ZLD Concept Note
ZLD Concept Note
ZLD Concept Note
For
Prepared by
April-2016
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Acknowledgement
The concept note is prepared as per the discussion with the members of the
SGTPA on 14th March, 2016 and their requirements. The note includes the
important issues like SWOT analysis, the global scenario of ZLD, challenges
against ZLD, its alternatives and some suggestions as to where and why ZLD
shall be implemented. The note further includes the data/feedback pertaining
to field visits, photographs related to the visits, environmental issues of the textile
sector and the need and viability of ZLD.
J.K. Vyas
Head
Industrial Pollution Prevention,
Centre for Environment Education
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Contents
Sr No Chapters Page No
2 SWOT analysis 8
10 Alternatives to ZLD 19
12 Comments/suggestions 20
1. Background
The Ministry of Environment Forest &Climate Change (MOEF&CC) has prepared
a draft for circulation to the textile industries to achieve Zero Liquid Discharge
(ZLD) if their waste water discharge is more than 25KLD and also to the clusters of
the textile sector regardless of their effluent discharge quantity. The ministry has
invited comments/suggestions in this regard from concerned stake holders. The
comments/suggestions are to be sent to the MS and DD CPCB New Delhi.
CEE -Ahmedabad is entrusted with the task of preparation of the concept note
in this regard by SGTPA-Surat and accordingly this note is prepared.
In China, the discovery and consequent development of sericulture and spin silk
methods got initiated at 2640 BC while in Egypt the art of spinning linen and
weaving developed in 3400 BC. The discovery of machines and their
widespread application in processing natural fibers was a direct outcome of the
industrial revolution of the 18th and 19th centuries. The discoveries of various
synthetic fibers like nylon created a wider market for textile products and
gradually led to the invention of new and improved sources of natural fiber. The
development of transportation and communication facilities facilitated the path
of transaction of localized skills and textile art among various countries.
The textile industry is one of the oldest and largest industrial sectors in India and
our country is the second largest producer of textile and garment next to China.
The textile units are scattered all over India. (Figure-1) The textile industry in India
constitutes one of the country’s major export sectors. India makes a major
contribution to world trade in cotton yarn, accounting for some 25% of the total.
Indian Textiles Industry has an overwhelming presence in the economic life of
the country. Apart from providing one of the basic necessities of life, the textile
industry also plays a pivotal role through its contribution to industrial output,
employment generation and export earnings of the country.
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Indian textile industry can be divided in to several segments some of which are
as under:
Silk: INDIA is the second largest producer of silk and contributes world’s
18% raw silk production.
Wool: INDIA has 3rd largest ship population in the world, having 6.15 crores
sheep, producing 45 million kg of raw wool, and accounting for 3.1% of
the total world wool production, INDIA’S rank 6th amongst clean wool
producer countries and 9th amongst greasy wool producers.
Jute: INDIA is the largest producer and second largest exporter of the jute
goods.
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Mexico (NAFTA), Turkey Proximity to market, duty Lack China and India’s
and quota free degree of
competitiveness
HELPFUL HARMFUL
(for your objective) (for your objective)
Strengths Weakness
Tradition in Textiles and long operating The textile industry of India is one of
experience the highly disintegrated industries.
Large and growing domestic market Few segments of this industry are
Strong raw material base not highly productive.
Production across entire textile value There is a huge dependency of the
chain industry on cotton.
Stable, low-risk economy, safe for The mill segment is gradually
(Within Organization)
industry’s segments like handicrafts and same time, steadily improving the
apparels. quality of the products.
External
The textile industry is water and labor intensive and produces pollutants of
different forms. The manufacturing operation also generates vapors during
dyeing, printing and curing of dye or color pigments. Dust emission is associated
with fiber processing/boiler operation. Other than these process operations,
textile mills have wood, coal or oil fired boilers and thermic fluid heaters which
are point emission sources.
Major environmental issues in textile industry result from wet processing. Wet
processes may be carried out on yarn or fabric. The transformation of raw
cotton to final usable form involves different stages. The various important wet
processes involved in the textile industry are as follows:
Sizing / Slashing: This process involves sizing of yarn with starch or polyvinyl
alcohol (PVA) or carboxyl methyl cellulose (CMC) to give necessary tensile
strength and smoothness required for weaving. The water required for sizing
varies from 0.5 to 8.2 litre / kg of yarn with an average of 4.35litre / kg.
Desizing: The sizing components which are rendered water soluble during
sizing are removed from the cloth to make it suitable for dyeing and further
processing. This can be done either through acid (sulphuric acid) or with
enzymes. The required water at this stage varies from 2.5 to 21 L /Kg. with an
average of 11.75 L/Kg.
Scouring / Kiering: This process involves removal of natural impurities such
as greases, waxes, fats and other impurities. The desized cloth is subjected to
scouring. This can be done either through conventional method (kier boiling) or
through modern techniques (continuous scour). Kiering liquor is an alkaline
solution containing caustic soda, soda ash, sodium silicate and sodium peroxide
with small amount of detergent. The water required for this process varies from
20 – 45 L/ Kg. with an average of 32.5 L/Kg.
