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fundamental relationship between the pressure of a gas and the volume it occupies.
Robert Boyle put chemistry on a firm scientific footing, transforming it from a field bogged down in
alchemy and mysticism into one based on measurement. He defined elements, compounds, and
mixtures, and he coined the new term ‘chemical analysis,’ a field in which he made several powerful
contributions.
Known for In 1834, he made his first contribution to the creation
• Second law of thermodynamics of modern thermodynamics by publishing a report
entitled Mémoire sur la puissance motrice de la chaleur
• Ideal gas law
(Memoir on the Motive Power of Heat), in which he
• Clapeyron's theorem developed the work of the physicist Nicolas Léonard
Sadi Carnot, deceased two years before. Though Carnot
• Clapeyron's theorem of three moments
had developed a compelling analysis of a generalized
• Clapeyron equation heat engine, he had employed the clumsy and already
• Clausius-Clapeyron unfashionable caloric theory.
Clapeyron also worked on the characterization of perfect gases, the equilibrium of homogeneous
solids, and calculations of the statics of continuous beams, notably the theorem of three moments.
Clapeyron is well known in thermodynamics through the Clausius–Clapeyron equation that describes the
variation of the vapor pressure with temperature; few are aware that he made his career as a railroad
engineer and locomotive designer.
Jacques-Alexandre-César Charles
Charles's Law
Robert William Boyle
Boyle's Law
Benoît Paul Émile Clapeyron
Charles's law defines the direct relationship between temperature and volume. When the
parameters of a system change, Charles's law helps us anticipate the effect the changes have on
volume and temperature.