Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                

코레츠키 화공열역학 2판 솔루션 ch2

Download as pdf or txt
Download as pdf or txt
You are on page 1of 136

1

T T Tv TT T T

2
) )
2
TP Tv
))) 2 q q
q
TP
T P

3
3

4
4
2

5
5

6
6

7
7

8
8
) )

)))
) ) TP Tv
) )
) )
))
) )
) )

9
9
) ) q 0

)))
) )
) ) u

0
11

E T W W

W F Tx xxTx xx 2
2
:

E xx 2
2

x
1

U W

2
13

3
14

:T

+
W

U T W

T  W

T
: W

Wrrrr Wtqut

    

Trrrr Ttqut
U rrrr Trrrr Wrrrr U tqut Ttqut Wtqut
Trrrr Ttqut

4
15

: :

T T
:

:
W

 

P T 2
U

U T W 0

T W

T 2 W

W :

5
16

6
17

) )

Pv 

)))

7
18

mH 2 O 05

q q

2 28

T 25 º 298 5 K

v l
q qH O
qH O
2 2

v
qH O P 0 T 298 5 K
2

l
qH P 0 T 298 5 K
2O

rrrrrr  rrrrr
mmmmm
]]]]]]]

q q3

P
aamamaam
q2

rrrrrr rrrrr

q q q2 q3
qHl trt
2O
25 º q l
H 2O 25 º 0 qHv 2trt
O 25 º qHl trt
2O
25 º
qHv 2O 25 º 0 qHv 2trt
O 25 º

8
:

v l
q qH O
25 º 3 7 qH O
25 º 3 7
2 2

v trt J
qH O
2547 2 :2T 25 º
2

l trt J
qH O
04 87 :2T 25 º
2

J
q 2442 3

J
T 05 2442 3 22 2 J

30 208 20
200

W ttt 30 208 200 7488 J

T 22 2 J
00 % 00 % 6 3%
W 7488 J

9
19
3
v xv v x vl 0 373

J
u xu v x u l 355

3
v2 v 0 373

w 0

T2 v2

P2 0

J
u2 3 92

J
q u2 u 838

20
1) )

)))
3
v 79

J
v v P T 20 u3 2 537 3

P2 3 05
J
w 6 7 05
gg
2
J
q 780
gg

2
2 28

H T

H T m q

3
L 0 00
t L
m 0
v 3
0 00 0

22

J J J
u ul 2 00 ul 25 4 9 02 04 87 3 4 5

J
T m u 0 3 4 05 3 4 5 J

T 3 4 5 J
T 0 52
t 60
0

22
3

) )

J
u 2967 8 00 400 º

J
u 2 2659 8 50 200 º

J
u u 2 u 308 0

)))

T2 T2
u u2 u Tv TT TP R TT
T T

TP R A TT TT 2 TT 2 ET 3
T2
u R A TT TT 2 TT 2 ET 3 TT
T

T 2 T E
u R A T2 T T2 T 2 T23 T 3 T T2 4 T 4
2 3 T2 T 4

A 3 470
T 45 0 3
T 0
T 2 04
E 0

23
J
R 83 4
K
T 400 273 5 K 673 5 K
T2 200 273 5 K 473 5 K

J
u 555

J [ : 2 T] 000 J J
u 555 308
8 0 48 [ : 2 T] 000 J

308 308
%TeeeereTTe 00 % 0 03%
308 0

24
4
) )

2 3

U T W

)))
24

U 0

2 38

P2 P2
W TRT T RT
P P

T RT Pt
P2
W Pt
P

5
W 8 05 25 0 3 3
8
W 940 J

0J T W
T 940 J

) )

T 0

U W

25
U 0
T2
U T Tv T 0
T
T2 T
T2 30 º

26
5

) )

] ammhmB
a

Pm]]m]]

am
mh
2

A
2
m

3a3m 3a32 3a3a


r ]m a]m]]]

24

u 0

q 0

u q w 0

2 38

P2
W TRT
P

W P2
w RT
T P

27
J
w 83 4 88 273 5 K
K 3
J
w 3299

J
q w 3299

)))

