ALLEN

PHYSICS
SECTION-1 : (Maximum Marks: 80) 3. Ice at –20°C is added to 50 g of water at 40°C.
This section contains 20 questions. Each question When the temperature of the mixture reaches
has 4 options for correct answer. Multiple-Choice 0°C, it is found that 20 g of ice is still
Questions (MCQs) Only one option is correct. For unmelted. The amount of ice added to the water
each question, marks will be awarded as follows: was close to
Full Marks : +4 If correct answer is selected.
Zero Marks : 0 If none of the option is (Take, specific heat of water = 4.2 J/g/°C
selected. specific heat of ice = 2.1 J/g/°C and heat of
Negative Marks : –1 If wrong option is selected. fusion of water at 0°C = 334 J/g)
1. 1 mol of a gas with γ 7 is mixed with 1 mol
=
(A) 40 g
5
5 (B) 50 g
of a gas with γ = then the value of
, γ for
3 (C) 60 g
the resulting mixture is
7
(D) 100 g
(A)
5 4. At what temperature is the rms velocity of a
(B) 2 hydrogen molecule equal to that of an oxygen
5 molecule at 47°C ?
(C) 24
16
(A) 80 K
(D) 12 (B) –73 K
7
(C) 3 K
2. When a system is taken from state i to state f
along the path iaf, it is found that Q = 50 cal. (D) 20 K
and W = 20 cal. Along the path ibf Q = 36 cal. 5. A copper ball of mass 100 g is at a temperature
W along the path ibf is T. It is dropped in a copper calorimeter of mass
100 g, filled with 170 g of water at room
temperature. Subsequently, the temperature of
the system is found to be 75°C. T is (Given,
room temperature = 30°C, specific heat of
copper = 0.1 cal/g°C)
(A) 885°C (B) 1250°C
(A) 6 cal. (B) 16 cal.
(C) 825°C (D) 800°C
(C) 66 cal. (D) 14 cal.

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6. One mole of diatomic ideal gas undergoes a 8. Helium gas goes through a cycle ABCDA
cyclic process ABC as shown in figure. The (consisting of two isochoric and isobaric lines)
process BC is adiabatic. The temperatures at A, as shown in figure. Efficiency of this cycle is
B and C are 400 K, 800 K and 600 K, nearly (Assume the gas to be close to ideal gas)
respectively. Choose the correct statement.

(A) 15.4% (B) 9.1%

(A) The change in internal energy in whole
cyclic process is 250 R (C) 10.5% (D) 12.5%
(B) The change in internal energy in the 9. A container with insulating walls is divided
process CA is 700 R into two equal parts by a partition fitted with a
(C) The change in internal energy in the valve. One part is filled with an ideal gas at a
process AB is –350 R pressure p and temperature T, whereas the
other part is completely evacuated. If the valve
(D) The change in internal energy in the
is suddenly opened, the pressure and
process BC is –500 R
temperature of the gas will be
7. The given p-V diagram represents the
(A) p (B) p T
thermodynamic cycle of an engine, operating with ,T ,
2 2 2
an ideal monatomic gas. The amount of heat,
extracted from the source in a single cycle is (D) T
(C) p, T p,
2
10. A thermally insulated vessel contains an ideal
gas of molecular mass M and ratio of specific
heats γ . It is moving with speed v and its
suddenly brought to rest. Assuming no heat is
lost to the surroundings, its temperature
increases by
(B) 13 (A) γ − 1)
( (B) γMv2
(A) p0 V0 ( ) p 0 V0 M v2 K K
2 2γR 2R
(C) 11 (C) γ − 1) (D) (γ − 1)
( ) p 0 V0 (D) 4p0 V0 (
M v2 K M v2 K
2 2R 2 (γ + 1) R
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11. 100 g of water is heated from 30°C to 50°C. 14. The temperature-entropy diagram of a
Ignoring the slight expansion of the water, the reversible engine cycle is given in the figure.
change in its internal energy is (specific heat of Its efficiency is
water is 4184 J/kg/K)
(A) 8.4 kJ (B) 84 kJ
(C) 2.1 kJ (D) 4.2 kJ
12. Two rigid boxes 1/2 containing different ideal
gases are placed on a table. Box A contains one
mole of nitrogen at temperature T0, while box (A) 1 (B) 1 (C) 1 (D) 2
B contains one mole of helium at temperature 2 4 3 3
(7/3)T0.The boxes are then put into thermal 15. A Carnot engine takes 3 × 106 cal. of heat from
contact with each other and heat flows between a reservoir at 627°C and gives it to a sink at
them until the gases reach a common final 27°C. The work done by the engine is
temperature (ignore the heat capacity of boxes). (A) 4.2 × 106 J (B) 8.4 × 106 J
Then, the final temperature of the gases, Tf, in (C) 16.8 × 106 J (D) zero
terms of T0 is
16. If 1022 gas molecules each of mass 10–26 kg
(A) 3 (B) 7 collide with a surface (perpendicular to it)
Tf = T0 Tf = T0
7 3 elastically per second over an area 1 m2 with a
(C) Tf =
3
T0
(D) Tf =
5
T0
speed 104 m/s, the pressure exerted by the gas
2 2 molecules will be of the order of
13. An ideal gas is enclosed in a cylinder at (A) 104 N/m2 (B) 108 N/m2
pressure of 2 atm and temperature, 300 K. The
mean time between two successive collisions is (C) 103 N/m2 (D) None of these
6 × 10–8 s. If the pressure is doubled and 17. The specific heats, Cp and CV of a gas of
temperature is increased to 500 K, the mean diatomic molecules, A are given (in units of J
time between two successive collisions will be mol–1 K–1) by 29 and 22, respectively. Another
gas of diatomic molecules B, has the
close to corresponding values 30 and 21. If they are
(A) 4 × 10 8 s
−
treated as ideal gases, then
(B) 3 × 10 6 s
−
(A) A has a vibrational mode but B has none
(B) Both A and B have a vibrational mode each
(C) 2 × 10 7 s
−

