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    MSDS-RIPSTAR 122-Part 2

    Uploaded by

    Ankita Baban Gavade
    This document provides safety information about a hardener component of an epoxy resin putty. It lists the product identification and manufacturer, describes health and physical hazards, outlines first aid measures, firefighting guidance, handling and storage advice, exposure controls, physical/chemical properties, and other details.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    MSDS-RIPSTAR 122-Part 2

    Uploaded by

    Ankita Baban Gavade
    35 views6 pages
    This document provides safety information about a hardener component of an epoxy resin putty. It lists the product identification and manufacturer, describes health and physical hazards, outlines first aid measures, firefighting guidance, handling and storage advice, exposure controls, physical/chemical properties, and other details.

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    © © All Rights Reserved

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    PDF, TXT or read online from Scribd

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    This document provides safety information about a hardener component of an epoxy resin putty. It lists the product identification and manufacturer, describes health and physical hazards, outlines first aid measures, firefighting guidance, handling and storage advice, exposure controls, physical/chemical properties, and other details.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    35 views6 pages

    MSDS-RIPSTAR 122-Part 2

    Uploaded by

    Ankita Baban Gavade
    This document provides safety information about a hardener component of an epoxy resin putty. It lists the product identification and manufacturer, describes health and physical hazards, outlines first aid measures, firefighting guidance, handling and storage advice, exposure controls, physical/chemical properties, and other details.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    RIPSTAR® 122 (Part 2)

    Safety Data Sheet


    1. Identification of the substance/preparation and of the company/undertaking

    Article no. (Manufacturer / Supplier): RIPSTAR 122 (Part 2)


    Identification of the substance or preparation: Hardener component of epoxy resin base putty
    Recommended use: Construction Chemical

    Name of the company:


    SP Concare Pvt. Ltd. Plot No. D-61, Miraj Block,
    Miraj M.I.D.C, Dist. Sangli-416 410
    Maharashtra, India.

    Emergency phone: +91 9561921967

    2. Hazards identification

    Hazard designation:

    Xi Irritant

    No Dangerous for the environment

    Critical hazard to man and environment:


    36/38 Irritating to eyes and skin.
    43 May cause sensitization by skin contact.

    3. Composition/information on ingredients

    Chemical characterization (preparation)


    Description: Hardener
    Dangerous ingredients:

    EC-no.: Identification of the hazard: Labelling % By


    CAS-No.: R phrases: (67/548/EEC or weight
    INDEX no.: REACH-no.: 1999/45/EC)
    Remark:
    203-950-6 Polyamine Adducts C 92-95
    9012-28-6
    612-059-00-5

    Additional information
    * Substance with a common (EC) occupational exposure limit value. Full text
    of R-phrases: see section 16.
    4. First aid measures

    General information:
    In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth, place in
    unconscious position and seek medical advice.
    Following inhalation:
    Move victim to fresh air. Put victim at rest and keep warm. In case of irregular breathing or respiratory arrest provide artificial
    respiration.
    After skin contact:
    Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do not use
    solvents or thinners.
    Following eye contact:
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    Seek medical advice.
    After ingestion:
    If swallowed, rinse mouth with water (only if the person is conscious). Consult physician immediately. Keep victim calm. Do not
    induce vomiting.

    5. Firefighting measures

    Suitable extinguishing media: alcohol resistant foam, Carbon dioxide, Powder, spray mist, (water)
    Extinguishing media which must not be used for safety reasons: High power water jet
    Special exposure hazards arising from the substance itself, combustion products, resulting gases:
    Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage. Special
    Protective equipment for fire-fighters: Provide a conveniently located respiratory protective device.
    Additional information: Cool closed containers that are near the source of the fire. Do not allow water used to extinguish fire to
    enter drains, ground or waterways. Treat runoff as hazardous.

    6. Accidental release measures

    Personal precautions:
    Keep away from sources of ignition. Ventilate affected area. Do not inhale vapors. See protective measures under point 7 and 8.
    Environmental precautions:
    Do not empty into drains or the aquatic environment. If the product contaminates lakes, rivers or sewages, inform competent
    authorities in accordance with local regulations.
    Methods for cleaning up:
    Isolate leaked material using non-flammable absorption agent (e.g., sand, earth, vermiculite, diatomaceous earth) and collect it for
    disposal in appropriate containers in accordance with the local regulations (see chapter 13). Clean using cleansing agents. Do not
    use solvents.