u q

u 0
q 0

w PE Tv

w PE Tv PE v 2 v

v2 v

J
83 4 88 273 5 K 3
RT2 K
v2 0 030
P2 05
J
83 4 88 273 5 K 3
RT K
v 00 0
P 3 05

PE P

28
3 3
w 3 05 0 030 00 0

J
w 6000

u q w 0
J
q w 6000

29
6

U T

2 26

T2
T T Tv TT
T

T2
T T T P TT
T

5
T 85 3
0 02698

23

323 5 K
J
T 85 3 83 4 2 486 49 0 3 T TT
K 294 5 K

T 3 6 J

30
7

U T W

26

t2
W PE Tt
t

W PE t2 t

3
v 0 0264 0 400 º

3
3
t m v 3 0 0264 0 07923

t2 v2

W 748740 J
t2 t 0 07923 3 0 4536 3
PE 6
20 0
3 3
t2 0 4536
v2 0 5 2
m2 3

v2 P2 2

3
T2 400 º 20 0 5 2

U T

3
3
J
u 2 2945 2 20 0 5 2

J
u 2832 4 00 400 º

J J
U m u 2 u 3 2945 2 2832 4 338 4 J

U W

T U W
T 338400 [J] 748740 J 09 06 J

32
8

U W

T T2
L T T T2

T2 t2
T Tv TT PE Tt
T t

Tv PE

TTv T2 T PE t2 t

t2 T

TRT2
t2
P2
Pt
T
TR

PE P2

5
P2 P t
2
T2
7
TR
2

33
P 2
P2
t 0 L
T 0
L
R 0 083 4
K

T2 206 K

W U TTv T2 T

Pt 2 0 L
T 24 K
TR L
0 083 4
K

W 727 J

34
9

23

U W

W P2t2 Pt
x

2 27

P 2
t 0 L
P2

W t2
2 48

Pt x TtTtt

P x x
t2 t
P2

TP 7
x
Tv 5

t2 64 L

W 9 L 900 J

U 900 J

35
2 26

T2
U T Tv TT
T

Tv

5
U T R T2 T
2

P t

T 240 6 K

T2 97 3 K

36
30

u 0

u 2 u

J
u 26 9 2 200 400 º

J
u 2 26 9 2

u 2 P2

J
T2 327 5 º 00 u 2 26 9 2

3
v2 0 020 2

3
3
tvettel mv2 0 0 020 2 0 020

37
31

u 0

T2 T 0
T2 T 300 K

T T2
Pt P2t2

t2 2t

P
P2 5
2

38
3

    5

P At A
TA 04
RT A
P Tt T
TT 20 5T A
RT T

U 0 UA UT
0 T ATv T2 A T A T T Tv T2 T T T
0 T2 A T A 5 T2 T T T
T2 A 5T2 T T A 5T T

2
P2 A P2 T P2

3 T A RT2 A T T RT2 T T AR
tT 0 02 T2 A 5T2 T
P2 P2 P2

T AR T AR
P2 T2 A 5T2 T T A 5T T 300
tT tT

39
T2 A 5T2 T T A 5T T TtTtt

T2 A 5 T2 T

TATv TTA PE Tt PT TtA

t T
TT TT RTT
TATv TTA Tv 5TTT TtA
5 0 02 tA

Tv TTT tA
R TT 0 02 tA

32 2
T2 T 0 02 t2 A
300 00

32 2
T2 T
t2 A 0 02 0 0
300

322
T2 T T T RT2 T
t2 T 0 02 t2 A 00
300 P2

2 244 6 K
2 577 2 K

3
2 0 0 36
3
2 0 0064

40
33

U T

u J
Tv 2 75
T v K

) )

T2 T
Tv T2 T Pext v2 v RPext
P2 P

T2

T2 422 K

)))

T2 T J
w Pext v2 v RPext 3 200
P2 P

4
34

25
T8 H 8 l O2 g 8TO2 g 9 H 2O g
2

) )
T
T2

T2v
P2 P
Tv
T1 50%
TtT e 88
25
TO2 5 88 64 2
2
0 79
TN2 64 2 6 7 7
02
Tv 78 9

2
25
TO2 0 5 8 8 55
2
TN2 6 77
TTO2 8 88 70 4
TH 2O 9 88 79 2
T2v 822 0

:
T2v
P2 P 05
Tv

)))

T RT
T U H rxT Pt TT8 H 8 qrxT P2 P
P

H rxT 00 298 K

42
25
qrxT 298 e qte 9 qte 9 qte q te qte
e TO2 H2O T8 H 8 2 O2

J
5 22
T8 H 8

00 2 7

T 46 000 J

43
35

25
T8 H 8 l O2 g 8TO2 g 9 H 2O g
2

7
T8 H 8 l O2 g 8TO g 9 H 2O g
2

4
t 88 70 tt 88 8
5 5

) )
T
T2

T2v
P2 P
Tv
T1 50%
TtT e 88
25
TO2 5 88 64 2
2
0 79
TN2 64 2 6 7 7
02
Tv 78 9

2
25 7
TO2 64 2 05 t 05 tt 6 7
2 2
TN2 6 77
TTO2 8 t 56
TTO 8 tt 4
TH 2O 9 t 9 tt 79
T2v 828 2

:
T2v
P2 P 06
Tv

44
)))

T RT
T U H rxT Pt t qrxT t tt qrxT tt P2 P
P

H rxT 00 298 K

25
qrxT t 298 e qte 9 qte 9 qte qte qte
e TO2 H 2O T8 H 8 2 O2

J
5 22
T8 H 8

qrxT tt 298 e qte 9 qte 9 qte qte


e TO H 2O T8 H 8

J
2 960
T8 H 8

00 2 7

T 42 000 J

45
38
) )

