Version: 1.

1
Revision Date: 06/02/2015

SAFETY DATA SHEET

1. Identification

Identification
Product name: FLOZOL® 2252D
Additional identification
Chemical name: Formaldehyde, polymers with phenol

Recommended use and restriction on use

Recommended use: Not determined.
Restrictions on use: Not determined.

Details of the supplier of the safety data sheet

Supplier
Company Name: THE LUBRIZOL CORPORATION
Address: 29400 LAKELAND BOULEVARD
WICKLIFFE, OH 44092-2298
US
Telephone: (440)943-1200

Emergency telephone number:

FOR TRANSPORT EMERGENCY CALL CHEMTREC (+1)703 527 3887, OR WITHIN USA 800 424 9300
(LUBRIZOL)

2. Hazard(s) identification

Hazard Classification
Physical Hazards
Flammable liquids Category 4
Health Hazards
Serious Eye Damage/Eye Category 2A
Irritation
Unknown toxicity
Acute toxicity, oral 57.6 %
Acute toxicity, dermal 0.0 %
Acute toxicity, inhalation, vapor 100.0 %
Acute toxicity, inhalation, dust 57.6 %
or mist

Label Elements:

Hazard Symbol:

Signal Word: Warning

Hazard Statement: Combustible liquid.

Causes serious eye irritation.

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Precautionary Statement:

Prevention: Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Wear protective
gloves/protective clothing/eye protection/face protection. Wash
thoroughly after handling. Avoid release to the environment.

Response: If in eyes: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention. In
case of fire: Use CO2, dry chemical or foam for extinction.
Water can be used to cool and protect exposed material.

Storage: Store in well-ventilated place. Keep cool.

Disposal: Dispose of contents/container to an appropriate treatment and

disposal facility in accordance with applicable laws and
regulations, and product characteristics at time of disposal.

Other hazards which do not result None identified.

in GHS classification:

3. Composition/information on ingredients

General information:

Chemical name CAS number Percent by Weight

Formaldehyde, polymers with phenol Not determined. 50 - 60%

Petroleum naphtha 64742-47-8 40 - 50%

4. First-aid measures

Ingestion: Rinse mouth. Get medical attention if symptoms occur.

Inhalation: Remove exposed person to fresh air if adverse effects are observed.

Skin Contact: Take off contaminated clothing and wash before re-use. Wash with soap
and water. If skin irritation occurs, get medical attention.

Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/attention.

Most important symptoms/effects, acute and delayed

Symptoms: See section 11.

Indication of immediate medical attention and special treatment needed

Treatment: Treat symptomatically.

5. Fire-fighting measures

General Fire Hazards: Move containers from fire area if you can do so without risk.

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Suitable (and unsuitable) extinguishing media

Suitable extinguishing CO2, Dry chemical or Foam. Water can be used to cool and protect
media: exposed material.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

Specific hazards arising from Vapors may cause a flash fire or ignite explosively. Prevent buildup of
the chemical: vapors or gases to explosive concentrations. Vapors may travel
considerable distance to a source of ignition and flash back. Water may
cause splattering. Container may rupture on heating. A solid stream of
water will spread the burning material. Material creates a special hazard
because it floats on water. See section 10 for additional information.

Special protective equipment and precautions for firefighters

Special fire fighting No data available.
procedures:

Special protective Firefighters must use standard protective equipment including flame
equipment for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.

6. Accidental release measures

Personal precautions, ELIMINATE all ignition sources (no smoking, flares, sparks or flames in
protective equipment and immediate area). Ventilate area if spilled in confined space or other poorly
emergency procedures: ventilated areas. Personal Protective Equipment must be worn, see
Personal Protection Section for PPE recommendations.

Methods and material for Eliminate all ignition sources if safe to do so. Dike far ahead of larger spill
containment and cleaning up: for later recovery and disposal. Pick up free liquid for recycle and/or
disposal. Residual liquid can be absorbed on inert material. Stop the flow of
material, if this is without risk. Prevent entry into waterways, sewer,
basements or confined areas.

Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so.

7. Handling and storage

Precautions for safe handling: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Avoid contact with eyes. Observe good industrial
hygiene practices. Provide adequate ventilation. Wear appropriate personal
protective equipment. Wash hands thoroughly after handling.

Maximum Handling Not determined.

Temperature:

Conditions for safe storage, Keep cool. Store in a well-ventilated place. Do not store near potential
including any sources of ignition.
incompatibilities:

Maximum Storage Not determined.

