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1. Alternative conceptions in
chemistry teaching
This chapter provides a brief introduction to the topic of learners’ ideas in science, and in particular
to the types of alternative conceptions that have been uncovered among chemistry students in
schools and colleges.
’because the copper sulfate has a chemical inside it that turned the water blue’
a student in class of 1 1-1 2 year olds
A compound is:
’because fluorine wants to gain an electron and hydrogen wants to lose one’
a student on post-16 course
The above comments were made by students responding to probes that are included in this
publication. These comments, and many others like them reported in the research literature, show
that students often develop alternative ideas about the science they are taught in school.
Teachers are usually aware when students are not paying attention, and respond accordingly.
Teachers also have ways of finding out when learners do not understand. In an ideal world we create
the type of supportive learning environment where students are keen to learn, take responsibility for
asking when unsure, and are confident to speak up without feeling self-conscious or in danger of
ridicule.
Even when our classrooms and teaching laboratories do not match this ideal, teachers learn to use
questioning techniques to check learners’ understanding.’ As effective learning requires regular
reinforcement and review, forgetting is a more difficult problem for the teacher to tackle, particularly
where there is much material to cover and classes are not seen frequently. However, even in this
area, teachers can take every opportunity to bring in previous work and relate this to new topics, and
can encourage effective study skills in their students.
N o doubt such professional techniques are very useful, but - even with the improvements they may
bring - w e do not expect all the class to get near perfect marks o n the end of topic tests.
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O f course sometimes youngsters may just feel they ought to think of an answer because of the social
pressure of being asked by an adult.2 The influential Swiss psychologist Jean Piaget described how
young children would often ’romance’ up an answer when they were asked something that they did
know about.3 However, research evidence suggests that many of the answers that students produce
cannot be explained in that way and there is a great deal of research evidence available to consider.
Over the past twenty years there has been a vast research effort to ask students all sorts of questions
about many different science topics - before, during and after teaching. There are now thousands of
papers in research journals and conference proceedings presenting the results of this research, and a
range of books discussing the finding^.^ In view of the great diversity of this work (undertaken in the
UK, New Zealand, Australia and many other countries; with learners of various ages from young
children to graduates; and in aspects of biology, physics and chemistry) it is not surprising that the
‘experts’ do not all agree on all the details of what this research tells us. However, there is a general
consensus on many important points, and it i s certainly agreed that learners hold a wide range of
ideas about many scientific topics - ideas that often contradict the science they will meet in school
and college.’
Students as scientists?
It i s certainly very clear that teachers can not safely assume that their students w i l l come to classes
without any preconceived ideas about a topic, giving the teacher a ’blank slate’ on which to impress
scientific know Iedge.
The late Rosalind Driver (who was very influential in undertaking and encouraging research into
learners’ ideas) described ’the pupil as scientist’, and explained that from a young age children
behave like amateur scientists, finding patterns in the world and forming conjectures to explain these
patterns.6
Of course, the youngsters are not professional scientists, and so their thinking does not always match
scientific standard^.^ The important point was that by the time a student comes to secondary science
he or she will have built up a great many of their own explanations about the way the world works,
and many of these will be at odds with the scientific view. (The student will also have studied
science in primary school, but may well - despite having being given satisfactory explanations -
have misinterpreted that teaching in the terms of their prior conceptions).
One way in which Driver found that students were rather poor scientists was in the way they treated
data. Driver found that students were often unable to see that the results of an experiment should
have refuted their ideas about what was going on. Indeed, she found that often students would ‘see’
and record what their preconceptions told them to expect to see - and so their recorded results
matched their expectations rather than what they were meant to observe. (If one wished to be cynical
one might suggest that Driver got her slogan wrong - and that her book should have been called ’the
pupil as politician’, ’the pupil as Freudian analyst’ or ‘the pupil as Marxist historian’.)