(C) A has one vibrational mode and B has two

(D) 0.5 × 10 8 s −

(D) A is rigid but B has a vibrational mode

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18. n moles of an ideal gas with constant volume SECTION-2 : (Maximum Marks: 20)
heat capacity CV undergo an isobaric expansion This section contains 05 Questions, all questions are
by certain volume. The ratio of the work done mandatory The answer to each question is a
in the process, to the heat supplied is Numerical Value Type questions.
(A) 4nR For each question, enter the correct numerical value
C V + nR (in decimal notation, truncated/rounded off to the
(B) 4nR second decimal place; e.g. 6.25, 7.00, –0.33, –.30,
C V − nR 30.27, –127.30, if answer is 11.36777..... then both
(C) nR
11.36 and 11.37 will be correct)
C V − nR
Answer to each question will be evaluated according
(D) nR to the following marking scheme:
C V + nR Full Marks : +4 If ONLY the correct numerical
19. 2 kg of a monoatomic gas is at a pressure of 4 × value is entered as answer.
104 N/m2. The density of the gas is 8 kg/m3. Zero Marks : 0 In all other cases.
What is the order of energy of the gas due to its 1. An open glass tube is immersed in mercury in
thermal motion ? such a way that a length of 8 cm extends above
(A) 106 J (B) 103 J the mercury level. The open end of the tube is
then closed and sealed and the tube is raised
(C) 104 J (D) 105 J vertically up by additional 46 cm. What will be
20. In a process, temperature and volume of one length of the air column (in cm) above mercury
mole of an ideal monoatomic gas are varied in the tube now? (Atmospheric pressure = 76
according to the relation VT = k, where k is a cm of Hg)
constant. In this process, the temperature of the 2. A Carnot engine, having an efficiency of
gas is increased by ΔT . The amount of heat 1
η = as heat engine is used as a refrigerator.
absorbed by gas is (where, R is gas constant) 10
If the work done on the system is 10 J, the
(A) 1
kRΔT amount of energy absorbed (in joule) from the
2
2k
reservoir at lower temperature is -
(B) ΔT
3 3. A thermometer graduated according to a linear
(C) 1 scale reads a value x0, when in contact with
RΔT
2 boiling water and x0/3, when in contact with
(D) 3 ice. What is the temperature of an object in °C,
RΔT
2 if this thermometer in the contact with the
object reads x0/2 ?
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4. Two Carnot engines A and B are operated in
series. The first one, A receives heat at T1(=
600 K) and rejects to a reservoir at temperature
T2. The second engine B receives heat rejected
by the first engine and in turn rejects to a heat
reservoir at T3(= 400 K). Calculate the
temperature T2 (in Kelvin) if the work outputs
of the two engines are equal.
5. A sample of an ideal gas is taken through the
cyclic process abca as shown in the figure. The
change in the internal energy of the gas along
the path ca is –180 J. The gas absorbs 250 J of
heat along the path ab and 60 J along the path
bc. The work done by the gas (in joule) along
the path abc is

