This document provides a material safety data sheet for Repsol Aries 46 lubricant oil. Some key details include:
- It is a lighter than water, combustible lubricating oil intended for use as a turbine and compressor oil.
- Health effects include mild skin and respiratory irritation from exposure to mists and vapors. Ingestion may cause gastrointestinal irritation.
- It should be stored in a cool, well-ventilated area away from strong oxidants and sources of ignition.
- Personal protective equipment like gloves and safety goggles should be used when handling the product.
This document provides a material safety data sheet for Repsol Aries 46 lubricant oil. Some key details include:
- It is a lighter than water, combustible lubricating oil intended for use as a turbine and compressor oil.
- Health effects include mild skin and respiratory irritation from exposure to mists and vapors. Ingestion may cause gastrointestinal irritation.
- It should be stored in a cool, well-ventilated area away from strong oxidants and sources of ignition.
- Personal protective equipment like gloves and safety goggles should be used when handling the product.
This document provides a material safety data sheet for Repsol Aries 46 lubricant oil. Some key details include:
- It is a lighter than water, combustible lubricating oil intended for use as a turbine and compressor oil.
- Health effects include mild skin and respiratory irritation from exposure to mists and vapors. Ingestion may cause gastrointestinal irritation.
- It should be stored in a cool, well-ventilated area away from strong oxidants and sources of ignition.
- Personal protective equipment like gloves and safety goggles should be used when handling the product.
This document provides a material safety data sheet for Repsol Aries 46 lubricant oil. Some key details include:
- It is a lighter than water, combustible lubricating oil intended for use as a turbine and compressor oil.
- Health effects include mild skin and respiratory irritation from exposure to mists and vapors. Ingestion may cause gastrointestinal irritation.
- It should be stored in a cool, well-ventilated area away from strong oxidants and sources of ignition.
- Personal protective equipment like gloves and safety goggles should be used when handling the product.
2. HAZARDS IDENTIFICATION PHYSICAL / CHEMICAL TOXICITY (SYMPTOMS)
Lighter than water. It can obstruct sewers Inhalation: Short-term exposures to vapours and oil mists cause irritation of the respiratory tract. Long- and water intakes. term exposures can cause lung fibrosis preceded by broncho-pulmonary symptoms in concentrations over 5 mg/m3. Combustible. Ingestion/Aspiration: Intestinal absorption is very low. Accidental intake of large amounts causes irritation of the gastrointestinal tract, nausea, vomiting and diarrhoea.
Contact skin/eyes: Low skin percutaneous toxicity in short-term exposures. Long-term exposures produce smarting, redness, irritation and dermatitis due to defatting of the keratyn layer. No skin sensitization has been registered in animal tests or human cases. Repeated exposure to vapours or liquid cause irritation.
General toxic effects: Mild skin irritation and respiratory tract irritation are the most common effects.
3. COMPOSITION General composition: Additivated lubricant oil. Complex combination of saturated hydrocarbons having carbon numbers in the range of C15 -C50. Base oil contains less than 2% PCA’s (DMSO extract according to IP346). Contains anticorrosion, antioxidant and antifoaming additives.
Dangerous components Range % Classification S Phrases
NP
REPSOL ARIES 46
Rev.:1.1 Date:April 25th 2011 Doc:33/0763/5G.09 1 de 5
4. FIRST-AID MEASURES Inhalation: In case of inhalation remove the victim to fresh air. Administer oxygen if necessary. Call for medical attention.
Ingestion/Aspiration: Do not induce vomiting. If conscious have the victim drink water.
Contact skin/eyes: Flush with plenty of water and soap. Flush with plenty of water during at least 15 minutes. Call for medical aid.
Non suitable extinguishing agents: Water applied directly may be ineffective due to dispersion of the material.
Combustion products: CO2, H2O, CO (in defect of air), SO2, and NOx.
Special measures: Not required.
