Kellers

Safety Data Sheet Page 1
Keller’s Reagent
Section 1: Identification
MANUFACTURER: PACE Technologies
3601 E. 34th St.
Tucson, AZ 85713
INFORMATION PHONE: 520-882-6598
EMERGENCY PHONE: CHEMTREC 800-424-9300 (US) Day or night
Customer No. 16568
TRADE NAME: Keller’s Reagent
CHEMICAL FAMILY: Corrosive, Acidic, Inorganic, N.O.S. (Hydrochloric Acid,

Hydrofluoric Acid, Nitric Acid Mixture)
HMIS RATING: HEALTH: 4 FLAMMABILITY: 0 REACTIVITY: 2
HAZARD RATING:
LEAST: 0 SLIGHT: 1 MODERATE: 2 HIGH: 3 EXTREME: 4
Section 2: Hazard(s) Identification

Oxidizing liquids (Category 3), H272
GHS Classification
Corrosive to metals (Category 1), H290
in accordance with
Acute toxicity, Oral (Category 2), H300
29 CFR 1910
Acute toxicity, Dermal (Category 1), H310
(OSHA HCS)
Skin corrosion (Category 1B), H314
Serious eye damage (Category 1), H318
Acute toxicity, Inhalation (Category 2), H330
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
PICTOGRAM(s):
SIGNAL WORD: Danger
HAZARD Hazard Statement(s):

STATEMENTS: H272- May intensify fire; oxidizer
H290- May be corrosive to metals
H300- Fatal if swallowed
H310- Fatal in contact with skin
Copyright 2016-2018 © · All rights reserved

PACE Technologies · 3601 E. 34th St · Tucson, AZ 85713 USA
Telephone +1 520-882-6598 · FAX +1 520-882-6599 · pace@metallographic.com
Emergency phone number (CHEMTREC 800-424-9300)
Keller’s Reagent
H314- Causes severe skin burns and eye damage
H318 - Causes serious eye damage
H330- Fatal if inhaled
H335- May cause respiratory irritation
PRECAUTIONARY Precautionary Statement(s):

STATEMENTS:
Preventions:
P210- Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220- Keep/Store away from clothing combustible materials.
P221- Take any precaution to avoid mixing with combustibles.
P234- Keep only in original container.
P260- Do not breathe dust/fume/gas/mist/vapors/spray.
P262- Do not get in eyes, on skin, or on clothing.
P264- Wash skin thoroughly after handling.
P270- Do not eat, drink or smoke when using this product.
P271-Use only outdoors or in a well-ventilated area.
P280- Wear protective gloves/protective clothing/eye protection/face protection.
P284- P403+P233-Store in a well-ventilated place. Keep container tightly closed.
Response:
P301+310- IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P350- IF ON SKIN: Gently wash with plenty of soap and water.
P305+P351+P338- IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310- Immediately call a POISON CENTER or doctor/physician.
P320- Specific treatment is urgent (see Section 4 SDS).
P321- Specific treatment urgent (see Section 4 SDS).
P330- Rinse mouth.
P322- Specific measures (see Section 4 SDS).
P361- Remove/Take off immediately all contaminated clothing.
P363- Wash contaminated clothing before reuse.
P370+P378- In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for
extinction.
Storage:
P403+P233-Store in a well-ventilated place. Keep container tightly closed.
P405- Store locked up.
P406- Store in corrosive resistant container with a resistant inner liner.
Disposal:
P501- Dispose of contents/container to Federal, State and Local Regulations.
Emergency Overview
--------------------------
POISON! DANGER! CORROSIVE. EXTREMELY HAZARDOUS LIQUID
AND VAPOR. CAUSES SEVERE BURNS WHICH MAY NOT BE
IMMEDIATELY PAINFUL OR VISIBLE. MAY BE FATAL IF
SWALLOWED OR INHALED. LIQUID AND VAPOR CAN BURN SKIN,
EYES AND RESPIRATORY TRACT. CAUSES BONE DAMAGE.