The important point that Driver recognised was that this failure to record results accurately was not
due to laziness, or stubbornness or being deliberately awkward. Students were not being arrogant -
just human. Driver’s observations reflected something very important about the human perceptive
system: we often see what we expect to see rather than what is in front of our eyes. From a
physiological point of view w e do not see with our eyes, but with our brains, and the signals from the
eyes are only part of the information being used to make sense of the world. This can be seen by
referring to one of the books presenting optical illusions,8 which show how our brains attempt to
interpret what we see in terms of the patterns we expect.
Professional scientists receive training in applying practical and analytical techniques to help them
learn to give precedence to the data, and to be (less) biased by their expectations in experimental
work. Students in school are only just starting out on their training in scientific method.
Certain researchers who have worked in the field have suggested that because some of the alternative
ways of explaining science revealed in research have seemed to be loosely associated clusters of
ideas or logically incoherent, then learners’ ideas are always like this.’” In my o w n research I have
found that learners’ thinking can be very variable. Students, like any of us, can have strongly held
beliefs, as well as vague notions, and relatively isolated ideas as well as logically developed
frameworks of conceptions.
1. In any class, for any science topic, students are likely to hold a wide range of alternative ideas
about the topic;
2. not all of these ideas will be highly significant in terms of impeding the intended learning; but
1. Sometimes the new learning does seem to successfully supplant the old ideas without too many
problems.
2. Sometimes the learner treats the new ideas as if they are unrelated to their previous thinking. The
science that has been learnt in school seems to be ‘stored’ separately from the existing ideas.
Sometimes when this happens the student may use one set of ideas to answer formal science
questions, but a different set of ideas in everyday situations.
This research suggests that when the same scientific principle is tested in an abstract ‘scientific’
context, it will be answered differently to an equivalent question testing the same principle, but set in
a novel everyday context.”’ 14, 1 5 , 1 6 , ” This may have consequences for examiners looking to set
questions in novel everyday contexts,
’[A] question o n differences between the element iron and its compounds ... set in the context of
breakfast cereal content was.. . [often] answered using everyday understanding rather than scientific
knowledge, for example stating that iron i s inedible, whereas iron compounds are edible.’’8
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Some science educators feel it i s satisfactory for learners to acquire separate versions of scientific
ideas which they apply in academic and everyday (or ’life-world’) contexts, and some students seem
to be able to successfully retain workable versions of the ideas in both of these ‘d~mains’.’’~ ”
3. However, it i s often found that when the student stores the new ideas separately they are soon
forgotten. Although tests shortly after the teacher’s presentation may be encouraging, it i s
sometimes found that re-testing weeks and months later leads to the student returning to their
original way of thinking about the topic.2’ This is disappointing as the learning that occurs
appears to have been rather superficial (and does not survive to end of course examinations, let
alone through later life). Indeed it may be found that experiments that were presented to
demonstrate the scientific ideas are now recalled as having different results - results which
support the students’ original way of thinking about the topic. Retrieval of information from
memory is known to be a reconstructive process, where much of a ‘memory’ is often inferred
from specific items of recaIi.’”’’
4. Sometimes little or no learning takes place because the learner is unable to make sense of the
teacher’s presentation in terms of their existing ideas. In this case the learner’s ideas may seem
unchanged by the lesson.
5. Sometimes the learner is able to make sense of the teacher’s presentation in terms of their o w n
alternative way of thinking about the topic. This may result in the student learning new material,
but not in the way intended. The learner unintentionally distorts the teacher’s words to fit into the
existing framework. Often, when this happens, neither the teacher nor the student are aware that
the student is reinterpreting the material in this way - at least not until the new learning is elicited
in a test.
This may mean that there is no fundamental change in the way the learner understands the topic,
despite new learning having taken place (as the new ideas are all made to fit with the existing
understanding). However it is also possible for the process of ‘making sense of the teacher’ to lead to
the student’s ideas starting to change. The result may be a hybrid understanding of a topic
somewhere between what the student started out with, and what the teacher intended.
