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Loctite 567

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Safety Data Sheet according to (EC) No 1907/2006 as amended

Page 1 of 17

SDS No. : 546886


V006.0
LOCTITE 567 Revision: 15.07.2022
printing date: 21.03.2024
Replaces version from: 21.10.2021

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
LOCTITE 567

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Anaerobic Sealant

1.3. Details of the supplier of the safety data sheet


Henkel Ltd
Adhesives
Wood Lane End
HP2 4RQ Hemel Hempstead

Great Britain

Phone: +44 (1442) 278000

ua-productsafety.uk@henkel.com
For Safety Data Sheet updates please visit our website https://mysds.henkel.com/index.html#/appSelection or www.henkel-
adhesives.com.

1.4. Emergency telephone number


24 Hours Emergency Tel: +44 (0)1442 278497

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture

Classification (CLP):
Skin irritation Category 2
H315 Causes skin irritation.
Serious eye irritation Category 2
H319 Causes serious eye irritation.
Skin sensitizer Category 1
H317 May cause an allergic skin reaction.
Specific target organ toxicity - single exposure Category 3
H335 May cause respiratory irritation.
Target organ: respiratory tract irritation
Chronic hazards to the aquatic environment Category 3
H412 Harmful to aquatic life with long lasting effects.

2.2. Label elements

Label elements (CLP):


SDS No.: 546886 V006.0 LOCTITE 567 Page 2 of 17

Hazard pictogram:

Contains 3,3,5 Trimethylcyclohexyl methacrylate

Signal word: Warning

Hazard statement: H315 Causes skin irritation.


H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

Supplemental information Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe
spray or mist.

Precautionary statement: "***" ***For consumer use only: P101 If medical advice is needed, have product
container or label at hand. P102 Keep out of reach of children. P501 Dispose of
contents/container in accordance with national regulation.***

Precautionary statement: P273 Avoid release to the environment.


Prevention P280 Wear protective gloves.
P261 Avoid breathing vapors.

Precautionary statement: P302+P352 IF ON SKIN: Wash with plenty of soap and water.
Response P337+P313 If eye irritation persists: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

2.3. Other hazards

None if used properly.


Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

Following substances are present in a concentration >= 0,1% and fulfill the criteria for PBT/vPvB, or were identified as
endocrine disruptor (ED):

This mixture does not contain any substances in concentration ≥ the concentration limit that are assessed to be a PBT, vPvB
or ED.

SECTION 3: Composition/information on ingredients


3.2. Mixtures
SDS No.: 546886 V006.0 LOCTITE 567 Page 3 of 17

Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components Concentration Classification Specific Conc. Limits, M- Add.


CAS-No. factors and ATEs Information
EC Number
REACH-Reg No.
3,3,5 Trimethylcyclohexyl 2,5- < 25 % Aquatic Chronic 2, H411 STOT SE 3; H335; C >= 10 %
methacrylate Skin Sens. 1B, H317
7779-31-9 STOT SE 3, H335
231-927-0 Skin Irrit. 2, H315
01-2120748527-45 Eye Irrit. 2, H319

Titanium dioxide 1- < 5 % Carc. 2, Inhalation, H351


13463-67-7
236-675-5
01-2119489379-17

Cumene hydroperoxide 0,1- < 1 % STOT RE 2, H373 Skin Irrit. 2; H315; C 3 - < 10 %
80-15-9 Skin Corr. 1B, H314 Eye Dam. 1; H318; C 3 - < 10 %
201-254-7 Acute Tox. 2, Inhalation, H330 Eye Irrit. 2; H319; C 1 - < 3 %
01-2119475796-19 Aquatic Chronic 2, H411 Skin Corr. 1B; H314; C >= 10 %
Acute Tox. 4, Oral, H302 STOT SE 3; H335; C >= 1 %
Acute Tox. 4, Dermal, H312 =====
Org. Perox. E, H242 dermal:ATE = 1.100 mg/kg
STOT SE 3, H335

