02 g/cm3 at 25°C
Water Solubility Polymerized.
Partition Coefficient: Not applicable
Auto-ignition Not available
Temperature
Decomposition Not applicable
Temperature
Viscosity Not applicable
Particle Characteristics Not applicable

Section 10. Stability and Reactivity

Stability of Substance Stable under recommended storage and handling conditions.

Reactivity Rapid exothermic polymerization will occur in the presence of
water, amine, alkalis and alcohols.
Conditions to Avoid Extreme temperatures, moisture
Incompatible Materials Fast polymerization will occur in the presence of water, amine,
alkalis and alcohols.
Hazardous Decomposition No dangerous decomposition products known.
Products

Section 11 Toxicological Information

Acute Effects:

Swallowed Not applicable.

Dermal Not applicable.
Inhalation May cause respiratory irritation.
Eye Causes severe eye irritation.
Skin Causes skin irritation.

Chronic Effects:

Product Name: SG SDS Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 6 October 2020 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 4
Carcinogenicity Not applicable.
Reproductive Not applicable.
Toxicity
Germ Cell Not applicable.
Mutagenicity
Aspiration Not applicable.
STOT/SE Not applicable.
STOT/RE Not applicable.

Individual component information:

Acute Toxicity:
Chemical Name Oral – LD50 Dermal – LD50 Inhalation – LC50
Ethyl cyanoacrylate >5000 mg/kg >2000 mg/kg (rabbit) -
(7085-85-0) (rat)
Hydroquinone 593 mg/kg (rat) - -
(123-31-9)

Section 12. Ecotoxicological Information

HSNO Classes: 9.1D = Harmful to aquatic life.

Persistence and No data available

degradability
Bioaccumulation No data available
Mobility in Soil No data available
Other adverse effects No data available

Toxicity for individual components:

Aquatic toxicity: Hydroquinone LC50 (fish): 0.044mg/L (IUCLD(1995))

Do not allow to enter waterways.

Section 13. Disposal Considerations

Disposal Method:
Dispose of container through approved landfill. Unwanted product should be disposed of
according to local regulations. Contact supplier for guidance if unsure.

Precautions or methods to avoid: None known.

Section 14 Transport Information

This product is NOT classified as a Dangerous Good for transport in NZ ; NZS

5433:2012

Section 15 Regulatory Information

EPA Approval No: Surface Coatings and Colourants (subsidiary) - HSR002670

HSNO Classification: 6.1E(resp), 6.3A, 6.4A, 9.1D

HSW (HS) Regulations 2017 and EPA Notices Trigger Quantity

Certified Handler Not required
Location Certificate Not required
Tracking Trigger Quantities Not required
Signage Trigger Quantities 10 000L (9.1D)
Emergency Response Plan 10 000L (9.1D)
Secondary Containment 10 000L (9.1D)
Restriction of Use Only use for the intended purpose.

Product Name: SG SDS Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 6 October 2020 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 5
Section 16 Other Information

Glossary
EC50 Median effective concentration.
EEL Environmental Exposure Limit.
EPA Environmental Protection Authority
HSNO Hazardous Substances and New Organisms.
HSW Health and Safety at Work.
LC50 Lethal concentration that will kill 50% of the test organisms
inhaling or ingesting it.
LD50 Lethal dose to kill 50% of test animals/organisms.
LEL Lower explosive level.
OSHA American Occupational Safety and Health Administration.
TEL Tolerable Exposure Limit.
TLV Threshold Limit Value-an exposure limit set by responsible
authority.
UEL Upper Explosive Level
WES Workplace Exposure Limit

References:
1. EPA Hazardous Substances (Safety Data Sheets) Notice 2017
2. Workplace Exposure Standards and Biological Exposure Indices Nov 2017 edition.
3. Assigning a hazardous substance to a HSNO Approval (Aug 2013).
4. Transport of Dangerous goods on land NZS 5433:2012
5. HSW (Hazardous Substances) Regulations 2017

Disclaimer
This document has been prepared by TCC (NZ) Ltd and serves as the suppliers Safety Data
Sheet ('SDS'). It is based on information concerning the product which has been provided to
TCC (NZ) Ltd or obtained from third party sources and is believed to represent the current state
of knowledge as to the appropriate safety and handling precautions for the product at the time
of issue. Further clarification regarding any aspect of the product should be obtained directly
from the manufacturer. While TCC (NZ) have taken all due care to include accurate and up-to-
date information in this SDS, it does not provide any warranty as to accuracy or completeness.
As far as lawfully possible, TCC (NZ) Ltd accept no liability for any loss, injury or damage
(including consequential loss) which may be suffered or incurred by any person as a
consequence of their reliance on the information contained in this SDS
The information herein is given in good faith, but no warranty, express or implied is made.
Please contact the New Zealand distributor, if further information is required.
Issue Date: 6 October 2020 Review Date: 6 October 2025

Product Name: SG SDS Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 6 October 2020 Tel: 64 9 475 5240 www.techcomp.co.nz
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