If you read some of the journal articles and books in the Notes and references section you will find
references to a whole range of terms. Students’ ideas may be described as intuitive, informal,
misconceived, alternative, preconceived, prior, folk, life-world, etc; they may be ideas, concepts,
conceptions, frameworks and so on.
The reason why so many terms are used i s (in my view) because learners’ ideas are so varied. Some
aspects of thinking may well reflect the structure of the human cognitive apparatus (iethe way nerve
cells in the brain work together), and could be considered ’intuitive’. Other ideas are picked up from
the social milieu - the playground, television, listening to parents and older siblings etc - and may be
described as ’informal’. If a student misinterprets what a teacher has said we might call their idea a
‘misconception’.
O f course, many ideas that learners have can not be so easily classified. Brain structure; early
experience of the world; the quirks of language; things heard, seen and read out of school; and
classroom experiences may all play a part in building up new ideas. All new learning is interpreted
through existing ideas, so few notions that people have can be said to derive from just one source.
I will refer to learners’ ideas that do not match science as being ’alternative’, that just means they are
different, without needing to consider how they arise. (Later it will be suggested that it is useful to
distinguish those alternative conceptions which seem to derive partly from the way we teach topics,
to those which students seem to acquire regardless of how we teach - see Chapter 4.)
Two terms that are commonly used are ’alternative conceptions’ and ’alternative frameworks’. I tend
to use these terms to have slightly different meanings so that;
There are some examples given below. However, you should bear in mind that it is not always
obvious whether an elicited conception is actually part of a more complex framework, and in some
articles and books you will find these terms are used interchangeably, as if they are synonymous. It i s
less important which terms we use to describe students’ ideas, than to (a) recognise that students have
alternative conceptions that may interfere with learning, and (b) know how to diagnose and try and
respond to them. That i s what this publication is about.
A common alternative conception from biology concerns the origin of the matter in plants such as
trees. When people are given a piece of wood and asked h o w the material got into the tree they
commonly reply that most of it came from the soil, although this is not the ‘scientific’ answer. I have
seen footage of American engineering graduates and graduating science teachers in England
confidently explaining that the mass of the tree came from the soil. Presumably most of these
graduates would have been able to explain the basics of photosynthesis (had that been the question)
and perhaps they had stored their learning about the abstract scientific process (where the carbon in
the tree originates from gaseous carbon dioxide in the air) in a different compartment from their
‘everyday knowledge’ that plants get their nutrition from the soil.
When national UK test data was analysed by researchers for the Children’s Learning in Science
Project (CLiSP), it was concluded that only a third of 15 year old students used scientifically
acceptable ideas about plant nutrition.”
Although the literature which describes alternative conceptions in science is vast, a very good (if
slightly dated now) overview relating to the secondary science curriculum is available.‘8
Teachers may be able to see examples of their o w n students’ alternative conceptions when using
probes, such as Elements, compounds and mixtures, and others, in the companion volume to this
book.
the nucleus of an atom gives rise to a certain amount of attractive force which i s shared between
the electrons in the atom.
atom or ion the nuclear force is shared among a smaller number of electrons - so they each
experience more force than before. (This i s certainly an easier way of explaining the phenomena
than the accepted scientific version!)
This is one example of where ideas from physics are used to explain aspects of chemistry, and it
might be thought that students studying both subjects would not be likely to hold this alternative
conception. However, it seems some students store their physics and chemistry learning in different
memory domains, and do not easily apply their understanding about forces and electrostatics in
c hem istry.3’
There are many other examples of alternative conceptions relating to chemistry topics. The Royal
Society of Chemistry has commissioned a report on alternative conceptions in chemistry, which is
freely available for consultation or downloading on the Internet.3L
in a nucleus the neutrons have the job of neutralising the charge o n the proton^;'^
isomers are always members of the same class of compounds (eg both alcohols, but not an
alcohol and an ether);’5
The first example shows the importance of language in learning science. Hans-Jurgen Schmidt
believes the label (’neutralisation’) suggests to students that the process should give a neutral product.