N,N-Diethyl-p-toluidine 0,1- < 1 % Acute Tox. 3, Oral, H301


613-48-9 Acute Tox. 3, Dermal, H311
210-345-0 Acute Tox. 3, Inhalation, H331
STOT RE 2, H373
Aquatic Chronic 3, H412

N,N-dimethyl-o-toluidine 0,1- < 1 % STOT RE 2, H373


609-72-3 Acute Tox. 3, Oral, H301
210-199-8 Acute Tox. 3, Dermal, H311
Acute Tox. 3, Inhalation, H331
Aquatic Chronic 3, H412

1,4-Naphthalenedione 0,01- < 0,1 % Acute Tox. 3, Oral, H301 M acute = 10


130-15-4 Skin Corr. 1C, H314 M chronic = 1
204-977-6 Skin Sens. 1, H317
Eye Dam. 1, H318
Acute Tox. 1, Inhalation, H330
STOT SE 3, H335
Aquatic Acute 1, H400
Aquatic Chronic 1, H410

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Move to fresh air. If symptoms persist, seek medical advice.

Skin contact:
Rinse with running water and soap.
Obtain medical attention if irritation persists.

Eye contact:
Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist.

Ingestion:
Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.
SDS No.: 546886 V006.0 LOCTITE 567 Page 4 of 17

4.2. Most important symptoms and effects, both acute and delayed
EYE: Irritation, conjunctivitis.

SKIN: Redness, inflammation.

RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness.

SKIN: Rash, Urticaria.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media:
water, carbon dioxide, foam, powder

Extinguishing media which must not be used for safety reasons:


High pressure waterjet

5.2. Special hazards arising from the substance or mixture


In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released.
5.3. Advice for firefighters
Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Additional information:
In case of fire, keep containers cool with water spray.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Avoid contact with skin and eyes.
Wear protective equipment.
Ensure adequate ventilation.
Keep away from sources of ignition.

6.2. Environmental precautions


Do not empty into drains / surface water / ground water.

6.3. Methods and material for containment and cleaning up


Dispose of contaminated material as waste according to Section 13.
For small spills wipe up with paper towel and place in container for disposal.
For large spills absorb onto inert absorbent material and place in sealed container for disposal.

6.4. Reference to other sections


See advice in section 8

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid skin and eye contact.
See advice in section 8

Hygiene measures:
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.
Good industrial hygiene practices should be observed.

7.2. Conditions for safe storage, including any incompatibilities


Ensure good ventilation/extraction.
Refer to Technical Data Sheet
SDS No.: 546886 V006.0 LOCTITE 567 Page 5 of 17

7.3. Specific end use(s)


Anaerobic Sealant
SDS No.: 546886 V006.0 LOCTITE 567 Page 6 of 17

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Valid for
Great Britain

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Ethene, homopolymer 10 Time Weighted Average EH40 WEL
9002-88-4 (TWA):
[DUST, INHALABLE DUST]
Ethene, homopolymer 4 Time Weighted Average EH40 WEL
9002-88-4 (TWA):
[DUST, RESPIRABLE DUST]
Titanium dioxide 4 Time Weighted Average EH40 WEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE, RESPIRABLE]
Titanium dioxide 10 Time Weighted Average EH40 WEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE, TOTAL
INHALABLE]
Silicon dioxide 6 Time Weighted Average EH40 WEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS, INHALABLE
DUST]
Silicon dioxide 2,4 Time Weighted Average EH40 WEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS, RESPIRABLE
DUST]
Silicon dioxide 4 Time Weighted Average EH40 WEL
112945-52-5 (TWA):
[Dust, respirable dust]
Silicon dioxide 10 Time Weighted Average EH40 WEL
112945-52-5 (TWA):
[Dust, inhalable dust]
Propane-1,2-diol 10 Time Weighted Average EH40 WEL
57-55-6 (TWA):
[PROPANE-1,2-DIOL, PARTICULATES]
Propane-1,2-diol 150 474 Time Weighted Average EH40 WEL
57-55-6 (TWA):
[PROPANE-1,2-DIOL, TOTAL VAPOUR
AND PARTICULATES]

