Copyright © McGraw-Hill Education. All rights reserved.

No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 = −

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 V    G 
 
RT  P  RT  T


H    G 
   
 T  RT   P
2
RT

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 

H  T  1 d  T 
 
RT 2 RT 2 RT dT
d  T 
H   T   T
dT

1 d  T  
S   T   T   T   RT ln P 
T dT 
d  T 
S   R ln P
dT

d  T   RT 
U   T   T  P 
dT  P 
d  T 
U   T   T  RT
dT

d  d  T   d  T  d 2  T  d  T 
Cp    T   T   T 
dT  dT  dT dT 2 dT
d 2  T 
C p  T
dT 2

d  d  T   d  T  d 2  T  d  T 
Cv     T   T  RT    T  R
dT  dT  dT dT 2 dT
d 2  T 
Cv  T  R  Cp  R
dT 2

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
  dS 
    V
 dP T
 dH 
   1   T V
 dP T


S   V P
H  1   T V P

   

S  2.095  103 K -1  1.551 103 m3 kg -1  819000 Pa = -2.66 Pa m3 kg-1 K -1 = -2.66 J kg-1 K -1

 
H  1  2.095  103 K -1  270 K  1.551 103 m3 kg -1  819000 Pa=552 J kg-1

dH  C p dT  1   T VdP

V 1   T 
dT   dP
Cp

V 1   T 
T   P
Cp

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 

2
 T  7
1 
V sat  Vc Zc r 
2
1T
 Vc Zc c 
7 T

 2 
1 V   ln V     T  7
   ln Vc  1   ln Z c 
V T T T   Tc  
 
5
2ln Z c  T  7
  1  
7Tc  Tc 

2
 360  7
1 
V  262.7 *0.282 408.1   132 cm3 mol-1  0.000132 m3 mol-1

5
2ln 0.282  360  7
  1  0.00408 K -1
7 * 408.1  408.1 


0.000132 m3 mol-1 1  0.00408*360 

T    2000000 Pa   0.766 K
2.78 J g -1 K -1 *58.123 g mol-1

 

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 

 dS 
    V
 dP T
 dH 
   1   T V
 dP T


1  V  1
    dV   dP
V  P T V
V 
ln      P  P1 
 V1 
V  V1 exp    P  P1  

 
V2  1003 cm3 kg-1 exp 45 106 bar -1 1499 bar  937.6 cm3 kg-1  9.376  104 m3 kg-1

P2
Vave 2

W  Vave PdP 
2

P2  P12 
P1

S  Vave P

H  1   T Vave P

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
      


 
V2  1003 cm3 kg-1 exp 45  106 bar -1  1499 bar  937.5741 cm3 kg-1  9.375741  104 m3 kg-1

W  45 106 bar 1 *970.3 cm3 kg-1 / 2* 15002   1  bar

2 2
 49120 bar cm3 kg-1  4.91 kJ kg 1

S  250 106 K-1 *970.3 cm3 kg 1 *1499 bar  363.6 bar cm3 kg1 K1  36.4 J kg1 K1

 
H  1  250 106 K-1 *298.15 K *970.3 cm3 kg 1 *1499 bar  1.346 106 bar cm3 kg 1  134.6 kJ kg 1

      
   

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 RT a RT a  RT
P  2     2a
V b V 1 1 1  b
b
  2

P 1 a
Z  
 RT 1  b  RT


GR d
RT

  Z  1 
0
 Z  1  ln Z


GR  1 a  d 
RT
 
 
 1  b  RT
0
 1
 
 Z  1  ln Z


GR  1

1 a
     d   Z  1  ln Z
RT  1  b    RT  
0
 

GR  1  1  b a 
RT
 
0
 
 1  b    RT 
 
d   Z  1  ln Z


GR  b a 
RT
 
0
  d   Z  1  ln Z
 1  b  RT 

G R
a
  ln 1  b     Z  1  ln Z
RT RT

p

ZRT

GR  bP  aP
  ln 1    2 2  Z  1  ln Z
RT  ZRT  ZR T

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 bP a aP
 , and q  
RT bRT  R 2T 2

GR    q
  ln 1     Z  1  ln Z
RT  Z Z

GR Z   q
  ln    Z  Z  1  ln Z
RT  Z 
GR q
 ln Z  ln  Z      Z  1  ln Z
RT Z
GR q
 Z  1  ln  Z    
RT Z


