Inr21700 48G

SAMSUNG SDI Confidential Proprietary.
Spec. No. INR21700-48G Version No. Tentative
SPECIFICATION OF PRODUCT
Tentative version
(TBD)
for Lithium-ion rechargeable cell

Model : INR21700-48G
Oct., 2015
Samsung SDI Co., Ltd.

Battery Business Division
1. Scope
This product specification has been prepared to specify the rechargeable lithium-ion cell
('cell') to be supplied to the customer by Samsung SDI Co., Ltd.
2. Description and Model

2.1 Description Cell (lithium-ion rechargeable cell)
2.2 Model INR21700-48G
3. Nominal specifications
Item Specification
Min. 4,700mAh (Typical 4,800mAh)
- Charge: 0.3C(1440mA),4.2V,
3.1 Standard discharge capacity 0.02C(96mA) cutoff @ RT
- Discharge : 0.2C(960mA), 2.5V cutoff @ RT
* 1C = 4,800mA
Min. 17.04Wh (Typical 17.4Wh)
- Charge: 0.3C(1440mA),4.2V,
3.2 Standard discharge energy
0.02C(96mA) cutoff @ RT
- Discharge : 0.2C(960mA), 2.5V cutoff @ RT
3.3 Charging voltage 4.20V
3.4 Nominal voltage 3.6V (0.2C discharge)
CC-CV
3.5 Charging method
(constant voltage with limited current)
Standard charge: 1,440mA
3.6 Charging current Rapid charge : 4,800mA Note 1
Standard charge : 5hours
3.7 Charging time Rapid charge : 2.5hours
3.8.1 Max. charge current Refer to Fig. 1 Note 1
3.8.2 Max. pulse charge current TBD
3.9.1 Max. discharge current 9,600mA (not for cycle life)

35A for 10sec, 25A for 30sec, 18A for 60sec
3.9.2 Max. pulse discharge current
(ambient temperature 23℃)
3.10 Discharge cut-off voltage 2.50V
3.11 Cell weight Max. : 69g

Refer to cell drawing Fig. 2
3.12 Cell dimension Max. height to top : 70.15mm
(W/O tube, W/O Washer) Max. height to crimping : 70.15mm
Max. upper diameter : 21.1mm
1 Samsung SDI., Energy Business Division.

3.13 Operating temperature Charge : 0 to 50℃ (Fig. 1)

(Cell surface temperature) Discharge: -20 to 60℃
1 year : -20~25℃ Note 2

3.14 Storage temperature 3 months : -20~45℃ Note 2
1 month : -20~55℃ Note 2
Note (1): Rapid charge current of 4,800mA is not recommended for long life cycle.
Max charge current for reliable cycle life at T2~T4 region is 0.33C(1,584mA) in
Fig.1, charge current of 0.3C (1,440mA) is recommended for long life cycle at
standard temperature region.
Note (2): If the cell is kept as ex-factory status (30% of charge),
the capacity recovery rate is more than 90%.
Maximum charge current (1.58A)

1.58
0.96
Operating region (current)
T1=0 T2=10 T3=45 T4=50C

T1~T2 : low temperature region
T2~T3 : standard temperature region
T3~T4 : high temperature region
Maximum charge voltage (4.20V )

4.20
4.10
4.00
Operating region (voltage)
T1=0 T2=10 T3=45 T4=50C
Fig. 1. Charging operating window for reliable cycle life.

4. Outline dimensions
Fig. 2. Outline dimensions of INR21700-48G.
5. Bottom vent corrosion resistance

Corrosion under 2mm and no electrolyte leakage after 1,500 hrs of High Temperature
(65℃) and Humidity (85% RH) Endurance test.
6. Standard test conditions

6.1 Environmental conditions
Unless otherwise specified, all tests stated in this specification are
conducted at temperature 23±3℃ and humidity under 65%.
6.2 Measuring equipment

