Crude Oil Processing
Crude Oil Processing
Crude Oil Processing
Chapter I
1) Ultimate analysis:-
It lists the composition in percentages of the elements , C , H,
N , O and S.
-1-
Tells very little about the type of cpds present or physical
characteristic of crude oil.
Useful in determining the omout of sulfur that must be
removed.
( see attached tab. 21. 1 , 2 , 3 . for all analysis types )
2) chemical analysis:-
-2-
Base of crude oil:-
-3-
Bubble point pressure and Dew point.
With crude oils , the fluid may be subcooled l.q. but with
some dissolved gas.
When the reservoir press. Slow down, gases starts to come out
frer solution, this point named bubble point pressure, at which
point the flow characteristics change.
Dew Point
When large amount of one phase present in equilib
With very traces of other phase.
Here l.q phase is at min.
Oil FVF :-
It is the vol. That would be occupied at some P&T by STB
oil plus oxy gas dissolved in the oil at these P&T
correlation.
It is a function of the composition of a system and conditions
under which gas & l.q. are separated.
Values of oil FVF at reservoir T and various pressures
obtained from PVT analysis of reservoir fluid sample.
يمكن النظر إلي العالقات العملية و األمثلة الموجودة في
Oil system correlation chapters.
Factors affecting oil viscosity
Composition
Dissolved gas
-4-
Visc increases with decrease API gravity and Decrease with
Temp.
Dissolved gas lightens the oil and thus decreases visc. only
increase P leads to increase VISC.
Chapter 2 يمكن النظر إلي التعريفات الموجودة في نهاية-: مهمة
which is correlation in oil system. و من التعريفات المهمة أيضا
Condensate:-
Hydrocarbon that exist in the producing formation either as a
liq. or as condensable vap. Liquefaction of gaseous components
of the condensate usually occurs reduction of well fluid temp.
to surface operating.
-5-
Oil & G as Separators
Oil and gas separator designates a pressure vessel used for
separating well fluid produced from oil and gas wells into
gaseous and liq. Components.
-6-
In the case of water knockout for use near the wellhead, gas
and liq. One usually discharged from the bother of the vessel.
The dry type gas scrubber uses mist extractors and other
internals similar to oil and gas separator e.g. coalescing type
mist extractor.
-7-
Filter medium in the vessel is used to remove dust, line scale,
rust and other foreign material from the gas. Filters usually used
to remove liq. From gas also.
1- A vessel (includes: -
a) Primary separation device and /or
session.
b) Secondary separator device (gravity)
setting separator system.
c) Mist extractor to remove small liq
particles from gas.
d) Gas out let.
e) Liq setting (separator section) to gas or
vapor from oil.
f) Oil outlet.
g) Water outlet.
2- Adequate volumetric liq. Capacity to handle liq. Surges
(slugs) from the wells and for flow lines.
-8-
In general as sequence: -
Oil and gas separator is the first vessel where the well fluid
flows through after it leaves the producing wells.
Other equipment Such as heater, water know outs…
Installed upstream of separator.
-9-
advanced technique will assist in removed of non solution
gas like
Automatic custody transfer.
Agitation.
Heat
Special baffling
Coalescing packs
Filtering materials
3- separation of water from oil by either: -
pressure reduction ( by chocks , valves) such water
removal prevent problems like corrosion hydrate
formation and the formation tight emulsion that may
represent difficulties to resolve into oil , water
By using chemicals and gravity separation.
by knockout vessel ( If the 3 phase separation is not large
enough to separate water adequately separation done as in
a free water
if the water is emulsified use emulsion treater to remove
it
2 functions of oil and gas separators
ry
-
Foam is formed when press is reduced on certain
types of crude; results bubbles of gas are encased in a
thinfilm of oil when gas cause out of soln.
Oil foam will not be stable or long-lasting-unless a
foaming agent is present in the oil , crude oil more likely
to foam when :
a) API gravity less than 40 API .
b) Operating temp. less than 160 F0.
c) Crud oil is viscose, greater than 5000 SSU (S3
cp.).
Foaming greatly reduces the capacity of oil & gas
separator because longer retention time is required to
separator adequate given amount of crude.
-
broken. This design can increase separator capacity by
10-50%.
The main factor assisting foaming breaking are:
Settling, agitation (baffling) heat chemicals,
centrifugal force.
These methods or factors used also to remove
entrained gas than oil.
2. Paraffin (separation )ثاني مشكلة في ال
-
Methods used to remove gas from oil
1. Settling.
2. Agitation.
3. Baffling.
4. Heat.
5. Chemicals.
6. Centrifugal force.
1. Crude oil :
The free gas general of separator crud oil will vary depending
on many variables: -
2. Separated water
-
If it is less than 0.2 special attention is required since the
small difference in the densities of oil and water results in
complete separation
3. Gases.
I) Classification by configuration
1- vertical
2- horizontal
3- spherical
-
II) Classification by function
1- Test Separator
as well tester on well checker
may be vertical , horizontal or spherical
may be two phase or 3 phase
permanently or ported on skid
equipped by various types of meters to measure oil ,
gas and water content
2- production separation
used to separate the produced well fluids from a well , gp
of wells or a lease on a daily or continuos basis
Also may be horizontal , vertical or spherical
2 or 3 phase
ranged in size from 12-15 ft in diam and length from 6 to
40 ft long
-
4- Metering separation
5- Foam separate
6- Elevated separation
To capture the max. Amount of. And minimize the loss of gas to
a to low press gas system
7- stage separates
1ry separation
( density differences (gravity Sepon )
impingement and or / coalescence
centrifugal force
diverging vortex separators
centrifugal gas scrubbers
-
comparison of oil and gas separators
See tab 12.5
Estimating the sizes and capacities of oil and gas
separators.
-
stability of emulsion
crude oil with low API gravity (high density)will form a
more stable and higher percentage volume of emulsion
than oils of high API gravity .
Asphaltic - based oil have a tending to emulsify more
readily than paraftin - based oils
High visc .crude oil usually form a more stable emulsion
than low viscosty oil since viscosity prevents movement of
dispersed water droplets and retard their coalescence.
also high viscosity / high density oil usually contain more
emulsifiers lighter
-
Desalter
Oil desalting is the process of removing water-soluble salts from
oil stream. Types of salts mainly
Cl, ca, mg. A large no. of these salts normally removed in the
separation and heater treater process .
-
Important Note
-
Multistage Desalting
-
Also must prevent water level from reaching hight of the
electrodes
Loading rate is the major controlling factor in sizing
vessels for coalescing units( vessels are sized for a certain
vol. Flow per unit time per square foot of grid area.
Field exp. Tens to indicate that electrostatic treaters are
efficient at reducing water content in the crude to the 0.5
to 0.1 % level , this makes these treaters attractive for
desalting operations.
Mixing equipment
Manual globe valve
Spray nozzles ( cheaper than static meters ( see fig 6)
Static mixer( using pieces of corrugated plat
perpendicular to each other
-
Gas Injection Pressure
Maintenance
-
Areal sweep effeciency
Percentage of the total reservoir or pore volume within the
swept area, the area contacted by the displacing fluid .
Injection operations
Types Of Injection
-
Surface Facilities For Water Flooding And Salt
Water Disposal
-
Treating Hydrocarbons From Water
Gravity separation
Dispersion
Coalescence
Skim tanks and vessels
Skim pile ( fig 15-18)
Gas floatation units
Dissolved gas units (fig 15-19,20
Dispersed Gas Units