Molar Enthalpy Worksheet

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Molar Enthalpy Worksheet

A change in enthalpy (ΔH) is a measurement of energy transfer in the form of heat. Molar enthalpy is the
enthalpy change per mole of a substance involved in a transformation. Examples of transformations are phase
changes, dissolving and chemical reactions.
The units are generally expressed as kJ/mole. Thus, the molar enthalpy of fusion for water is the energy in
kilojoules required to melt one mole of ice at its melting point. Positive molar enthalpies (+ΔH) indicate that
energy is being gained by the substance, whereas negative molar enthalpies (-ΔH) indicate that energy is lost.
Complete the problems below on a separate piece of paper. Show all work, and express answers with significant
figures and proper labels (units and substance).
1. Calculate the molar enthalpy of solidification (ΔHsolidification) when 10.00kJ of energy are lost as 30.00g of
water are frozen at 0ºC. Remember that this value will be negative, because energy is lost when water
freezes. (Hint: start by finding out how many moles of water that are freezing)
2. Compare your answer in question #1 to the value given for ΔHfusion in problem 19b on p.353 of your
textbook. What do you notice? Explain the coincidence, thinking about the difference between
solidification and fusion.
3. Calculate the molar enthalpy of condensation (ΔHcondensation) for ammonia when 50.0g of NH3 gas turn into a
liquid at its boiling point. 68,500J of energy are released in the process.
4. Calculate the energy absorbed when 2.0x103g of dry ice (CO2) sublimate at the normal sublimation point.
The molar enthalpy of sublimation is 8.647kJ/mol.
5. Methane (CH4) has a normal boiling point of -161.6 ºC. At this temperature, the ΔHcondensation = -8.17kJ/mol.
If 16.5g of liquid methane vaporize, how much energy is absorbed?
6. How much energy is required to melt a 20.0 lb bag of ice at 0ºC? A pound (lb.) of ice is equivalent to
0.4536 kg. The ΔHfusion of ice is +6.009kJ/mol.
7. When water vaporizes at its normal boiling point, its ΔHvaporization = +40.79kJ/mol. Calculate the number of
moles of water that condense if 3456kJ of energy are released.
8. What mass of aluminum metal would absorb 250.0 kJ when it melted at its melting point? The molar
enthalpy of fusion for aluminum is +10.71kJ/mol.
Molar Enthalpy Worksheet
A change in enthalpy (ΔH) is a measurement of energy transfer in the form of heat. Molar enthalpy is the
enthalpy change per mole of a substance involved in a transformation. Examples of transformations are phase
changes, dissolving and chemical reactions.
The units are generally expressed as kJ/mole. Thus, the molar enthalpy of fusion for water is the energy in
kilojoules required to melt one mole of ice at its melting point. Positive molar enthalpies (+ΔH) indicate that
energy is being gained by the substance, whereas negative molar enthalpies (-ΔH) indicate that energy is lost.
Complete the problems below on a separate piece of paper. Show all work, and express answers with significant
figures and proper labels (units and substance).
1. Calculate the molar enthalpy of solidification (ΔHsolidification) when 10.00kJ of energy are lost as 30.00g of
water are frozen at 0ºC. Remember that this value will be negative, because energy is lost when water
freezes. (Hint: start by finding out how many moles of water that are freezing)
2. Compare your answer in question #1 to the value given for ΔHfusion in problem 19b on p.353 of your
textbook. What do you notice? Explain the coincidence, thinking about the difference between
solidification and fusion.
3. Calculate the molar enthalpy of condensation (ΔHcondensation) for ammonia when 50.0g of NH3 gas turn into a
liquid at its boiling point. 68,500J of energy are released in the process.
4. Calculate the energy absorbed when 2.0x103g of dry ice (CO2) sublimate at the normal sublimation point.
The molar enthalpy of sublimation is 8.647kJ/mol.
5. Methane (CH4) has a normal boiling point of -161.6 ºC. At this temperature, the ΔHcondensation = -8.17kJ/mol.
If 16.5g of liquid methane vaporize, how much energy is absorbed?
6. How much energy is required to melt a 20.0 lb bag of ice at 0ºC? A pound (lb.) of ice is equivalent to
0.4536 kg. The ΔHfusion of ice is +6.009kJ/mol.
7. When water vaporizes at its normal boiling point, its ΔHvaporization = +40.79kJ/mol. Calculate the number of
moles of water that condense if 3456kJ of energy are released.
8. What mass of aluminum metal would absorb 250.0 kJ when it melted at its melting point? The molar
enthalpy of fusion for aluminum is +10.71kJ/mol.

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