EVEREST Engineering College Sanepa-2, Lalitpur, Nepal, Tel: 01-5520742

2080-5-23 Hints & Solution

Section – I 16.(a) sp hybridized carbon is acidic in nature due to
1 having 50% s- character.
1.(b) We have, f = 17.(c) Na2SO4 is salt of strong acid (i.e.H2SO4) &
2π LC
strong base ( i.e.NaOH) when a neutral salt & a
1
LC = = [T2] base is mixed to make a solution then solution
4π2f2 become basic i.e.pH > 7
P ×B
A P
2.(a) Unit vector (n^) = P P 18.(a)
|A × B| 19.(a) For n=1, l=0 which is inconsistent in option (a)
8^i – 8j^ – 8k^ 20.(a) Weight of nitrogen = 0.2 × 14 = 2.8g
=
8 3 Weight of carbon = 12×3×1023/6 × 1023 = 6 g
1 ^ ^ ^ Weight of Sulphur = 1×32 = 32 g
= (i – j – k)
3 ∴ Weight of silver = 7 g
3.(b) When ice melts level of waster is same. But due 21.(d) Size of anion > size of cation& size of cation or
to decrease in temp. to 4°C, volume decreases anion ↑s down the group
because density is maximum at 4°C.
22.(d) Generally, for a compound acidity ↑s as its
4.(b) m = Vρ during winter density is more so mass central ion's oxidation state increases
increases.
Here, oxidation no of nitrogen increases as
As θ↓, m↑ follows:
5.(a) Vessel being filled with water behaves as closed NH3 < N2H4 < N2H2 < N3H
organ pipe. As more and more water is filled, l
So, property of compound vary from basic
v
( )
decreases and frequency increases f =
4l
23.(c)
(NH3) to acidic( N3H)
Mohr's salt is double salt
6.(d) Use right hand palm rule.
24.(d) Pt., Rh is used as catalyst in Ostwald's process
7.(d) In equpotential surface, ∆V = 0
W = q∆V = 0 and varies with potential 25.(a)
me 4 26.(c)
8.(c) R=
8ε02h3c 27.(d)
As 'm' is reduced to half, R also become half. 28.(c)
9.(a) P = ρgh 29.(d) p ⇒ q is equivalent to ~q ⇒ ~p.
or, h ∝ g–1 30.(b)
∆h ∆g
or, = – = –(2)% = +2% 31.(b) 4sin–1x + cos–1x = π
h g
1 v2 2 or, 3sin–1x + sin–1x + cos–1x = π
mk2 × 2 π
KEr 2 r k2 5 2 or, 3sin–1x + =π
10.(a) = = 2 2= = 2
KET 1 k2 k +r 2 7
2
mv (
2
r2 )
+1 5
+1
or, sin–1x =
π
11.(d) Sound is mechanical wave and needs material 6
medium to propagate. π 1
∴ x = sin =
12.(d) Electric field strength is zero inside a hollow 6 2
sphere. a b
13.(d) δ = 180° – 2i 32.(a) From sine law, =
sinA sinB
= 180° – 2 × 30° = 120°
6 2 b
14.(b) In TV wave frequency is modulated. = ∴ b = 12
sin30° sin45°
15.(a) R – C ≡ N has tendency to donate as well as
accept lone pair electrons. AlCl3 has a vacant p- 33.(b) Total no. of ways = 5c1 + 5c2 + 5c3 = 25
orbital so it can accept a pair of electrons.ROH 34.(b) loge(1 – 2x) is valid if –1 ≤ 2x < 1
and R2NH are nucleophiles because of having
lone pair electrons. 1 1
⇒ – ≤x<
2 2

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 EVEREST Engineering College Sanepa-2, Lalitpur, Nepal, Tel: 01-5520742
2080-5-23 Hints & Solution
n(n + 1) 46.(d)
35.(c) 1 + 2 + ... + n = 55 ⇒ = 55
2 47.(c) We have, l2 + m2 + n2 = 1
2 1 1 1
∴
13 + 23 + ... + n3 = (n(n2+ 1)) = 55 = 3025
2 + + =1
c2 c2 c2