HR  Z  d 
RT
 Z 1 T 
 
 T   
0

 Z  a
  
 T   RT 2


HR a d  a
 RT
aP
 Z 1 T 2 
 Z 1  Z 1
RT RT ZR 2T
0

H R
q
 Z 1
RT Z

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 S R H R GR
 
R RT RT
SR q  q 
 Z 1   Z  1  ln  Z    
R Z  Z 
SR
 ln  Z   
R

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 ⁡

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 θ≡

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 ICPH (K) H (J/mol)
2 2
T 1 (K) T 2 (K) A B (1/K) C (1/K ) D (K )
382.02 810.93 3.47 1.45E-03 0.00E+00 1.21E+04 1876.0 15597.3

T2
MW (g/mol)
1
    
Cp B 2 C 3 1 18.02
dT A T2 T1 
ICPH º T2 T12 T2 T13 D 
R 2 3 T2 T1
H (J/g)
T1
865.6
H (Btu/lbm)
372.1

S (J/(mol K))
2 2
T 1 (K) T 2 (K) A B (1/K) C (1/K ) D (K ) ICPS
382.02 810.93 3.47 1.45E-03 0.00E+00 1.21E+04 3.266 27.15

T2 MW (g/mol)
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2 18.02
RT T1 2 2
T1
S (J/(g K))
1.507
S (Btu/(lbm R))
0.3599

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 −

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 


Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T2
1 1 
R    
Cp B 2 C 3
ICPH T0,T;A,B,C,D  º dT  A T  T0   T  T02  T  T03  D   
T1
2 3  T T0 

C (1/K2) D (K2) ICPH (K) H (J/mol)

ig
T0(K) T (K) A B (1/K)
723.15 413.15 3.47 1.45E-03 0 1.21E+04 -1343.6 -11171.7

T
T   D  T 2  T02 

Cp
ICPS  T0,T;A,B,C,D º dT  A ln    B T  T0    C  2 2  
 T T0  2 
T0
RT  T0   

T0 (K) T (K) A B (1/K) C (1/K2) D (K2) ICPS Sig (J/(mol K))

723.15 413.15 3.47 1.45E-03 0 1.21E+04 -2.416 -20.0858

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
723.15 30 647.1 220.55 0.345

dB0 dB1
0 1
Tr Pr B B dTr dTr HR /RTc HR (J mol -1)
1.1175 0.1360 -0.2703 0.0311 0.5056 0.4051 -0.1334 -717.78

0.422 dB0 0.675

B 0.083
0  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

T (K) P (bar) Tc (K) Pc (bar) 

723.15 30 647.1 220.55 0.345

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
1.1175 0.1360 0.5056 0.4051 -0.0878 -0.73

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Pale blue boxes are input fields, pink boxes are the final output.

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
413.15 2.35 647.1 220.55 0.345

dB0 dB1
0 1
Tr Pr B B dTr dTr HR /RTc HR (J mol -1)
0.6385 0.0107 -0.7822 -0.9933 2.1675 7.4444 -0.0442 -237.82

