Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Article no.: 171301V03800
Date of print: 18.05.2010
V 1301 ECO-BA EN
Revision date: 18.05.2010 page:1 / 5
1. Identification of the substance/preparation and of the company/undertaking
Article no. (manufacturer / supplier):
Identification of the substance or preparation:
171301V03800
V 1301 ECO-BA
Thinner
Supplier (manufacturer/importer/downstream user/distributor):
Lackwerke Peters GmbH + Co KG
Hooghe Weg 13
47906 Kempen
Telephone: ++49-2152-2009-0
Telefax: ++49-2152-2009-70
Dept. responsible for information:
Arbeitssicherheit und Umweltschutz
Emergency telephone:
E-mail: tilman.sehlen@peters.de
++49-2152-2009-78
This number is serviced during office hours.
2. Hazards identification
hazard designation:
Critical hazard to man and environment:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
3. Composition/information on ingredients
chemical characterization (preparation)
description: mixture of solvents
Dangerous ingredients:

EC-no.:
CAS-No.:
INDEX no.:
Identification of the hazard:
R phrases:
REACH-no.:
danger symbol(s):
Remark:
% by
weight
202-496-6
96-29-7
616-014-00-0
2-butanone oxime
21-40-41-43
Xn < 0,5
204-658-1
123-86-4
607-025-00-1
n-butyl acetate
10-66-67
50 - 100
Additional information
* Substance with a common (EC) occupational exposure limit value.
Full text of R-phrases: see section 16.
4. First aid measures
General information:
In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth,
place in unconscious position and seek medical advice.
Following inhalation:
Move victim to fresh air. Put victim at rest and keep warm. In case of irregular breathing or respiratory arrest provide artificial
respiration. Get immediate medical advice/attention.
After skin contact:
Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do
not use solvents or thinners.
Following eye contact:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. Seek medical advice.
after ingestion:
If swallowed, rinse mouth with water (only if the person is conscious). Consult physician immediately. Keep victim calm. Do
not induce vomiting.
5. Fire fighting measures
Suitable extinguishing media:
alcohol resistant foam, Carbon dioxide, Powder, spray mist, (water)
Extinguishing media which must not be used for safety reasons:
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Article no.: 171301V03800
Date of print: 18.05.2010
V 1301 ECO-BA EN
Revision date: 18.05.2010 page:2 / 5
High power water jet
Special exposure hazards arising from the substance itself, combustion products, resulting gases:
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
Special protective equipment for fire-fighters:
Provide a conveniently located respiratory protective device.
Additional information:
Cool closed containers that are near the source of the fire. Do not allow water used to extinguish fire to enter drains, ground or
waterways. Treat runoff as hazardous.
6. Accidental release measures
Personal precautions
Keep away from sources of ignition. Ventilate affected area. Do not inhale vapours. See protective measures under point 7
and 8.
Environmental precautions
Do not empty into drains or the aquatic environment. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
methods for cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see chapter 13). Clean using cleansing agents.
Do not use solvents.
7. Handling and storage

Handling
Information for safe handling:
Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Only
use material in places where open light, fire and other sources of ignition can be kept away. Electrical equipment must be
protected meeting the accepted standard. Product may become electrostatically charged. Ensure the grounding of containers,
apparatus, pumps and suction equipment. Anti-static clothing including shoes are recommended. Floors must be electrically
conductive. Keep away from heat sources, sparks and open flames. Use only spark proof tools.
Avoid contact with skin, eye and clothing. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid
breathing swarf. When using do not eat, drink or smoke.
Personal protection equipment: refer to chapter 8.
Do not empty containers with pressure - no pressure vessel! Always keep in containers that correspond to the material of the
original container. Follow the legal protection and safety regulations.
Precautions against fire and explosion:
Vapours are heavier than air and will spread at floor level. Vapours form explosive mixtures with air.
Storage
Requirements for storerooms and containers:
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks.
Information about storage in one common storage facility:
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information concerning storage conditions:
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 5 and 25C. Protect from
heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access only for
authorised persons. Store carefully closed containers upright to prevent any leaks.
8. Exposure controls / Personal protection equipment
Technical measures to prevent exposure
Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and
solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.
Components with workplace or biological limit values to be monitored:

