Appendix E

S E L E C T E D T H E R M ODYNAMIC DATA AT 298.15 K

D H f° S° D G f° D H f° S° D G f°
(kJ (J mol−1 (kJ (kJ (J mol−1 (kJ
Species mol−1) K−1) mol−1) Species mol−1) K−1) mol−1)

Aluminum Bismuth
Al(s) 0 28.3 0 Bi(s) 0 56.74 0
AlCl3(s) −704.2 110.7 −628.9 BiCl3(s) −379.1 177.0 −315.0
Al2O3(s) −1676 50.92 −1582 Bi2O3(s) −573.88 151.5 −493.7
AlPO4(s) −1733.8 90.76 −1617.9 Bi2S3(s) −143.1 200.4 −140.6
Al2(SO4)3(s) −3440.84 239.3 −3099.94
Boron
Antimony B(s) 0 5.86 0
Sb(s) 0 45.69 0 BCl3(ℓ) −427.2 206.3 −387.4
Sb4O6(s) −1417.1 246.0 −1253.0 B2H6(g) 35.6 232.11 86.7
Sb2O5(s) −971.9 125.1 −829.2 BF3(g) −1137.00 254.12 −1120.33
SbCl5(ℓ) −440.2 301 −350.1 H3BO3(s) −1094.33 88.83 −968.92
SbCl3(s) −382.17 184.1 −259.4 NaBH4(s) −183.34 104.68 −119.54

Argon Bromine
Ar(g) 0 154.843 0 Br(g) 111.8 174.9 82.4
Br2(ℓ) 0 152.23 0
Arsenic
Br2(g) 30.91 245.4 3.14
As(s) 0 35.1 0
BrF3(g) −255.6 292.4 −229.5
H3As(g) 66.44 222.78 68.93
HBr(g) −36.4 198.59 −53.43
As2O5(s) −924.87 105.4 −782.3
AsCl3(ℓ) −305.0 216.3 −259.4 Cadmium
Cd(s) 0 51.76 0
Barium
CdCl2(s) −391.50 115.27 −343.93
Ba(s) 0 62.8 0
CdO(s) −258.2 54.8 −228.4
BaCl2(s) −860.1 126 −810.9
CdS(s) −161.9 64.9 −156.5
BaCO3(s) −1216.3 112.1 −1137.6
BaF2(s) −1207.1 96.36 −1156.8 Calcium
Ba(NO3)2(s) −992.07 213.8 −796.59 Ca(s) 0 41.6 0
BaO(s) −553.5 70.42 −525.1 Ca(g) 192.6 154.8 158.9
2+
BaSO4(s) −1465 132 −1353 Ca (aq) −542.8 −53.1 −553.5
CaBr2(s) 682.8 130 −663.6
Beryllium
CaC2(s) −62.8 70.3 −67.8
Be(s) 0 9.54 0
CaCO3(s) −1207 92.9 −1129
BeCl2(s) −490.4 82.68 −445.6
CaCl2(s) −795.0 114 −750.2
BeF2(s) −1026.8 53.35 −979.4
CaF2(s) −1215 68.87 −1162
BeO(s) −609.6 14.14 −580.3
CaH2(s) −189 42 −150
Be(OH)2(s) −907.1 50.2 −817.6
CaO(s) −635.5 40 −604.2
BeSO4(s) −1205.20 77.91 −1093.80

538

Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. WCN 02-200-203
Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s).
Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol−1 (kJ (kJ (J mol−1 (kJ
Species mol−1) K−1) mol−1) Species mol−1) K−1) mol−1)

CO(NH2)2(s) −334 105 −198

CaS(s) −482.4 56.5 −477.4
Ca(NO3)2(s) −938.39 193.3 −743.07 CH3CN(ℓ) 54 150 99
Ca(OH)2(s) −986.6 76.1 −896.8 C3H3N(ℓ) 172.9 188 208.6
Ca(OH)2(aq) −1002.8 76.15 −867.6 CO(g) −110.5 197.6 −137.2
Ca3(PO4)2(s) −4120.8 236.0 −3884.7 CO2(g) −393.5 213.6 −394.4
CaSO4(s) −1433 107 −1320 CO2(aq) −413.80 117.6 −385.98