0.422 dB0 0.675

B 0.083
0  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

dB0 dB1
dTr dTr

dB0 0.675
 2.6
dTr Tr
dB1 0.722
 5.2
dTr Tr

SR dB 0 dB1
Pr 
dT

R  r dTr

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 T (°C) P (MPa) H l (kJ/kg) S l (kJ/(kg K)) H v (kJ/kg) S v (kJ/(kg K)) H (kJ/kg) S (kJ/(kg K))
127.41 0.250 535.34 1.6072 2716.5 7.0524 2607.4 6.7801
127.54 0.251 535.91 1.6086 2716.7 7.0511 2607.7 6.7790
127.67 0.252 536.46 1.6100 2716.9 7.0498 2607.9 6.7778
127.80 0.253 537.02 1.6114 2717.0 7.0485 2608.0 6.7766
127.94 0.254 537.58 1.6128 2717.2 7.0472 2608.2 6.7755
128.07 0.255 538.13 1.6142 2717.4 7.0458 2608.4 6.7742
128.19 0.256 538.68 1.6155 2717.6 7.0445 2608.7 6.7731
128.32 0.257 539.23 1.6169 2717.8 7.0432 2608.9 6.7719
128.45 0.258 539.78 1.6183 2717.9 7.0419 2609.0 6.7707
128.58 0.259 540.33 1.6196 2718.1 7.0407 2609.2 6.7696
128.71 0.260 540.87 1.6210 2718.3 7.0394 2609.4 6.7685
128.84 0.261 541.42 1.6223 2718.5 7.0381 2609.6 6.7673
128.96 0.262 541.96 1.6237 2718.6 7.0368 2609.8 6.7661
129.09 0.263 542.50 1.6250 2718.8 7.0355 2610.0 6.7650
129.22 0.264 543.04 1.6264 2719.0 7.0343 2610.2 6.7639
129.34 0.265 543.57 1.6277 2719.2 7.0330 2610.4 6.7627
129.47 0.266 544.11 1.6290 2719.3 7.0318 2610.5 6.7617
129.59 0.267 544.64 1.6303 2719.5 7.0305 2610.8 6.7605
129.72 0.268 545.18 1.6317 2719.7 7.0293 2611.0 6.7594
129.84 0.269 545.71 1.6330 2719.9 7.0280 2611.2 6.7583
129.97 0.270 546.24 1.6343 2720.0 7.0268 2611.3 6.7572

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 ⋅ ⋅


 


Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
   

  




 
 

dP sat
H  T V  818.1* 2.996 *1.888  4628 ft 3psia lb-1
m  856.5 Btu lb m
-1
dT

 

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar)  Tr Pr
468.15 135 369.8 42.48 0.152 1.2660 3.1780

Table Points
Tr Pr Z0 Z1 (HR )0/(RTc) (HR )1/(RTc) (SR )0/R (SR )1/R
Tr (1) Pr(1) 1.20 3.00 0.5425 0.1095 -2.801 -0.934 -1.727 -0.991
Tr(1) Pr(2) 1.20 5.00 0.7069 -0.0141 -3.166 -1.84 -1.827 -1.767
Tr(2) Pr(1) 1.30 3.00 0.6344 0.2079 -2.274 -0.3 -1.299 -0.29
Tr(2) Pr(2) 1.30 5.00 0.7358 0.0875 -2.825 -1.066 -1.554 -0.73

Interpolated Values 0.6140 0.1636 -2.4968 -0.5883 -1.4627 -0.5780

Final Values
Z 0.6389 HR /(RTc) -2.58623 SR /R -1.55056
3 R
V (cm /mol) 184.2 H (J/mol) -7951.4 SR (J/(mol K)) -12.8914

T2
1 1 
R    
Cp B 2 C 3
ICPH T0,T;A,B,C,D  º dT  A T  T0   T  T02  T  T03  D   
T1
2 3  T T0 

C (1/K2) D (K2) ICPH (K) H (J/mol)

ig
T0(K) T (K) A B (1/K)
308.15 468.15 1.213 2.88E-02 -8.82E-06 0.00E+00 1766.0 14683.6
T
T   D  T 2  T02 

Cp
ICPS  T0,T;A,B,C,D º dT  A ln    B T  T0    C  2 2  
 T T0  2 
T0
RT  T0   

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 H   H R  400 K,38 bar    C igp dT  H R T f ,1 bar 
Tf

400 K

H   H R  400 K,38 bar   

Tf
C igp dT  0
400 K

C igp dT  H R  400 K,38 bar 

Tf
400 K

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar)  Tr Pr
400.15 38 365.6 46.65 0.14 1.0945 0.8146

Table Points
Tr Pr Z0 Z1 R 0
(H ) /(RT c)
R 1
(H ) /(RT c) (SR)0/R (SR)1/R
Tr (1) Pr(1) 1.05 0.80 0.7130 -0.0032 -0.995 -0.691 -0.656 -0.642
Tr(1) Pr(2) 1.05 1.00 0.6026 0.0220 -1.359 -0.877 -0.965 -0.820
Tr(2) Pr(1) 1.10 0.80 0.7649 0.0236 -0.827 -0.507 -0.537 -0.470
Tr(2) Pr(2) 1.10 1.00 0.6880 0.0476 -1.120 -0.617 -0.742 -0.577

Interpolated Values 0.7533 0.0224 -0.8674 -0.5359 -0.5659 -0.4973

Final Values
Z 0.7565 HR/(RT c) -0.94242 SR/R -0.63548
3 R R
V (cm /mol) 662.4 H (J/mol) -2864.57 S (J/(mol K)) -5.28337