    7. Handling and storage

    Handling Information for safe handling:


    Avoid formation of flammable and explosive vapor concentrations in the air and exceeding the exposure limit values. Only use
    material in places where open light, fire and other sources of ignition can be kept away. Electrical equipment must be protected
    meeting the accepted standard. Product may become electrostatically charged. Ensure the grounding of containers, apparatus,
    pumps and suction equipment. Anti-static clothing including shoes are recommended. Floors must be electrically conductive. Keep
    away from heat sources, sparks, and open flames. Use only spark proof tools. Avoid contact with skin, eye, and clothing. Do not
    inhale dusts, particulates, and spray mist when using this preparation. Avoid breathing swarf. When using do not eat, drink or
    smoke. Personal protection equipment: refer to chapter 8. Do not empty containers with pressure – no pressure vessel! Always
    keep in containers that correspond to the material of the original container. Follow the legal protection and safety regulations.

    Precautions against fire and explosion:


    Vapors are heavier than air and will spread at floor level. Vapors form explosive mixtures with air.
    Storage Requirements for storerooms and containers:
    Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
    empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorized persons. Store carefully
    closed containers upright to prevent any leaks.

    Information about storage in one common storage facility:


    Keep away from strongly acidic and alkaline materials as well as oxidizers.

    Further information concerning storage conditions:


    Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15° and 40°C. Protect
    from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
    only for authorized persons. Store carefully closed containers upright to prevent any leaks.

    8. Exposure controls / Personal protection equipment

    Technical measures to prevent exposure:


    Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and
    solvent vapor concentration below the exposure limit values, a suitable respiratory protection must be used.
    Components with workplace or biological limit values to be monitored:

    EC-no.: description: type: Value unit


    CAS-No.: STEL (EC) TWA (EC)

    Additional information:
    Stated values are taken from the then applicable German TRGS 900 Oder the German VCI table for exposure limit values.
    TWA (EC): Occupational exposure limit value
    STEL (EC): Short term occupational exposure limit value

    Occupational exposure controls:


    Respiratory protection:
    If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must
    be used. Only use breathing apparatus with CE-label including the four-digit identification number.
    Hand protection:
    For prolonged or repeated handling, the following glove material must be used: gloves made from nitril-/neoprene rubber.
    Observe the instructions and details for use, storage, maintenance, and replacement provided by the protective glove
    manufacturer.
    Penetration time of glove material depending on intensity and duration of exposure to skin: Recommended protective gloves
    brand: DIN EN 374 Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
    Eye protection:
    Wear closely fitting protective glasses in case of splashes.
    Skin protection:
    Wear antistatic clothing of natural fibers (.le. cotton) or heat resistant synthetic fibers.
    Preventive measures:
    After contacting clean skin thoroughly with water and soap or use appropriate cleanser.

    9. Physical and chemical properties

    Appearance:
    State of matter: Liquid
    Paint: Brown
    Odor: typical
    Safety relevant basis data unit Method Remark:
    Flash point: > 200°C DIN 53213
    Decomposition temperature: > 200°C
    Melting point: NA
    Boiling point: > 200°C
    Vapor pressure (at temperature in °C): 0.15 mmHg (Benzyl alcohol)
    Specific gravity (at temperature in °C): 23 1.12
    Solubility in water (g/l): not soluble
    Vapor density: >1
    Flammability: Combustible substance.
    Auto ignition temperature: NA
    Flammable limits lower: NA
    Flammable limits upper: NA

    10. Stability and reactivity

    Conditions to avoid:
    Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
    chapter 7. Hazardous decomposition byproducts may form with exposure to high temperatures.
    Materials to avoid:
    Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
    Hazardous decomposition products:
    Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
    smoke, nitrogen oxides.

    11. Toxicological information

    No data on preparation itself available.