Keller’s Reagent
REACTION WITH CERTAIN METALS GENERATES FLAMMABLE
AND POTENTIALLY EXPLOSIVE HYDROGEN GAS.
---------------------------------------------------------------------------------------------------
Health Rating: 4 - Extreme (Poison)
Flammability Rating: 0 - None
Reactivity Rating: 2 - Moderate
Contact Rating: 4 - Extreme (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT
HOOD; PROPER GLOVES
Storage Color Code: White (Corrosive)
---------------------------------------------------------------------------------------------------
Potential Health Effects

----------------------------------
Exposure to hydrofluoric acid can produce harmful health effects that may not be
immediately apparent. Concentrated nitric acid is extremely hazardous; it is
corrosive, reactive, an oxidizer, and a poison. The following hazards are for
concentrated solutions. Hazards of less concentrated solutions may be reduced.
Degree of hazard for reduced concentrations is not currently addressed in the
available literature.
Inhalation:
Severely corrosive to the respiratory tract. May cause sore throat, coughing,
labored breathing and lung congestion/inflammation, where symptoms may
include severe burns of the mouth, throat, and stomach, leading to death.
Ingestion:
Corrosive. May cause sore throat, abdominal pain, diarrhea, vomiting, severe
burns of the digestive tract, and kidney dysfunction.
Skin Contact:
Corrosive to the skin. Skin contact causes serious skin burns which may not be
immediately apparent or painful. Symptoms may be delayed 8 hours or longer.
The fluoride ion readily penetrates the skin causing destruction of deep tissue
layers and even bone.
Eye Contact:
Corrosive to the eyes. Symptoms of redness, pain, blurred vision, and permanent
eye damage may occur.
Chronic Exposure:
Intake of more than 6 mg of fluorine per day may result in fluorosis, bone and
joint damage. Hypocalcemia and hypomagnesemia can occur from absorption of
fluoride ion into blood stream.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, eye problems, or impaired kidney or
respiratory function may be more susceptible to the effects of this substance.

Keller’s Reagent
Section 3: Composition/Information on Ingredients

HAZARD INGREDIENTS
CHEMICAL CAS NUMBER % PRESENT Hazardous
Hydrogen Fluoride 7664-39-3 1-5% Yes
Hydrogen Chloride 7647-01-0 5-10% Yes
Nitric Acid 7697-37-2 5-10% Yes
Water 7732-18-5 90-95% No
Section 4: First-Aid Measures

For any route of contact: Detailed First Aid procedure should be planned before
beginning work with HF etchants.
Inhalation:
Get medical help immediately. If patient is unconscious, give artificial respiration
or use inhalator. Keep patient warm and resting, and send to hospital after first aid
is complete.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water.
Never give anything by mouth to an unconscious person. Get medical attention
immediately.
Skin Contact:
1) Remove the victim from the contaminated area and immediately place him
under a safety shower or wash him with a water hose, whichever is available. 2)
Remove all contaminated clothing. Handle all HF-contaminated material with
gloves made of appropriate material, such as PVC or neoprene. 3) Keep washing
with large amounts of water for a minimum of 15 minutes. 4) Have someone
make arrangements for medical attention while you continue flushing the affected
area with water. 5) If the following materials are available, limit the washing to
five minutes and immerse the burned area in a solution of 0.2% iced aqueous
Hyamine 1622 or 0.13% iced aqueous Zephiran Chloride. If immersion is not
practical, towels should be soaked with one of the above solutions and used as
compresses for the burn area. Ideally compresses should be changed every 2
minutes. Alternately, 2.5% calcium gluconate gel should be massaged into the
affected area. 6) Seek medical attention as soon as possible for all burns
regardless of how minor they may appear initially. Hyamine 1622 is a trade name
for tetracaine benzethonium chloride, Merck Index Monograph 1078, a