U T W

Pv 5 TtTtt

v2

P 5
v2 v 5
P2

P 20
3 3
0
v 0
0
P2 00

3
v2 0 0342

T2 524 7 K
J
u 2 3094 6

26

46
t2
W PE Tt
t

v 2
w PE Tv
v

Pv 5 P v 5 TtTtt

v 2 v 2
P v 5 5
w Tv P v Tv
5 5
v v v v

3
J
w 2 840 284

J
W 0 284 2840 J

2
m33
Pm]]m]]

03

]
23 k]]a

3a32 3a30 3am3


r ]m a ]a]]

47
T U

J J
U m u 2 u 0 3094 6 2602 8 49 8 J

T U W 49 8 J 2840 J 2078 J

)))
U

v 2
W mPE Tv
v

PE P2

W 6580 J

2
m33
Pm]]m]]

k]]a
03

]
23

3a32 3a30 3am3


r ]m a ]a]]

48
T

T U W 49 8 J 6580 J 662 J

) )

U W

W U 49 8 J

 

ve
5
W m P2 v2 ve P v Tv 49 8000 J
5
v v

ve

3
ve 0 078

5
v
Pe P
ve
Pe 29 0

49
Pe ve Pvv

2
m33

Pm]]m]]
03 k]]a

i
]
23

3a32 3a30 3am3


r ]m a ]a]]

00

W m Pe ve v P2 v2 ve 49 8000 J

5
v
Pe P
ve

v e:

5
v
W m P ve v P2 v 2 ve 49 8000 J
ve

ve

3
ve 0 043

50
Pe 70 8

2
Pm]]m]] m33

i
03

k]]a ]
23

3a32 3a30 3am3


r ]m a ]a]]

3
ve 0 0762

Pe 30 0

2
m33
Pm]]m]]

03

k]]a ]
23

3a32 3a30 3am3


r ]m a ]a]]

5
39

) )

Fgg]gg]PaP FmmmPammmA

nnn]nn

FmmggPm]
F]mgPa]mgA

mg xx
Pgrt Prtm A A

txAx
mg x t
Pgrt Prtm A A2

5 5 2040 98 2 2 x 0 02 3
2 0 0
2 2 2
0 0

x 50 04

mg x t
WA Prtm A Tt
A2
te te
mg x t
WA Prtm Tt T t
A 2
te te A
3 2
5 2 50 04 2 0 02 02
WA 3 00 0 0 03 0 05
2 2 2
0

52
WA 5 03 J

3a5aJ
-W P m3gssm]sg gssm]s P 5 aJ
a
k V
Pm]]m]]

2
A

2
gg
2 A
k]]a

]
m

ammm

3a3m 3a3a 3a35


mm]ma ]

)))

T T
Pe te 05 0 03 3
T 35
Pe te 2 05 0 05 3

t 0 0385 3

53
t te
WT Pgrt Tt PgrtTt
te t

t t te t ee
5 6 5
WT 2 0 2 Tt 5 0 5 tT t 3 0 2 Tt 5 06 5 tT t
te te t t

WT 3 85 J

a
Pm]]m]]

2 gg
2 A

gg
A

]
m
k]]a
ammm

3a3m 3a3a 3a35


mm]ma]

) )

Pt

te te
TtTtt
WT rev Pgrt Tt Tt
35
te te t

54
35
TtTtt 05 0 05 3
75 03

2800 J

Pm]]m]]

2
2

]
m
k]]a]sv
ammm

3a3m 3a3a 3a35


mm]ma]

55
40

  2
 

200 º

3
v l e 0 00 56

3
v v e 0 2736

J 200 º
u l e 850 64

J
u v e 2595 3

P trt 553 8

t 0 05m v l e 0 95m v v e

3
t 05

m 4 3

mv 0 95m 3 92
ml 0 05m 0 207

P T

56
3
v2 e 0 35202
600 200 º
J
u 2 e 2638 9

t2
m2 0 284
v2

553 8

600 200 º


J
u e u 2 e 2638 9 600 200 º

U m2 mv e m l e u e m2 u 2 e m v e u v e m l e u l e

U 54 0 J

600
26

te
W PE Tt PE t e te
te

PE 600000
te m2 mv e m l e v2 e 55 3

3 3 3
te 0 05 06

57
v2 e te

W 570 J

T.

