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ENB 04 0553 Rev B Bearing Materials Technical Information

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TECHNICAL INFORMATION

Bearing Materials
The bearing industry uses different materials for the production of the various bearing components.
The materials are processed to achieve desirable properties to maximize bearing performance and life.
The materials described here are the most commonly used. Additional information can be found in the
Technical Information Sheets for Balls, Closures, and Retainers.
Chrome Steel – SAE 52100
The most common material used to produce the load carrying components in precision ball bearings,
roller bearings, and tapered roller bearings is 52100 chrome steel. These components are the inner
and outer rings, balls and rollers. The chemical composition of this steel has high carbon and about
1.5% chromium content. Using controlled processing and heat-treating methods the finished bearing
components have high strength to resist cracking and a hard surface to resist subsurface rolling contact
fatigue. The typical surface hardness for bearing components made from this material ranges from 60-
64 on the Rockwell hardness C scale (Rc).

Extra clean 52100 chrome steel


The raw steel used to produce high precision miniature bearings is processed with additional melting
steps. The result is a type of steel with very uniform fine grain material structure, the bearing contact
surfaces can be super finished very smooth so the bearing is very quiet.

The most common heat treating method for chrome steel is to thru harden the steel in a controlled
atmosphere furnace. Bearings manufactured from chrome steel can operate at continuous
temperatures up to 120°C.

Where higher temperatures are encountered, it is possible to Heat Stabilize the bearing components.
By varying the heat treating process, bearings can be produced so they are capable of operating at
temperatures of 220°C, and higher. For these applications, the components must be subjected to a
tempering treatment at a higher temperature corresponding to the service temperature. This elevated
tempering treatment has a detrimental effect on the hardness of the material and the load carrying
capacity of the bearing is reduced.

SAE 52100 is an excellent general purpose bearing steel. Due to its excellent hardness and wear
resistance, it exhibits good fatigue life in rolling element bearings. However, the corrosion resistance of
chrome steel is poor because of the low chromium content. The surfaces of the bearings must be
protected with a coating of rust inhibitor or oil to stop oxidation.

As can be seen in the following table, the standard chemical composition of chromium steel will vary
depending on the country where it is produced.

Designation C% Si% Mn% P% Cr% Mo% Ni% S%


Country Carbon Silicon Manganese Phosphorous Chromium Molybdenum Nickel Sulfur
AISI 52100
.95-1.1 .15-.35 .5 max .012 max 1.3-1.6 .08 max .25 max .025 max
USA
100CR6
.95-1.1 .15-.35 .25-.45 .03 max 1.35-1.65 .1 max - .02 max
Germany
SUJ2
.95-1.1 .15-.35 .5 max .025 max 1.3-1.6 .08 max .25 max .025 max
Japan
GCR15
.95-1.05 .15-.35 .25-.45 .027 max 1.4-1.65 .1 max .23 max .02 max
China

AST Bearings LLC “Value Beyond the Part™” U.S. Toll Free (800) 526-1250
222 New Road Headquarters (973) 335-2230
Parsippany, NJ 07054 www.ASTBearings.com Fax (973) 335-6987
© Copyright 2010 AST Bearings LLC – All rights reserved. DOCUMENT NO. ENB-04-0553 REV. B
.
TECHNICAL INFORMATION

Stainless Steels
Stainless steel materials are used to make bearing components because it is more resistant to surface
corrosion due to the higher content of chromium (~18%) with the addition of nickel. The chromium
reacts with oxygen to form a layer of chromium oxide on the surface, creating a passive film.

Martensitic Stainless Steel- AISI 440C


The carbon content in 400 series stainless steels is high enough so it can be hardened using standard
heat-treating methods up to Rc58. Due to the lower hardness, the load carrying capacity is 20% lower
in bearings made from this material, than they are with 52100 chrome steel bearings. The level of
carbon content means the components are magnetic. The corrosion resistance is “good”, when 440C
material is exposed to fresh water and mild chemicals. This material is primarily used by US bearing
manufacturers.