Keller’s Reagent
quaternary ammonium compound sold by Rohm & Haas, Philadelphia. Zephiran
Chloride is a trade name for benzalkonium chloride, Merck Index Monograph
1059, also a quaternary ammonium compound, sold by Sanofi-Synthelabo Inc.,
New York, NY.
Eye Contact:
1) Irrigate eyes for at least 30 minutes with copious quantities of water, keeping
the eyelids apart and away from eyeballs during irrigation. 2) Get competent
medical attention immediately, preferably an eye specialist. 3) If a physician is
not immediately available, apply one or two drops of ophthalmic anesthetic, (e.g.,
0.5% Pontocaine Hydrochloride solution). 4) Do not use oily drops, ointment or
HF skin burn treatments. Place ice pack on eyes until reaching emergency room.
Note to Physician:
General: For burns of moderate areas, (greater than 8 square inches), ingestion
and significant inhalation exposure, severe systemic effects may occur, and
admission to a critical care unit should be considered. Monitor and correct for
hypocalcemia, cardiac arrhythmias, hypomagnesemia and hyperkalemia. In some
cases renal dialysis may be indicated.
Inhalation: Treat as chemical pneumonia. Monitor for hypocalcemia, 2.5%

calcium gluconate in normal saline by nebulizer or by IPPB with 100% oxygen
may decrease pulmonary damage. Bronchodilators may also be administered.
Skin: For deep skin burns or contact with concentrated HF (over 50%) solution,
consider infiltration about the affected area with 5% calcium gluconate [equal
parts of 10% calcium gluconate and sterile saline for injection]. Burns beneath the
nail may require splitting the nail and application of calcium gluconate to the
exposed nail bed. For certain burns, especially of the digits, use of intra-arterial
calcium gluconate may be indicated.
Eyes: Irrigation may be facilitated by use of Morgan lens or similar ocular

irrigator, using 1% aqueous calcium gluconate solution [50ml of calcium
gluconate 10% in 500 ml normal saline].
AN ALTERNATIVE FIRST AID PROCEDURE: The effect of HF, i.e. onset of

pain, particularly in dilute solutions, may not be felt for up to 24 hours. It is
important, therefore, that persons using HF have immediate access to an effective
antidote even when they are away from their work place in order that first aid
treatment can be commenced immediately.
We recommend that any person in contact with HF should carry, or have access to
a tube of HF Antidote Gel at all times; ideally with one tube at the work place,
one on the person and one at home.
It is imperative that any person who has been contaminated by HF should seek
medical advice when the treatment by HF Antidote Gel has been applied.

Keller’s Reagent
REFERENCES: 1. Browno, T.D. Treatment of Hydrofluoric Acid Burns 2.
Sprout, W.L. et al Treatment of Severe Hydrofluoric Acid Exposures (Journal of
American Occupational Medicine 25:12, 1993) 3. Bracken, W.M. et al
Comparative Effectiveness of Topical Treatments for Hydrofluoric Acid Burns,
University of Kansas (Journal of Occupational Medicine 27:10:1985) 4. Burke,
W.J. , et al Systemic Fluoride Poisoning Resulting from A Fluoride Skin Burn
(Journal of Occupational Medicine (5,39:1973)
HF ANTIDOTE GEL:
Distributed by Pharmascience Inc.
8400 Darnley Rd. Montreal, Canada. H4T 1M4
Phone: ( 514 ) 340 - 1114
Fax: ( 514 ) 342 - 7764
U.S. (Buffalo, NY) distributor: 1-800-207-4477
Section 5: Fire-Fighting Measures

Fire:
Not considered to be a fire hazard. Fire may produce poisonous or irritating gases.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Keep upwind of fire. Use water or carbon dioxide on fires in which Hydrofluoric
Acid is involved. Halon or foam may also be used. In case of fire, the sealed
containers can be kept cool by spraying with water.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-
contained breathing apparatus with full facepiece operated in the pressure demand
or other positive pressure mode. Avoid getting water in tanks or drums; water can
cause generation of heat and spattering. In contact with air, the acid gives off
corrosive fumes which are heavier than air.
Section 6: Accidental Release Measures

Notify safety personnel, provide adequate ventilation, and remove ignition
sources since hydrogen may be generated by reactions with metals. Wear
appropriate personal protective equipment as specified in Section 8. Do not flush
to sewers or waterways. Spills: Evacuate the danger area. Apply magnesium
sulfate (dry) to the spill area. Follow up with inert absorbent and add soda ash or
magnesium oxide and slaked lime. Collect in appropriate plastic containers and
save for disposal. Wash spill site with soda ash solution. NOTE: Porous materials
(concrete, wood, plastic, etc.) will absorb HF and become a hazard for an
indefinite time. Such spills should be cleaned and neutralized immediately. US
Regulations (CERCLA) require reporting spills and releases to soil, water and air
Keller’s Reagent
in excess of reportable quantities. The toll free number for the US Coast Guard
National Response Center is (800) 424-8802.
Section 7: Handling and Storage