Occupational Exposure Limits

Valid for
Ireland

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Ethene, homopolymer 10 Time Weighted Average IR_OEL
9002-88-4 (TWA):
[DUSTS NON-SPECIFIC]
Ethene, homopolymer 4 Time Weighted Average IR_OEL
9002-88-4 (TWA):
[DUSTS NON-SPECIFIC]
Titanium dioxide 10 Time Weighted Average IR_OEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE]
Titanium dioxide 4 Time Weighted Average IR_OEL
13463-67-7 (TWA):
[TITANIUM DIOXIDE]
Silicon dioxide 6 Time Weighted Average IR_OEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS]
Silicon dioxide 2,4 Time Weighted Average IR_OEL
112945-52-5 (TWA):
[SILICA, AMORPHOUS]
Silicon dioxide 10 Time Weighted Average IR_OEL
112945-52-5 (TWA):
SDS No.: 546886 V006.0 LOCTITE 567 Page 7 of 17

[DUSTS NON-SPECIFIC]
Silicon dioxide 4 Time Weighted Average IR_OEL
112945-52-5 (TWA):
[DUSTS NON-SPECIFIC]
Propane-1,2-diol 10 Time Weighted Average IR_OEL
57-55-6 (TWA):
[PROPANE-1,2-DIOL]
Propane-1,2-diol 150 470 Time Weighted Average IR_OEL
57-55-6 (TWA):
[PROPANE-1,2-DIOL]

Predicted No-Effect Concentration (PNEC):

Name on list Environmental Exposure Value Remarks


Compartment period
mg/l ppm mg/kg others
3,3,5 Trimethylcyclohexyl methacrylate aqua 0,0019
7779-31-9 (freshwater) mg/l
3,3,5 Trimethylcyclohexyl methacrylate aqua (marine 0,00019
7779-31-9 water) mg/l
3,3,5 Trimethylcyclohexyl methacrylate aqua 0,019 mg/l
7779-31-9 (intermittent
releases)
3,3,5 Trimethylcyclohexyl methacrylate sewage 100 mg/l
7779-31-9 treatment plant
(STP)
3,3,5 Trimethylcyclohexyl methacrylate sediment 0,141
7779-31-9 (freshwater) mg/kg
3,3,5 Trimethylcyclohexyl methacrylate sediment 0,014
7779-31-9 (marine water) mg/kg
3,3,5 Trimethylcyclohexyl methacrylate Soil 0,027
7779-31-9 mg/kg
Titanium dioxide Predator no potential for
13463-67-7 bioaccumulation
.alpha.,.alpha.-Dimethylbenzyl aqua 0,0031
hydroperoxide (freshwater) mg/l
80-15-9
.alpha.,.alpha.-Dimethylbenzyl aqua 0,031 mg/l
hydroperoxide (intermittent
80-15-9 releases)
.alpha.,.alpha.-Dimethylbenzyl aqua (marine 0,00031
hydroperoxide water) mg/l
80-15-9
.alpha.,.alpha.-Dimethylbenzyl sewage 0,35 mg/l
hydroperoxide treatment plant
80-15-9 (STP)
.alpha.,.alpha.-Dimethylbenzyl sediment 0,023
hydroperoxide (freshwater) mg/kg
80-15-9
.alpha.,.alpha.-Dimethylbenzyl sediment 0,0023
hydroperoxide (marine water) mg/kg
80-15-9
.alpha.,.alpha.-Dimethylbenzyl Soil 0,0029
hydroperoxide mg/kg
80-15-9
SDS No.: 546886 V006.0 LOCTITE 567 Page 8 of 17

Derived No-Effect Level (DNEL):