Miniature bearings made from conventional 440C stainless steel will be slightly noisy because the large
carbides that normally concentrate at the grain boundaries are exposed in the raceway finishing
process. Larger bore bearings are not as affected by this condition. Bearings made from 400 series
stainless steel can operate at higher temperatures than chrome steel, up to 250°C continuous.
Bearings made from this material are generally more expensive than chrome steel bearings.

Martensitic Stainless Steel – ACD34


Many miniature bearing manufacturers make their rings and balls with a stainless steel material with
slightly lower carbon and chromium content than AISI 440C – ACD34. After heat treatment, this
material has smaller carbides so the bearing will have superior low noise characteristics while offering
the same corrosion resistance as 440C. For bearings produced from this material, some manufacturers
will publish the same load ratings as those for chrome steel. This is due to the use of tightly controlled
heat treating methods that result in hardness up to Rc 60. Although this is one of the most widely used
stainless steels for ball bearings, there is no AISI designation for this material.

Martensitic Stainless Steel – SV30


Martensitic stainless steel can be modified during the processing of the raw steel by lowering the
carbon content and introducing nitrogen as an alloying element. The nitrogen increases the saturation
of the chromium which transforms into chromium nitrides, instead of chromium carbides. The result is a
high strength, high hardness steel with a superior microstructure that extends fatigue life by as much
100% (double) in certain applications. This material also offers better corrosion resistance than 440C
and ACD34, up to 5 times. Bearings manufactured from this material can carry a price premium of 20-
40%. More information is available in the SV30 Technical Information Sheet.

Heat Treatment of Bearing Steels


When bearing steels are in their soft (unhardened) state, metallurgists refer to their structure as being
in the pearlite state. In order to harden the steel it must be heated to a very high temperature and then
cooled very rapidly. When heated in the heat treat furnace to 1,750˚F, the structure transforms from
pearlite to what is known as austenite. After quenching (very rapid cooling), the structure then
transforms from austenite to martensite. Once transformed to martensite, the steel becomes very hard.
However, at this point it is not considered "thermally stabilized". This is because not all of the austenite
transforms into martensite during the quenching process. This phenomenon is called "retained
"austenite".

AST Bearings LLC “Value Beyond the Part™” U.S. Toll Free (800) 526-1250
222 New Road Headquarters (973) 335-2230
Parsippany, NJ 07054 www.ASTBearings.com Fax (973) 335-6987
© Copyright 2010 AST Bearings LLC – All rights reserved. DOCUMENT NO. ENB-04-0553 REV. B
.
TECHNICAL INFORMATION

If the steel is not thermally stabilized, the retained austenite will over an extended period of time
(possibly years) transform into martensite. This transformation is accompanied by an increase in
volume that is called metallurgical growth (not to be confused with thermal growth). Metallurgical
Growth will cause a change in dimension and form of any steel parts such as bearings' even at room
temperature.

While not a problem with low precision commodity type bearings, in high precision (ABEC 5P, 7P, 9P)
miniature bearings this lack of dimensional stability can cause problems. In order to eliminate this
unwanted metallurgical growth, the steel must be subjected to thermal stabilization. This is
accomplished by repeated cycles of chilling at -120˚F and tempering to transform a large percentage of
the retained austenite to martensite.

The tables below show the chemical composition of the stainless steel alloys discussed above.
Designation C% Si% Mn% P% Cr% Mo% Ni% S%
Country Carbon Silicon Manganese Phosphorous Chromium Molybdenum Nickel Sulfur
AISI 440C
.95-1.2 1.0 max 1.0 max .04 max 16-18 .75 max .25 max .03 max
USA
SUS440C
.95-1.2 1.0 max 1.0 max .04 max 16-18 .75 max .25 max .03 max
JAPAN
9Cr18
.90-1.05 .75 max .75 max .035 max 16-19 .75 max .23 max .03 max
CHINA