Temperature:

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8. Exposure controls/personal protection

Control Parameters:
Occupational Exposure Limits
Chemical name type Exposure Limit Values Source

Petroleum naphtha - Non- TWA 200 mg/m3 US. ACGIH Threshold Limit Values (02 2012)
aerosol. - as total
hydrocarbon vapor
Petroleum naphtha REL 100 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2010)

Appropriate engineering Adequate ventilation should be provided so that exposure limits are not
controls: exceeded. Mechanical ventilation or local exhaust ventilation may be
required.

Individual protection measures, such as personal protective equipment

General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level.

Eye/face protection: Safety glasses. If potential for splash or mist exists, wear chemical goggles
or faceshield.

Skin Protection
Hand Protection: Use nitrile or neoprene gloves. Use good industrial hygiene practices. In
case of skin contact, wash hands and arms with soap and water.

Other: Wear apron or protective clothing in case of contact.

Respiratory Protection: A respiratory protection program compliant with all applicable regulations
must be followed whenever workplace conditions require the use of a
respirator. Under normal use conditions, respirator is not usually required.
Use appropriate respiratory protection if exposure to dust particles, mist or
vapors is likely. Use self-contained breathing apparatus for entry into
confined space, for other poorly ventilated areas and for large spill clean-up
sites.

Hygiene measures: Observe good industrial hygiene practices. Avoid contact with eyes. When
using do not smoke.

9. Physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Dark
Odor: Mild
Odor threshold: No data available.
pH: No data available.
Freezing point: No data available.
Boiling Point: No data available.
Flash Point: 153 °F (67 °C) (Pensky-Martens Closed Cup)

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Evaporation rate: No data available.

Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: No data available.
Vapor density: No data available.
Relative density: 0.87 60.1 °F (15.6 °C)
Solubility(ies)
Solubility in water: Insoluble in water
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Auto-ignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: 90 mm2/s ( 104 °F (40 °C) )

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.

Possibility of Hazardous Will not occur.

Reactions:

Conditions to Avoid: Heat, sparks, flames.

Incompatible Materials: Strong oxidizing agents.

Hazardous Decomposition Thermal decomposition or combustion may generate smoke, carbon

Products: monoxide, carbon dioxide, and other products of incomplete combustion.

11. Toxicological information

Information on likely routes of exposure

Inhalation: No data available.

Ingestion: No data available.

Skin Contact: No data available.

Eye contact: Causes serious eye irritation.

Information on toxicological effects

Acute toxicity
Oral
Product: Swallowing material may cause irritation of the gastrointestinal
lining, nausea, vomiting, diarrhea, and abdominal pain. Ingestion
can cause central nervous system effects such as headache,
dizziness, drowsiness, and generalized weakness.
Not classified for acute toxicity based on available data.

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Dermal
Product: Not classified for acute toxicity based on available data.
Inhalation
Product: High concentrations may cause headaches, dizziness, nausea,
behavioral changes, weakness, drowsiness and stupor.
Not classified for acute toxicity based on available data.
Skin Corrosion/Irritation:
Product: Prolonged or repeated skin contact as from clothing wet with
material may cause dermatitis. Symptoms may include redness,
edema, drying, and cracking of the skin.
Remarks: Not classified as a primary skin irritant.

Serious Eye Damage/Eye Irritation:

Product: Remarks: Causes serious eye irritation.

Respiratory sensitization:
No data available

Skin sensitization:
Petroleum naphtha Classification: Not a skin sensitizer. (Literature)

Specific Target Organ Toxicity - Single Exposure:

Petroleum naphtha If material is misted or if vapors are generated from heating,
exposure may cause irritation of mucous membranes and the upper
respiratory tract.

Aspiration Hazard:
Petroleum naphtha Material can be aspirated into the lungs during the act of swallowing
or vomiting. This could result in severe injury to the lungs and death.

Chronic Effects
Carcinogenicity:
No data available

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogenic components identified

US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

No carcinogenic components identified

Germ Cell Mutagenicity:

Petroleum naphtha In vitro and in vivo genetic toxicity studies were negative.

Reproductive toxicity:
No data available

Specific Target Organ Toxicity - Repeated Exposure:

Petroleum naphtha Repeated overexposure to petroleum naphtha can cause nervous

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system damage.

