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Soal Tugas Hukum I Termodinamika

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Soal Tugas Hukum I Termodinamika

Soal 1
A sample consisting of 2.00 mol He is expanded isothermally at 22°C from 22.8 dm 3 to 31.7
dm3 (a) reversibly, (b) against a constant external pressure equal to the final pressure of the
gas, and (c) freely (against zero external pressure). For the three processes calculate q, w,
∆U, and ∆H.

Soal 2
A sample of 4.50 g of methane occupies 12.7 dm 3 at 310 K. (a) Calculate the work done
when the gas expands isothermally against a constant external pressure of 200 Torr until its
volume has increased by 3.3 dm 3. (b) Calculate the work that would be done if the same
expansion occurred reversibly.

Soal 3
The constant-pressure heat capacity of a sample of a perfect gas was found to vary with
temperature according to the expression Cp /(J K−1 ) = 20.17 + 0.3665(T/K). Calculate q, w,
∆U, and ∆H when the temperature is raised from 25°C to 200°C (a) at constant pressure, (b)
at constant volume.

Soal 4
A piece of zinc of mass 5.0 g is dropped into a beaker of dilute hydrochloric acid. Calculate
the work done by the system as a result of the reaction. The atmospheric pressure is 1.1 atm
and the temperature 23°C.

Soal 5
A sample of 5.0 mol CO2 is originally confined in 15 dm 3 at 280 K and then undergoes
adiabatic expansion against a constant pressure of 78.5 kPa until the volume has increased
by a factor of 4.0. Calculate q, w, ∆T, ∆U, and ∆H. (The final pressure of the gas is not
necessarily 78.5 kPa.)

Soal 6
A sample consisting of 1 mol of perfect gas atoms (for which C V,m = 3/2 R) is taken through
the cycle shown in Fig. 2.34. (a) Determine the temperature at the points 1, 2, and 3. (b)
Calculate q, w, ∆U, and ∆H for each step and for the overall cycle. If a numerical answer
cannot be obtained from the information given, then write in +, −, 0, or ? as appropriate.
Soal 7
A sample consisting of 2.0 mol CO 2 occupies a fixed volume of 15.0 dm 3 at 300 K. When it is
supplied with 2.35 kJ of energy as heat its temperature increases to 341 K. Assume that CO 2
is described by the van der Waals equation of state, and calculate w, ∆U, and ∆H.

Soal 8
A sample of 1.00 mol perfect gas molecules with Cp,m = 7/2 R is put through the following
cycle: (a) constant-volume heating to twice its initial volume, (b) reversible, adiabatic
expansion back to its initial temperature, (c) reversible isothermal compression back to 1.00
atm. Calculate q, w, ∆U, and ∆H for each step and overall.

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