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    Revision Capsule - Chemistry PDF

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    pytr
    This document provides a summary of key concepts in physical chemistry. It defines common physical chemistry terms like molecular mass, empirical formula, and electron energy levels. It also summarizes concepts like Heisenberg's uncertainty principle, molecular orbital theory, and relative bond strengths. Formal charge and Fajan's rule for determining ionic character are defined. Finally, the document outlines equations for calculating properties like electron kinetic energy, electron potential energy, and electron shell energies.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Revision Capsule - Chemistry PDF

    Uploaded by

    pytr
    784 views8 pages
    This document provides a summary of key concepts in physical chemistry. It defines common physical chemistry terms like molecular mass, empirical formula, and electron energy levels. It also summarizes concepts like Heisenberg's uncertainty principle, molecular orbital theory, and relative bond strengths. Formal charge and Fajan's rule for determining ionic character are defined. Finally, the document outlines equations for calculating properties like electron kinetic energy, electron potential energy, and electron shell energies.

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    Revision Capsule - Chemistry.pdf

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    This document provides a summary of key concepts in physical chemistry. It defines common physical chemistry terms like molecular mass, empirical formula, and electron energy levels. It also summarizes concepts like Heisenberg's uncertainty principle, molecular orbital theory, and relative bond strengths. Formal charge and Fajan's rule for determining ionic character are defined. Finally, the document outlines equations for calculating properties like electron kinetic energy, electron potential energy, and electron shell energies.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    784 views8 pages

    Revision Capsule - Chemistry PDF

    Uploaded by

    pytr
    This document provides a summary of key concepts in physical chemistry. It defines common physical chemistry terms like molecular mass, empirical formula, and electron energy levels. It also summarizes concepts like Heisenberg's uncertainty principle, molecular orbital theory, and relative bond strengths. Formal charge and Fajan's rule for determining ionic character are defined. Finally, the document outlines equations for calculating properties like electron kinetic energy, electron potential energy, and electron shell energies.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 8

    I REVISION CAPSULE - CHEMISTRY

    I
    PHYSICAL CHEMISTRY

    Multiplied by 0
    Amountofa ----....-----r-­ Number
    0 substance
    (in gram)
    Mo 1 arm ass of
    entities
    he
    E = hv = -

    Volume ofg as (in L) at STP


    A= h
    O Molecular mass
    ✓2mxK.E.
    No. ofspectral lines produced when an electron drops from
    Average relative mass of one molecule
    n(n-1)
    1 n th level to ground level = - --
    - x mass of C-12 atom 2
    12 Heisenberg's Uncertainty Principle (rue) (�p) � h/4rc
    0
    O Molecular mass = 2 xVD Nodes (n - 1) = total nodes,£ = angular nodes,
    O Eq. wt. ofmetal
    0
    (n - £ - 1) = Radial nodes
    wt. of metal
    - - - - - X1.008 Orbital angular momentum : -J£ (£ + l) !.!___ = ,J£(£ + l)h
    -
    wt. of H 2 displaced 0 2rc
    O (i) % ionic character
    wt. of metal
    0 Eq. wt. ofmetal =
    . x8 Actual dipole moment
    wt. of oxygen combmed x100
    Calculated dipole moment
    wt. of metal
    x 35_5 (ii) Dipole moment is helpfu l in
    wt. of chlorine combined
    predicting geometry and polarity
    0 Molecular formula = (Empirical formula)n ofmolecule.
    Energy ofelectron in species with one Fajan's Rule: Following factors are helpful in increasing
    electron. 0
    covalent character in ionic compounds
    -2rc 2 me-4Z 2
    En =-- 2 - (i) Small cation (ii) Big anion
    ATOMIC n h2 (iii) High charge on cation/anion
    STRUCTURE For energy in SI system, (iv) Cation having pseudo inert gas configuration (ns2 p6d 10 )
    -2rc 2 me4 Z 2 e.g. Cu+,Ag+,zn +2 ,Cd+2
    En
    n 2 h 2 (4rci:o) 2
    =
    0 M.O. theory:
    2 (i) Bond order = ½(Nb-Na)
    En = -13\2Z kJ mol-1 (ii) Higher the bond order, higher is the bond dissociation
    n energy,greater is the stability,shorter is the bond length.
    nh Formal charge (F.C.) on an atom in a Lewis structure
    mvr = - 0
    2rc = [total number of valence electrons in the free atoms]

    - [total number ofnon-binding (lone pair) electrons]


    n 2 h2 2
    r= =o.529 [ �) A
    4rc mZe
    2 2
    Z - _!_ [total number ofbonding (shared) electrons]
    Total energy ofelectron in the nth shell 2
    0 Relative bond strength: sp3 d2 >dsp 2 >sp3 >sp 2 >sp >p-p
    e 2 ( kZe 2 1 kZe 2 0
    = K.E. + P.E. = kZ- + 1--j = -- (Co-axial)> s - p> s - s> p - p (Co-lateral)
    2rn \ rn 2rn

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    1
    ;_1e_�_1a_y�l 2
    0

    ;_�_
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