Carbon COCl2(g) −223.0 289.2 −210.5

C(s, graphite) 0 5.740 0 CS2(g) 117.4 237.7 67.15
C(s, diamond) 1.897 2.38 2.900 (CH3)2SO(ℓ) −203 188 −99
C(g) 716.7 158.0 671.3 C6H12O6(s) −1274.5 212.1 −910.56
(glucose)
CCl4(ℓ) −135.4 216.4 −65.27
C12H22O11(s) −2221.7 360.24 −1544.3
CCl4(g) −103 309.7 −60.63 (sucrose)
CHCl3(ℓ) −134.5 202 −73.72
Cesium
CHCl3(g) −103.1 295.6 −70.37
Cs(s) 0 85.23 0
CH2Cl2(g) −121.46 177.8 −67.26
Cs+(aq) −248 133 −282
CH3Cl(g) −80.83 234.58 −57.37
CsF(aq) −568.6 123 −558.5
CF4(g) −925 261.61 −879
CF2Cl2(g) −477 301 −440 Chlorine
CH3CF3(ℓ) −737 280 −668 Cl2(g) 0 223.0 0
CH4 (g) −74.81 186.2 −50.75 Cl(g) 121.7 165.1 105.7
C2H2(g) 226.7 200.8 209.2 Cl−(g) −226 — —
−
C2H4(g) 52.26 219.5 68.12 Cl (aq) −167.29 56.48 −131.26
C2H6(g) −84.86 229.5 −32.9 ClO(g) 101.22
C3H6(g) 20.41 266.9 62.75 ClO2(g) 104.60 249.4 123.4
C3H8(g) −103.8 269.9 −23.49 Cl2O(g) 80 266 98
C4H10(g) (n-butane) −126.5 310.03 −15.71 ClF(g) −54.48 217.89 −55.94
C6H6(ℓ) 49.03 172.8 124.5 ClF3(g) −163.2 281.61 −123.0
C8H18(ℓ) (n-octane) −250.3 361.2 16.32 HCl(g) −92.31 186.8 −95.30
CH3OH(ℓ) −238.66 126.8 −166.27 HCl(aq) −167.4 55.10 −131.2
C2H5OH(ℓ) −277.7 161 −174.9
Chromium
C2H5OH(g) −235.1 282.6 −168.6 Cr(s) 0 23.8 0
HCOOH(aq) −425.6 92.0 −351 Cr2O3(s) −1139.7 81.2 −1058.1
HCOOH(ℓ) −424.72 128.95 −361.35 Cr2Cl3(s) −556.5 123.0 −486.1
HCHO(g) −108.57 218.77 −102.53 (NH4) 2Cr2O7(s) −1807 — —
CH3CHO(g) −166.19 250.3 −128.86
Cobalt
CH3COOH(ℓ) −484.5 159.8 −389.9
Co(s) 0 30.04 0
H2C2O4(s) −828.93 115.6 −697.2
CoO(s) −237.94 52.97 −214.20
H2C2O4(aq) −825.1 45.61 −673.9
Co3O4(s) −891 102.5 −774
HCN(g) 135.1 201.78 124.7
CoCl2(s) −312.5 109.16 −269.8
CH3NH2(g) 23.0 243.3 32.16
CoSO4(s) −888.3 118.0 −782.3

Appendix E 539

Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. WCN 02-200-203
Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s).
Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol−1 (kJ (kJ (J mol−1 (kJ
Species mol−1) K−1) mol−1) Species mol−1) K−1) mol−1)