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPH (K) H (J/mol)

400 362.9176 1.637 2.27E-02 -6.92E-06 0.00E+00 -344.5 -2864.6

T2
1
    
Cp B 2 C 3 1
dT A T2 T1 
ICPH º T2 T12 T2 T13 D 
R 2 3 T2 T1
T1

C igp 1
 400 K,38 bar   400 K  S R  363 K,1 bar 
Tf
S  S R
dT  R ln
T 38

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPS S (J/(mol K))
400 362.9176 1.637 2.27E-02 -6.92E-06 0.00E+00 -0.903 -7.51

T2
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2
RT T1 2 2
T1

H   H R  423 K, 22 bar    C igp dT  H R T f ,1 bar 

Tf

423 K

H   H R  423 K, 22 bar   
Tf
C igp dT  0
423 K

C igp dT  H R  423 K, 22 bar 

Tf
 423 K

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
423 22 369.8 42.48 0.152

dB0 dB1
0 1
Tr Pr B B dTr dTr HR/RT c HR (J mol-1)
1.1439 0.5179 -0.2573 0.0412 0.4759 0.3589 -0.4443 -1366.04

0.422 dB0 0.675

B 0 0.083  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

RTc  dTr dTr
B1 0.139
0.172 dB1 0.722  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPH (K) H (J/mol)

423 408.9078 1.213 2.88E-02 -8.82E-06 0.00E+00 -164.3 -1366.0

T2
1
    
Cp B 2 C 3 1
dT A T2 T1 
ICPH º T2 T12 T2 T13 D 
R 2 3 T2 T1
T1

C igp 1
 423 K, 22 bar   423 K  S R  408.9 K,1 bar 
408.9
S  S R
dT  R ln
T 22

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
423 22 369.8 42.48 0.152

dB0 dB1
R R -1 -1
Tr Pr dTr dTr S /R S (J mol K )
1.1439 0.5179 0.4759 0.3589 -0.2747 -2.28

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPS S (J/(mol K))

423 408.9078 1.213 2.88E-02 -8.82E-06 0.00E+00 -0.395 -3.28

T2
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2
RT T1 2 2
T1

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
373.15 1 369.8 42.48 0.152

dB0 dB1
0 1
Tr Pr B B dTr dTr HR /RTc HR (J mol -1)
1.0091 0.0235 -0.3330 -0.0266 0.6594 0.6889 -0.0261 -80.20

0.422 dB0 0.675

B 0.083
0  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

T (K) P (bar) Tc (K) Pc (bar) 

373.15 10 369.8 42.48 0.152

dB0 dB1
Tr Pr B0 B1 dTr dTr HR /RTc HR (J mol -1)
1.0091 0.2354 -0.3330 -0.0266 0.6594 0.6889 -0.2608 -801.97

0.422 dB0 0.675

B 0 0.083  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
373.15 1 369.8 42.48 0.152

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
1.0091 0.0235 0.6594 0.6889 -0.0180 -0.1496

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Pale blue boxes are input fields, pink boxes are the final output.

T (K) P (bar) Tc (K) Pc (bar) 

373.15 10 369.8 42.48 0.152

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
1.0091 0.2354 0.6594 0.6889 -0.1799 -1.4955

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Pale blue boxes are input fields, pink boxes are the final output.

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
318.15 16 304.2 73.83 0.224

dB0 dB1
0 1
Tr Pr B B dTr dTr HR /RTc HR (J mol -1)
1.0459 0.2167 -0.3098 -0.0035 0.6007 0.5718 -0.2325 -588.04

0.422 dB0 0.675

B 0.083
0  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

T2
1 1 
R    
Cp B 2 C 3
ICPH T0,T;A,B,C,D  º dT  A T  T0   T  T02  T  T03  D   
T1
2 3  T T0 

C (1/K2) D (K2) ICPH (K) H (J/mol)

ig
T0(K) T (K) A B (1/K)
318.15 302.71 5.457 1.05E-03 0.00E+00 -1.16E+05 -70.7 -588.0

dB0 dB1
dTr dTr

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 0.422
B 0 0.083
Tr1.6
0.172
B1 0.139
Tr4.2
dB0 0.675
 2.6
dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
 
 5.2
dTr Tr

T2
1 1 
 R dT  AT  T   2 T   
Cp B C 3
ICPH T0,T;A,B,C,D  º 0
2
 T02  T  T03  D   
T1
3  T T0 

C (1/K2) D (K2) ICPH (K) H (J/mol)

ig
T0(K) T (K) A B (1/K)
318.15 303.83 5.457 1.05E-03 0.00E+00 -1.16E+05 -65.7 -546.0

T (K) P (bar) Tc (K) Pc (bar) 

318.15 16 304.2 73.83 0.224

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
1.0459 0.2167 0.6007 0.5718 -0.1579 -1.31

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
303.8 1.0133 304.2 73.83 0.224

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
0.9987 0.0137 0.6773 0.7270 -0.0115 -0.10

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

T
T   D  T 2  T02 

Cp
ICPS  T0,T;A,B,C,D º dT  A ln    B T  T0    C  2 2  
 T T0  2 
T0
RT  T0   

T0 (K) T (K) A B (1/K) C (1/K2) D (K2) ICPS Sig (J/(mol K))

318.15 303.83 5.457 1.05E-03 0.00E+00 -1.16E+05 -0.211 -1.7557

Tf C igp 120
S   dT  R ln 0
523 K T 3800
ig
Tf C
 dT  28.73 J/(mol K)
p
523 K T

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPS S (J/(mol K))
523.15 308.167 1.424 1.44E-02 -4.39E-06 0.00E+00 -3.456 -28.73

T2
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2
RT T1 2 2
T1

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPH (K) H (J/mol)

523.15 308.167 1.424 1.44E-02 -4.39E-06 0.00E+00 -1425.6 -11852.5

T2
1
    
Cp B 2 C 3 1
dT A T2 T1 
ICPH º T2 T12 T2 T13 D 
R 2 3 T2 T1
T1

C igp
 S R T f ,1.2 bar   0
1.2
S   S R  523 K,38 bar   
Tf
dT  R ln
523 K T 38
ig
C
 S R T f ,1.2 bar 
1.2
dT  S R  523 K,38 bar   R ln
Tf

p
523 K T 38
C igp
dT  S R  523 K,38 bar   28.73 J/(mol K)  S R T f ,1.2 bar 
Tf
523 K T

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
523.15 38 282.3 50.4 0.87

dB0 dB1
Tr Pr dTr dTr SR/R SR (J mol-1 K-1)
1.8532 0.7540 0.1357 0.0292 -0.1215 -1.01

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

Tf C igp
523 K T
dT  1.01  28.73  29.74 J/(mol K)

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPS S (J/(mol K))

523.15 301.3147 1.424 1.44E-02 -4.39E-06 0.00E+00 -3.577 -29.74

T2
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2
RT T1 2 2
T1

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPH (K) H (J/mol)

523.15 301.3147 1.424 1.44E-02 -4.39E-06 0.00E+00 -1462.6 -12160.3

T2
1
    
Cp B 2 C 3 1
dT A T2 T1 
ICPH º T2 T12 T2 T13 D 
R 2 3 T2 T1
T1

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
523.15 38 282.3 50.4 0.87

dB0 dB1
Tr Pr B0 B1 dTr dTr HR/RT c HR (J mol-1)
1.8532 0.7540 -0.0743 0.1261 0.1357 0.0292 -0.1984 -465.77

0.422 dB0 0.675

B 0 0.083  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

RTc  dTr dTr
B1 0.139
0.172 dB1 0.722  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

H   H R  523 K,38 bar   

301 K
C igp dT  465.8  12160.3  11695 J/mol
523 K

C igp
 S T f K, 2.6 bar   0
2.6 R
S  S R  493 K,30 bar   
Tf
dT  R ln
493 K T 30

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 Tf C igp
 493 K T
dT  20.33 J/(mol K)

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPS S (J/(mol K))

493 367.472 1.131 1.92E-02 -5.56E-06 0.00E+00 -2.445 -20.33

T2
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2
RT T1 2 2
T1

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPH (K) H (J/mol)

493 367.472 1.131 1.92E-02 -5.56E-06 0.00E+00 -1050.1 -8730.7

T2
1
    
Cp B 2 C 3 1
dT A T2 T1 
ICPH º T2 T12 T2 T13 D 
R 2 3 T2 T1
T1

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 C igp 2.6
S   S R  493 K,30 bar   
Tf
dT  R ln 0
493 K T 30