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 ALLEN
CHEMISTRY
SECTION-1 : (Maximum Marks: 80) 3. In IUPAC system CH3 – CN is named as :
This section contains 20 questions. Each question (A) Acetonitrile
has 4 options for correct answer. Multiple-Choice
Questions (MCQs) Only one option is correct. For (B) Cyanomethane
each question, marks will be awarded as follows: (C) Methyl cyanide
Full Marks : +4 If correct answer is selected.
Zero Marks : 0 If none of the option is (D) Ethanenitrile
selected. 4. The relation between given compound is :-
Negative Marks : –1 If wrong option is selected.
1. Number of 1°, 2°, 3° and 4° C present in
compound are respectively

(A) Chain isomerism

(B) Position isomerism
(A) 7, 4, 5 and 1 (B) 7, 3, 4 and 1 (C) Functional isomerism
(C) 7, 3, 5 and 1 (D) 7, 4, 4 and 1 (D) Metamerism
2. Which of the following are not position isomers ? 5. The correct decreasing order of priority for the
functional groups of organic compounds in the
(A) CH3 – CH2 – CH = CH2 and
IUPAC system of nomenclature is :
CH3 – CH = CH – CH3
(A) – CONH2,– CHO,– SO3H,– COOH
(B) CH3 – CH2 – CH2 – OH and
(B) – COOH,– SO3H,– CONH2,– CHO
(C) – SO3H,– COOH,– CONH2,– CHO
and (D) – CHO,– COOH,– SO3H,– CONH2
(C)
6. Which of the following pairs of hydrocarbon
are functional groups isomers :-
(A) Propyne, Propene
(D)
and (B) Propyne, Allene
(C) Isoprene, Isobutylene
(D) Butadiene, Butene
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 ALLEN
7. C4H6O2 does not represent :- 11. The correct IUPAC name of the compound is :
(A) A diketone
(B) A compound with two aldehyde groups
(C) An alkenoic acid
(D) An alkanoic acid (A) 1, 2, 3-Triaminobutane-1, 3-dione
8. The IUPAC name of out of the (B) 2, 4-Diamino-3-oxobutanamide
following I, II and III is : (C) 1, 3-Dioxobutane-1, 2, 4-triamine
(I) N, N, 2-Trimethylpropan-1-amine
(D) 1, 3, 4-Triaminobutane-2, 4-dione
(II) 2-Methyl-N, N-dimethylpropan-1-amine
(III) 2, N, N-Trimethylpropane-1-amine 12. IUPAC name of the following molecule is
(A) I (B) III
(C) Both (I) and (II) (D) Both (II) and (III)
9.
The correct IUPAC name of is :
(A) 2-Bromobenzene-1,4-dioic acid
(A) 1, 4-Diethyl-2-methyl-5-propylcyclohexane (B) 3-Bromobenzene-1,4-dicarboxylic acid
(B) 1, 4-Diethyl-5-methyl-2-propylcyclohexane (C) 2-Bromobenzene-1,4-dicarboxylic acid
(C) 2, 5-Diethyl-1-methyl-4-propylcyclohexane (D) 3-Bromobenzene-1,6-dicarboxylic acid
(D) 2, 5-Diethyl-4-methyl-1-propylcyclohexane 13. IUPAC name of picric acid is
10. The correct IUPAC numbering in the (A) 2,4,6-Trinitrobenzene carboxylic acid

compound is : (B) 2,4-Dinitrobenzene carboxylic acid

(C) 2,4,6-Trinitrophenol
(A) (B) (D) 2,4-Dinitrophenol
14. Which one of the compound is not isomer of
others ?
(A) (B)
(C) (D)

(C) (D)

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15. How many cyclic isomers are possible for 19.
compound having molecular formula C4H6 The IUPAC name of is :
(A) 4
(A) 3, 3-dimethyl-1-hydroxycyclohexane
(B) 6
(B) 1, 1-dimethyl-3-cyclohexanol
(C) 5
(C) 3, 3-dimethyl-1-cyclohexanol
(D) 3
(D) 1, 1-dimethyl-3-hydroxy cyclohexane
16. The IUPAC name of is :
20. Chain isomerism is related with :
(A) Pent-3-en-1-yne
(A) different arrangements of C-atoms
(B) Pent-2-en-4-yne
(B) different number of C-atoms in the parent
(C) Pent-4-en-2-yne chain
(D) Pent-1-yn-3-ene (C) both (a) and (b)
17. (D) position of methyl group in the same
The IUPAC name of is : parent chain