T U W 54 0 J 570 J J

58
41

A A
0 20 2 2

700 250 2 2
:2 T :2 T
:2 T :2 T

50 0

p 0[ ] 20 [ ]
T 700 [ ] 250 [ ]
v 0 44779 [ 32 ] 0 44 [ 32 ]
u 3475 35 [ J2 ] 2679 58 [ J2 ]
3
t 00 0 05 3
t
m 0 [ ] 0 090 [ ]
v

t A t T 3 3
0 06
v2 0 30
m A m T 0 20

2 Tx0
Wx0

U T W 0

U2 U m A u A m Tu T

U2 m Au A m Tu T J
u2 3 2
m2 m A m T

u2 v2

T2 500 [ ] P2 200 [ ]

59
3
t2 A v 2 A m2 A 0 30 0 09 0 267

x 0 267 0 0 67

60
4

5
T1

2
T2
P2 0

T1 278 K
P1 3

2
T2

u w

Tv T2 T PE Tv PE v2 v

Tv TP R T2

T2 T P2T
Tv T2 T PE R R T2
P2 P P

P2
PE

R RP2
T2 T
Tv Tv P

RP2 Tv
T2 T 237 K
Tv P T P

6
43

W P t

4 3 4 3
t r 05 54 3 0 0436 3
3 3

W 0 325 05 0 0436 3
0 3
44 7 J

62
44

) )

3
vT 0 003 55

3
t 00
m 3 7
vT 3
0 003 55

)))

t ml v l m v v v x m v l xm v v

3
v v 6940

3
:2T
l
v 0 00 043

x 0 00 25

0 25%

) )

U T

63
U mu 2 x m u l xm u v

J
u 2 2029 58 :2T
3
u l 4 7 33

3
:2T
v
u 2506

U 5 02 6 J 5 0 06 J

64
45

) )
:

Tu
q
Tt

TU

Tv TT
q T Tturr
Tt

Tv

Tv T Tturr qt T

q
t
Tv
T Tturr Te

T1

T3
ee]eee]]eee

Tgs]]
]n]e

65
)))
L 6 6
22 º

q
t
Tv
T Tturr Te
22 º 2º Te0
T 20 º

0 t 4 2º

q
4
Tv
2º 2º 20 º e
q
0 73
Tv

6 t 2

T 4 5º

66
46
rtt rlrTTe

Tm
meT mtut meT
Tt

m2 t
Tm meT Tt
m 0

t
m2 m meT Tt
0

ETerg rlrTTe

TU
mtut qtut meT qeT T Wt
Tt t t tut eT

TU
meT qeT
Tt t t

U2 t t
TU meT qeT Tt qeT meT Tt
U 0 0

U2 U m 2 u 2 m u m2 m qeT

m2 m

67
t
m2
v2
t
m
v

u 2 qeT u qeT
0
v2 v

J
u 2583 6

3 :2T
v 0 9444

J
qeT 3 77 2 6 400 º

T 600 º 4427 6
T 500 º 375 9
T 450 º 558 6

500 º 450 º

T2 464 4 º

68
47
295 K

TeT T 295 K

rtt rlrTTe

TT
TeT Ttut TeT
Tt

T2 t
TT TeT Tt
T 0

t
T2 T TeT Tt
0

ETerg rlrTTe
xe pe

TU
TeT qeT Ttut qtut T W
Tt t t

TU
TeT qeT
Tt t t

0
50

U2 t t
TU TeT qeT Tt qeT TeT Tt
U 0 0

T2u2 T u T2 T qeT

69
T2 u 2 T u T2 T qeT

T2 u 2 qeT T u qeT

qeT ueT PeT veT ueT RTeT u RT

T2 u 2 u T2 RT T u u T RT

T2 Tv T2 T T2 RT T RT

3
Tv TP R R
2

3
T2 T2 T T2T TT
2

3T2T2 5T2T 2T T

T1

T T
3 2 T2 5 2 T 2T
T T

T2 P2T
T P T2

P2T P2T
3 T2 5 T 2T
P T2 P T2

70
P2T
5
P
T2 434 [K]
P
3 2 2
P

)))