EC-no.:
CAS-No.:
description: type: Value
STEL (EC) TWA (EC)
unit
204-658-1
123-86-4
n-butyl acetate 966
200
724
150
mg/m3
ppm
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Article no.: 171301V03800
Date of print: 18.05.2010
V 1301 ECO-BA EN
Revision date: 18.05.2010 page:3 / 5
Additional information
Stated values are taken from the then applicable German TRGS 900 oder the German VCI table for exposure limit values.
TWA (EC): Occupational exposure limit value
STEL (EC): Short term occupational exposure limit value
Occupational exposure controls:
Respiratory protection:
If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must
be used. Only use breathing apparatus with CE-label including the four-digit identification number.
Hand protection:
For prolonged or repeated handling the following glove material must be used: Nitrile rubber
Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove
manufacturer. Breakthrough times and swelling characteristics of the material must be taken into consideration. Recommended
protective gloves brand: DIN EN 374 Barrier creams can help protecting exposed skin areas. In no case should they be used
after contact.
Eye protection:
Wear closely fitting protective glasses in case of splashes.
Skin protection:
Wear antistatic clothing of natural fibers (.le. cotton) or heat resistant synthetic fibers.
Preventive measures:
After contact clean skin thoroughly with water and soap oder use appropriate cleanser.
9. Physical and chemical properties
Appearance:
State of matter: liquid
Paint: colourless
Odour: ester-like
Safety relevant basis data unit Method Remark:
Flash point: 27 C DIN 51755
Ignition temperature (AIT): 420 C DIN 51794
lower explosion limit: 1,4 Vol-%
Upper explosion level: 7,5 Vol-%
Vapour pressure at 20 C: 13,93 mbar
density at 20 C: 0,88 g/cm DIN 53217
Solubility in water (g/l): insoluble
pH at 20 C: not applicable
Viscosity at 20 C: 12 s 4 mm DIN 53211
Solvent separation test (%): < 3 %
Solid content (%): 1 % by weight
solvent content:
organic solvents: 100 % by weight
Water: 0 % by weight
10. Stability and reactivity
Conditions to avoid:
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
chapter 7. Hazardous decomposition byproducts may form with exposure to high temperatures.
Materials to avoid:
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
Hazardous decomposition products:
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides.
11. Toxicological information
Practical experience
Other observations:
Inhaling of solvent components above the MWC-value can lead to health damage, e.g. irritation of the mucous membrane and
respiratory organs, as well as damage to the liver, kidneys and the central nerve system. Indications for this are: headache,
dizziness, fatigue, amyosthenia, drowsiness, in serious cases: unconsciousness. Solvents may cause some of the
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Article no.: 171301V03800
Date of print: 18.05.2010
V 1301 ECO-BA EN
Revision date: 18.05.2010 page:4 / 5
aforementioned effects through skin resorption. Repeated or prolonged contact with the preparation may cause removal of
natural fat from the skin resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye
irritation and reversible damage.
Summarized evaluation of the CMR properties:
The components in this formulation do not meet the criteria for classification as CMR category 1 or 2.
There is no information available on the preparation itself . The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified according to the toxicological dangers.See
chapters 2 and 15 for details.
12. Ecological information
Type judging:
There is no information available on the preparation itself .
Do not empty into drains or the aquatic environment.
Results of PBT assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC
and is not classified as dangerous for the environment.
13. Disposal considerations
Appropriate disposal/Product:
Recommendation:
Do not empty into drains or the aquatic environment. This material and its container must be disposed of in a safe way. Waste
disposal according to EC Directives 75/442/EEC and 91/689/EEC on waste and hazardous waste in their latest versions.
Control report for waste code/ waste marking according to EAKV:
140603 other solvents and solvent mixtures
Contaminated packaging:
Recommendation:
Cleaned containers may be recycled. Vessels not properly emptied are special waste.

14. Transport information

Transport according to ADR/RID, IMDG and ICAO/IATA.
Overland transport (ADR/RID)
Class: 3
Label: 3
UN No.: 1123
Hazard identification number (Kemler No.): 30
Official directive for the transport: Butyl acetates
Packing Group: III
Tunnel restriction code: D/E
Transport by sea (IMDG)
Class: 3
Label: 3
EmS-No.: F-E, S-E
UN No.: 1123
Official directive for the transport: BUTYL ACETATES
contains: Butylacetat 98 %ig
Packing Group: III
Marine pollutant: not applicable
Air transport (ICAO-TI / IATA-DGR)
Class: 3
Label: 3
UN No.: 1123
Official directive for the transport: Butyl acetates
Packing Group: III
15. Regulatory information
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Article no.: 171301V03800
Date of print: 18.05.2010
V 1301 ECO-BA EN
Revision date: 18.05.2010 page:5 / 5
EU-Regulations
Chemical Safety Assessment
Chemical safety assessments for substances in this preparation were not carried out.
Labelling (67/548/EEC or 1999/45/EC)
Danger symbol(s) and danger term(s) for dangerous materials and preparations:
Contains:
not applicable
R phrases:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
S phrases:
24 Avoid contact with skin.
51 Use only in well-ventilated areas.
Special labelling of particular preparations:
99 Contains 2-butanone oxime. May produce an allergic reaction.
Other regulations (EU):
Data concerning the Directive 1999/13/EC on the limitation of emissions of volatile organic compounds (VOC-RL)
VOC-value (in g/l) ISO 11890-2: 876
VOC-value (in g/l) ASTM D 2369: 876
National regulations
Informations on working limitations:
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe employment restrictions under the law for the protection of young people at work (94/33/EC).
16. Additional information
Wording of the r-phrases under paragraph 3:
21 Harmful in contact with skin.
40 Limited evidence of a carcinogenic effect.
41 Risk of serious damage to eyes.
43 May cause sensitization by skin contact.
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
Further remarks:
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations. Without written approval, the product must not be used for purposes different from those mentioned in chapter
1.
It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and
regulations. The details in this safety data sheet describe the safety requirements of our product and are not to be regarded
as guaranteed attributes of the product.
Annex
At present, data / information on exposure scenarios are not available, so that an evaluation of the preperation cannot yet be
made.