C igp
dT  S R  493 K,30 bar   20.33 J/(mol K)
Tf
 493 K T

T (K) P (bar) Tc (K) Pc (bar) 

493.15 30 305.3 48.72 0.1

dB0 dB1
Tr Pr dTr dTr SR/R SR (J mol-1 K-1)
1.6153 0.6158 0.1940 0.0597 -0.1231 -1.02

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Tf C igp
 493 K T
dT  21.35 J/(mol K)

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPS S (J/(mol K))

493 361.4254 1.131 1.92E-02 -5.56E-06 0.00E+00 -2.568 -21.35

T2
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2
RT T1 2 2
T1

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
361 2.6 305.3 48.72 0.1

dB0 dB1
Tr Pr dTr dTr SR/R SR (J mol-1 K-1)
1.1824 0.0534 0.4366 0.3021 -0.0249 -0.21

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

C igp
dT  S R  493 K,30 bar   20.33 J/(mol K)  S R T f , 2.6 bar 
Tf
 493 K T
Tf C igp
 493 K T
dT  1.02  20.33  0.21  21.14 J/(mol K)

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPS S (J/(mol K))

493 362.6735 1.131 1.92E-02 -5.56E-06 0.00E+00 -2.543 -21.14

T2
T
    
Cp C 2 D 2
ICPS º
dT A ln  2 B T2 T1  T2 T12 T2 T1 2
RT T1 2 2
T1

H   H R  493 K,30 bar    C igp dT  H R  363 K, 2.6 bar 

363 K

493 K

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
493 30 305.3 48.72 0.1

dB0 dB1
0 1 R R -1
Tr Pr B B dTr dTr H /RT c H (J mol )
1.6148 0.6158 -0.1130 0.1160 0.1942 0.0597 -0.2615 -663.72

0.422 dB0 0.675

B 0 0.083  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

RTc  dTr dTr
B1 0.139
0.172 dB1 0.722  
 5.2
Tr4.2 dTr Tr

T 1 (K) T 2 (K) A B (1/K) C (1/K2) D (K2) ICPH (K) H (J/mol)

493 363 1.131 1.92E-02 -5.56E-06 0.00E+00 -1083.3 -9006.2

T2
1
    
Cp B 2 C 3 1
dT A T2 T1 
ICPH º T2 T12 T2 T13 D 
R 2 3 T2 T1
T1

T (K) P (bar) Tc (K) Pc (bar) 

363 2.6 305.3 48.72 0.1

dB0 dB1
0 1 R R -1
Tr Pr B B dTr dTr H /RT c H (J mol )
1.1890 0.0534 -0.2369 0.0559 0.4304 0.2935 -0.0415 -105.38

0.422 dB0 0.675

B 0 0.083  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

RTc  dTr dTr
B1 0.139
0.172 dB1 0.722  
 5.2
Tr4.2 dTr Tr

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T2 T2
Cp  7.8  Cp
S   dT  R ln    dT  17.08 J mol1 K 1
ig

323.15
T  1  323.15 T

T (K) P (bar) Tc (K) Pc (bar) 

323.15 1 425.1 37.96 0.2

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
0.7602 0.0263 1.3770 3.0046 -0.0521 -0.4332

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Pale blue boxes are input fields, pink boxes are the final output.

T2
Cp
 dT  17.08  0.43  S R T2 , 7.8 bar   16.65  S R T2 , 7.8 bar  J mol1 K 1
323.15
T

T2
Cp

323.15
T
dT  17.08 J mol1 K 1

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T
T   D  T 2  T02 

Cp
ICPS  T0,T;A,B,C,D º dT  A ln    B T  T0    C  2 2  
 T T0  2 
T0
RT  T0   

T0 (K) T (K) A B (1/K) C (1/K2) D (K2) ICPS Sig (J/(mol K))

323.15 376.56 1.935 3.69E-02 -1.14E-05 0.00E+00 2.054 17.0803

T (K) P (bar) Tc (K) Pc (bar) 

376.56 7.8 425.1 37.96 0.2

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
0.8858 0.2055 0.9251 1.3563 -0.2458 -2.0440

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Pale blue boxes are input fields, pink boxes are the final output.

T2
Cp
 dT  17.08  0.43  S R T2 , 7.8 bar   16.65  2.044  18.69 J mol1 K 1
323.15
T

T
T   D  T 2  T02 

Cp
ICPS  T0,T;A,B,C,D º dT  A ln    B T  T0    C  2 2  
 T T0  2 
T0
RT  T0   

T0 (K) T (K) A B (1/K) C (1/K2) D (K2) ICPS Sig (J/(mol K))

323.15 381.69 1.935 3.69E-02 -1.14E-05 0.00E+00 2.248 18.6893

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar) 
381.69 7.8 425.1 37.96 0.2

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
0.8979 0.2055 0.8932 1.2641 -0.2355 -1.9579

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Pale blue boxes are input fields, pink boxes are the final output.

T2
Cp
 dT  17.08  0.43  S R T2 , 7.8 bar   16.65  1.958  18.604 J mol1 K 1
323.15
T

T
T   D  T 2  T02 

Cp
ICPS  T0,T;A,B,C,D º dT  A ln    B T  T0    C  2 2  
 T T0  2 
T0
RT  T0   

T0 (K) T (K) A B (1/K) C (1/K2) D (K2) ICPS Sig (J/(mol K))

323.15 381.42 1.935 3.69E-02 -1.14E-05 0.00E+00 2.238 18.6041

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T2
1 1 
R    
Cp B 2 C 3
ICPH T0,T;A,B,C,D  º dT  A T  T0   T  T02  T  T03  D   
T1
2 3  T T0 

C (1/K2) D (K2) ICPH (K) H (J/mol)

ig
T0(K) T (K) A B (1/K)
323.15 381.42 1.935 3.69E-02 -1.14E-05 0.00E+00 787.9 6550.6

T (K) P (bar) Tc (K) Pc (bar) 

323.15 1 425.1 37.96 0.2

dB0 dB1
0 1
Tr Pr B B dTr dTr HR /RTc HR (J mol -1)
0.7602 0.0263 -0.5714 -0.4051 1.3770 3.0046 -0.0568 -200.75

0.422 dB0 0.675

B 0.083
0  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

T (K) P (bar) Tc (K) Pc (bar) 

381.42 7.8 425.1 37.96 0.2

dB0 dB1
Tr Pr B0 B1 dTr dTr HR /RTc HR (J mol -1)
0.8972 0.2055 -0.4189 -0.1322 0.8948 1.2688 -0.3033 -1071.92

0.422 dB0 0.675

B 0 0.083  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 ⋅ − ⋅

56.0056

59.04121

61.1392

62.579174

63.39535

63.32491

62.15734

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 P2 V2
(kPa) T2 (K) (cm^3/g) mass (kg)
1 384.09 303316 0.00576956
100 384.82 3032.17 0.577144421
200 385.57 1515.61 1.154650603
300 386.31 1010.08 1.732536037
400 387.08 757.34 2.310719096

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 2.5 387.5

387
2
386.5

1.5 386
Mass (kg)

T2 (K)
385.5
1 385

384.5
0.5
384

0 383.5
0 50 100 150 200 250 300 350 400
P2 (kPa)

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 T (K)
500
P (bar)
20
Tc (K)
425.2
Pc (bar)
42.77

0.19
Z
0.9074 
Z  1  B0   B1  TP
r
r
0 1
dB dB
0 1
Tr Pr B B dTr dTr HR /RTc HR (J mol -1)
1.1759 0.4676 -0.2426 0.0519 0.4429 0.3109 -0.3849 -1360.65

0.422 dB0 0.675

B 0.083
0  2.6
Tr1.6 dTr Tr HR  dB0  dB1

Pr B 0 Tr  
B1 Tr

dB1 0.722 RTc  dTr dTr
B1 0.139
0.172  
 5.2
Tr4.2 dTr Tr
Pale blue boxes are input fields, pink boxes are the final output.

T (K) P (bar) Tc (K) Pc (bar) 

500 20 425.2 42.77 0.19

dB0 dB1
Tr Pr dTr dTr SR /R SR (J mol -1 K-1)
1.1759 0.4676 0.4429 0.3109 -0.2347 -1.9517

dB0 0.675
 2.6
dTr Tr SR dB 0 dB1
Pr 
dT

R  r dTr
dB1 0.722
 5.2
dTr Tr

Pale blue boxes are input fields, pink boxes are the final output.