Name on list Application Route of Health Effect Exposure Value Remarks


Area Exposure Time
3,3,5 Trimethylcyclohexyl methacrylate Workers inhalation Long term 16,45 mg/m3
7779-31-9 exposure -
systemic effects
3,3,5 Trimethylcyclohexyl methacrylate Workers dermal Long term 46,7 mg/kg
7779-31-9 exposure -
systemic effects
3,3,5 Trimethylcyclohexyl methacrylate General inhalation Long term 2,9 mg/m3
7779-31-9 population exposure -
systemic effects
3,3,5 Trimethylcyclohexyl methacrylate General dermal Long term 1,67 mg/kg
7779-31-9 population exposure -
systemic effects
3,3,5 Trimethylcyclohexyl methacrylate General oral Long term 1,67 mg/kg
7779-31-9 population exposure -
systemic effects
Titanium dioxide Workers inhalation Long term 10 mg/m3 no potential for
13463-67-7 exposure - local bioaccumulation
effects
Titanium dioxide General oral Long term 700 mg/kg no potential for
13463-67-7 population exposure - bioaccumulation
systemic effects
.alpha.,.alpha.-Dimethylbenzyl Workers inhalation Long term 6 mg/m3
hydroperoxide exposure -
80-15-9 systemic effects

Biological Exposure Indices:


None

8.2. Exposure controls:

Engineering controls:
Ensure good ventilation/extraction.

Respiratory protection:
Ensure adequate ventilation.
An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly
ventilated area
Filter type: A (EN 14387)

Hand protection:
Chemical-resistant protective gloves (EN 374).
Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes
permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time
as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy
with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably
shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g.
temperature). If signs of wear and tear are noticed then the gloves should be replaced.

Eye protection:
Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing.
Protective eye equipment should conform to EN166.

Skin protection:
Wear suitable protective clothing.
Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts.
SDS No.: 546886 V006.0 LOCTITE 567 Page 9 of 17

Advices to personal protection equipment:

The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be
conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions.
Personal protective equipment should conform to the relevant EN standard.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Physical state liquid
Delivery form paste
Colour Off white
Odor mild
Melting point Not available.
Initial boiling point > 149 °C (> 300.2 °F)no method
Flammability Currently under determination
Explosive limits Currently under determination
Flash point > 93 °C (> 199.4 °F)
Auto-ignition temperature Currently under determination
Decomposition temperature Currently under determination
pH Not available.
pH Product is non-soluble (in water).
Viscosity (kinematic) Currently under determination
Solubility (qualitative) Currently under determination
Partition coefficient: n-octanol/water Currently under determination
Vapour pressure Not available.
Density Currently under determination
Relative vapour density: Not available.
Particle characteristics Currently under determination

9.2. Other information


Other information not applicable for this product

SECTION 10: Stability and reactivity


10.1. Reactivity
Reacts with strong oxidants.
Strong bases.
Acids.
Reducing agents.

10.2. Chemical stability


Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions


See section reactivity

10.4. Conditions to avoid


Stable under normal conditions of storage and use.

10.5. Incompatible materials


See section reactivity.

10.6. Hazardous decomposition products


carbon oxides.
Hydrocarbons
nitrogen oxides
Rapid polymerisation may generate excessive heat and pressure.
SDS No.: 546886 V006.0 LOCTITE 567 Page 10 of 17

SECTION 11: Toxicological information

1.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute oral toxicity:

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Species Method


CAS-No. type
3,3,5 Trimethylcyclohexyl LD0 > 5.000 mg/kg rat OECD Guideline 401 (Acute Oral Toxicity)
methacrylate
7779-31-9
3,3,5 Trimethylcyclohexyl LD50 > 5.000 mg/kg rat OECD Guideline 401 (Acute Oral Toxicity)
methacrylate
7779-31-9
Titanium dioxide LD50 > 5.000 mg/kg rat OECD Guideline 425 (Acute Oral Toxicity: Up-and-Down
13463-67-7 Procedure)
Cumene hydroperoxide LD50 382 mg/kg rat other guideline:
80-15-9
1,4-Naphthalenedione LD50 124 mg/kg rat equivalent or similar to OECD Guideline 401 (Acute Oral
130-15-4 Toxicity)

