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    Chemistry A-1 (2023,1st Sem)

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    shrabani.mahata
    This document is an assignment for a chemistry course at NIST Institute of Science & Technology. It contains 10 questions across 2 competencies assessing various levels of understanding. The questions cover topics like photoelectric effect, quantum mechanics, hermitian operators, quantization of energy, absorption and transmission of light, effects of solvent polarity on transitions, vibrational energy of HCl, rotational spectrum of CO, degrees of freedom in systems, and phase diagrams. Students are asked to calculate, derive, explain, and analyze physical concepts. They must submit their responses by November 15th, 2023 for a total of 50 marks.

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    Chemistry A-1 (2023,1st Sem)

    Uploaded by

    shrabani.mahata
    11 views2 pages
    This document is an assignment for a chemistry course at NIST Institute of Science & Technology. It contains 10 questions across 2 competencies assessing various levels of understanding. The questions cover topics like photoelectric effect, quantum mechanics, hermitian operators, quantization of energy, absorption and transmission of light, effects of solvent polarity on transitions, vibrational energy of HCl, rotational spectrum of CO, degrees of freedom in systems, and phase diagrams. Students are asked to calculate, derive, explain, and analyze physical concepts. They must submit their responses by November 15th, 2023 for a total of 50 marks.

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    Chemistry A-1(2023,1st Sem)

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    This document is an assignment for a chemistry course at NIST Institute of Science & Technology. It contains 10 questions across 2 competencies assessing various levels of understanding. The questions cover topics like photoelectric effect, quantum mechanics, hermitian operators, quantization of energy, absorption and transmission of light, effects of solvent polarity on transitions, vibrational energy of HCl, rotational spectrum of CO, degrees of freedom in systems, and phase diagrams. Students are asked to calculate, derive, explain, and analyze physical concepts. They must submit their responses by November 15th, 2023 for a total of 50 marks.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    11 views2 pages

    Chemistry A-1 (2023,1st Sem)

    Uploaded by

    shrabani.mahata
    This document is an assignment for a chemistry course at NIST Institute of Science & Technology. It contains 10 questions across 2 competencies assessing various levels of understanding. The questions cover topics like photoelectric effect, quantum mechanics, hermitian operators, quantization of energy, absorption and transmission of light, effects of solvent polarity on transitions, vibrational energy of HCl, rotational spectrum of CO, degrees of freedom in systems, and phase diagrams. Students are asked to calculate, derive, explain, and analyze physical concepts. They must submit their responses by November 15th, 2023 for a total of 50 marks.

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    NIST Institute of Science & Technology (AUTONOMOUS)

    www.nist.edu (Approved by AICTE, New Delhi, Affiliated to BPUT: Rourkela)


    INSTITUTE PARK, PALLUR HILLS, BERHAMPUR, ODISHA -761 008

    ASSIGNMENT NO # 01

    Sub with Code - Chemistry, 22FY1BS02T


    Program: B.Tech. Semester: 1st (Batch-2023)
    Due Date – 15-11-2023 Full Mark-- 50

    Each question carries 5 marks

    Q. No CO* Level (1) Remembering (2) Understanding (3) Applying (4) Analyzing (5) Evaluating (6)
    Creating

    A light of wave number 2.5 x 10 -3 nm-1 strikes a certain metal surface having work function
    1 1 2 of 2.15 eV. Calculate the kinetic energy and velocity of the emitted photo electron in eV.

    Show that the normalized wave functions (with n=1 and n=2) associated with the particle
    are orthogonal?
    2 1 3

    What is hermitian operator? Prove that the eigen values of hermitian operator are real.
    3 1 3

    Derive the expression for energy of a particle moving in a one dimensional box of length L
    to show that energy of free particle in one dimensional box is quantized
    4 1 4
    .

    A 2×10-3 m thick glass sheet transmits 10% of the incident light of same wavelength 300nm.
    5 1 3 What % of light of the same wavelength will be absorbed by 1×10-3 m thick glass sheet?

    6 1 3 Explain the effect of polarity of the solvent on each type of transition.

    The force constant of HCl gas is 481Nm -1. Calculate vibrational energy (in Joules), zero-
    point energy and vibrational frequency of HCl molecule. (at. wt; H=1.673×10 -27 kg, Cl=
    7 1 3 58.06×10-27kg).

    8 1 4 The first line in the rotational spectrum of CO is 4.2423 cm-1. Calculate B, rco?

    What is Degree of freedom? Find the no. of components and degrees of freedom of the
    following systems.
    9 2 3 i. NaCl-KBr-H2O
    ii. Saturated solution of NaCl at room temperature

    What is meant by the term component? Draw a labeled phase diagram of water system and
    10 2 3 explain the term metastable equilibrium.

    CO1. Know the basic concept of quantum mechanics, Predict the structure of molecule through interaction of
    electromagnetic radiation such as UV-Vis, IR, and Microwave at molecular level
    CO2. Understand and analyze phase transition and know the conditions of different stable and metastable phase
    equilibria for both single and binary system
    NIST Institute of Science & Technology (AUTONOMOUS)
    www.nist.edu (Approved by AICTE, New Delhi, Affiliated to BPUT: Rourkela)
    INSTITUTE PARK, PALLUR HILLS, BERHAMPUR, ODISHA -761 008

    CO1. Know the basic concept of quantum mechanics, Predict the structure of molecule through interaction of
    electromagnetic radiation such as UV-Vis, IR, and Microwave at molecular level
    CO2. Understand and analyze phase transition and know the conditions of different stable and metastable phase
    equilibria for both single and binary system

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