36.(a) A2 = I c2 = 3 ⇒ c = ± 3
1 + 2 + 3 + ... n
x 1 x 1 1 0
[ ][ ] [ ]
1 0 1 0 = 0 1
48.(d) Arithmetic mean =
n
1 n(n + 1) n + 1
x2 + 1 x 1 0 = =
[
or, ] [ ] x 1 = 0 1
49.(c) 50.(a) 51.(c)
n 2
52.(b)
2
53.(d) 54.(a)
⇒ x2 + 1 = 1 ⇒ x = 0 55.(b) 56.(a) 57.(b) 58.(c) 59.(d) 60.(a)
lim lim 3
37.(c) 2x = 2, x +1=1+1=2
x→1 x→1 Section – II
lim 61.(d) V = nVe = 2Ve ∴ n = 2
By squeeze theorem, f(x) = 2
x→1
Velocity in free space (V) = n2 – 1 Ve
lim 2x – sin–1x
38.(c) By continuity, f(0) = = 22 – 1 V e
x → 0 2x + tan–1x
sin–1x = 3 Ve
2–
lim x 2–1 1
= = = x µ
x→0 tan–1x 2 + 1 3 62.(a) =
L µ+1
× 100%
2+
x
x x 0.25
39.(d) f '(x) = e g'(x) + g(x) e [Product rule] = × 100% = 20%
0.25 + 1
∴ f '(0) = g'(0) + g(0) = 1 + 2 = 3
u
40.(d)
dx
I1 – cosx = I
dx 1
= Icosec2 dx
x 63.(d) ucosθ = ⇒ θ = 60°
2
2x 2 2
2sin
2 u2sin2 × 60° 3 u2
R= =
g 2 g
 cot 2x
1  + c = –cotx + c 64.(c) Q = ms∆θ = ρVs∆θ
= –
2 1  2
 2 
x2 y2
= ρ. (43 πr ) s∆θ
3

41.(d) Solving + = c Q ∝ r3
2 2
x2 + y2 = 2c (Family of concentric circles) 65.(d) As beaker appears half-filled, apparent height of
water = height of air column
 11 10 01  11 10 01
42.(a)   = –  = 21 – h
–1 0 –1 1 0 1 Where h = actual height of water filled in
= 0 [‡ R2 = R3] beaker.
43.(c) (aP × Pb)2 = (|aP| |bP| sinθ)2 RD h
µ= =
1 2 AD 21 – h
= (4.2 sin30°)2 = ( )
8.
2
= 16
4
=
h
44.(c) For horizontal line, slope = 0 3 21 – h
(2 – k) h = 12 cm
i.e. – =0
–3 + k 1 1 1 1 1 1
∴ k=2 66.(d) = – = – =
f D d 25 30 150
45.(b) For circle, coeff. of x2 = coeff. of y2
f = 150 cm
k 1
i.e. = 100 100 2
3 4 P= = =+ D
f 150 3
3
∴ k=
4

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 EVEREST Engineering College Sanepa-2, Lalitpur, Nepal, Tel: 01-5520742
2080-5-23 Hints & Solution
78.(d)
67.(b) L = 10 log10(II ) 0 79.(d) A + 2B → AB2
I 1 mole 2 mole 1 mole
100 = 10 log (
10 )
10 –12 2 mole 4 mole
I = 10 –2 So, B is limiting reactant thus 1 mole
P = IA = 10–2 × 0.5 × 2 = 10–2 W 80.(b) pH = 5 & diluted to 100 times then new concn is
68.(c) Length of diagonal of cube = 3b distance of 10–5 N
So, 10–7N H+ ion is also consider from H2O
d 3
each charge from the centre = =
2 2
b Thus final concn is 2 × 10–7N
Hence pH = 6.7
∴ Total potential at centre
q 4q 81.(d)
(V) = 8. = 1
3 3 πε0b 82.(b) Here, f(x) =
4πε0. b |x| – x
2
V V ∴ f(x) is defined when |x| – x > 0
69.(d) F = qE = q. = e i.e. |x| > x
l l
Fl 4.8 × 10–19 × 5 It is possible if x < 0
V= = = 15 volt ∴ x∈(–∞, 0)
e 1.6 × 10–19
dI –3
40 × 10 (11 – 1) 1 1 1
70.(a) | |
ε= L
dt
=
4 × 10–3
= 100 V 83.(c) + +
ab bc ca
c+a+b
71.(b) I = I0e–µx =
abc
I0
= I e–µx
2 0 =
2s
‡ R = abc
eµx = 2
4R∆  4∆ 
µx = 0.693 1
=
0.693 0.693 ∆
2R.
µ= = = 0.3 s
x 2.303 mm
1  ∆
t 6400 = ‡r= 
72.(b) No. of half lives (n) = = =8 2Rr  s
T1/2 800
n 8 84.(b) Pa + Pb + Pc = 0
N 1 1
N0
= () ()
2
=
2 Squaring,
P|2 + |cP|2 – 2(aP.bP + bP.cP + Pc .aP) = 0
|aP|2 + |b
N
Fraction that have been decayed = 1 –
N0 or, 2(aP.bP + bP.cP + Pc .aP) = –(9 + 16 + 25)