Acute dermal toxicity:

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Species Method


CAS-No. type
3,3,5 Trimethylcyclohexyl LD0 > 2.000 mg/kg rat OECD Guideline 402 (Acute Dermal Toxicity)
methacrylate
7779-31-9
3,3,5 Trimethylcyclohexyl LD50 > 2.000 mg/kg rat OECD Guideline 402 (Acute Dermal Toxicity)
methacrylate
7779-31-9
Titanium dioxide LD50 > 10.000 mg/kg rabbit not specified
13463-67-7
Cumene hydroperoxide Acute 1.100 mg/kg Expert judgement
80-15-9 toxicity
estimate
(ATE)

Acute inhalative toxicity:

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Test atmosphere Exposure Species Method


CAS-No. type time
Titanium dioxide LC50 > 6,82 mg/l dust 4h rat not specified
13463-67-7
Cumene hydroperoxide LC50 1,370 mg/l vapour 4h rat not specified
80-15-9
1,4-Naphthalenedione LC50 0,046 mg/l dust/mist 4h rat OECD Guideline 403 (Acute
130-15-4 Inhalation Toxicity)

Skin corrosion/irritation:

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Result Exposure Species Method


CAS-No. time
Titanium dioxide not irritating 4h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion)
13463-67-7
Cumene hydroperoxide corrosive rabbit Draize Test
80-15-9
1,4-Naphthalenedione Category 1C rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion)
130-15-4 (corrosive)
SDS No.: 546886 V006.0 LOCTITE 567 Page 11 of 17

Serious eye damage/irritation:

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Result Exposure Species Method


CAS-No. time
Titanium dioxide not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion)
13463-67-7

Respiratory or skin sensitization:

The mixture is classified based on threshold limits referring to the classified substances present in the mixture.

Hazardous substances Result Test type Species Method


CAS-No.
3,3,5 Trimethylcyclohexyl sensitising Mouse local lymphnode mouse OECD Guideline 429 (Skin Sensitisation:
methacrylate assay (LLNA) Local Lymph Node Assay)
7779-31-9
Titanium dioxide not sensitising Mouse local lymphnode mouse equivalent or similar to OECD Guideline
13463-67-7 assay (LLNA) 429 (Skin Sensitisation: Local Lymph
Node Assay)
Titanium dioxide not sensitising Buehler test guinea pig OECD Guideline 406 (Skin Sensitisation)
13463-67-7
1,4-Naphthalenedione sensitising not specified guinea pig not specified
130-15-4

Germ cell mutagenicity:

The mixture is classified based on threshold limits referring to the classified substances present in the mixture.

Hazardous substances Result Type of study / Metabolic Species Method


CAS-No. Route of activation /
administration Exposure time
3,3,5 Trimethylcyclohexyl negative bacterial reverse with and without OECD Guideline 471
methacrylate mutation assay (e.g (Bacterial Reverse Mutation
7779-31-9 Ames test) Assay)
Titanium dioxide negative bacterial reverse with and without OECD Guideline 471
13463-67-7 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
Titanium dioxide negative in vitro mammalian with and without OECD Guideline 473 (In vitro
13463-67-7 chromosome Mammalian Chromosome
aberration test Aberration Test)
Titanium dioxide negative mammalian cell with and without OECD Guideline 476 (In vitro
13463-67-7 gene mutation assay Mammalian Cell Gene
Mutation Test)
Titanium dioxide negative in vitro mammalian without equivalent or similar to OECD
13463-67-7 cell micronucleus Guideline 487 (In vitro
test Mammalian Cell
Micronucleus Test)
Cumene hydroperoxide positive bacterial reverse without OECD Guideline 471
80-15-9 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)

Carcinogenicity

The mixture is classified based on threshold limits referring to the classified substances present in the mixture.