(1) Ammeter and Voltmeter

The ammeter should have an accuracy of the grade 0.5mA or higher.
The voltmeter should have an accuracy of the grade 0.5mV or higher.
(2) Slide caliper
The slide caliper should have 0.05 mm scale or higher.
(3) Impedance meter
The impedance meter with AC 1kHz should be used.
(4) Weighing machine
The weighing machine should have an accuracy of the grade 0.001g or higher
7. Characteristics
7.1 Standard charge

This "Standard charge" means charging the cell with charge current
1440mA and constant voltage 4.2V at 23℃, 96mA cutoff.
7.2 Standard discharge capacity

The standard discharge capacity is the initial discharge capacity of the cell, which is
measured with discharge current of 960mA with 2.5V cut-off at 23℃ within 1 hour
after the “Standard charge”. In this case the minimum capacity of the standard discharge
capacity is 4,700mAh in warranty.
Standard discharge capacity ≥ 4,700mAh
7.3 Standard discharge energy

The standard energy is the initial discharge energy of the cell, which is
measured with discharge current of 960mA with 2.5V cut-off at 23℃ within 1 hour
after the “Standard charge”. In this case the minimum capacity of the standard discharge
capacity is 17.04Wh in warranty.
Standard discharge energy ≥ 17.04Wh
7.4.1 Initial internal impedance (AC resistance)

Initial internal impedance measured at AC 1kHz after Standard charge.
Initial internal impedance ≤ 35mΩ
7.4.2 DC impedance
DC impedance is measured at 50% SOC(state of charge) state.
After Standard charge, discharge with constant current of 2,400mA for 1hr followed by
30min rest time (Check voltage at this time – V1). Discharge with constant current of
2,400mA for 30sec (and check voltage at 10sec – V2)
Initial DC impedance = (V1-V2)[mV] / 2400[mA] ≤ 50mΩ
7.4.3 DC impedance growth (DCR (%) increase)

DC impedance growth means % increased DC impedance after cycle or storage test
compared with initial DC impedance
DCR (%) increase = [ (*DCR(f) / **DCR(i)) – 1] x 100
* DCR(i) : initial DC impedance, **DCR(f) : DC impedance after cycle or storage test

7.5 Temperature dependence of discharge capacity

Discharge capacity comparison according to the discharging temperature, measured with
constant current discharge at 23℃ with 960mA and 2.5V cut-off after charging at the
following temperatures,
Charge temperature Discharge temperature

23℃ -10℃ 0℃ 23℃ 60℃
Relative capacity 70% 80% 100% 90%
Note: If the charge temperature and discharge temperature is not the same,
the interval for temperature change is 3 hours.
Minimum capacity (4,700mAh) is 100% Percentage as an index of the relative
capacity.
7.6 Temperature dependence of charge capacity

Discharge capacity comparison according to the charging temperature, measured with
constant current discharge at 23℃ with 960mA and 2.5V cut-off after charging at the
following temperature is as follows,
Charge temperature Discharge temperature

0℃ 23℃ 45℃
23℃
Relative capacity 70% 100% 80%
Note: If charge temperature and discharge temperature is not the same,

the interval for temperature change is 3 hours.
Minimum capacity (4,700mAh) is 100% Percentage as an index of the relative
capacity.
7.7 Charge rate capabilities

Discharge capacity is measured with constant current 960mA and 2.5V cut-off
after the cell is charged with 4.2V as follows.
Charge Condition
0.2C 0.3C 0.5C 1.0C
Current
(960mA) (1,440mA) (2,400mA) (4,800mA)
Cut-off 7h or 0.05C 5h or 0.05C 3.0h or 0.05C 2.5h or 0.05C
Relative discharge capacity 100% 100% 95% 90%
7.8 Discharge rate capabilities

Discharge capacity according the discharging current is measured with 2.5V
cut-off after the standard charge is as follows,

Discharge Condition
Current 0.2C 0.5C 1C 2C
(960mA) (2,400mA) (4,800mA) (9,600mA)
Relative 100% 95% 90% 80%
capacity
Note: Minimum capacity(4,700mAh) is 100% as an index of the relative capacity.
7.9 Cycle life performance
Temperature 23℃ 45℃