Keep in tightly closed polyethylene containers. Store in a cool, dry place with
adequate ventilation separated from other chemicals. Protect from physical
damage. Storage facilities should be constructed for containment and
neutralization of spills. Handling and storage of HF etchants requires special
materials and technology for containers, pipes, valves, etc., which is available
from suppliers. Containers of this material may be hazardous when empty since
they retain product residues (vapors, liquid); observe all warnings and precautions
listed for the product.
Section 8: Exposure Controls/ Personal Protection

Airborne Exposure Limits:
Hydrogen fluoride:
-OSHA Permissible Exposure Limit (PEL):
3 ppm (TWA) as F.
ACGIH Threshold Limit Value (TLV):
0.5 ppm (TWA) as F; 2 ppm (STEL) Ceiling as F
For Nitric Acid:
OSHA Permissible Exposure Limit (PEL):
2 ppm (TWA)
ACGIH Threshold Limit Value (TLV):
2 ppm (TWA); 4 ppm (STEL)
For Hydrochloric acid:
- OSHA Permissible Exposure Limit (PEL):
5 ppm (Ceiling)
- ACGIH Threshold Limit Value (TLV):
2 ppm (Ceiling), A4 Not classifiable as a human carcinogen
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee
exposures as low as possible. Local exhaust ventilation is generally preferred
because it can control the emissions of the contaminant at its source, preventing
dispersion of it into the general work area. Please refer to the ACGIH document,
Industrial Ventilation, A Manual of Recommended Practices, most recent edition,
for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with an acid gas
cartridge may be worn up to 50 times the exposure limit or the maximum use
Keller’s Reagent
concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. For emergencies or instances where the exposure
levels are not known, use a full-facepiece positive-pressure, air-supplied
respirator. WARNING: Air purifying respirators do not protect workers in
oxygen-deficient atmospheres. Since the IDLH is low (30 ppm), the above
cartridge system is not specifically approved for HF. (3M Respirator Selection
Guide)
Skin Protection:
Wear protective clothing, including boots or safety shoes with polyvinyl chloride
(PVC) or neoprene. Use chemical goggles and/or a full face shield. Wear
coveralls with long sleeves, gauntlets and gloves of PVC or neoprene. A high
degree of protection is obtained with an air-inflated suit with mask and safety belt.
Use protection suitable for conditions.
Eye Protection:
Use chemical safety goggles and/or full face shield where splashing is possible.
Maintain eye wash fountain and quick drench facilities in work area.
Section 9: Physical and Chemical Properties

Appearance:
Colorless, fuming liquid.
Odor:
Acrid odor. Do not breathe fumes.
Solubility:
Infinitely soluble.
Specific Gravity:
1.15 -1.18
pH:
No information found.
% Volatiles by volume @ 21C (70F):
100 (as water and acid)
Boiling Point:
ca. 100C (ca. 212F)
Melting Point:
< -36C (< -33F)
Vapor Density (Air=1):
Essentially the same as water.
Evaporation Rate (BuAc=1):
Essentially the same as water.

Keller’s Reagent
Section 10: Stability and Reactivity

Stability:
Stable at room temperature (68F) when stored and used under proper conditions.
Hazardous Decomposition Products:
On contact with metals, liberates hydrogen gas. On heating to decomposition,
could yield toxic fumes of fluorides. Attacks glass and other silicon containing
compounds. Reacts with silica to produce silicon tetrafluoride, a hazardous
colorless gas.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Hydrofluoric acid is incompatible with arsenic trioxide, phosphorus pentoxide,
ammonia, calcium oxide, sodium hydroxide, sulfuric acid, vinyl acetate,
ethylenediamine, acetic anhydride, alkalis, organic materials, most common
metals, rubber, leather, water, strong bases, carbonates, sulfides, cyanides, oxides
of silicon, especially glass, concrete, silica, fluorine. Will also react with steam or
water to produce toxic fumes.
Nitric acid (concentrated) is incompatible with most substances, especially strong
bases, metallic powders, carbides, hydrogen sulfide, turpentine, and combustible
organics.
Conditions to Avoid:
Heat, incompatibles.
Section 11: Toxicological Information