Copper Iron
Cu(s) 0 33.15 0 Fe(s) 0 27.3 0
CuBr(s) −104.6 96.11 −100.8 FeCl2(s) −340.67 117.9 −302.3
CuCl(s) −137.2 86.2 −119.86 FeCl3(s) −399.49 142.3 −334.00
CuCl2(s) −220.1 108.07 −175.7 FeCO3(s) −741 93 −667
CuI(s) −67.8 96.7 −69.5 Fe(CO)5(ℓ) −774.0 338 −705.4
CuO(s) −157 42.63 −130 Fe(CO)5(g) −733.8 445.2 −697.3
Cu2O(s) −168.6 93.14 −146.0 FeO(s) −272 — —
CuS(s) −53.1 66.5 −53.6 Fe2O3 −824.2 87.40 −742.2
Cu2S(s) −79.5 120.9 −86.2 (s, hematite)
CuSO4(s) −771.36 109 −661.8 Fe3O4 −1118 146 −1015
(s, magnetite)
Fluorine
Fe(OH)2(s) −569.0 88 −486.5
F−(g) −322 — —
Fe(OH)3(s) −823.0 106.7 −696.5
F−(aq) −332.6 — −278.8 FeS2(s) −177.5 122.2 −166.7
F(g) 78.99 158.6 61.92 FeSO4(s) −928.4 107.5 −820.8
F2(g) 0 202.7 0
Lead
HF(g) −271 173.7 −273
Pb(s) 0 64.81 0
HF(aq) −320.08 88.7 −296.8
PbCl2(s) −359.4 136 −314.1
Germanium PbO(s, yellow) −217.3 68.70 −187.9
Ge(s) 0 3 0 PbO2(s) −277.4 68.6 −217.33
GeH4(g) 91 217 113 Pb(OH)2(s) −515.9 88 −420.9
GeCl4(g) −496 348 −457 PbS(s) −100.4 91.2 −98.7
GeO2(s) −551 55 −497 PbSO4(s) −919.94 148.57 −813.14

Gold Lithium
Au(s) 0 48 0 Li(s) 0 28.0 0

Helium LiAlH4(s) −116.3 78.74 −44.7

He(g) 0 126.150 0 LiCl(s) −408.61 59.33 −384.37
LiF(s) −615.97 35.65 −587.71
Hydrogen
LiH(s) −90.54 20.008 −68.35
H(g) 218.0 114.6 203.3
LiNO3(s) −483.13 90.0 −381.1
H2(g) 0 130.6 0
LiOH(s) −487.23 50 −443.9
H2O(ℓ) −285.8 69.91 −237.2
LiOH(aq) −508.4 4 −451.1
H2O(g) −241.8 188.7 −228.6
−187.8 109.6 −120.4 Magnesium
H2O2(ℓ)
Mg(s) 0 32.5 0
Iodine Mg (aq)2+ −454.668 −138.1 −455.57
I(g) 106.6 180.66 70.16
MgBr2(s) −524.3 117.2 −503.8
I2(s) 0 116.1 0
MgCl2(s) −641.8 89.5 −592.3
I2(g) 62.44 260.6 19.36
MgCO3(s) −1095.8 65.7 −1012.1
ICl(g) 17.78 247.4 −5.52 MgF2(s) −1123.4 57.24 −1070.2
HI(g) 26.5 206.5 1.72 MgI2(s) −364.0 129.7 −358.2

540 Appendix E

Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. WCN 02-200-203
Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s).
Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol−1 (kJ (kJ (J mol−1 (kJ
Species mol−1) K−1) mol−1) Species mol−1) K−1) mol−1)