Voltage 4.2 V
Charge
Current 1,440mA (0.3C)
(CC-CV)
Cut-off 240mA
Discharge Current 4,800mA (1.0C)

(CC) Cut-off 2.5V
Cycle 500 cycles 500 cycles
Capacity 3,525mAh 3,290mAh

DC-IR (%) increase 60 % 70 %
7.9.1 Standard cycle life at room temperature with 4.2V

Each cycle is an interval between the charge current 1,440mA and constant voltage
4.2V at 23℃, with 240mA cutoff and the 4,800mA discharge of current with 2.5V
cut-off. Both of DCR(i) and DCR(f) should be measured at 23℃
Capacity after 500cycles.
Capacity ≥ 3,525mAh (75% of the minimum standard capacity)

DCR(%) increase ≤ 60 %
7.9.2 Cycle life at high temperature of 45℃

Each cycle is an interval between the charge current 1,440mA and constant voltage
4.2V at 45℃, with 240mA cutoff and the 4,800mA discharge of current with 2.5V
cut-off. Both of DCR(i) and DCR(f) should be measured at 45℃
Capacity after 500cycles.
Capacity ≥ 3,290mAh (70% of the minimum standard capacity)


7.10.1 Storage characteristics

Recoverable capacity after storage for 30days at 55℃ after the standard charged,
measured with discharge current 960mA with 2.5V cut-off at 23℃.
Capacity recovery(after the storage) ≥ 4,230mAh

(90% of minimum standard capacity)
7.10.2 Storage characteristics

Recoverable capacity after storage for 1year at 20℃ after the standard charged,
measured with discharge current 960mA with 2.5V cut-off at 23℃.
Capacity recovery(after the storage) ≥ 4,230mAh

(90% of minimum standard capacity)
7.11 Status of the cell as of ex-factory or outgoing inspection

The cell should be shipped in 30% charged state. In this case, OCV is from 3.520V to
3.620V.
8. Mechanical Characteristics
8.1 Drop Test

Test method: Each fully charged cell or battery is dropped three times from a height of
1.0 m onto a concrete floor. The cells or batteries are dropped so as to
obtain impacts in random orientations. After the test, the sample shall be
put on rest for a minimum of one hour and then a visual inspection shall
be performed.
Criteria: No fire, no explosion
(Test shall be performed with the following criteria IEC 62133)
8.2 Vibration Test

Test method: As to the UN transportation regulation (UN38.3), for each axis (X and Y
axis with cylindrical cells) 7Hz→200Hz→7Hz for 15min,
repetition 12 times totally 3hours, the acceleration 1g during 7 to 18Hz
and 8g (amplitude 1.6mm) up to 200Hz.
Criteria: No leakage, with less than 10mV of OCV drop
9. Safety
9.1 Overcharge Test

Test method: To charge the standard charged cell with 12V and 3C(14,400mA) at 23℃
for 7 hours.
Criteria: No fire, and no explosion.

(Overcharge test shall be performed with the UL1642 standard)

9.2 External short-circuit test

Test method: Fully rated charged cell is to be short-circuited by connecting the positive
and negative terminals of the battery with a circuit load having a
resistance load of 80 ±20mΩ. The battery is to discharge until a fire or
explosion is obtained, or until it has reached a completely discharged
state of less than 0.2V and the battery case temperature has returned to
±10°C of ambient temperature. The return to near ambient of the battery
(cell) casing in an indication of ultimate results.
Tests are to be conducted at 20 ±5°C and at 55 ±5°C.

External short-circuit test shall be performed with the UL1642 standard
9.3 Forced discharge test

Test method: A discharged cell is subjected to a reverse charge at 1.0C(4,800mA)
for 90 min at 23°C.