Hazardous components Result Route of Exposure Species Sex Method


CAS-No. application time /
Frequency
of treatment
Titanium dioxide not carcinogenic oral: feed 103 w rat male/female not specified
13463-67-7 daily
SDS No.: 546886 V006.0 LOCTITE 567 Page 12 of 17

Reproductive toxicity:

The mixture is classified based on threshold limits referring to the classified substances present in the mixture.

Hazardous substances Result / Value Test type Route of Species Method


CAS-No. application
Titanium dioxide NOAEL P >= 1.000 mg/kg one- oral: feed rat OECD Guideline 443
13463-67-7 generation (Extended One-Generation
NOAEL F1 >= 1.000 mg/kg study Reproductive Toxicity
Study)

STOT-single exposure:

No data available.

STOT-repeated exposure::

The mixture is classified based on threshold limits referring to the classified substances present in the mixture.

Hazardous substances Result / Value Route of Exposure time / Species Method


CAS-No. application Frequency of
treatment
3,3,5 Trimethylcyclohexyl NOAEL 1.000 mg/kg oral: gavage 28 d rat OECD Guideline 422
methacrylate daily (Combined Repeated
7779-31-9 Dose Toxicity Study with
the Reproduction /
Developmental Toxicity
Screening Test)
Titanium dioxide NOAEL > 1.000 mg/kg oral: gavage 92 d rat OECD Guideline 408
13463-67-7 daily (Repeated Dose 90-Day
Oral Toxicity in Rodents)
Cumene hydroperoxide inhalation: 6 h/d rat not specified
80-15-9 aerosol 5 d/w

Aspiration hazard:

No data available.

11.2 Information on other hazards

not applicable
SDS No.: 546886 V006.0 LOCTITE 567 Page 13 of 17

SECTION 12: Ecological information


General ecological information:
Do not empty into drains / surface water / ground water.

12.1. Toxicity

Toxicity (Fish):

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Exposure time Species Method


CAS-No. type
3,3,5 Trimethylcyclohexyl LC50 1,9 mg/l 96 h Brachydanio rerio (new name: OECD Guideline 203 (Fish,
methacrylate Danio rerio) Acute Toxicity Test)
7779-31-9
Titanium dioxide LC50 Toxicity > Water 48 h Leuciscus idus OECD Guideline 203 (Fish,
13463-67-7 solubility Acute Toxicity Test)
Cumene hydroperoxide LC50 3,9 mg/l 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish,
80-15-9 Acute Toxicity Test)
N,N-dimethyl-o-toluidine LC 50 46 mg/l 96 h Fathead minnow (Pimephales
609-72-3 promelas)
1,4-Naphthalenedione LC50 0,045 mg/l 96 h Oryzias latipes OECD Guideline 203 (Fish,
130-15-4 Acute Toxicity Test)

Toxicity (Daphnia):

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Exposure time Species Method


CAS-No. type
3,3,5 Trimethylcyclohexyl EC50 14,43 mg/l 48 h Daphnia magna OECD Guideline 202
methacrylate (Daphnia sp. Acute
7779-31-9 Immobilisation Test)
Titanium dioxide EC50 Toxicity > Water 48 h Daphnia magna OECD Guideline 202
13463-67-7 solubility (Daphnia sp. Acute
Immobilisation Test)
Cumene hydroperoxide EC50 18,84 mg/l 48 h Daphnia magna OECD Guideline 202
80-15-9 (Daphnia sp. Acute
Immobilisation Test)
1,4-Naphthalenedione EC50 0,026 mg/l 48 h Daphnia magna OECD Guideline 202
130-15-4 (Daphnia sp. Acute
Immobilisation Test)