Hydrofluoric acid: Inhalation rat LC50: 1276 ppm/1H; Investigated as a mutagen,
reproductive effector.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Hydrogen Fluoride (7664-39-3) No No None
Hydrogen Chloride (7647-01-0) No No None
Nitric Acid (7697-37-2) No No None
Water (7732-18-5) No No None
Section 12: Ecological Information

Environmental Fate:
If the pH is > 6.5, soil can bind fluorides tightly. High calcium content will
immobilize fluorides, which can be damaging to plants when present in acid soils.
Environmental Toxicity:
Keller’s Reagent
This material is expected to be slightly toxic to aquatic life. 60
ppm/*/Fish/Lethal/Fresh Water *=time period not specified. >
300ppm/48hr./Shrimp/LC50/Aerated Saltwater
Section 13: Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as
hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA
approved waste facility. Processing, use or contamination of this product may
change the waste management options. State and local disposal regulations may
differ from federal disposal regulations. Dispose of container and unused contents
in accordance with federal, state and local requirements.
Section 14: Transportation Information

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: Corrosive, Acidic, Inorganic, N.O.S. (Hydrochloric
Acid, Hydrofluoric Acid, Nitric Acid Mixture)
Hazard Class: 8
UN/NA: UN 3264
Packing Group: III
Label Codes: 8
For less then 1000 ml, product can be shipped as a limited quantity
NMFC: 45617-12
Shipping Class CL100
International (Air, I.C.A.O.)

-----------------------------
Proper Shipping Name: Corrosive, Acidic, Inorganic, N.O.S. (Hydrochloric
Acid, Hydrofluoric Acid, Nitric Acid Mixture)
Hazard Class: 8
UN/NA: UN 3264
Packing Group: III
Label Codes: 8

Keller’s Reagent
Section 15: Regulatory Information

--------\Chemical Inventory Status - Part 1\--------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Hydrogen Fluoride (7664-39-3) Yes Yes Yes Yes
Hydrochloric Acid (7647-01-0) Yes Yes Yes Yes
Nitric Acid (7697-37-2) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\--------------------------------

--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Hydrogen Fluoride (7664-39-3) Yes Yes No Yes
Hydrochloric Acid (7647-01-0) Yes Yes No Yes
Nitric Acid (7697-37-2) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\--------------

-SARA 302- ------SARA 313-----
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- -------------
Hydrogen Fluoride (7664-39-3) 100 100 Yes No
Hydrochloric Acid (7647-01-0) 5000 500 Yes No
Nitric Acid (7697-37-2) 1000 1000 Yes No
Water (7732-18-5) No No No No
--------\Federal, State & International Regulations - Part 2\---------------

-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Hydrogen Fluoride (7664-39-3) 100 U134 No
Hydrogen Chloride (7647-01-0) 5000 No No
Nitric Acid (7697-37-2) 1000 No No
Water (7732-18-5) No No No
Chemical Weapons Convention: Yes TSCA 12(b): No CDTA: No

SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: Yes (Mixture / Liquid)
Australian Hazchem Code: 2R

Poison Schedule: S7, S6
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled
Products Regulations (CPR) and the MSDS contains all of the information
required by the CPR.