u q w q

Tv 5R J
u T2 T T2 T 28 9
W 2 W

J
q 28 9

) ) P2T2 P3T3
P2T2
P3 34
T3

7
48
rtt rlrTTe

TT
TeT Ttut TeT
Tt

T2 t
TT TeT Tt
T 0 0

t
T2 TeT Tt
0

ETerg rlrTTe
xe pe

TU
TeT qeT Ttut qtut T W
Tt t t

TU
TeT qeT W
Tt t t

U2 t t t
TU TeT qeT Tt W Tt qeT TeT Tt W qeT T2 W
U 0 0 0

W T2 Pext v2 v T2 Pext v2

72
T2u 2 T2 qeT Pext v2

u2 qeT Pext v2 ueT PeT veT Pext v2

u 2 ueT PeT veT Pext v2

P T
Tv T2 TeT RTeT R ext 2
P2

Tv R
T2 TeT 333 K
Pext
Tv R
P2

73
49
vm]vsmmmggmmgggm
g]sggs]smggmgmgmsm
t]ggmmgm

r
Tm mPm233m]C
xmmPm3a4
VmPm3a3mmma

rtt rlrTTe

Tm
meT mtut mtut
Tt

m2 t
Tm mtut Tt
m 0

t
m2 m mtut Tt
0

ETerg rlrTTe

TU
mtut qtut T
Tt t t

m 2 u 2 t t t
TU mtut qtut T Tt qtut mtut Tt TTt
m u 0 0 0

T m2u2 m u m2 m qtut

74
2

3
v x v e xvg 0 6 00 0 4 0 274 0 05

3
v2 0 274

3
t 00
m 3
0 96
v
0 05

3
t2 00
m2 3
0 0785
v2
0 274

m2 m 0 75

J
u x u e xu g 0 6 850 64 0 4 2597 5 549

J
u 2 2595 3

J
qtut 2793 2

T m2u2 m u m2 m qtut 228 J

75
50

rtt rlrTTe

Tm
meT mtut meT
Tt

m2 t
Tm meT Tt
m 0

t
m2 m meT Tt
0

ETerg rlrTTe

TU
mtut qtut meT qeT T Wt
Tt t t tut eT

TU
meT qeT
Tt t t

U2 t t
TU meT qeT Tt qeT meT Tt
U 0 0 0

U2 m2 u 2 m2 qeT

u 2 qeT

76
J
u 2 3632 5 9 800 º

J
qeT 3632 5

qeT 9

TeT 600 º

77
5

Ttut q ex ep tut TeT q ex ep eT T Wt


tut eT

q2 q

q q T

T2 T 25

78
53

m]]
nm m3m
g

J
q3 32 3 5

J grrrrr ? 3
q4 280 4 v3 0 0734

TTO2 q2 q mH 2O q4 q3

TTO2 TP T
mH 2O 0 6
q4 q3

L
t3 mH 2O v3 6

79
54
) )

T2 T T

Ttut q ex ep tut TeT q ex ep eT T Wt


tut eT

Wt T q2 q T TP T 25

)))

Wt T q2 q T

T 0

80
55
) )

T2 T T

T T q2 q T TP T

Pt
T TP T2 T 9 030
RT
)))

Pt
T TP T 3 300
RT

) )

T 9 030+3 300 40 330

8
56

Ttut q ex ep tut TeT q ex ep eT T Wt


tut eT

T T2 q2 T3q3 T q T2 q2 q T3 q3 q

J
q3 q TPl T 52

T 43 273
J
q2 q TPl T q vrp TPv T 43 2
40 273 T

J J
T 6 52 4 43 2 320

82
57
) )

)))

J
qvrp qlv 2430 5

3 J
T 05 0 2430 5 20
60

83
58

) )

0 L

TU
T Wt
Tt t t

Wt T

U T Wt t

Wt 5
T
t 36000

U 44 000 J 44 J

)))

t
0

Eg Wrever

Wrever
L

84
Wt
Wrever
Wt 5
Wrever 0
05

Wrever

Eg 0000

m t22 t 2 0000
2

m 200

t2 0

t 0

85
59

Ttut q ex e p tut TeT q ex e p eT T Wt


tut eT

TeT T Ttut T2

Wt T2 q2 q eg 2 eg

q2 q 2 29 2

T2

q2 q T p TT R A TT TT 2 TT 2
ET 3 TT
T

ex 2 ex T

2 2
ex 2 ex W rer t2 t
2

P2t2 T2 RT2
P2t2
T2
RT2

2
T2 t2
t2
4

86
T2
P2 T2 2t2
Wt R A TT TT 2 TT 2 ET 3 TT W rer t2 2 t 2
RT2 4 2
T
2

W 4 84 06 [ ] 4 84 [ ]

87
60

30 20

00 50

0 Tq q2 T

T
q2 q
T

2
2
eTerl grt

Tp
424 4 394 0 3T 4 392 0 6T 2
R

T K

T2
T
q2 q 424 4 394 0 3T 4 392 0 6 T 2 TT
T
T

T J
5590
T

88
61

WÝt

350 308

600 32 2

Wt 2 T eg eP

T2 T2
Wt
q T p TT R 2 3 28 785 0 3 T 8 824 0 6 T 2 TT
T
T T

89
6

) )

T T2 q2 Tq

T2 T

T T q2 q

T2
T TR A TT TT 2 TT 2 ET 3 TT
T

A 3 376
T 0 557 0 3
T 0
T 0 03 05
E 0
J
R 83 4
K

T 20

T 373 5 K
T2 773 5 K

T 245063 245

90
)))