12. Ecological information

Ecotoxicity
Fish
Formaldehyde, polymers with LC 50 (Rainbow Trout, 96 h): 33.24 mg/l
phenol

Petroleum naphtha LC 50 (Rainbow Trout, 4 d): > 1,000 mg/l

Aquatic Invertebrates
Petroleum naphtha EC 50 (Water flea (Daphnia magna), 2 d): > 1,000 mg/l

Toxicity to Aquatic Plants

Petroleum naphtha EC 50 (Green algae (Selenastrum capricornutum), 3 d): > 1,000
mg/l
LC 50 (Green algae (Selenastrum capricornutum), 3 d): > 1,000 mg/l

Toxicity to soil dwelling organisms

No data available

Sediment Toxicity
No data available

Toxicity to Terrestrial Plants

No data available

Toxicity to Above-Ground Organisms

No data available

Toxicity to microorganisms
Formaldehyde, polymers with EC 50 (Sludge, 3 h): > 1,000 mg/l
phenol

Persistence and Degradability

Biodegradation
Formaldehyde, polymers with OECD TG 301 C, 1 %, 28 d, Not readily degradable.
phenol

Petroleum naphtha OECD TG 301 F, 69 %, 28 d, Readily biodegradable

Bioaccumulative Potential
Bioconcentration Factor (BCF)
No data available

Partition Coefficient n-octanol / water (log Kow)

No data available

Mobility:
No data available

Other Adverse Effects: No data available.

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13. Disposal considerations

Disposal instructions: Treatment, storage, transportation, and disposal must be in accordance

with applicable Federal, State/Provincial, and Local regulations.
Dispose of packaging or containers in accordance with local, regional,
national and international regulations. Empty container contains product
residue which may exhibit hazards of product.

Contaminated Packaging: Container packaging may exhibit hazards.

14. Transport information

DOT
UN Number: NA 1993
UN Proper Shipping Name: Combustible liquid, n.o.s.(Petroleum naphtha, Naphthalene)
Transport Hazard Class(es)
Class: CBL
Label(s): –
Packing Group: III
Marine Pollutant: No
Special precautions for user: None established

IMDG
Not regulated.

IATA
Not regulated.

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

None known.

Shipping descriptions may vary based on mode of transport, quantities ,temperature of the material, package size, and/or origin and
destination It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the
transportation of the material. Review classification requirements before shipping materials at elevated temperatures.

15. Regulatory information

US Federal Regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
None present or none present in regulated quantities.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Fire Hazard Immediate
(Acute) Health
Hazards

SARA 302 Extremely Hazardous Substance

SARA 304 Emergency Release Notification
SARA 311/312 Hazardous Chemical
SARA 313 (TRI Reporting)
This product may contain chemical(s) regulated under the Superfund Amendments and Reauthorization
Act (SARA). For additional information please contact Lubrizol Customer Assistance: America(s):
AmerLZAMCustomerAssistance@Lubrizol.com ; Europe: EMEAICustomerAssistance@Lubrizol.com ;
Asia: APCustomerAssistance@Lubrizol.com

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US State Regulations
US. California Proposition 65
This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth
defects or other reproductive harm.
Ethyl benzene 4.00PPM
Naphthalene 4.00PPM
Benzene 424.00PPB
Toluene 423.00PPB

Inventory Status
Australia (AICS)
May require notification before sale under Australian regulations.
Canada (DSL/NDSL)
All components are in compliance with the Canadian Environmental Protection Act and are present on the
Domestic Substances List.
China (IECSC)
This product may require notification in China.
European Union (REACh)
To obtain information on the REACH compliance status of this product, please visit Lubrizol.com/REACH, or
e-mail us at REACH_MSDS_INQUIRIES@Lubrizol.com
Japan (ENCS)
May require notification in Japan.
Korea (ECL)
May require notification before sale in Korea.
New Zealand (NZIoC)
May require notification before sale under New Zealand regulations.
Philippines (PICCS)
All components are in compliance with the Philippines Toxic Substances and Hazardous and Nuclear
Wastes Control Act of 1990 (R.A. 6969).
Switzerland (SWISS)
All components are in compliance with the Environmentally Hazardous Substances Ordinance in
Switzerland.
Taiwan (TCSCA)
May require notification before sale in Taiwan.
United States (TSCA)
All components of this material are on the US TSCA Inventory.
The information that was used to confirm the compliance status of this product may deviate from the chemical
information shown in Section 3.

16.Other information, including date of preparation or last revision

HMIS Hazard ID

Health * 2

Flammability 2

Physical Hazards 0

Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not
possible; *Chronic health effect

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NFPA Hazard ID

2 Flammability
2 0 Health
Reactivity
Special hazard.
Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not possible

Issue Date: 06/02/2015

Version #: 1.1
Source of information: Internal company data and other publically available resources.
Further Information: Contact supplier (see Section 1)
Disclaimer: As the conditions or methods of use are beyond our control, we do not
assume any responsibility and expressly disclaim any liability for any use of
this product. Information contained herein is believed to be true and accurate
but all statements or suggestions are made without warranty, expressed or
implied, regarding accuracy of the information, the hazards connected with
the use of the material or the results to be obtained from the use thereof.
Compliance with all applicable federal, state, and local regulations remains
the responsibility of the user.

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