    Practical experience:
    Other observations:
    Inhaling of solvent components above the TWA-value can lead to health damage e.g., irritation of the mucous membrane and
    respiratory organs, as well as damage to the liver, kidneys, and the central nerve system. Indications for this are: headache,
    dizziness, fatigue, amyosthenia, drowsiness, in serious cases: unconsciousness. Solvents may cause some of the aforementioned
    effects through skin resorption. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
    resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye irritation and reversible
    damage.
    Summarized evaluation of the CMR properties:
    The components in this formulation do not meet the criteria for classification as CMR category 1 or 2.
    There is no information available on the preparation itself. The preparation has been assessed following the conventional
    method of the Dangerous Preparations Directive 1999/45/EC and classified according to the toxicological dangers. See
    chapters 2 and 15 for details.

    12. Ecological information

    Type judging:
    There is no information available on the preparation itself.
    Do not empty into drains or the aquatic environment.
    Results of PBT assessment
    The components in this formulation do not meet the criteria for classification as PBT or vPvB.
    The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is
    classified for eco-toxicological properties accordingly. See Sections 2 and 15 for details.
    13. Disposal considerations

    Appropriate disposal/Product:
    Recommendation:
    Do not empty into drains or the aquatic environment. This material and its container must be disposed of in a safe way.

    Waste disposal according to EC Directives 75/442/EEC and 91/689/EEC on waste and hazardous waste in their latest versions.

    Control report for waste code/ waste marking according to EAKV:


    080409 waste adhesives and sealants containing organic solvents or other dangerous substances
    Contaminated packaging:
    Recommendation:
    Cleaned containers may be recycled. Vessels not properly emptied are special waste.

    14. Transport information

    Transport according to ADR/RID, IMDG and ICAO/IATA.

    Overland transport (ADR/RID)


    Class: 8
    Label: 8
    UN No.: 2735
    Hazard identification number (Kemler No.): 80
    Official directive for the transport : Polyamines, liquid, corrosive, n.o.s.
    Packing Group: III
    Tunnel restriction code: E
    Transport by sea (IMDG)
    Class: 8
    Label: 8
    EmS-No.: F-A, S-F
    UN No.: 2735
    Official directive for the transport: POLYAMINES, LIQUID, CORROSIVE, N.O.S.,
    Packing Group: III
    Marine pollutant: NA

    Air transport (ICAO-TI / IATA-DGR)


    Class: 8
    Label: 8
    UN No.: 2735
    Official directive for the transport: Polyamines, liquid, corrosive, n.o.s,
    Packing Group: III

    15. Regulatory information

    EU-Regulations
    Chemical Safety Assessment
    Chemical safety assessments for substances in this preparation were not carried out.
    Labelling (67/548/EEC or 1999/45/EC)
    Danger symbol(s) and danger term(s) for dangerous materials and preparations:
    Xi Irritant

    N Dangerous for the environment

    Contains:
    reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700)
    R phrases:
    36/38 Irritating to eyes and skin.
    43 May cause sensitization by skin contact.
    51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

    S phrases:
    24 Avoid contact with skin.
    26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
    37 Wear suitable gloves.
    61 Avoid release to the environment. Refer to special instructions/Safety data sheets.

    Special labelling of particular preparations:


    92 Contains epoxy constituents. May produce an allergic reaction.

    Other regulations (EU):


    Data concerning the Directive 1999/13/EC on the limitation of emissions of volatile organic compounds (VOC-RL)
    VOC-value (in g/l) ISO 11890-2: 0,000
    VOC-value (in g/l) ASTM D 2369: 0,000
    National regulations
    Information on working limitations:
    Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
    Observe employment restrictions under the law for the protection of young people at work (94/33/EC).

    16. Additional information

    Wording of the r-phrases under paragraph 3:


    21/22 Harmful in contact with skin.
    34 Causes burns.
    43 May cause sensitization by skin contact.
    52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

    Further remarks:
    The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and EU
    regulations. Without written approval, the product must not be used for purposes different from those mentioned in chapter 1. It is
    always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and regulations. The
    details in this safety data sheet describe the safety requirements of our product and are not to be regarded as guaranteed attributes
    of the product.
    Reason for issue: Updated.

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