20 T

9
63

T2 q e g 2 T q eg 0

T T2

q2 q eg e g 2 t 2 t2 2
2

q2 q t2 2
2

J
q 2827 9 03 0 200 º

J
q2 2675 5 03 :2T 00

t2 552

At2
m
v2

92
3
v2 6940

A 3 07 0 3 2

93
64

T 2 q ex 2 T q ex 0

eg 2 eg

q2 q ex 2

T2
q2 q R A TT TT 2 TT 2 ET 3 TT W T 3 H 8 t22
2
T

A 2 3
T 28 785 0 3
T 8 824 0 6
T 0
E 0

J
R 83 4
K

W T3 H 8 0 044

T2

T2 4 92 K

94
65

T 2 q ex 2 T q ex 0

T T2

T2
T P TT W rer t2 2 t 2
2
T

Pt P At P2 A2t2
T T T2

A2,

P T2
t2 t
2 P2 T

T2 2
P T2
R A TT TT 2
TT 2 3
ET TT W rer t t2
2 2 P2 T
T

T2 38 K

38 K
t2 300 2
2 5 343 5 K

95
66

0 Tq T2 q2 Wt

T T2

Wt T q2 q

2 58 2

T2
Wt TR A TT TT 2 TT 2 ET 3 TT
T

A 3 355
3
T 0 575 0
T 0
T 600
E 0
T 50

T 300 K

T2. T2.

Pt x TtTtt

96
x x
T RT T RT
P P2 2 2
P P2
P xT x P2 x T2x

725 527
725
T2 300 K 579 K
725
0

Wt 4 74

97
67

) )

T T2 Ttut

Pt P2t2
Ttut
RT RT2

05 5 0 3 2 05 2 5 0 3
Ttut
8 3 4 373 5 8 3 4 293 5
Ttut 0 366 2

)))

0 TeT qeT Ttut qtut


eT tut
Ttut qtut Tq T2 q2 T qtut q T2 qtut q2 0

Ttut Ttut
3
TR 3 267 5 324 0 T TT T2 R 3 267 5 324 0 3 T TT 0
373 5 293 5

Ttut 329K

98
68

) )

67 0 8 3
2 3
2

Pt 0 35 0 5 67 0 8 3 2 7
T 7 45 0 2
RT 8 3 4 J2 K 273 5 K

7 45 0 7 2

)))
2
2

L x 2
Tt
Ttttrl
Tt
Ttttrl
x

H Tt qtut qeT T

T
Tt
T2
T P TT
T

99
T
Ttttrl
T2
x T P TT
T

T
vtttrl
T2
7 45 0 7 2
x T P TT
T

) )
:4 :4
2

T
T2
7 45 0 7 2 T2
x T P HeH 4 TT T P N 2 TT
vtttrl HeH 4 T T
FrTttr
vtttrl N 2 T2
T
T P HeH 4 TT
T2
7 45 0 7 2
x T P N 2 TT T
T

TP N 2
FrTttr
T P HeH 4

22 298 K

FrTttr 0 67

00
69
0

K
323 5 2592 6
]T]TnT]e
373 5 2687 5
423 5 2783 0333
473 5 2879 5 mmPm3a333aP
2
m7 mma024mPm7 m23a5aa
5333 2
523 5 2977 3 R mP mm

573 5 3076 5 4333

673 5 3279 5 a333

773 5 3489 1 s]gsgm


2333
873 5 3705 4 a ]]mam)1 s]gsgm)
m333
973 5 3928 7
073 5 4 59 3
3 533 m333 m533 2333
73 5 4396 4
e
273 5 4640 6
373 5 489 2
473 5 5 47 8
573 5 5409 7

Tq J J
TP 624 0 0006624T 3 5 6 0 00 434T R
TT P K K

35 6 0 00 434
3 470 0 00 450
% 3 4

0
70

Tq T2 q2

m q m2 q2

q q2

J
q 3398 3 8 500 º

J
q2 3398 3

q2 P2 T2 L

T2 457 º

02
71

) )
27
2 38

P2
W TRT
P

P2
w RT
P

J
R 83 4
K
T 300 K
P2 00
P 500

J
w 40 4

)))

R
w T2 T
x

5
TP R
2
3
Tv R
2

03
5
x
3

T2
2 48

Pt x TtTtt
Pv x TtTtt

RT
v
P
R P

x
P Tx TtTtt
x
P T x P2 x
T2 x

T2

T2 57 6 K

T2

J
w 775 9

04
7

) )

q q l 00 º q l 0º
u u l 00 º u l 0º


00º :
00 º 06 3

J
q l 00 º 4 9 02

J
q l 0º q l 0 6 3 00 º 0

J
u l 00 º 4 89

J
u l 0º u l 0 6 3 00 º 0

J
q 4 9 02

J
u 4 89

)))