(A) 1-(1-Methylethyl)Cyclobutane
(B) 2-(Propyl) Cyclobutane
(C) (2-Propyl) Cyclobutane
(D) 2-Cyclobutylpropane
18. The IUPAC name of the following compound
is :

(A) 3, 4, 4-Trimethylheptane
(B) 3, 4, 4-Trimethyloctane
(C) 2-Butyl-2-methyl-3-ethylbutane
(D) 2-Ethyl-3, 3-dimethylheptane
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SECTION-2 : (Maximum Marks: 20)
This section contains 05 Questions, all questions are
mandatory The answer to each question is a
Numerical Value Type questions.

For each question, enter the correct numerical value

(in decimal notation, truncated/rounded off to the
second decimal place; e.g. 6.25, 7.00, –0.33, –.30,
30.27, –127.30, if answer is 11.36777..... then both
11.36 and 11.37 will be correct)
Answer to each question will be evaluated according
to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical
value is entered as answer.
Zero Marks : 0 In all other cases.
1. What is the degree of unsaturation in a

compound .

2. How many amines are possible with the

molecular formula C4H11N (structural isomers
only) :-
3. How many benzenoid isomers are possible for
molecular formula C7H8O :-
4. How many alkenes (only structural isomers)
are possible with the molecular formula C4H8
5. The minimum number of carbon atoms present
in an organic compound to be able to show
position isomerism is :-

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MATHEMATICS
SECTION-1 : (Maximum Marks: 80) 4. If it is not possible to draw any tangent from
This section contains 20 questions. Each question the point (1/4, 1) to the parabola
has 4 options for correct answer. Multiple-Choice y2 = 4x cos θ + sin 2 θ, then θ belongs to
Questions (MCQs) Only one option is correct. For
(A) π π (B) π π
each question, marks will be awarded as follows: [− , ] [− , 0
]−{ }
2 2 2 2
Full Marks : +4 If correct answer is selected.
Zero Marks : 0 If none of the option is (C) π π
(− , )−{ } 0 (D) None of these
selected. 2 2
–
Negative Marks : –1 If wrong option is selected. 5. If the line cuts the parabola
y − √3x + 3 = 0
–
1. If the normals at the end points of a variable y2 = x + 2 at A and B, and if P ≡ (√3, 0) ,
chord PQ of the parabola y2 – 4y – 2x = 0 are then PA × PB is equal to
perpendiculars then the tangents at P and Q will (A) 2 (√–3 + 2) (B) 4√–3
intersect at 3 2
(A) x + y = 3 (B) 3x – 7 = 0 – –
(C) 4 (2 − √3) (D) 4 (√3 + 2)
(C) y + 3 = 0 (D) 2x + 5 = 0 3 3
6. If α α − 1)
( , lies inside the ellipse
2. The co-ordinates of the point on the parabola
y2 = 8x, which is at minimum distance from 16x 2 + 9y2 − 16x = 0, then α lies in the
the circle x2 + (y + 6)2 = 1 are : interval
(A) (2, –4) (B) (18, –12) (A) 9 (B) 25
( , 1) 1
( , )
25 9
(C) (2, 4) (D) None of these
(C) −9
3. The equation of the hyperbola whose foci are (− , 1 ) (D) None of these
25
5
(6, 5), (–4, 5) and eccentricity is 7. If y + b = m 1 (x + a) and y + b = m 2 (x + a)
4
are two tangents to y2 = 4ax, then
(A) (x − 1) 2 y − 5)2
(
− = 1
16 9 (A) m1 + m2 = 0
2 2
(B) x y
− = 1 (B) m1 m2 = 1
16 9
(C) ( x − 1) 2 ( y − 5)2 (C) m1 m2 = − 1
− = − 1
16 9 (D) m1 m2 = a
(D) None of these

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8. The equation of common tangents to the ellipse 12. The tangent at a point P on the hyperbola
2 x2 y2
x 2 + 2y2 = 1 and the circle x 2 + y2 = is − = 1 meets one of its directrices in F.
3 a2 b2
– If PF subtends an angle θ at the corresponding
(A) √ 7 –
y= – x + √3
√2 focus, then θ equals
(B) y = 7x + √–3 (A) π (B) π
−− – 4 2
(C) y = √7x +√ 2
3π
(C) (D) π
(D) None of these 4