Mg3N2(s) −461.1 87.86 −401.1 NH4Cl(s) −314.4 94.6 −201.5

Mg(NO3)2(s) −790.65 164.0 −589.4 NH4Cl(aq) −300.2 — —
MgO(s) −601.8 27 −569.6 NH4HCO3(s) −847 12.1 −666
Mg(OH)2(s) −924.7 63.14 −833.7 NH4I(s) −201.4 117 −113
Mg3(PO4)2(s) −3780.7 189.20 −3538.7 NH4NO3(s) −365.6 151.1 −184.0
MgS(s) −347 — — (NH4)2SO4(s) −1180.85 220.1 −901.67
MgSO4(s) −1284.9 91.6 −1170.6 NF3(g) −125 260.6 −83.3
NO(g) 90.25 210.7 86.57
Manganese
NO2(g) 33.2 240.0 51.30
Mn(s) 0 32.01 0
N2O(g) 82.05 219.7 104.2
MnCl2(s) −481.29 118.24 −440.50
N2O3(g) 83.72 321.28 139.46
MnO(s) −385.22 59.71 −362.90
N2O4(g) 9.16 304.2 97.82
MnO2(s) −520.03 53.05 −465.14
N2O5(g) 11 356 115
Mn2O3(s) −959.0 110.5 −881.1
N2O5(s) −43.1 178 114
Mn3O4(s) −1387.8 155.6 −1283.2
NOCl(g) 52.59 264 66.36
MnSO4(s) −1065.25 112.1 −957.36
HNO3(ℓ) −174.1 155.6 −80.79
Mercury HNO3(g) −135.1 266.2 −74.77
Hg(ℓ) 0 76.02 0
HNO3 (aq) −206.6 146 −110.5
Hg(g) 61.32 174.96 31.82
HgCl2(s) −224.3 146 −178.6 Oxygen
O2(g) 0 205.0 0
Hg2Cl2(s) −224 146 −179
O(g) 249.2 161.0 231.8
HgO(s, red) −90.83 70.29 −58.56
O3(g) 143 238.8 163
HgS(s, red) −8.2 82.4 −50.6
OF2(g) 23 246.6 41
Neon
Ne(g) 0 146.328 0 Phosphorus
P(g) 314.6 163.1 278.3
Nickel P4(s, white) 0 177 0
Ni(s) 0 30.1 0
P(s, red) −18.4 22.8 −12.1
NiCl2(s) −82.0 52.97 −79.5
P4(g) 58.91 279.98 24.44
Ni(CO)4(g) −602.9 410.4 −587.3
PCl3(g) −306.4 311.7 −286.3
NiO(s) −244 38.6 −216
PCl5(g) −398.9 353 −324.6
NiS(g) −82.0 52.97 −79.5
PF3(g) −918.8 273.24 −897.5
NiSO4(s) −872.91 92 −759.7
PH3(g) 5.4 210.1 13
Nitrogen P4O10(s) −2984 228.9 −2698
N2(g) 0 191.5 0 H3PO4(s) −1281 110.5 −1119
N(g) 472.704 153.19 455.579 H3PO4(aq) −1288.34 158.2 −1142.54
NH3(g) −46.11 192.3 −16.5
Potassium
NH3(aq) −80.29 111.3 −26.50
K(s) 0 63.6 0
NH4+(aq) −132.51 113.4 −79.31
KBr(s) −393.798 95.90 −380.66
N2H4(ℓ) 50.63 121.2 149.2
KCl(s) −436.5 82.6 −408.8
(NH4)3AsO4(aq) −1268 — —
KClO3(s) −391.2 143.1 −289.9
NH4Br(s) −270.83 113 −175.2
KClO4(s) −432.747 82.59 −409.14

Appendix E 541

Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. WCN 02-200-203
Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s).
Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol−1 (kJ (kJ (J mol−1 (kJ
Species mol−1) K−1) mol−1) Species mol−1) K−1) mol−1)

K2CO3(s) −1151.02 155.52 −1063.5 AgS(s) −32.59 144.01 −40.67

K2Cr2O4(s) −1403.7 200.12 −1295.7 AgSCN(s) 87.9 131.0 101.36
K2Cr2O7(s) −2061.5 291.2 −1881.8 Ag2SO4(s) −715.88 200.4 −618.41
KF(s) −567.27 66.57 −537.75
Sodium
KI(s) −327.9 106.4 −323.0
Na(s) 0 51.0 0
KMnO4(s) −837.2 171.71 −737.6
Na(g) 108.7 153.6 78.11
KNO3(s) −494.63 133.05 −394.86
Na+(g) 601 — —
KO2(s) 284.93 116.7 −239.4 +
Na (aq) −240.2 59.0 −261.9
K2O2(s) −494.1 102.1 −425.1
NaBr(s) −359.9 86.82 −348.98
KOH(s) −424.7 78.91 −378.9
NaCl(s) −411.0 72.38 −384
KOH(aq) −481.2 92.0 −439.6
NaCl(aq) −407.1 115.5 −393.0
K2SO4(s) −1437.79 175.56 −1321.37
NaClO4(s) −383.30 142.3 −254.85
Rubidium NaCN(s) −87.49 118.49 −76.4
Rb(s) 0 76.78 0 NaCH3COO(s) −708.80 123.0 −607.18
RbOH(aq) −481.16 110.75 −441.24 Na2CO3(s) −1131 136 −1048
NaF(s) −573.647 51.46 −543.494
Selenium
Se(s) 0 42.442 0 NaH(s) −56.275 40.016 −33.46