q q v 00 º q l 00 º
u u v 00 º u l 00 º

05
J
q v 2676 0

J
ql 4 9 02

J
u v 2506 5

J
u l 4 89

J
q 2256 99

J
u 2087 59

5
5 39

06
73
T2 :3
2

TP
A TT TT 2 TT 2 ET 3
R

T 300 K

J
R 83 4
K

AvE 2

A T 03 T 06 T 0 5 E 09

T2 3 639 0 506 0 0 227 0


:3 3 5778 3 02 0 0 86 0

5
T P Ar R
2

T 300 K

J
T P Ar 20 785
K
J
T P O2 29 420
K
J
T P NH 3 35 560
K

07
T2

:3

3 22

08
74

2 28

T H

H m q2 q

J
q2 q 0 2584 6

J
q q 0 9 8

J J
T 2 2584 6 9 8

T 4785 6 J

te
W PE Tt
te

W PE m v2 v

3
v2 v 0 4 674

3
v v 0 0 00 0

09
3
W 0000 2 4 674 0 00 0 293 5 J

0
75

T U

m2 m

m ml mv

T m u 2 u m u 2 m l u l m v u v

J
u l 9 79
:2T 0
J
u v 2437 9

t2 t m l v l m v v v
v2
m2 m ml mv
3
v l 0 00 0 0

3
:2T 0
l
v 4 674

3
v2 335

J
u 2 25 4 6

T 652 J

2
76
L

H 0

e w

H me qe m w qw 0

me qe m w qw

3
tw 0 0004
mw 0 399
vw 3
0 00 003

mw 0 399
Tw 22 5
W H 2O
0 0 80 48

me
Te 5 55
W H 2O

 0
º

Te T P e 0 0º q eut TP w T e 0 ºT TwT P w T e 25 º

23

TP e 4 96 R
TP w 9 069 R

J
q eut 60

3
Te.

Te 3 2 º

)))

Te q eut
FrrTtetTlrteTt
Tw T P w T e Tw e
J
5 55 6000
FrrTtetTlrteTt 09
J
22 5 9 069 8 3 4 3 2º 25 º
K
PerTeTtlrteTt 9 %

4
77

T2 Tl Tv

U T

T Tl Tv u2 Tl u l Tvu v

0º 4 68

ul 0
uv u vrp 0 º
2

u2 u vrp 0 º TP R TT
273 K

T 2 T
2

RT2
P2
v2

v2 vv vl

3
RT
t Tv vv Tv 0 00485
P

3
t
v2 0 00243
Tl Tv

5
P2 T2

T
P trt A
T trt T

P trt P2 T trt T2

RT2 T
A
v2 T2 T

3
R 83 4 0 5
K

T2 30 7 K

u vrp

qvrp qv ql u Pv v u Pv l

vv vl

u vrp q vrp Pv v q vrp RT

J
u vrp 0 º 4 39

30 7 K
l v
T T T u vrp 0 º TP R TT Tl 0 T v uvrp 0 º
273 K

6
T 8 J

7
78
2 35

qrxT ve q e
e

298 K
3

) )

vTH 4 g
vO2 g
vTO2 g
vH 2O g

3 32

J
q e 298 74 8
TH 4 g

J
q e 298 0
O2 g

J
q e 298 393 5
TO2 g

J
q e 298 24 82
H 2O g

2 35

qrxT 298 vTH 4 g q e 298 vO2 g q e 298 vTO2 g q e 298 v H 2 O g q e 298


TH 4 g O2 g TO2 g H 2O g
J J J J
qrxT 298 74 8 0 393 5 24 82

J
qrxT 298 560 52

8
)))
J
qrxT 298 604 53

) )
J
qrxT 298 206 2

) )
J
qrxT 298 4 5

) )
J
qrxT 298 905 38

9
79

2:2 + 522 T2 2 T2 + :2T

) )

TT 2 H 2

298 K 2 35 3

qrxT ve q e
e
qrxT qe 2 5 qe 2 qe qe
T2 H 2 O2 TO2 H 2O
J
qrxT 255 06

H rxT 298 TT 2 H 2 qrxT 255 06 J

TO2 2 5 TT 2 H 2 25

TT 2 H 2 TO2 TN 2 TTO2 TH 2O
25 0 0 0
2 T 0 0 0 2

22

A T 03 T 06 T 0 5 E 09
2:2 6 32 952 0 299 0
T2 3 639 0 506 0 0 227 0
T2 5 457 045 0 57 0
:2T 3 470 45 0 0 2 0

T2

20
T2
H rxT 298 Te 2 T P e TT 0
298 e

T2 6 69 K

)))

TT 2 H 2

TO2 25

N2
TN 2 TO2 9 40
O2 rer

TT 2 H 2 TO2 TN 2 TTO2 TH 2O
25 9 40 0 0
2 0 0 9 40 2

A T 03 T 06 T 0 5 E 09
2:2 6 32 952 0 299 0
T2 3 639 0 506 0 0 227 0
T2 5 457 045 0 57 0
:2T 3 470 45 0 0 2 0
2 3 280 0 593 0 0 04 0

T2 2792 K

2
) )

TO2 5

N2
TN 2 TO2 8 80
O2 rer

TT 2 H 2 TO2 TN 2 TTO2 TH 2O
5 88 0 0
2 0 25 88 2

T2 787 K

22
80
) )

