SAFETY DATA SHEET

Revision date 25-November-2020 Revision Number 2

1. Identification
Product identifier

Product Name TERGITOL(R) NP-10, SURFACTANT

Other means of identification

Product Code(s) T1273

Synonyms None

Recommended use of the chemical and restrictions on use

Recommended use No information available

Restrictions on use No information available

Details of the supplier of the safety data sheet

Supplier Address
Spectrum Chemical Mfg. Corp.
14422 South San Pedro St.
Gardena, CA 90248
(310) 516-8000

Emergency telephone number

Emergency Telephone Chemtrec 1-800-424-9300

2. Hazard(s) identification
Classification

Acute toxicity - Oral Category 4

Acute toxicity - Inhalation (Vapors) Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Serious eye damage/eye irritation Category 1

Hazards not otherwise classified (HNOC)

Not applicable

Label elements
Danger

Hazard statements
Harmful if swallowed
Harmful if inhaled
Causes serious eye damage
Appearance No information available Physical state Liquid Odor No information available

Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wear eye protection/ face protection

Precautionary Statements - Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor
IF INHALED: Remove person to fresh air and keep comfortable for breathing
Call a POISON CENTER or doctor if you feel unwell
IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell
Rinse mouth

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Unknown acute toxicity

2 % of the mixture consists of ingredient(s) of unknown acute oral toxicity

Other information
May be harmful in contact with skin.

3. Composition/information on ingredients
Substance

Not applicable.

Mixture

Chemical name CAS No Weight-% Trade secret

Nonylphenol polyethylene glycol ether 127087-87-0 >= 97 *
Polyethylene Glycol 25322-68-3 <= 3 *
Dinonylphenyl polyoxyethylene 9014-93-1 <= 2 *
1,4-Dioxane 123-91-1 0.002 *

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. First-aid measures
Description of first aid measures

General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur. If symptoms
persist, call a physician. If breathing has stopped, give artificial respiration. Get medical
attention immediately.
Eye contact Get immediate medical advice/attention. Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.

Skin contact Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical
attention if irritation develops and persists.

Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Get medical attention.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination. Avoid breathing vapors or mists. Use personal protective equipment as
required. See section 8 for more information.

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Coughing and/ or wheezing. Difficulty in breathing.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. Fire-fighting measures
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.

Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.

Specific hazards arising from the No information available.

chemical

Hazardous combustion products Carbon monoxide. Carbon dioxide (CO2).

Explosion data
Sensitivity to mechanical impact none.

Sensitivity to static discharge none.

Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Ensure adequate ventilation. Avoid breathing vapors or mists.

Other information Refer to protective measures listed in Sections 7 and 8.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. Handling and storage
Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Avoid breathing
vapors or mists. Ensure adequate ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children. Store locked up.

8. Exposure controls/personal protection

Control parameters

Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.

Chemical name ACGIH TLV OSHA PEL NIOSH IDLH

1,4-Dioxane No data available 100 ppm TWA -
123-91-1 360 mg/m3 TWA

Appropriate engineering controls

Engineering controls Showers

Eyewash stations
Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.

Hand protection Wear suitable gloves.

Skin and body protection Wear suitable protective clothing.

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

General hygiene considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product.

9. Physical and chemical properties

Information on basic physical and chemical properties
Physical state Liquid
Appearance No information available
Color Colorless to pale yellow
Odor No information available
Odor threshold No information available

Property Values Remarks • Method

pH no data available None known
Melting point / freezing point no data available None known
Boiling point / boiling range > 250 °C / 482 °F None known
Flash point 197 °C / 386.6 °F None known
Evaporation rate no data available None known
Flammability (solid, gas) no data available None known
Flammability Limit in Air None known
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapor pressure No data available None known
Vapor density no data available None known
Relative density 1.0622 None known
Water solubility Completely soluble in water None known
Solubility(ies) no data available None known
Partition coefficient No data available None known
Autoignition temperature no data available None known
Decomposition temperature None known
Kinematic viscosity no data available None known
Dynamic viscosity No data available None known

Other information
Explosive properties No information available
Oxidizing properties No information available
Softening point No information available
Molecular weight Av. M.W. = 66
VOC Content (%) No information available
Liquid Density No information available
Bulk density No information available

10. Stability and reactivity

Reactivity No information available.

Chemical stability Stable under normal conditions.

Possibility of hazardous reactions None under normal processing.

Conditions to avoid Excessive heat.

Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.

Hazardous decomposition products None known based on information supplied.

11. Toxicological information

Information on likely routes of exposure

Product Information .