(The examples students meet early in their school chemistry usually do, which reinforces the idea!) A
similar effect may explain why students often expect all freezing temperatures to be experienced as
cold, and all melting temperatures (even for the same substances) to always be experienced as hot.37
This effect could also be important in the second example where students are taught that a nucleus
contains positive charges (which they should know w i l l repel each other) and neutrons. The natural
tendency to look for an explanation, and the suggestive label, might explain why students hold this
alternative conception.
The third example is an example of learners applying the wrong level of generalisation. Students
appreciate some key aspects of what isomers are, but restrict the application of the idea to within a
single class of compounds. This is not a difficult conception for teachers to tackle, as long as they are
able to diagnose it.
The fourth alternative conception in the list refers to an error in categorisation, with the term
’hydrogen bond’ taken to mean a covalent bond to hydrogen, rather than a type of intermolecular
bond. It seems this idea sometimes arises because students meet hydrogen bonds in biology in the
context of nucleic acids and proteins, before they have studied this type of bonding in chemistry (see
Chapters 7 and 10). If some teachers simply label a bond as a hydrogen bond without being clear
what this means, it is not surprising that students’ attempts to make sense of the information in terms
of their existing knowledge may lead them to assuming the bond is covalent.
Students commencing post-1 6 science courses often only have any detailed knowledge of two types
of chemical bond - ionic and covalent - so in the absence of any charges being shown, any bond
drawn as a line is likely to be identified as a covalent bond.
N o w this explanation may seem to suggest that some biology teachers are being careless in not
making it clear that a hydrogen bond is a particular type of bond. Yet the research evidence suggests
that many post-16 students have great difficulty in learning about new types of bonding. Although
classing a hydrogen bond as a covalent bond can be considered as an alternative conception, it may
also be part of a more complex alternative framework - the octet framework - for thinking about
chemical bonding, that has been found to be quite common by the time a student leaves school.
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Without describing all the evidence for this framework in detail, the following overview shows how
this i s not just a set of unrelated alternative conceptions. Some aspects of the framework are quite
close to scientific thinking, and others may appear quite bizarre - but it is the way these ideas can be
integrated into a coherent scheme that is so significant (see Chapter 10).
own their
Electrons chemical Reactions
entities
Van der
Waals
Hydrogen are
This framework appears to develop from learners’ attempts to understand why bonds form, and why
reactions occur. According to this alternative framework:
W the reactions occur, and bonds form, so that atoms can obtain full outer shells (or octets) of
electrons; and
W there are two ways that atoms can obtain full shells: by electron transfer (ionic bond) or electron
s ha ri ng (covaIent bond i ng).
Students often take the idea that ‘everything is made of atoms’ too seriously (see Chapter 6). For one
thing they take the meaning that everything i s made from atoms to mean that the reactants in
chemical reactions always start off as atoms. So they think that sodium chloride is made from atoms
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of sodium which donate electrons to atoms of chlorine - even though this i s not a very likely process
chemically! As the ionic bond is identified with the process of electron transfer, each ion is only
considered to be fully bonded to one counter ion (see Chapter 8).
Atoms are considered to maintain their discrete identity within molecules, so that bonding electrons
are still considered to belong to (and be part of) the atom from which they originated. Students
therefore expect atoms to reclaim ‘their own’ electrons when the bond breaks (making it difficult for
students to appreciate heterolytic bond fission). Some students even think that ions must be
discharged by electrons returning to ’their own’ atoms before new ionic compounds can be
precipitated (see Chapter 9).
Because students usually fail to appreciate the physical (that is, electrical) basis of bonding they
explain chemical change in anthropomorphic terms: that atoms ’want’ or ‘need’ to have full shells
(see Chapter 6). O f course there are very few chemical processes where reactants consist of atoms
with partially filled electron shells - so this only makes sense because students tend to think of
chemical processes as starting with atoms (see Chapter 9).