Chronic toxicity to aquatic invertebrates

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Exposure time Species Method


CAS-No. type
Titanium dioxide NOEC Toxicity > Water 21 d Daphnia magna OECD Guideline 202
13463-67-7 solubility (Daphnia sp. Chronic
Immobilisation Test)

Toxicity (Algae):
SDS No.: 546886 V006.0 LOCTITE 567 Page 14 of 17

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Exposure time Species Method


CAS-No. type
3,3,5 Trimethylcyclohexyl EC10 0,43 mg/l 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga,
methacrylate Growth Inhibition Test)
7779-31-9
Titanium dioxide EC50 Toxicity > Water 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga,
13463-67-7 solubility Growth Inhibition Test)
Titanium dioxide NOEC Toxicity > Water 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga,
13463-67-7 solubility Growth Inhibition Test)
Cumene hydroperoxide EC50 3,1 mg/l 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga,
80-15-9 (reported as Scenedesmus Growth Inhibition Test)
subspicatus)
Cumene hydroperoxide NOEC 1 mg/l 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga,
80-15-9 (reported as Scenedesmus Growth Inhibition Test)
subspicatus)
1,4-Naphthalenedione NOEC 0,07 mg/l 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga,
130-15-4 Growth Inhibition Test)
1,4-Naphthalenedione EC50 0,42 mg/l 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga,
130-15-4 Growth Inhibition Test)

Toxicity to microorganisms

The mixture is classified based on calculation method referring to the classified substances present in the mixture.

Hazardous substances Value Value Exposure time Species Method


CAS-No. type
Titanium dioxide EC0 Toxicity > Water 24 h Pseudomonas fluorescens DIN 38412, part 8
13463-67-7 solubility (Pseudomonas
Zellvermehrungshemm-
Test)
Cumene hydroperoxide EC10 70 mg/l 30 min not specified not specified
80-15-9
1,4-Naphthalenedione EC50 5,94 mg/l 3h activated sludge of a OECD Guideline 209
130-15-4 predominantly domestic sewage (Activated Sludge,
Respiration Inhibition Test)

12.2. Persistence and degradability

Hazardous substances Result Test type Degradability Exposure Method


CAS-No. time
3,3,5 Trimethylcyclohexyl not readily biodegradable. aerobic 16,8 % 28 d OECD Guideline 301 F (Ready
methacrylate Biodegradability: Manometric
7779-31-9 Respirometry Test)
Cumene hydroperoxide not readily biodegradable. aerobic 3% 28 d OECD Guideline 301 B (Ready
80-15-9 Biodegradability: CO2 Evolution
Test)
N,N-Diethyl-p-toluidine not readily biodegradable. 1% 14 d other guideline:
613-48-9
N,N-dimethyl-o-toluidine not readily biodegradable. 1% 14 d other guideline:
609-72-3
1,4-Naphthalenedione not readily biodegradable. aerobic 0% 28 d OECD Guideline 301 F (Ready
130-15-4 Biodegradability: Manometric
Respirometry Test)

12.3. Bioaccumulative potential

Hazardous substances Bioconcentratio Exposure time Temperature Species Method


CAS-No. n factor (BCF)
Cumene hydroperoxide 9,1 calculation OECD Guideline 305
80-15-9 (Bioconcentration: Flow-through
Fish Test)

12.4. Mobility in soil


SDS No.: 546886 V006.0 LOCTITE 567 Page 15 of 17

Hazardous substances LogPow Temperature Method


CAS-No.
3,3,5 Trimethylcyclohexyl 5,25 20 °C OECD Guideline 117 (Partition Coefficient (n-octanol / water), HPLC
methacrylate Method)
7779-31-9
Cumene hydroperoxide 1,6 25 °C OECD Guideline 117 (Partition Coefficient (n-octanol / water), HPLC
80-15-9 Method)
1,4-Naphthalenedione 1,71 not specified
130-15-4

12.5. Results of PBT and vPvB assessment

Hazardous substances PBT / vPvB


CAS-No.
3,3,5 Trimethylcyclohexyl methacrylate Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
7779-31-9 Bioaccumulative (vPvB) criteria.
Titanium dioxide According to Annex XIII of regulation (EC) 1907/2006 a PBT and vPvB assessment shall not
13463-67-7 be conducted for inorganic substances.
Cumene hydroperoxide Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
80-15-9 Bioaccumulative (vPvB) criteria.
1,4-Naphthalenedione Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
130-15-4 Bioaccumulative (vPvB) criteria.