Special hazards: NP
Protective equipment: Heat-resistant suit and gloves. Self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Hazard of physical fouling to coasts, Personal precautions: Avoid prolonged contact with contaminated clothes soils, etc, due to low solubility and high viscosity of the oils. Avoid or with the product and inhalation of vapours and mists. the material entering water intakes.
Cleanup methods: Treat as an accidental oil spill or leak; Avoid Personal protection: Suitable protective clothing, gloves and goggles dispersion of the material with mechanical barriers. Remove with should be worn during the clean up operation. physical or chemical treatment.
7. HANDLING AND STORAGE
Handling:
General precautions: Avoid prolonged contact and inhalation of mists and vapours from heated oils. During transfer avoid contact with air, use pumps and connections properly earthed to prevent generation of electrostatic charges. The contaminated air should be filtered before discharge.
Specific conditions: Safety goggles and gloves should be used. Do not weld or carry out any activity that could generate sparks in areas close to product storage. Do not weld in empty tanks without previous purging.
Storage:
Temperature and decomposition products: Carbon monoxide (toxic gas) and asphyxiants could be emitted at high temperatures by incomplete combustion.
Dangerous reactions: NP
Storage conditions: Containers properly labelled and sealed, placed in cool and well ventilated areas. Do not smoke, weld or do any work that can produce flames or sparks in storage area.
Incompatible materials: Strong oxidants.
REPSOL ARIES 46
Rev.:1.1 Date:April 25th 2011 Doc:33/0763/5G.09 2 de 5
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protection: Eye protection: Safety goggles to avoid splashes.
Respiratory protection: The product is slightly volatile at room
temperature and does not present special risks. In presence of heated oils, wear protective masks to avoid vapour inhalation.
Skin protection: Gloves (polyethylene, polyvinyl chloride and Other protective equipment:Showers and eye-washers in the working area. neoprene; do not use neither natural nor butyl rubber)
General precautions: Avoid prolonged contact and inhalation of mists and vapours from heated oils. Local exhaust ventilation should be installed to capture and remove emissions near to the point of generation.
Specific hygiene measures: Contaminated footwear should be discarded. Contaminated clothing should not be taken home for laundering. Regular changing of underwear is also important if penetration of outer clothing occurs. Disposable wipes should be used. Washing/Showering facilities with a non-solvent based skin cleaner, hot water and soap must be provided and used. Use skin reconditioning cream after work.
Water solubility: Insoluble. Solubility: Organic solvents.
Other data: Fire point: 220 oC min. (ASTM D-92)
10. STABILITY AND REACTIVITY
Stability: Stable at room temperature. Conditions to avoid: Exposure to open flames.
Materials to avoid: Strong oxidants react with oils and organic materials.
Hazardous decomposition/combustion products: Carbon monoxide (toxic gas) and asphyxiants could be emitted at high temperatures by incomplete combustion.
Polymerization risk: NP Conditions to avoid: NP
REPSOL ARIES 46
Rev.:1.1 Date:April 25th 2011 Doc:33/0763/5G.09 3 de 5
11. TOXICOLOGICAL INFORMATION Routes of exposure: Contact with skin, eyes and inhalation. Ingestion is not frequent.
Acute and chronic effects: No malignant acute effects are known. Irritation by contact with liquid and prolonged inhalation of vapours or oil mists are the most common effects. LD50>15 g/Kg (oral-rat) LD50>5 g/Kg (skin-rat)
Carcinogenicity: Base oil: IARC classification: Group 3 (The agent is not classifiable as to its carcinogenicity to humans)
Reproductive toxicity: No evidences.
Medical conditions which increase hazard to exposure: Respiratory tract deficiencies and dermatological problems.
12. ECOLOGICAL INFORMATION
Pollutant potential:
Persistence and degradability:The material is oily and viscous and floats on water. It presents a high physical fouling potential, mainly in sea- spills; by contact destroys small aquatic organisms and makes living difficult for upper organisms, not allowing the sunlight to reach underlying marine ecosystems, affecting its normal development. It is not readily biodegradable.
