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    CH2010 Chemical Engineering Thermodynamics Assignment - 2

    Uploaded by

    Aryan Pandey
    The document contains 5 questions regarding thermodynamics concepts. Question 1 involves calculating the net heat interaction and changes in enthalpy and Helmholtz free energy for a gas in a closed vessel undergoing irreversible operations. Question 2 involves estimating the power required for an isentropic compression process of oxygen gas. Question 3 involves estimating the work and cooling requirements for compressing and cooling CO2 gas. Question 4 involves determining temperature, pressure, and latent heat values at the triple point for ammonia. Question 5 involves calculating initial and final mole fractions of vapor for a material undergoing a phase change at constant volume heating.

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    CH2010 Chemical Engineering Thermodynamics Assignment - 2

    Uploaded by

    Aryan Pandey
    60 views2 pages
    The document contains 5 questions regarding thermodynamics concepts. Question 1 involves calculating the net heat interaction and changes in enthalpy and Helmholtz free energy for a gas in a closed vessel undergoing irreversible operations. Question 2 involves estimating the power required for an isentropic compression process of oxygen gas. Question 3 involves estimating the work and cooling requirements for compressing and cooling CO2 gas. Question 4 involves determining temperature, pressure, and latent heat values at the triple point for ammonia. Question 5 involves calculating initial and final mole fractions of vapor for a material undergoing a phase change at constant volume heating.

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    The document contains 5 questions regarding thermodynamics concepts. Question 1 involves calculating the net heat interaction and changes in enthalpy and Helmholtz free energy for a gas in a closed vessel undergoing irreversible operations. Question 2 involves estimating the power required for an isentropic compression process of oxygen gas. Question 3 involves estimating the work and cooling requirements for compressing and cooling CO2 gas. Question 4 involves determining temperature, pressure, and latent heat values at the triple point for ammonia. Question 5 involves calculating initial and final mole fractions of vapor for a material undergoing a phase change at constant volume heating.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    60 views2 pages

    CH2010 Chemical Engineering Thermodynamics Assignment - 2

    Uploaded by

    Aryan Pandey
    The document contains 5 questions regarding thermodynamics concepts. Question 1 involves calculating the net heat interaction and changes in enthalpy and Helmholtz free energy for a gas in a closed vessel undergoing irreversible operations. Question 2 involves estimating the power required for an isentropic compression process of oxygen gas. Question 3 involves estimating the work and cooling requirements for compressing and cooling CO2 gas. Question 4 involves determining temperature, pressure, and latent heat values at the triple point for ammonia. Question 5 involves calculating initial and final mole fractions of vapor for a material undergoing a phase change at constant volume heating.

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    CH2010

     Chemical  Engineering  Thermodynamics  


    Assignment-­‐2  
    Date:      20.09.2018  

    1. In a closed vessel, 3 kJ of work is done on 2 moles of a gas by some series of irreversible


    operations. In this process, pressure increases from 10 bar to 20 bar and temperature from
    300 K to 320 K. The gas obeys the equation of state: P(v – b) = RT, where b = 5x10-5
    m3/mol. At 10 bar over the temperature range of interest, the specific heat capacity of the gas
    at constant volume can be calculated as Cv = 0.1 T (where T is in K).

    (a) Calculate the net heat interaction of the given system with the environment.

    (b) Determine the change of enthalpy ΔH and change of Helmholtz free energy ΔA for the
    system mentioned above.

    2. In an isentropic process, an oxygen gas at 150 K is compressed from 30 bar to 100 bar with
    an efficiency of 80%. Estimate the power required for the compressor if the gas flow rate is
    10 kg/s. Assume that the above system obeys the Peng-Robinson equation of state with
    Tc = 154.6 K, Pc = 50.46 bar, Cp = 29.3 J/mol K and an acentric factor of 0.021.

    3. In an enhanced oil recovery operation, an adiabatically compressed CO2 is cooled at constant


    pressure and then flooded into an oil-bearing reservoir encased with steel pipe as given in
    below figure. Estimate the work and cooling requirements of CO2 with T0 = 25 °C while
    assuming that the CO2 obeys van der Waals EOS.

    Specific heat of CO2 at constant pressure is given as (T is in K):

    𝐶!! 𝑇 = 𝑎 + 𝑏𝑇 + 𝑐𝑇 ! + 𝑑𝑇 ! 𝐽 𝑚𝑜𝑙 𝐾 ,

    where a = 19.8, b = 0.07344, c = 0.5602 x 10-4, d = 1.715 x 10-8.


    !"#!
    4. The vapor pressure of liquid ammonia near the triple point isgiven by 𝑙𝑛𝑃 = 24.38 − !
    which is the equation of liquid-vapor boundary curve in a P-T diagram, where P is in Pa,
    !"#$
    Similarly, vapor pressure of solid ammonia is given as 𝑙𝑛𝑃 = 27.92 − !
    , where P is in Pa.

    Estimate/Determine the following:

    i) Temperature and pressure at triple point


    ii) Latent heats of sublimation and vaporization
    iii) Latent heat of fusion at the triple point

    5. A constant latent heat of vaporization of 5×10! 𝐽 𝑚𝑜𝑙 exists along the coexistence curve for
    a particular material. Consider one mole of this material is in a liquid-vapor equilibrium at
    300K and 105 Pa. On heating at constant volume V of 0.01 m3, system pressure increases to
    2×10! 𝑃𝑎 (Note that this is not a small ΔP). Find the initial and final mole fractions of vapor
    !!
    phase (𝑥 ≡ ! )
    ! !!!

    Assume the following,

    • Vapor phase is mono-atomic ideal gas


    • Molar volume of liquid is much lower than the Molar volume of gas

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