Bleaching: Bleaching removes the natural coloring materials and renders
the cloths white. More often the bleaching agent used is alkaline hydrochloride
or chlorine. For bleaching the good quality fibre, normally peroxide is used. The
chemicals used in peroxide bleaching are sodium peroxide, caustic soda,
sulphuric acid and certain soluble oils. The water and chemical requirement and
the effluent generation normally vary based on the type of operation and the
material (yarn / cloth) to be processed. Bleaching the yarn both through
hypo‐chloride and hydrogen peroxide methods require same quantity of water
and it varies between 24 to 32 L/kg. But in the cloth bleaching, the water
requirement is much higher and it fluctuates between 40 ‐ 48 L/kg.
Mercerizing: The process of Mercerization provides lustre, strength, dye
affinity and abrasion resistance to fabrics. It is generally carried out for cotton
fabrics only for easy dyeing. Mercerization can be carried out through cold
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caustic soda solution followed by washing with water several times. The water
required for this process varies from 17 to 32 L / kg, with an average of 24.5
Dyeing: Dyeing is the most complex step in wet processing which provides
attractive color for the product. Dyeing is carried out either at the fiber stage, or
as yarn or as fabrics. For dyeing process, hundreds of dyes and auxiliary
chemicals are used. In brief, the water requirement for dyeing purpose (include
all types and shades) varies from 36 – 176 L/kg with an average of 106. The
effluent generation during dyeing process fluctuates from 35 to 175 L/kg with an
average of 105 L/kg.
Table 2: The characteristics of the textile wastes after the various processes
As in the case of other countries, textile industries in India are also highly water
polluting, besides causing air pollution. Major air pollution sources are the boilers
and thermic fluid heaters. The liquid effluent characteristic and effluent quantity
vary according to the processes involved, chemicals used and the scale of
operation. Therefore, very often the quality of effluent from one industry varies
from the other similar industry.
As the textile manufacturing units use different type of raw materials, chemicals
and processes, the wastewater treatment may require the use of unit operations
specific to manufacturing processes in use. Techniques for treating industrial
process waste water in this sector are - source segregation and pre-treatment of
waste water streams.
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Tertiary Treatment
Textile effluents may require tertiary or advance treatment methods to remove
particular contaminants, dissolved salts or to prepare the treated effluent for
reuse. Some common tertiary operations are removal of residual organic color
compounds by adsorption and removal of dissolved solids by membrane
filtration. Sometimes the wastewater is also treated with ozone or other oxidizing
agent to destroy many contaminants. Evaporation and crystallization are other
methods to minimize effluent disposal problems.
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Adsorption
The adsorption process is used to remove color and other soluble organic
pollutants from effluent. The process also removes toxic chemicals such as
pesticides, phenols, cyanides and organic dyes that cannot be treated by
conventional treatment methods. Dissolved organics are adsorbed on surface
as waste water containing these is made to pass through adsorbent. Most
commonly used adsorbent for treatment is activated carbon.
The activated carbon once it is saturated needs replacement or regeneration.
The chemical regeneration can be done within the column either with acid or
other oxidizing chemicals.
Ion Exchange
Ion exchange process is normally used for the removal of inorganic salts and
some specific organic anionic components such as phenol. In the ion exchange
process the impurities from the effluent streams is transformed into another one
of relatively more concentrated with increased quantity of impurities because of
the addition of regeneration chemicals.
Reverse Osmosis
After primary, secondary and/or tertiary treatment, further purification by
removal of organics and dissolved salts is possible by use of reverse osmosis. The
process of reverse osmosis is based on the ability of certain specific polymeric
membranes, usually cellulose acetate or nylon to pass pure water at fairly high
rates and to reject salts. To achieve this, Water or waste water stream is passed
at high pressures through the membrane. The applied pressure has to be high
enough to overcome the osmotic pressure of the stream, and to provide a
pressure driving force for water to flow from the reject compartment through the
membrane into the clear water compartment.
RO membranes are susceptible to fouling due to organics, colloids and
microorganism. In a typical reverse osmosis system, the feed water is pumped
through a pre-treatment section which removes suspended solids and if
necessary, ions such as iron and magnesium which may foul the system. The
feed water is then passed through the reverse osmosis modules at high pressure.
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RO Stage
Primary RO Stage I
Influe Ozonati II
Parameters Treatme
nt on Perm Rejec Permeat
nt Reject
eate t e
pH 9.88 9.61 6.92 6.03 6.72 5.76 7.04
Total suspended
167 56 19 6 70 6 124
solids, mg/L
Total dissolved
3104 1946 3256 922 9830 196 17828
solids, mg/L
Chemical
oxygen 586 166 130 26 327 17 754
demand, mg/L
Biochemical
oxygen 190 41 41 1 16 02 208
demand, mg/L
Total Hardness,
96 ‐ ‐ ‐ 60 Nil 1080
mg/L
Chlorides, mg/L 334 636 692 314 108 34 4416
Colourle Colo Colourle
Color, % purity <10 <10 <10 10‐20
ss urless ss
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In view of the indiscriminate use of the water, its insufficiency, its conservation
and the issues related to the waste water disposal and the pollution of the
natural streams/rivers; the government is intending to issue a notification under
the E.P.A. -86 for implementation of ZLD in textile units having its effluent
discharge more than 25 m3 /day and also for all textile units in clusters
irrespective of their waste water discharge. The draft notification is issued in this
context by MoEF&CC. In Chennai the judiciary has directed the CETPs of the
textiles to go for ZLD in 2009 and then to the textile units in 2011.