1 255 ∴ a .b + Pb.cP + Pc .aP = –25

P P
=1– =
256 256
85.(d) |x|2 – |x| – 6 = 0
73.(a) Some ejected photoelectrons don't have K.E. so
minimum K.E. is 0 eV. (|x| – 3) (|x| + 2) = 0
74.(b) In the organic species having unipositive charge, Either, |x| = 3 ⇒ x = ±3
1, 2, 3, 4, and 5 carbons represent 1, 1, 2, 4 and or, |x| = –2 (no real roots)
8 isomers respectively. Product = 3 × (–3) = –9
75.(a) It is also known as (4+2) cycloaddition reaction. 86.(d) (4 + 3i)3 161 73
= – i i.e. 4th quadrant
i–1 2 2
76.(c) Al3++3e-→ Al, EAl= At.Wt/3
87.(d) |adj. A| = |C|
Cu2++2e-→ Cu, Ecu= At.Wt/2
or, |A|3–1 = |C|
Na++e-→ Na; ENa= At.Wt/1
When 3 "Faraday is passed; 1 k 3 
or, 42 = 1 3 3
Mole atom of Al deposited =1 2 4 4
Mole atom of Na deposited = 1 × 3/2 = 1.5 or, 16 = 2k – 6 (By expanding determinant)
Mole atom of Na deposited = 1 × 3 = 3 ∴ k = 11
77.(c) The balanced equation is
IO3- + 5I- + 6H+ → 3I2 + 3H2O

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 EVEREST Engineering College Sanepa-2, Lalitpur, Nepal, Tel: 01-5520742
2080-5-23 Hints & Solution
88.(b) Number of rectangles = 10C4 – 4C4 – 4C3 × 6C1 93.(c)
Y
= 210 – 1 – 24 = 185 x2 = 4a(y − 2a)

y = 6a
lim x – sinx 0
89.(c)
x → 0 x3 [ 0
form]
(0, 2a)
Using L Hospital's rule
X
O
lim 1 – cosx 0
x → 0 3x2 [ 0
form ] 6a
A = I xdy
lim sinx
=
x → 0 6x [00 form] = x lim→ 0 cosx6 = 16 2a
6a
= I 2 a y – 2a dy
90.(a) Total no. of cases = 40C2 = 780 2a
(y – 2a)3/2 6a 32a2
Sum of two integers is odd if one of them is odd =2 a  = sq. units
 3 2a 3
and other is even.  2 
No. of favourable cases = 20C1 × 20C1 = 400 94.(a) h = 1, k = –2
400 20 a2 = 4, b2 = 9
Required probability = = Vertices = (h ± a, k)
780 39
= (1 ± 2, –2)
= (3, –2) & (–1, –2)
dy 1
91.(b) = 95.(a) D.r's of OP = (a – 0, b – 0, c – 0)
dx 1 + x3
= (a, b, c)
Eqn of plane through P(a, b, c) is
(dydx) x=1 =
1
=
1 + 13 2
1
A(x – a) + B(y – b) + C(z – c) = 0 ....(i)
dy t 1 A B C
92.(b) – y= Since (i) is ⊥r to OP, = = = k (suppose)
dx 1 + t 1+t a b c
∴ A = ak, B = bk, C = ck
Which is a linear diff. eqn. with
Using in (i), a(x – a) + b(y – b) + c(z – c) = 0
I.F. = (t + 1) e–t ax + by + cz – a2 – b2 – c2 = 0
1 96.(d) x2 – 4x – 8y + 12 = 0
y(1 + t) e–t = I (1 + t) e–t dt
1+t i.e. (x – 2)2 = 8(y – 1)
y(1 + t) e–t = –e–t + c Comparing with (x – h)2 = 4a(y – k), 4a = 8
Length of latus rectum = 4a = 8
When t = 0, y = –1, So, –1 = –1 + c ⇒ c = 0
97.(c) 98.(c) 99.(a) 100.(d)
1
When t = 1, y.2.e–1 = –e–1 ⇒ y = –
2

…The End…