Mobility/bioaccumulative potential:There are no data to indicate that the product is significantly bioaccumulated by aquatic organisms or incidence in the trophic food chain, although it may cause long-term adverse effects in the aquatic environment, due to its high physical fouling potential.
Ecotoxicological effects: LL50 (Lethal loading)>1,000 mg/l (lubricant base oils). Dangerous for aquatic life in high concentrations (spillages).
13. DISPOSAL CONSIDERATIONS
Disposal methods (surplus): Recycling and recovery of base oils when possible.
Waste: Liquids and solids from industrial process; do not attempt to clean containers since residue is difficult to remove; dispose in a safe way.
Disposal: Only in specific prepared and controlled areas. Avoid releasing waste oils to sewers because they can destroy water treatment plant microorganisms.
Handling: Labelled and sealed containers. Avoid direct contact with waste oils.
Provisions: Companies which recover, dispose, store, transport or handle waste should comply with Dir. 2008/98/EC on waste, or other local, national or community provisions.
REPSOL ARIES 46
Rev.:1.1 Date:April 25th 2011 Doc:33/0763/5G.09 4 de 5
14. TRANSPORT INFORMATION Special precautions: Stable at room temperature and during transport. Store in cool well ventilated areas.
Additional information: UN Number: NP ADR/RID: Not classified
Hazard identification number: NP IATA-DGR: Not classified
Proper shipping name: NP IMDG: Not classified
15. REGULATORY INFORMATION
CLASSIFICATION LABELLING NP Symbols: NP
Phrases R NP
Phrases S NP
Other regulations: NP
16. OTHER INFORMATION
Data Bases consulted R phrases/Hazard Class-and-Category shown in the document: NP EINECS: European Inventory of Existing Commercial Substances. TSCA: Toxic Substances Control Act, US Environmental Protection Agency HSDB: US National Library of Medicine. RTECS: US Dept. of Health & Human Services
Legislation consulted Globally Harmonized System of Classification and Labelling of Chemicals (GHS). Regulation (EC) no 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (CLP). Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). Dir. 67/548/EEC about classification, labelling and packaging of dangerous substances (including amendments and adaptations in force). Dir. 1999/45/EC about classification, labelling and packaging of dangerous preparations (including amendments and adaptations in force). Dir. 91/689/EEC dangerous waste; Dir. 2008/98/EG waste management. Royal Decree 363/95: Regulation about notification of new substances and classification, packaging and labelling of dangerous substances. Royal Decree 255/2003: Regulation about classification, packaging and labelling of dangerous preparations. European Agreement concerning the international carriage of dangerous goods by road (ADR). Regulation on the international transport of dangerous goods on the railway. (RID) International maritime code of dangerous goods. (IMDG) International Air Transport Association (IATA) regulation pertaining to air shipment.
Glossary VLA-ED: Valor Límite Ambiental – Exposición Diaria
CAS: Chemical Abstract Service VLA-EC: Valor Límite Ambiental – Exposición Corta IARC: International Agency for Research on Cancer LD50: Lethal Dose Medium ACGIH: American Conference of Governmental Industrial Hygienists. LC50: Lethal Concentration Medium TLV: Threshold Limit Value EC50: Effective Concentration Medium TWA: Time Weighted Average STEL: Short-term Exposure Level IC50: Inhibitory Concentration Medium REL: Recommendable Exposure Limit BOD: Biological Oxygen Demand. PEL: Permissible Exposure Limit NP: Not Pertinent INSHT: Instituto Nal. de Seguridad e Higiene en el Trabajo | : Changes from the last revision
The information given in this document has been compiled based on the best existing information sources, latest available knowledge and according to the current requirements on classification, packaging and labelling of hazardous substances. It does not imply the information is exhaustive or accurate in all cases. It is the user’s responsibility to determine the validity of the information contained in this Material Safety Data Sheet to apply depending on the case. REPSOL ARIES 46
Rev.:1.1 Date:April 25th 2011 Doc:33/0763/5G.09 5 de 5