3:8 + 5T2 3 T2 + 4:2T

qrxT qe 5 qe 3 qe 4 qe
T3 H 8 O2 TO2 H 2O
J
qrxT 2 044 06

H rxT 298 TT 3 H 8 qrxT 2 044 06 J

TO2 5 TT 3 H 8 5

N2
TN 2 TO2 88
O2 rer

TT 3 H 8 TO2 TN 2 TTO2 TH 2O
5 88 0 0
2 T 0 0 88 3 4

) )2 2

A T 03 T 06 T 0 5 E 09
2 3 280 0 593 0 0 04 0
T2 5 457 045 0 57 0
:2T 3 470 45 0 0 2 0

T2

T2
H rxT 298 Te 2 T P e TT 0
298 e

T2 2374 K

23
)))

4: 0 + 322 T2 4 T2 + 5:2T

H rxT 298 2 657 06 J

TT 4 H 0 TO2 TN 2 TTO2 TH 2O
65 24 5 0 0
2 T 0 0 24 5 4 5

TP

T2 2376 K
) )

5: 2 + 8T2 5 T2 + 6:2T

H rxT 298 3 272 06 J

TT 5 H 2 TO2 TN 2 TTO2 TH 2O
8 30 0 0
2 0 0 30 5 6

T2

T2 2382 K

24
81

:4 + 2T2 T2 + 2:2T

2 35

J
qrxT 8 02 05

TTH 4

TTH 4
2
TO2 2
2
TN 2 7 52
2
TTO2
2
TH 2 O 2
2

H rxT 298 8 02 05 J

22

A T 03 T 06 T 0 5 E 09
:4 702 9 08 2 64 0 0
T2 3 639 0 506 0 0 227 0
T2 5 457 045 0 57 0
:2T 3 470 45 0 0 2 0
2 3 280 0 593 0 0 04 0

25
273
H rxT 298 Te 2
T P e TT 0
298 e

0 42

0 42 58%

26
8

U U 2 U 23 U3 0
U 2 50 J

U 2 T2 W2
T2 400 J

2 3

U 23 T23 W23
T23 0 J

U3 T3 W3
W3 250 J

U J W J T J
2 50 400 350
2 3 800 800 0
3 750 250 500

W T

W W 2 W23 W3 50 J
T T 2 T23 T3 50 J

27
83
2 20
29 3 4
2 3 4

RT
v
P

T K P v 3
2
073 60 0 00 49
2 073
3 298 02 0 24
4 298

2
0

T2 W2

2 38

P2
W2 TRT
P

W2 2 P2
2 3
P2
2 48

Pv x TtTtt

RT
P
v

28
Tv x TtTtt

T3 x x
v2 v
T2 3

3
v2 0 00504

RT2
P2 77
v2

W2

W2 0 89 J

W34 W2

3
T x x
v4 v 0 0367
T4
RT4
P4 0 675
v4

P4
W34 TRT3
P3

W34 30 J

29
TR
W T2 T
x

TR
W23 T3 T2 6 J
x
TR
W4 T T4 6 J
x

WTet W 2 W23 W34 W4

WTet 7 88 J

7 88
2 53

WTet 7 88
0 72
TH 0 89

TH W2 0 89 J 2 20

TT
TH

TT T3 T4 TH T T2

0 72

30
84
2 7

TH

QH

2
T2xT1 T1
P2 P1

3 4
T3 T4xT3 2 3
4
T1 T4 P3 P4 T2 T3
P1 P4 P2 P3

TT

2 3 4
2 4

RT
v
P

T K P 3
v 2
298
2 298 0 0248
3 258
4 258 02 0 07

2
0

T2 W2

2 38

3
P2
W2 TRTH
P

W2 2 P
4
P
2 48

Pv x TtTtt

RT
P
v

Tv x TtTtt

T4 x x
v v4
T

3
T4 x x
v v4 0 0748
T
RT
P 0 33
v

W2

W2 2 74 J

W34 W2

32
3
v3 0 0355

RT3
P3 0 60
v3

P4
W34 TRTT
P3

W34 2 37 J

TR
W23 TT TH 0 83 J
x
TR
W4 TH TT 0 83 J
x

WTet W 2 W23 W34 W4

WTet 0 367 J

0 367 J
2 54

TT
TOP
WTet

TT T34 3
4

T34 W34 2 37 J

33
2 37 J
TOP 6 45
0 367 J

34
85

) )
Pv 3
P

m33 4

3
3a3a5
2

v
v
)))
Pv 3 4

) )

m m2 m3 m4 m

mq mq4 TH

mq3 mq2 TT

J
q 3424 5 520 º 00

35
J J J
q2 0 0 68 77 0 90 2574 8 2334 2

75 75

J
q3 68 77 0 075

J
q4 342 8 80 º 00

J J
TH 00 2 3424 5 342 8 308 69

J J
TT 00 2 68 77 2334 2 2 6543

) )
2 52

WTet TTet 0

TTet 308 69 2 6543 9 626

WTet 9 626

) )

9 626
0 297
308 69

36

You might also like