9. A man running a race course notes that the sum 13. Tangents are drawn from the points on the line
x − y − 5 = 0 to x 2 + 4y2 = 4, then all the
of his distances from the two flag posts is
always 10 m and the distance between the flag chords of contact pass through a fixed point,
posts is 8 m. The equation of the path traced by whose coordinates are
him is (A) 4 1
( ,− )
5 5
(A) x2 y2 (B) x2 y2
+ = 1 + = 1
25 9 4 1 (B) 4 1
( , )
5 5
(C) x2 y2 (D) none of these
+ = 1
2 1 (C) 4 1
(− , )
10. Let P be a variable point on the ellipse 5 5
x2 y2 (D) none of these
+ = 1 with foci F1 and F2. Then the
100 64
maximum area of triangle PF1F2 is 14. The locus of the middle points of chords of
hyperbola 3x 2 − 2y2 + 4x − 6y = 0 parallel to
(A) 24 sq. unit (B) 48 sq. unit
y = 2x is
(C) 96 sq. unit (D) none of these
(A) 3x − 4y = 4
11. The curve with paramatric equations
x − 1 = 4 (cos θ + sin θ) , (B) 3y − 4x + 4 = 0

y + 3 = 7 (sin θ − cos θ) is (C) 4x − 4y = 3

(A) an ellipse (D) 3x − 4y = 2

(B) a parabola
(C) a hyperbola
(D) a circle

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 ALLEN
15. Locus of the points of intersection of 18. The angle of intersection between the curves y2
x2 y2 = 4x and x2 = 32y at point (16, 8) is:
perpendicular tangents to − = 1 is
9 16
(A) 1 3
(A) 2 2 tan −
( )
x + y = 25 5

(B) x 2 + y2 7 (B) 1 4
=
tan −
( )
5
(C) x 2 + y2 = 49
(C) π
(D) none of these π
(D)
16. If the two parabolas = 4x and = (x – k)y2 y2 2
have a common normal other than the x-axis 19. If C is the centre and A, B are two points on the
then k can be equal to: conic 4x 2 + 9y2 − 8x − 36y + 4 = 0 such that
1 1
(A) 1 (B) 2 ∠ACB = 90 ∘
, then + is :
CA2 CB 2
(C) 3 (D) 4 (A) 13
17. An ellipse has eccentricity 1/2 and one focus at 36
the point P(1/2, 1). Its one directrix is the (B) 36
13
common tangent, nearer to the point P, to the
circle x2 + y2 = 1 and the hyperbola x2 – y2 = 1. (C) 16
33
The equation of the ellipse, in the standard
(D) 33
form is:
16
(A) 1 2
( x+ 3
) y + 1)2
( 20. AP is perpendicular to PB, where A is the
+ = 2
1 1 vertex of parabola y2 = 4x and P is on the
9 12

1 2
parabola. If B lie on the axis of parabola, then
(B) ( x− ) y − 1)2
3
+
(
= 2 the locus of centroid of ΔP AB is:
1 1
9 12
(A) 9y2
1 2
3x + 4 =
(C) ( x− ) y − 1)2
(
2
3
+ = 1
1 1 (B) 9y2
9 12 3x − 4 =
2
(D) None of these
(C) 9y2
5x + 4 =
2
(D) None of these

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SECTION-2 : (Maximum Marks: 20) 4. x2 y2
A point P on the ellipse + = 1 has the
This section contains 05 Questions, all questions are 25 9
π
mandatory The answer to each question is a eccentric angle . The sum of the distances of
8
Numerical Value Type questions. d
P from the two foci is d. Then is equal to :
2
For each question, enter the correct numerical value
(in decimal notation, truncated/rounded off to the 5. The vertex of the parabola y2 = 8x is at the
second decimal place; e.g. 6.25, 7.00, –0.33, –.30, centre of a circle and the parabola cuts the
30.27, –127.30, if answer is 11.36777..... then both circle at the ends of its latus rectum. If the
11.36 and 11.37 will be correct) r2
radius of the circle is r, then is equal to :
5
Answer to each question will be evaluated according
to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical
value is entered as answer.
Zero Marks : 0 In all other cases.
1. x2 y2 1
If foci of the hyperbola and− =
169 106 25
2 2
x y
ellipse + = 1 coincides then value of a
a2 25
is
2. x2 y2
The hyperbola − = 1 passes through
a2 b2
the point (2, 3) & has the eccentricity 2. Then
the transverse axis of the hyperbola has the
length equal to
3. If the eccentricity of the hyperbola conjugate to
x2 y2
the hyperbola − = 1 is e, then 3e2 is
4 12
equal to :

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