H2Se(g) −9.7 219.02 15.9 NaHCO3(s) −950.81 101.7 −851.0

NaHSO4(s) −1125.5 113.0 −992.8
Silicon
NaH2PO4(s) −1538 128 −1387
Si(s) 0 18.8 0
Na2HPO4(s) −1749 151 −1609
SiBr4(ℓ) −457.3 277.8 −443.9
NaI(s) −287.78 98.53 −286.06
SiC(s) −65.3 16.6 −62.8
NaNO3(s) −467.85 116.52 −367.00
SiCl4(g) −657.0 330.6 −617.0
Na2O(s) −414.22 75.06 −375.46
SiCl4(ℓ) −687.0 239.7 −619.84
Na2O2(s) −510.87 95.0 −447.7
SiH4(g) 34.3 204.5 56.9
NaOH(s) −426.7 64.45 −379.49
SiF4(g) −1615 282.4 −1573
NaOH(aq) −469.6 49.8 −419.2
SiI4(g) −132 — —
Na3PO4(s) −1917.40 173.80 −1788.80
SiO2(s) −910.9 41.84 −856.7
Na2S(s) −364.8 83.7 −349.8
H2SiO3(s) −1189 134 −1092
Na2SO4(s) −1387.08 149.58 −1270.16
H4SiO4(s) −1481.1 192 −1332.9
Na2S2O3(s) −1123.0 155 −1028.0
Na2SiO3(s) −1079 — —
H2SiF6(aq) −2331 — — Strontium
Sr(s) 0 52.3 0
Silver
SrCl2(s) −828.9 114.85 −781.1
Ag(s) 0 42.55 0
SrCO3(s) −1220.1 97.1 −1140.1
Ag+(aq) 105.79 73.86 77.12
SrO(s) −592.0 54.4 −561.9
AgBr(s) −100.37 107.1 −96.90
AgCl(s) −126.904 96.085 −109.8 Sulfur
AgI(s) −61.84 115.5 −66.19 S(s, rhombic) 0 31.8 0

AgNO3(s) −124.39 140.92 −33.41 S(g) 278.8 167.8 −38.3

Ag2O(s) −31.05 121.3 −11.20 S8(g) 102.30 430.98 49.63

542 Appendix E

Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. WCN 02-200-203
Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s).
Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol−1 (kJ (kJ (J mol−1 (kJ
Species mol−1) K−1) mol−1) Species mol−1) K−1) mol−1)

S2Cl2(g) −18 331 −31.8 Tungsten

SF6(g) −1209 291.7 −1105 W(s) 0 32.6 0
H2S(g) −20.6 205.7 −33.6 WO3(s) −842.9 75.90 −764.1
H2SO4(ℓ) −814.0 156.9 −690.1
Uranium
H2SO4(aq) −907.5 17 −742.0
U(s) 0 50.21 0
SO2(g) −296.8 248.1 −300.2
UF6(s) −2147.4 377.9 −2063.7
SO3(g) −395.6 256.6 −371.1
UO2(s) −1084.9 77.03 −1031.7
SOCl2(ℓ) −206 — —
UO3(s) −1223.8 96.11 −1145.9
SO2Cl2(ℓ) −389 — —
Xenon
Tellurium Xe(g) 0 169.683 0
Te(s) 0 49.71 0
XeF2(g) −130 260 −96
TeO2(s) −322.6 79.5 −270.3
XeF4(g) −215 316 −138
Tin XeO3(g) 502 287 561
Sn(s, white) 0 51.55 0
Zinc
Sn(s, gray) −2.09 44.1 0.13
Zn(s) 0 41.63 0
SnCl2(s) −350 — —
ZnCl2(s) −415.05 111.46 −369.398
SnCl4(ℓ) −511.3 258.6 −440.2
ZnCO3(s) −812.78 82.4 −731.52
SnCl4(g) −471.5 366 −432.2
ZnO(s) −348.3 43.64 −318.3
SnO(s) −285.8 56.5 −256.9
Zn(OH)2(s) −643.25 81.6 −555.07
SnO2(s) −580.7 52.3 −519.7
ZnS(s) −205.6 57.7 −201.3
Titanium ZnSO4(s) −982.8 110.5 −871.5
Ti(s) 0 30.6 0
TiCl4(ℓ) −804.2 252.3 −737.2
TiCl4(g) −763.2 354.8 −726.8

Appendix E 543

Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. WCN 02-200-203
Copyright 2019 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s).
Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.