12.6. Endocrine disrupting properties

not applicable

12.7. Other adverse effects

No data available.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Product disposal:
Dispose of in accordance with local and national regulations.
Do not empty into drains / surface water / ground water.

Disposal of uncleaned packages:


After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an
authorised legal land fill site or incinerated.

Waste code
08 04 09* waste adhesives and sealants containing organic solvents and other dangerous substances
The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes
for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We
will be happy to advise you.
SDS No.: 546886 V006.0 LOCTITE 567 Page 16 of 17

SECTION 14: Transport information

14.1. UN number

ADR Not dangerous goods


RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA Not dangerous goods

14.2. UN proper shipping name

ADR Not dangerous goods


RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA Not dangerous goods

14.3. Transport hazard class(es)

ADR Not dangerous goods


RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA Not dangerous goods

14.4. Packing group

ADR Not dangerous goods


RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
IATA Not dangerous goods

14.5. Environmental hazards

ADR not applicable


RID not applicable
ADN not applicable
IMDG not applicable
IATA not applicable

14.6. Special precautions for user

ADR not applicable


RID not applicable
ADN not applicable
IMDG not applicable
IATA not applicable

14.7. Maritime transport in bulk according to IMO instruments

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Ozone Depleting Substance (ODS) (Regulation (EC) No 1005/2009): Not applicable
Prior Informed Consent (PIC) (Regulation (EU) No 649/2012): Not applicable
Persistent organic pollutants (Regulation (EU) 2019/1021): Not applicable
VOC content <3%
(2010/75/EC)
SDS No.: 546886 V006.0 LOCTITE 567 Page 17 of 17

15.2. Chemical safety assessment


A chemical safety assessment has not been carried out.

SECTION 16: Other information


The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
H242 Heating may cause a fire.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

ED: Substance identified as having endocrine disrupting properties


EU OEL: Substance with a Union workplace exposure limit
EU EXPLD 1: Substance listed in Annex I, Reg (EC) No. 2019/1148
EU EXPLD 2 Substance listed in Annex II, Reg (EC) No. 2019/1148
SVHC: Substance of very high concern (REACH Candidate List)
PBT: Substance fulfilling persistent, bioaccumulative and toxic criteria
PBT/vPvB: Substance fulfilling persistent, bioaccumulative and toxic plus very persistent and very
bioaccumulative criteria
vPvB: Substance fulfilling very persistent and very bioaccumulative criteria

Further information:
This Safety Data Sheet has been produced for sales from Henkel to parties purchasing from Henkel, is based on Regulation
(EC) No 1907/2006 and provides information in accordance with applicable regulations of the European Union only. In that
respect, no statement, warranty or representation of any kind is given as to compliance with any statutory laws or regulations
of any other jurisdiction or territory other than the European Union. When exporting to territories other than the European
Union, please consult with the respective Safety Data Sheet of the concerned territory to ensure compliance or liaise with
Henkel´s Product Safety and Regulatory Affairs Department (ua-productsafety.de@henkel.com) prior to export to other
territories than the European Union.

This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.

Dear Customer,
Henkel is committed to creating a sustainable future by promoting opportunities along the entire value chain. If you would
like to contribute by switching from a paper to the electronic version of SDS, please contact the local Customer Service
representative. We recommend to use a non-personal email address (e.g. SDS@your_company.com).

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
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