Keller’s Reagent
Section 16: Other Information

16.1 NFPA 704
0
3 2
COR
Top, Flammability: 0 – Minimal Hazard

Left, Health Hazard: 3 – Severe Hazard
Right, Reactivity: 2 – Moderate Hazard
Bottom, Special Notice: COR – Corrosive
Label First Aid:
IN ALL CASES, CALL PHYSICIAN IMMEDIATELY. First Aid procedures should be pre-
planned for HF emergencies. A supply of 50:50 water/magnesium sulfate paste or 2 1/2%
Calcium Gluconate paste should be available where first aid medications are administered. If
ingested, DO NOT INDUCE VOMITING. If patient is conscious, give large quantities of milk
or water and send to hospital. If inhaled and patient is unconscious, give artificial respiration or
use inhalator and send to hospital. In case of eye contact, wash open eyes with large but gentle
stream of water for 15 minutes. Place ice pack on eyes until reaching emergency room. In case of
skin contact, remove contaminated clothing and wash burn area with plenty of water to remove
acid. Cover burn area with a poultice of 50:50 water/magnesium sulfate paste or 2 1/2% calcium
gluconate paste. Leave in place until medical help arrives or patient is transferred to hospital.
Product Use:
Laboratory Reagent.
Disclaimer:
PACE Technologies, Inc. provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This document is
intended only as a guide to the appropriate precautionary handling of the material by a
properly trained person using this product. Individuals receiving the information must
exercise their independent judgment in determining its appropriateness for a particular
purpose. PACE TECHNOLOGIES, INC. MAKES NO REPRESENTATIONS OR
WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT
LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
Keller’s Reagent
ACCORDINGLY, PACE TECHNOLOGIES, INC. WILL NOT BE RESPONSIBLE FOR
DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
DATE PREPARED: 3/3/2016
DATE REVISED: 6/7/2018 AG


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Safety Data Sheet Page 1

INFORMATION PHONE: 520-882-6598

EMERGENCY PHONE: CHEMTREC 800-424-9300 (US) Day or night

Customer No. 16568

TRADE NAME: Keller’s Reagent

CHEMICAL FAMILY: Corrosive, Acidic, Inorganic, N.O.S. (Hydrochloric Acid,

HMIS RATING: HEALTH: 4 FLAMMABILITY: 0 REACTIVITY: 2

LEAST: 0 SLIGHT: 1 MODERATE: 2 HIGH: 3 EXTREME: 4

Section 2: Hazard(s) Identification

SIGNAL WORD: Danger

HAZARD Hazard Statement(s):

Copyright 2016-2018 © · All rights reserved

PRECAUTIONARY Precautionary Statement(s):

Copyright 2016-2018 © · All rights reserved

Potential Health Effects

Copyright 2016-2018 © · All rights reserved

Section 3: Composition/Information on Ingredients

CHEMICAL CAS NUMBER % PRESENT Hazardous

Hydrogen Fluoride 7664-39-3 1-5% Yes

Hydrogen Chloride 7647-01-0 5-10% Yes

Nitric Acid 7697-37-2 5-10% Yes

Water 7732-18-5 90-95% No

Section 4: First-Aid Measures

Copyright 2016-2018 © · All rights reserved

Inhalation: Treat as chemical pneumonia. Monitor for hypocalcemia, 2.5%

Eyes: Irrigation may be facilitated by use of Morgan lens or similar ocular

AN ALTERNATIVE FIRST AID PROCEDURE: The effect of HF, i.e. onset of

Copyright 2016-2018 © · All rights reserved

Section 5: Fire-Fighting Measures

Section 6: Accidental Release Measures

Section 7: Handling and Storage

Section 8: Exposure Controls/ Personal Protection

Section 9: Physical and Chemical Properties

Copyright 2016-2018 © · All rights reserved

Section 10: Stability and Reactivity

Section 11: Toxicological Information

Section 12: Ecological Information

Section 13: Disposal Considerations

Section 14: Transportation Information

International (Air, I.C.A.O.)

Copyright 2016-2018 © · All rights reserved

Section 15: Regulatory Information

--------\Chemical Inventory Status - Part 2\--------------------------------

--------\Federal, State & International Regulations - Part 1\--------------

--------\Federal, State & International Regulations - Part 2\---------------

Chemical Weapons Convention: Yes TSCA 12(b): No CDTA: No

Australian Hazchem Code: 2R

Copyright 2016-2018 © · All rights reserved

Section 16: Other Information

Top, Flammability: 0 – Minimal Hazard

DATE PREPARED: 3/3/2016

DATE REVISED: 6/7/2018 AG

Copyright 2016-2018 © · All rights reserved

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