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 T (K) P (bar) Tc (K) Pc (bar)  Tr Pr
400 200 304.2 73.83 0.224 1.3149 2.7089

Table Points
Tr Pr Z0 Z1 (HR )0/(RTc) (HR )1/(RTc) (SR )0/R (SR )1/R
Tr (1) Pr(1) 1.30 2.00 0.6908 0.1991 -1.56 -0.178 -0.891 -0.3
Tr(1) Pr(2) 1.30 3.00 0.6344 0.2079 -2.274 -0.3 -1.299 -0.481
Tr(2) Pr(1) 1.40 2.00 0.7753 0.1894 -1.253 -0.07 -0.663 -0.22
Tr(2) Pr(2) 1.40 3.00 0.7202 0.2397 -1.857 -0.044 -0.99 -0.29

Interpolated Values 0.6636 0.2083 -2.0087 -0.2327 -1.1376 -0.4046

Final Values
Z 0.7102 HR /(RTc) -2.06084 SR /R -1.22828
3 R
V (cm /mol) 118.1 H (J/mol) -5212.12 SR (J/(mol K)) -10.2119

ω ω

T P Tc1 Tc2 Pc1 Pc2 ω1 ω2

650 60 562.2 553.6 48.98 40.73 0.21 0.21
300 100 304.2 132.9 73.83 34.99 0.224 0.048
600 100 304.2 568.7 73.83 24.9 0.224 0.4
350 75 305.3 282.3 48.72 50.4 0.1 0.087
400 150 373.5 190.6 89.63 45.99 0.094 0.012
200 75 190.6 126.2 45.99 34 0.012 0.038
450 80 190.6 469.7 45.99 33.7 0.012 0.252
250 100 126.2 154.6 34 50.43 0.038 0.022

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 Tpc Ppc ω Tpr Ppr

557.9 44.855 0.21 1.165083 1.337644

218.55 54.41 0.136 1.372684 1.837897

436.45 49.365 0.312 1.374728 2.025727

293.8 49.56 0.0935 1.191287 1.513317

282.05 67.81 0.053 1.418188 2.212063

158.4 39.995 0.025 1.262626 1.875234

330.15 39.845 0.132 1.363017 2.00778

140.4 42.215 0.03 1.780627 2.368826

Z0 Z1 H0 H1 S0 S1
0.6543 0.1219 -1.395 -0.461 -0.89 -0.466
0.7706 0.1749 -1.214 -0.116 -0.658 -0.235
0.7527 0.1929 -1.346 -0.097 -0.729 -0.242
0.6434 0.1501 -1.51 -0.4 -0.944 -0.43
0.7744 0.199 -1.34 -0.049 -0.704 -0.224
0.6631 0.1853 -1.623 -0.254 -0.965 -0.348
0.7436 0.1933 -1.372 -0.11 -0.75 -0.25

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 0.9168 0.1839 -0.82 0.172 -0.361 -0.095

Z HR (J/mol) SR (J/mol K)
0.680 -6919.58 -8.21307
0.794 -2234.53 -5.73633
0.813 -4993.97 -6.68865
0.657 -3779.76 -8.18268
0.785 -3148.34 -5.95176
0.668 -2145.75 -8.09534
0.769 -3805.81 -6.50986
0.922 -951.151 -3.02505

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 =

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 ≡

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Tc := 647.1K Pc := 220.55bar

At Tr = 0.7: T := 0.7 Tc T = 452.97K

Find Psat in the Saturated Steam Tables at T = 452.97 K

T1 := 451.15K P1 := 957.36kPa T2 := 453.15K P2 := 1002.7kPa

Psat = 998.619 kPa Psat = 9.986 bar

Psatr:= Psatr := 0.045 ω := −1 − log(Psatr) ω = 0.344 Ans.

This is very close to the value reported in Table B.1 (ω = 0.345).

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 −

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 ω

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
 Estimated Value Table B.2
(kJ/mol) (kJ/mol)
Benzene 30.8 30.72
iso-butane 21.39 21.3
Carbon
tetrachloride 29.81 29.82
cyclohexane 30.03 29.97
n-Decane 39.97 38.75
n-Hexane 29.27 28.85
n-Ocatane 34.7 34.41
Toluene 33.72 33.18
o-Xylene 37.23 36.24

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without
the prior written consent of McGraw-Hill Education.
 ∙

Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without

the prior written consent of McGraw-Hill Education.