As bonding is understood in terms of the need to obtain octets or full shells, students find difficulty in
making sense of bonding that can not clearly be seen in these terms. Students w i l l have learnt two
mechanisms by which they think full shells can be achieved (electron transfer and electron sharing).
So metallic bonding is often seen (initially) as being like ionic and/or covalent bonds. Polar bonding is
usually seen as a type of covalent bond (rather than being something intermediate between covalent
and ionic). As we saw above, hydrogen bonding may be simply assumed to be a type of covalent
bond. When it becomes clear to the student that this is not what is meant, it i s then likely to be
dismissed as ‘just’ a force, and not a real chemical bond (see Chapter 8).
Students will have learnt about the stability of electronic structures isoelectronic with the noble gases
in their school science. Unfortunately they often generalise this idea beyond the point at which it i s
scientifically appropriate. Many students at this level consider an isolated sodium cation to be more
stable than the isolated atom, and assume than the atom w i l l spontaneously emit an electron, but that
the positive cation could not spontaneously attract a negative electron. Some students (even after
having studied patterns in successive ionisation energies) will claim that only one electron can be
removed from the sodium atom - as it then has an octet.
Any reader w h o doubts how common these ideas are might try some of the relevant diagnostic
probes included in this resource. Would you expect your students to tell you that a highly charged
anion of a metallic element (Na7-) is more stable than the neutral atom?The evidence from published
research, and the experiences of teachers trying out these resources for the RSC, suggest that many of
your students will argue that the sodium anion is more stable as it has a full [sic] outer shell of
electrons! (See Chapter 6).
Hopefully, reading through this section has persuaded you that students’ alternative conceptions in
chemistry should be taken seriously. This publication has been designed to help you tackle this issue
in the classroom. In this resource and its companion volume you will find:
H information about some of the key alternative conceptions that have been uncovered by research;
H copies of probes you can use to identify these ideas among your o w n students;
H ideas about teaching approaches that may help avoid students acquiring some common
alternative conceptions;
general ideas about helping your students develop appropriate scientific conceptions; and
examples of classroom activities that will help students construct the chemical concepts required
in the curriculum.
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2. K. S. Taber & M. Watts, Learners’ explanations for chemical phenomena, Chemical Education:
Research and Practice in Europe, 2000, 1 (3), 329-353, available at
http://www.uoi.gr/conf-sem/cerapie/ (accessed October 2001 ).
3. j. Piaget, The Child’s Conception of The World, St. Albans, UK: Granada, 1973.
4. Many useful references to the literature are given in the review article: K. S. Taber, Chemistry
lessons for universities?:a review of constructivist ideas, University Chemistry Education, 2000, 4
(2), 26-35.
5. Although learners’ ideas in science have attracted considerable attention, alternative conceptions
have also been found in other areas of the curriculum. See D. P. Newton, Teaching for
Understanding, London: RoutledgeFalmer, 2000.
6. R. Driver, The Pupil as Scientist? Milton Keynes: Open University Press, 1983.
7. For example: R. Driver, J. Leach, R. Millar & P. Scott, Young People’s Images ofscience,
Buckingham: Open University Press, 1996.
8. H. Dickson, Fantastic Optical lllusions and Puzzles, London: Lagoon Books, 1996.
9. One of the teachers who piloted materials for this project reported that his group of 13-14 year
olds ’were reluctant to relinquish their o w n ideas’ when presented with the materials on Elements,
compounds and mixtures.
10. G. Claxton, Minitheories: a preliminary model for learning science, in P. J . Black & A. M. Lucas,
Children’s Informal ldeas in Science, London: Routledge, 1993, 45-61.
11. J. Kuiper, Student ideas of science concepts: alternative frameworks?, lnternational journal of
Science Education, 1994, 16 (3), 279-292.
12. J. K. Gilbert, R. j. Osborne & P. J. Fensham, Children’s Science and its Consequences for
Teaching, Science Education, 1982, 66 (4), 623-633.