Forced discharge test shall be performed with the IEC62133 standard
9.4 Hot oven test

Test method: To heat the standard charged cell at heating rate of 5℃ per minute up to
130℃ and keep the cell in oven for 60 minutes.
9.5 Radiant heater test

Test method: Given the 10 C/min temperature ramping to 600±5℃, cell shall be inserted
Into the cell stand until it explodes.
Criteria: Fire or venting through up and bottom side accepted, but no side rupture
10. Warranty
Samsung SDI will be responsible for replacing the cell against defects or poor
workmanship for 18months from the date of shipping. Any other problem caused by
malfunction of the equipment or mix-use of the cell is not under this warranty.
The warranty set forth in proper using and handling conditions described above and
excludes in the case of a defect which is not related to manufacturing of the cell..
11. Transportation information

This product was tested and found to be in conformity with UN test (Manual of Tests and
Criteria Rev.4, PartⅢ subsection 38.3) for allowing shipping of the cells.
12. Storage for a long time

12.1 Storage for a long time
If the cell is kept for a long time (3 months or more), It is strongly recommended
that the cell is preserved at dry and temperature below 25℃.

13. Packaging
TBD

Please contact following offices when you need any help including safety concerns.
Samsung SDI emergency contact information
■ Samsung SDI Cheonan factory QA

508, Sungsung-dong, Cheonan-si, Chungnam, Korea
Tel : (+82) 70-7125-0593
■ Samsung SDI America office.

601 McCarthy Blvd. (Samsung SDIA) Milpitas CA 95035
Tel : +1-408-544-4528
Fax : +1-408-544-4961

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SAMSUNG SDI Confidential Proprietary.

Spec. No. INR21700-48G Version No. Tentative

for Lithium-ion rechargeable cell

Samsung SDI Co., Ltd.

Spec. No. INR21700-48G Version No. Tentative

2. Description and Model

3.8.1 Max. charge current Refer to Fig. 1 Note 1

3.8.2 Max. pulse charge current TBD

3.9.1 Max. discharge current 9,600mA (not for cycle life)

3.11 Cell weight Max. : 69g

1 Samsung SDI., Energy Business Division.

Spec. No. INR21700-48G Version No. Tentative

3.13 Operating temperature Charge : 0 to 50℃ (Fig. 1)

1 year : -20~25℃ Note 2

Maximum charge current (1.58A)

Operating region (current)

T1=0 T2=10 T3=45 T4=50C

Maximum charge voltage (4.20V )

T1=0 T2=10 T3=45 T4=50C

Fig. 1. Charging operating window for reliable cycle life.

2 Samsung SDI., Energy Business Division.

Spec. No. INR21700-48G Version No. Tentative

Fig. 2. Outline dimensions of INR21700-48G.

5. Bottom vent corrosion resistance

6. Standard test conditions

6.2 Measuring equipment

Spec. No. INR21700-48G Version No. Tentative

(1) Ammeter and Voltmeter

7.1 Standard charge

7.2 Standard discharge capacity

7.3 Standard discharge energy

7.4.1 Initial internal impedance (AC resistance)

7.4.3 DC impedance growth (DCR (%) increase)

* DCR(i) : initial DC impedance, **DCR(f) : DC impedance after cycle or storage test

4 Samsung SDI., Energy Business Division.

Spec. No. INR21700-48G Version No. Tentative

7.5 Temperature dependence of discharge capacity

Charge temperature Discharge temperature

Relative capacity 70% 80% 100% 90%

7.6 Temperature dependence of charge capacity

Charge temperature Discharge temperature

Note: If charge temperature and discharge temperature is not the same,

7.7 Charge rate capabilities

7.8 Discharge rate capabilities

5 Samsung SDI., Energy Business Division.

Spec. No. INR21700-48G Version No. Tentative

Note: Minimum capacity(4,700mAh) is 100% as an index of the relative capacity.

7.9 Cycle life performance

Temperature 23℃ 45℃

Discharge Current 4,800mA (1.0C)

Cycle 500 cycles 500 cycles

Capacity 3,525mAh 3,290mAh

7.9.1 Standard cycle life at room temperature with 4.2V

Capacity after 500cycles.

Capacity ≥ 3,525mAh (75% of the minimum standard capacity)

7.9.2 Cycle life at high temperature of 45℃

Capacity after 500cycles.

Capacity ≥ 3,290mAh (70% of the minimum standard capacity)