The industries i.e. textiles in different parts of the our country have adopted the
concept of ZLD strictly according to their requirements e.g. the units in Tirupur in
Chennai have installed ZLD system in order to comply with the directions of the
Hon’ble court.
In Rajasthan the industries opted for ZLD because of the directions from the
court, scarcity of water, its requirement for conservation.
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Sea Discharge
The state of Gujarat is blessed with the largest coastline in the country and so
the treated effluent from CETPs can be safely discharged in to the sea. Sea
discharge is a better alternative against ZLD. In sea discharge we have two
methods. One is to treat the mixed effluent with primary, secondary and tertiary
treatments and dispose into the sea. Here all the water and salt are lost in to the
sea.
Another method is to treat with the above methods and recover water for reuse
by RO Treatment. Then send the final reject to sea discharge. Here we recover
about 85% of the water for reuse and avoid only the Multiple Evaporator losing
the salt. But the reject from RO Plant will have more contaminants more than the
sea Discharge Norms. Hence the RO reject cannot be easily discharged into the
sea. Therefore only the fully treated water (Primary, Secondary &Tertiary) can be
discharged into the sea. But for this we have to carry-out a large scale
Environment Impact Assessment study through the renowned institutes like NIO
or NIOT. This may take some time.
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We have already seen that since the mixed effluent has a TDS of about 4,000-
6,000 ppm, we cannot discharge into inland surface water. There is one
possibility of mixing 1 – 2 times normal raw water with the treated effluent till the
TDS reaches less than 2,100 ppm and then discharge. This is to be done with
special permission from the Government. Even this is possible only after doing
primary, secondary and tertiary effluent treatment. If you assume a total effluent
generation from Tirupur Dyeing factories to be around 10 crore litres per day,
then we need another 10 – 20 crore litres of normal water per day to be mixed
with it. This will be against the principle of worldwide philosophy of “Water
Conservation”.
12. Comments/Suggestions:
Each state has its own uniqueness about its eco system and the
environment, therefore in all such states where sea disposal facility is
available, the system of disposal of treated effluent it may be allowed as
while disposing treated effluent in to the sea, huge dilution is available
and the impact on the marine eco system will be minimum.
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There are safe locations in the country especially in the state of Gujarat and
such other coastal states; where scientific disposal of the effluent in to the
sea is feasible and is at present being practiced very successfully. This mode
of disposal is practical, safe, cost effective and also environmentally
acceptable as it consumes less power compared to ZLD and has less carbon
foot print. Accordingly the option must be given to such states (SPCBs/PCCs)
to direct concerned textile industries/clusters to treat their effluent as per
marine norms and discharge at a point in to the sea to be decided by the
expert marine agency.
Imposing ZLD in the states where marine disposal is available will put
unnecessary huge financial burden and mental stress on industries/clusters
and there are all chances of closing down of the units/clusters leading to
huge unemployment and all other related nuisances.
The option of disposal of treated effluent in to the sea is a safe and cost
effective alternative to ZLD.
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The Member Secretary of a SPCB opined that ZLD should be tried in highly
polluting industries rather than textiles. Textile effluent is easily treatable to
achieve consented norms. In places of water scarcity, Treated Domestic
Sewage can be supplied to Industries, as being done in the cities of Surat
and Ahmedabad.
The ZLD plant consumes huge power and fuel leading to pollution of the
environment. Implementation of ZLD will require an investment of Rupees
One Lakh Eight Thousand Crores (6000MLD @ 18cr/MLD) in addition to
land for setting up the plants. In many existing industries and textile clusters
established by State Governments, availability of required land is a
constraint. Cost of acquiring land, wherever available is also variable. The
huge capital and operating expenses of the ZLD plants will render the
entire textile industry unviable, resulting in collapse of the whole chain. It is
important to note that the Textile Industry of India is the second largest
employment generating industry only after agriculture. Unskilled labour is
easily absorbed in this industry. The textile industry commands a high
position in the economy of the country and earns valuable foreign
exchange.
The Government has come up with revised Textile Upgradation Fund (TUF)
scheme to give capital subsidy to the new units and also to the existing
ones which want to bring modern machinery and increase output. The
approval to 24 Textile Parks in last one year and others are also given
earlier. Total would be 74 Textile Parks under which Rs.30000 crore
investment is expected, ZLD would be a big obstacle to attract
investments and the entire system would be out of the gear and will
critically affect the overall economy of our country.
Sand filters
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Pumps, Blower and pipeline network showing highly power extensive process of ZLD
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Aeration Tank