13. J. Bliss, I. Morrison & J. Ogborn, A longitudinal study of dynamics concepts, lnternationaljournal
of Science Education, 1988, 10 (1 1, 99-1 10.
14. R. Driver, The Pupil as Scientist! Milton Keynes: Open University Press, 1983.
15. D. Dumbrill & G. Birley, Secondary school pupils’ understandings of some key physics concepts,
Research in Education, 1987, 37, 47-59.
18. Qualifications and Curriculum Authority (QCA), Standards in Key Stage 3 Science (ZUUO), London:
QCA, 2001, 12.
19. J. Solomon, Getting to Know about Energy - in School and Society, London: Falmer Press, 1992.
20. G. Aikenhead, Renegotiating the culture of school science, in R. Millar, J. Leach & J. Osborne,
lmproving Science Education: the Contribution of Research, Buckingham: Open University Press,
2000.
21. P. Ceorghiades, Conceptual change learning in primary science: a step forward!, 1999, available
via Education-line, at http://www.leeds.ac.uk/educol/ (accessed October 2001).
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22. J. R. Anderson, Learning and Memory: An Integrated Approach (2nd Edition), New York: John
Wiley & Sons, 2000.
23. J. R. Anderson, Cognitive Psychology and its Implications (4th Edition), New York: W . H. Freeman
& Company, 1995.
24. I . 0. Abimbola, The problem of terminology in the study of student conceptions in science,
Science Education, 1988, 72 (2),175-1 84.
25. D. M. Watts & A. Zylbersztajn, A survey of some children’s ideas about force, Physics Education,
1981, 16 (6), 360-365.
26. J. K. Gilbert & A. Zylbersztajn, A conceptual framework for science education: The case study of
force and movement, European Journal of Science Education, 1985, 7 (2), 107-1 20.
27. B. Bell & A. Brook, Aspects of Secondary Students’ Understanding of Plant Nutrition: Full Report,
Leeds: Children’s Learning in Science Project, Centre for Studies in Science & Mathematics
Education, University of Leeds, 1984.
28. R. Driver, A. Squires, P. Rushworth & V. Wood-Robinson, Making Sense of Secondary Science:
Research into Children’s Ideas, London: Routledge, 1994.
29. K. S. Taber, The sharing-out of nuclear attraction: or I can’t think about Physics in Chemistry,
International journal o f Science Education, 1998, 20 (8), 1001-1 01 4.
30. K. S. Taber, Ideas about ionisation energy: an instrument to diagnose common alternative
conceptions, School Science Review, 1999, 81 (295),97-1 04.
31. K. S. Taber, The sharing-out of nuclear attraction: or I can’t think about Physics in Chemistry,
International journal of Science Education, 1998, 20 (8), 1001-1 01 4.
32. V. Barker, Beyond appearances: Students’ Misconceptions about Basic Chemical Ideas: London:
Royal Society of Chemistry, 2000, available on LearnNet at
www.chemsoc.org/learnNet/miscon.htm (accessed October 2001 ).
34. H-J.Schmidt and T. Baumgartner, Senior high school students’ concepts of isotopes - a
triangulation study. In press.
35. H-J.Schmidt, Conceptual difficulties with isomerism, journal of Research in Science Teaching,
1992, 29 (9),995-1 003.
36. K. S. Taber, Building the structural concepts of chemistry: some considerations from educational
research, Chemical Education: Research and Practice in Europe, 2001, 2 (2), 123-1 58, available
at http://www.uoi.gr/conf-sem/cerapie/ (accessed October 200 1 ).
37. A. Quinn, Conflicts in perception, in J. Sanger, The Teaching, Handling Information and Learning
Project, Research Report 67, London: The British Library, 1989.
38. K. S. Taber, An alternative conceptual framework from chemistry education, International journal
of Science Education, 1998, 20 (5), 597-608.