Inhalation Specific test data for the substance or mixture is not available. Harmful by inhalation.
(based on components).

Eye contact Specific test data for the substance or mixture is not available. Causes serious eye
damage. May cause irreversible damage to eyes.

Skin contact Specific test data for the substance or mixture is not available. May cause irritation. May be
harmful in contact with skin.

Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. Harmful if swallowed. (based on
components).

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing.

Acute toxicity

Numerical measures of toxicity

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 1,348.00 mg/kg

Unknown acute toxicity

2 % of the mixture consists of ingredient(s) of unknown acute oral toxicity

Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Nonylphenol polyethylene glycol > 1000 mg/kg ( Rat ) - -
ether
127087-87-0
Polyethylene Glycol = 22 g/kg ( Rat ) > 20 g/kg ( Rabbit ) -
25322-68-3 = 28 g/kg ( Rat )

1,4-Dioxane = 5170 mg/kg ( Rat ) = 7600 mg/kg ( Rabbit ) = 46 mg/L ( Rat ) 2 h

123-91-1

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation May cause skin irritation.

Serious eye damage/eye irritation Classification based on data available for ingredients. Causes burns. Risk of serious
damage to eyes.
Respiratory or skin sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.

Reproductive toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available.
Aspiration hazard No information available.

Other adverse effects No information available.

Interactive effects No information available.

12. Ecological information

Ecotoxicity .
Chemical name Algae/aquatic plants Fish Toxicity to Crustacea
microorganisms
Polyethylene Glycol - LC50: >5000mg/L (24h, - -
25322-68-3 Carassius auratus)
1,4-Dioxane - LC50: 10306 - - EC50: =163mg/L (48h,
123-91-1 14742mg/L (96h, water flea)
Pimephales promelas)
LC50: =9850mg/L (96h,
Pimephales promelas)
LC50: >10000mg/L (96h,
Lepomis macrochirus)

Persistence and degradability No information available.

Bioaccumulation Inherently biodegradable.

Chemical name Partition coefficient

1,4-Dioxane -0.42
123-91-1
Other adverse effects No information available.

13. Disposal considerations

Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.

Contaminated packaging Do not reuse empty containers.

14. Transport information

DOT not regulated

TDG not regulated

MEX not regulated

ICAO (air) not regulated

IATA not regulated

IMDG not regulated

RID not regulated

ADR not regulated

ADN not regulated

15. Regulatory information

International Inventories

TSCA Complies

DSL/NDSL Complies
EINECS/ELINCS Does not Comply
ENCS This product complies with ENCS:
IECSC This product complies with China:
KECL Complies
PICCS Complies
AICS All the constituents of this material are listed on the Australian Inventory of Chemical
Substances (AICS).

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances

US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

Chemical name SARA 313 - Threshold Values %

Nonylphenol polyethylene glycol ether - 127087-87-0 1.0
1,4-Dioxane - 123-91-1 0.1

SARA 311/312 Hazard Categories

Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate
classifications.

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.

Chemical name Hazardous Substances RQs Extremely Hazardous Substances RQs

1,4-Dioxane 100 lb final RQ -
123-91-1 45.4 kg final RQ

US State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

This product does not contain any substances regulated under applicable state right-to-know regulations

U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable

16. Other information

NFPA
Health hazards 3
Flammability 1
Instability 0
Physical and chemical properties -
HMIS
Health hazards 3
Flammability 1
Physical hazards 0
Personal protection X

Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value

Key literature references and sources for data used to compile the SDS
Agency for Toxic Substances and Disease Registry (ATSDR)
U.S. Environmental Protection Agency ChemView Database
European Food Safety Authority (EFSA)
EPA (Environmental Protection Agency)
Acute Exposure Guideline Level(s) (AEGL(s))
U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act
U.S. Environmental Protection Agency High Production Volume Chemicals
Food Research Journal
Hazardous Substance Database
International Uniform Chemical Information Database (IUCLID)
Japan GHS Classification
Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
NIOSH (National Institute for Occupational Safety and Health)
National Library of Medicine's ChemID Plus (NLM CIP)
National Library of Medicine's PubMed database (NLM PUBMED)
National Toxicology Program (NTP)
New Zealand's Chemical Classification and Information Database (CCID)
Organization for Economic Co-operation and Development Environment, Health, and Safety Publications
Organization for Economic Co-operation and Development High Production Volume Chemicals Program
Organization for Economic Co-operation and Development Screening Information Data Set
World Health Organization

Revision date 25-November-2020

Revision Note No information available.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet