SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Trade name DECIS
Product code (UVP) 80183062
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Insecticide
1.3 Details of the supplier of the safety data sheet
Supplier Bayer CropScience Ltd
Bayer Ltd
The Atrium, Blackthorn Road
Sandyford
Dublin 18
Ireland
Telephone +353-1-2999313
Responsible Department Email: ukinfo@bayercropscience.com
1.4 Emergency telephone no.
Emergency telephone no. 1800-409-399 (24 hr)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Flammable liquids: Category 3
H226 Flammable liquid and vapour.
Acute toxicity: Category 4
H302 Harmful if swallowed.
Aspiration hazard: Category 1
H304 May be fatal if swallowed and enters airways.
Skin irritation: Category 2
H315 Causes skin irritation.
Serious eye damage: Category 1
H318 Causes serious eye damage.
Acute toxicity: Category 4
H332 Harmful if inhaled.
Specific target organ toxicity - single exposure: Category 3
H335 May cause respiratory irritation.
Specific target organ toxicity - single exposure: Category 3
H336 May cause drowsiness or dizziness.
Acute aquatic toxicity: Category 1
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H400 Very toxic to aquatic life.

Chronic aquatic toxicity: Category 1
H410 Very toxic to aquatic life with long lasting effects.
2.2 Label elements
Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Hazard label for supply/use required.
Hazardous components which must be listed on the label:
 Deltamethrin
 Solvent Naphtha (petroleum), light aromatic

Signal word: Danger

Hazard statements
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H410 Very toxic to aquatic life with long lasting effects.
EUH401 To avoid risks to human health and the environment, comply with the instructions for
use.
Precautionary statements
P240 Ground/bond container and receiving equipment.
P280 Wear protective gloves/ protective clothing/ eye protection.
P305 + P351 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
+ P338 present and easy to do. Continue rinsing.
P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor/ physician.
P501 Dispose of contents/container to a licensed waste disposal contractor or collection site,
except for triple rinsed empty containers which can be disposed of as non-hazardous
waste.
2.3 Other hazards
Cutaneous sensations may occur, such as burning or stinging on the face and mucosae. However,
these sensations cause no lesions and are of a transitory nature (max. 24 hours).

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Chemical nature
Emulsifiable concentrate (EC)
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Deltamethrin 25 g/l
Hazardous components
Hazard statements according to Regulation (EC) No. 1272/2008
Name CAS-No. / Classification Conc. [%]
EC-No. / REGULATION (EC) No
REACH Reg. No. 1272/2008
Deltamethrin 52918-63-5 Aquatic Chronic 1, H410 2.81
258-256-6 Aquatic Acute 1, H400
Acute Tox. 3, H301
Acute Tox. 3, H331
Tetrapropylene benzene 11117-11-6 Acute Tox. 4, H312 > 1.00 – <
sulfonate, calcium salt 234-360-7 Skin Irrit. 2, H315 5.00
Eye Dam. 1, H318
Aquatic Chronic 3, H412
2-Methylpropan-1-ol 78-83-1 Flam. Liq. 3, H226 > 1.00 – <
201-148-0 STOT SE 3, H335 5.00
Skin Irrit. 2, H315
Eye Dam. 1, H318
STOT SE 3, H336
2,6-Di-tert-butyl-4- 128-37-0 Aquatic Acute 1, H400 > 0.10 – <
methylphenol 204-881-4 Aquatic Chronic 1, H410 0.25
01-2119555270-46-xxxx
Solvent Naphtha 64742-95-6 Flam. Liq. 3, H226 > 25.00
(petroleum), light aromatic 265-199-0 STOT SE 3, H336
01-2119486773-24-xxxx STOT SE 3, H335
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
Further information
Deltamethrin 52918-63-5 M-Factor: 1,000,000 (acute), 1,000,000 (chronic)
For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

General advice Move out of dangerous area. Place and transport victim in stable
position (lying sideways). Remove contaminated clothing immediately
and dispose of safely.
Inhalation Move the victim to fresh air and keep at rest. Call a physician or poison
control center immediately.
Skin contact Immediately wash with plenty of soap and water for at least 15
minutes. Warm water may increase the subjective severity of the
irritation/paresthesia. This is not a sign of systemic poisoning. In case
of skin irritation, application of oils or lotions containing vitamin E may
be considered. If symptoms persist, call a physician.
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Eye contact Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Warm water may increase the
subjective severity of the irritation/paresthesia. This is not a sign of
systemic poisoning. Apply soothing eye drops, if needed anaesthetic
eye drops. Get medical attention if irritation develops and persists.
Ingestion Rinse out mouth and give water in small sips to drink. Do NOT induce
vomiting. Do not leave victim unattended. Call a physician or poison
control center immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms Local:, Skin and eye paraesthesia which may be severe, Usually
transient with resolution within 24 hours, Skin, eye and mucous
membrane irritation, Cough, Sneezing
Systemic:, discomfort in the chest, Tachycardia, Hypotension, Nausea,
Abdominal pain, Diarrhoea, Vomiting, Blurred vision, Headache,
Anorexia, Somnolence, Coma, Convulsions, Tremors, Prostration,
Airway hyperreaction, Pulmonary oedema, Palpitation, Muscular
fasciculation, Apathy, Dizziness
4.3 Indication of any immediate medical attention and special treatment needed
Risks This product contains a pyrethroid. Pyrethroid poisoning should not be
confused with carbamate or organophosphate poisoning.
Treatment Systemic treatment: Initial treatment: symptomatic. Monitor: respiratory
and cardiac functions. In case of ingestion gastric lavage should be
considered in cases of significant ingestions only within the first 2
hours. However, the application of activated charcoal and sodium
sulphate is always advisable. Keep respiratory tract clear. Oxygen or
artificial respiration if needed. In case of convulsions, a
benzodiazepine (e.g. diazepam) should be given according to standard
regimens. If not effective, phenobarbital may be used.
Contraindication: atropine. Contraindication: derivatives of adrenaline.
There is no specific antidote. Recovery is spontaneous and without
sequelae.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Unsuitable High volume water jet

5.2 Special hazards arising Dangerous gases are evolved in the event of a fire.
from the substance or
mixture
5.3 Advice for firefighters
Special protective In the event of fire and/or explosion do not breathe fumes. In the event
equipment for firefighters of fire, wear self-contained breathing apparatus.
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Further information Remove product from areas of fire, or otherwise cool containers with
water in order to avoid pressure being built up due to heat. Whenever
possible, contain fire-fighting water by diking area with sand or earth.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Precautions Avoid contact with spilled product or contaminated surfaces. Remove
all sources of ignition. Use personal protective equipment.

6.2 Environmental Do not allow to get into surface water, drains and ground water. If the
precautions product contaminates rivers and lakes or drains inform respective
authorities.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid
binder, universal binder, sawdust). Keep in suitable, closed containers
for disposal. Clean floors and contaminated objects with plenty of
water.
Additional advice Check also for any local site procedures.

6.4 Reference to other Information regarding safe handling, see section 7.

sections Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling No specific precautions required when handling unopened
packs/containers; follow relevant manual handling advice. Ensure
adequate ventilation.
Advice on protection Keep away from heat and sources of ignition. Vapours may form
against fire and explosion explosive mixture with air. Take measures to prevent the build up of
electrostatic charge. Use only explosion-proof equipment.
Hygiene measures When using, do not eat, drink or smoke. Remove soiled clothing
immediately and clean thoroughly before using again. Contaminated
work clothing should not be allowed out of the workplace. Wash hands
thoroughly with soap and water after handling and before eating,
drinking, chewing gum, using tobacco, using the toilet or applying
cosmetics. Wash hands immediately after work, if necessary take a
shower.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage Store in a place accessible by authorized persons only. Keep containers
areas and containers tightly closed in a dry, cool and well-ventilated place. Protect from
freezing. Keep away from direct sunlight.
Advice on common storage Keep away from food, drink and animal feedingstuffs.
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Suitable materials Coextruded containers with an internal barrier layer made of ethylene
vinyl alcohol copolymer (EVOH)
Black mild steel sheet with interior coating
7.3 Specific end use(s) Refer to the label and/or leaflet.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components CAS-No. Control parameters Update Basis
2-Methylpropan-1-ol 78-83-1 225 mg/m3/75 ppm 2011 ELV (IE)
(STEL)
2-Methylpropan-1-ol 78-83-1 150 mg/m3/50 ppm 2011 ELV (IE)
(TWA)
2,6-Di-tert-butyl-4- 128-37-0 10 mg/m3 2011 ELV (IE)
methylphenol (TWA)

2,6-Di-tert-butyl-4- 128-37-0 2 mg/m3 OES BCS*

methylphenol (TLV)

Solvent Naphtha 64742-95-6 116 mg/m3/20 ppm 2014 EU

(petroleum), light aromatic (TWA) SCOELS

Solvent Naphtha 64742-95-6 290 mg/m3/50 ppm 2014 EU

(petroleum), light aromatic (STEL) SCOELS

Deltamethrin 52918-63-5 0.02 mg/m3 OES BCS*

(TWA)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
8.2 Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
following recommendations would apply.
Respiratory protection Wear respirator with an organic vapours and gas filter mask
(protection factor 10) conforming to EN140 type A or equivalent.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand protection Please observe the instructions regarding permeability and

breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the
contact time.
Wash gloves when contaminated. Dispose of when contaminated
inside, when perforated or when contamination on the outside cannot
be removed. Wash hands frequently and always before eating,
drinking, smoking or using the toilet.
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Material Nitrile rubber

Rate of permeability > 480 min
Glove thickness > 0.4 mm
Protective index Class 6
Directive Protective gloves complying with EN
374.
Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection Wear standard coveralls and Category 3 Type 6 suit.
If there is a risk of significant exposure, consider a higher protective
type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Form Liquid
Colour yellow
Odour aromatic
pH 4.0 - 6.0 at 1 % (23 °C) (deionized water)
Flash point 48 °C
Ignition temperature > 450 °C
The data refer to solvent naphtha petroleum.
Upper explosion limit 7.00 %(V)
The data refer to solvent naphtha petroleum.
Lower explosion limit 0.8 %(V)
The data refer to solvent naphtha petroleum.
Relative vapour density 1.00
The data refer to solvent naphtha petroleum.
Density ca. 0.89 g/cm³ at 20 °C
Water solubility miscible
Partition coefficient: n- Deltamethrin: log Pow: 6.4 at 25 °C
octanol/water
9.2 Other information Further safety related physical-chemical data are not known.
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SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
Thermal decomposition Stable under normal conditions.
10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of No hazardous reactions when stored and handled according to

hazardous reactions prescribed instructions.

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Store only in the original container.

10.6 Hazardous No decomposition products expected under normal conditions of use.

decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute oral toxicity LD50 (Rat) 416 mg/kg
Acute inhalation toxicity LC50 (Rat) 2.69 mg/l
Exposure time: 4 h
Irritating to respiratory system.
Acute dermal toxicity LD50 (Rat) > 2,000 mg/kg
Skin irritation Irritating to skin. (Rabbit)
Eye irritation Severe eye irritation. (Rabbit)
Sensitisation Non-sensitizing. (Guinea pig)
Assessment STOT Specific target organ toxicity – single exposure
Deltamethrin: Based on available data, the classification criteria are not met.
Assessment STOT Specific target organ toxicity – repeated exposure
Deltamethrin caused neurobehavioral effects and/or neuropathological changes in animal studies. The
toxic effects of Deltamethrin are related to transient hyperactivity typical for pyrethroid neurotoxicity.
Assessment mutagenicity
Deltamethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.
Assessment carcinogenicity
Deltamethrin was not carcinogenic in lifetime feeding studies in rats and mice.
Assessment toxicity to reproduction
Deltamethrin did not cause reproductive toxicity in a two-generation study in rats.
Assessment developmental toxicity
Deltamethrin caused developmental toxicity only at dose levels toxic to the dams. The developmental
effects seen with Deltamethrin are related to maternal toxicity.
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Aspiration hazard
May be fatal if swallowed and enters airways.
Further information
The toxicological data refer to a similar formulation.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.00925 mg/l
Exposure time: 96 h
Test conducted with a similar formulation.
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 0.00011 mg/l
invertebrates Exposure time: 48 h
Test conducted with a similar formulation.

Toxicity to aquatic plants EC50 (Raphidocelis subcapitata (freshwater green alga)) 60.5 mg/l
Exposure time: 96 h
Test conducted with a similar formulation.
12.2 Persistence and degradability
Biodegradability Deltamethrin:
Not rapidly biodegradable
Koc Deltamethrin: Koc: 10240000
12.3 Bioaccumulative potential
Bioaccumulation Deltamethrin: Bioconcentration factor (BCF) 1,400
Does not bioaccumulate.
12.4 Mobility in soil
Mobility in soil Deltamethrin: Immobile in soil
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Deltamethrin: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulative (vPvB).
12.6 Other adverse effects
Additional ecological No other effects to be mentioned.
information

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product It is best to use all of the product in accordance with label directions. If it
is necessary to dispose of unused product, please follow container label
instructions and applicable local guidelines.
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Contaminated packaging Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using
an integrated pressure rinsing device, or, by manually rinsing three
times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Follow advice on product label and/or leaflet.
Waste key for the unused 02 01 08* agrochemical waste containing hazardous substances
product

SECTION 14: TRANSPORT INFORMATION

ADR/RID/ADN
14.1 UN number 1993
14.2 Proper shipping name FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION)
14.3 Transport hazard class(es) 3
14.4 Packing group III
14.5 Environm. Hazardous Mark YES
Hazard no. 30
Tunnel Code D/E

This classification is in principle not valid for carriage by tank vessel on inland waterways. Please
refer to the manufacturer for further information.

IMDG
14.1 UN number 1993
14.2 Proper shipping name FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION)
14.3 Transport hazard class(es) 3
14.4 Packing group III
14.5 Marine pollutant YES

IATA
14.1 UN number 1993
14.2 Proper shipping name FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION )
14.3 Transport hazard class(es) 3
14.4 Packing group III
14.5 Environm. Hazardous Mark NO

14.6 Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No transport in bulk according to the IBC Code.
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SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Republic of Ireland Regulations
This material may be subject to some or all of the following regulations (and any subsequent
ammendments). Users must ensure that any uses and restrictions as indicated on the label and/or
leaflet are followed.
Supply and Use
European Communities (Prohibition of Certain Active Substances in Plant Protection Products)
Regulations 1981 (SI No 320/1981)
European Communities (Authorization, Placing on the Market, Use and Control of Plant Protection
Products) Regulations 2003 (SI No 83/2003)
European Communities (Classification, Packaging and Labelling of Plant Protection Products and
Biocide Products) Regulations 2001 (SI No 624/2001
2010 Code of Practice for the Safety, Health and Welfare at Work (Chemical Agents) Regulations, 2001
(SI No 619/2001)
Waste Treatment
Landfill Directive
Regulation on Substances That Deplete the Ozone Layer 1994 (EEC/3093/94)
Further information
WHO-classification: II (Moderately hazardous)
15.2 Chemical safety assessment
A chemical safety assessment is not required.

SECTION 16: OTHER INFORMATION

Text of the hazard statements mentioned in Section 3

H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Abbreviations and acronyms
ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
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ATE Acute toxicity estimate

CAS-Nr. Chemical Abstracts Service number
Conc. Concentration
EC-No. European community number
ECx Effective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
ELV Exposure Limit Value
EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
LDx Lethal dose to x %
LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
SI Statutory Instrument
TWA Time weighted average
UN United Nations
WHO World health organisation

The information contained within this Safety Data Sheet is in accordance with the guidelines
established by Regulation (EU) 1907/2006 and Regulation (EU) 2015/830 amending Regulation (EU)
No 1907/2006 and any subsequent amendments. This data sheet complements the user's instructions,
but does not replace them. The information it contains is based on the knowledge available about the
product concerned at the time it was compiled. Users are further reminded of the possible risks of
using a product for purposes other than those for which it was intended. The required information
complies with current EEC legislation. Addressees are requested to observe any additional national
requirements.
Reason for Revision: Safety Data Sheet according to Regulation (EU) No. 2015/830. The
following sections have been revised: Section 2: Hazards Identification.
Section 3: Composition / Information on Ingredients. Section 8:
Exposure Controls / Personal Protection.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.