Enhanced 440 Stainless Steel- ACD34


Designation C% Si% Mn% P% Cr% Mo% Ni% S%
Country Carbon Silicon Manganese Phosphorous Chromium Molybdenum Nickel Sulfur
KS440
.6-.7 1.0 max 1.0 max .03 max 12-13.5 .25 max - .01 max
JAPAN
X65Cr13
.6-.7 1.0 max 1.0 max .04 max 12-14 .75 max - .03 max
GERMANY

AISI316 Austenitic Stainless Steel


Bearing components made from 300 series stainless steel materials have greater corrosion resistance
and are non-magnetic because of the low carbon content. However, the tradeoff is that this material
cannot be hardened so the bearings can only operate under low loads and speeds. The surfaces of the
bearing undergo a chemical reaction with the oxygen called a passivation process; the passive film
developed on the surface protects the bearing from corrosion. The corrosion resistance is best when
the bearing is not completely submerged in liquid (such as underwater applications). Bearings made
from this material are usually special order items requiring minimum quantities; in addition they are
more expensive.

Other 300 Series Stainless Steel


The bearing shields, seal washers and ball retainers are sometimes made from AISI303 or AISI304
stainless steel because they have moderate corrosion resistance and are better for forming into the
various shapes.

Carbon Alloy Steel


Carbon steel materials are used to produce various components of bearings and have two basic types,
Medium versus Low Carbon Alloy Steel.

AST Bearings LLC “Value Beyond the Part™” U.S. Toll Free (800) 526-1250
222 New Road Headquarters (973) 335-2230
Parsippany, NJ 07054 www.ASTBearings.com Fax (973) 335-6987
© Copyright 2010 AST Bearings LLC – All rights reserved. DOCUMENT NO. ENB-04-0553 REV. B
.
TECHNICAL INFORMATION

Medium Carbon Alloy Steel


Bearings made from medium or low carbon alloy steel material are typically called “semi-precision” or
“commercial grade” bearings. The typical materials are AISI8620 or AISI4320. The inner and outer
rings are surface hardened in a heat-treating process call case hardening or carburizing. Bearings
made from these materials cannot carry high loads or operate at high speeds and they do not have
corrosion resistance. The bearings made from these materials are usually low cost.

Low Carbon Alloy Steel


Low carbon steel is used in the production of bearing cages, metal shields and metal washers around
which rubber is molded for seals. Common materials are AISI C1008 and C1010. The material needs
to be protected from corrosion with a coating of oil/grease (cages) or by plating (shields). Additional
information on Retainers and Closures can be found in the respective technical bulletins.

Plastics and Non-Metallic Materials

Cages
Plastic materials are sometimes used for bearing cages. The most common is molded nylon plastic but
molded acetal (POM) is also used. Other polymers are used in special bearing designs where specific
performance requirements such as high speed, or low torque or low noise are identified.

Cages made from phenolic (phenol-formaldehyde) materials are most common in high speed ball
bearings used in machine tool equipment spindles. The phenolic cages are lightweight and have high
strength. The cost of processing this material has led to an increase use of plastics in its place.
Additional information is contained in the Cages technical bulletin.

Seals
The most common seal material is nitrile rubber or Buna rubber. It has good mechanical properties,
can be used across a wide temperature range, is resistant to many chemicals and is low in cost.
Materials such as Viton and Silicone are expensive elastomers and they’re usually used when an
application requires their unique properties.

Ceramic Materials
Bearings made with ceramic materials fall into a specialty niche in the bearing industry. The most
common arrangement is a hybrid bearing, usually with stainless steel rings and ceramic balls. The
most common ceramic material used is silicon nitride. Balls made from this material are hard, up to
Rc78, and have a very smooth surface. Hybrid bearings are more expensive than all stainless steel
bearings.

AST Bearings LLC “Value Beyond the Part™” U.S. Toll Free (800) 526-1250
222 New Road Headquarters (973) 335-2230
Parsippany, NJ 07054 www.ASTBearings.com Fax (973) 335-6987
© Copyright 2010 AST Bearings LLC – All rights reserved. DOCUMENT NO. ENB-04-0553 REV. B
.

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