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Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)


according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 1 / 10

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Article No. (manufacturer/supplier): O10506
Trade name/designation UV-Varnish O10506 Dual Effect
UFI: RQA0-K0Y4-5009-RFR8
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Coating for graphic industry
Uses advised against:
No data available
1.3. Details of the supplier of the safety data sheet
manufacturer
Heidelberger Druckmaschinen AG
Kurfuersten-Anlage 60 Telephone: +49 6221 92 00
69115 Heidelberg - Germany Telefax: +49 6221 92 69 99
Department responsible for information:
Department Consumables
E-mail consumables-msds@heidelberg.com
1.4. Emergency telephone number
Giftinformationszentrum Nord +49 551 19240

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP]
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 2 / H411 Hazardous to the aquatic environment Toxic to aquatic life with long lasting effects.
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms

Warning

Hazard statements
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P273 Avoid release to the environment.
P280 Wear protective gloves and eye protection/face protection.
P391 Collect spillage.
Hazard components for labelling
Poly(oxy-1,2-ethanediyl), a,a'-[(1-
methylethylidene)di-4,1-phenylene]bis[whydroxy-, polymer with 1,3-
diisocyanatomethylbenzene, 2-propenoate
(ester) 3,5,5-trimethylhexanoate (ester)
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
2-Propenoic acid, reaction products with pentaerythritol
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Glycerol, propoxylated, esters with acrylic acid
Supplemental hazard information
not applicable
2.3. Other hazards
This product does not contain a substance that has endocrine disrupting properties with respect to humans as no
components meets the criteria.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 2 / 10

SECTION 3: Composition/information on ingredients


3.2. Mixtures
Description: Mixture of substances listed below with nonhazardous additions
Hazardous ingredients:
Classification according to Regulation (EC) No 1272/2008 [CLP]
EC No.: REACH No.:
CAS No.: Designation weight-%
Index No.: classification: // Remark

2146146-71-4 Poly(oxy-1,2-ethanediyl), a,a'-[(1- 50 < 100


methylethylidene)di-4,1-phenylene]bis[whydroxy-, polymer with 1,3-
diisocyanatomethylbenzene, 2-propenoate
(ester) 3,5,5-trimethylhexanoate (ester)

Skin Sens. 1B H317 / Aquatic Chronic 2 H411


613-584-2 01-2119969511-34-XXXX
64401-02-1 ethoxylated bisphenol A diacrylate 12,5 < 20
Aquatic Chronic 2 H411

157811-87-5 silicone acrylate 5 < 10


Eye Irrit. 2 H319
500-130-2 01-2119490020-53-XXXX
55818-57-0 4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, 2,5 < 5
acrylate
Skin Sens. 1 H317 / Aquatic Chronic 2 H411
500-114-5 01-2119487948-12-XXXX
52408-84-1 Glycerol, propoxylated, esters with acrylic acid 1 < 2,5
Eye Irrit. 2 H319 / Skin Sens. 1 H317
256-032-2 01-2119484613-34-XXXX
42978-66-5 (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate 0,5 < 1
607-249-00-X Eye Irrit. 2 H319 / STOT SE 3 H335 / Skin Irrit. 2 H315 / Skin Sens. 1
H317 / Aquatic Chronic 2 H411
Specific concentration limit (SCL): STOT SE 3 H335 >= 10
629-850-6 01-2119490003-49-XXXX
1245638-61-2 2-Propenoic acid, reaction products with pentaerythritol 0,1 < 0,25
Acute Tox. 4 H302 / Skin Irrit. 2 H315 / Eye Dam. 1 H318 / Skin Sens. 1
H317 / Aquatic Chronic 2 H411
Additional information
Full text of classification: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth,
place in recovery position and seek medical advice.
In case of inhalation
Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial
respiration.
Following skin contact
Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do
not use solvents or thinners. Following skin contact
Conditions to avoid UV-radiation/sunlight
Causes mild skin irritation.
After eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek
medical advice immediately.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 3 / 10

Following ingestion
If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm.
Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
alcohol resistant foam, carbon dioxide fire blanket, Powder, spray mist, (water)
Unsuitable extinguishing media
strong water jet
5.2. Special hazards arising from the substance or mixture
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device. Cool closed containers that are near the source of the fire. Do
not allow water used to extinguish fire to enter drains, ground or waterways.
Additional information
No data available
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see section 13). Clean using cleansing
agents. Do not use solvents.
6.4. Reference to other sections
Observe protective provisions (see section 7 and 8).
SECTION 7: Handling and storage
Persons with a history of skin sensitisation problems should not be employed in any process in which this product is used.
7.1. Precautions for safe handling
Advices on safe handling
Use only in well-ventilated areas. Keep away from heat sources, sparks and open flames. Avoid contact with skin, eyes and
clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using
do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure - no
pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal
protection and safety regulations.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks.
Hints on joint storage
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Protect
from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 4 / 10

only for authorised persons. Store carefully closed containers upright to prevent any leaks. Keep only in the original
container.
7.3. Specific end use(s)
Observe technical data sheet.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limit values
not applicable

DNEL:
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
DNEL long-term dermal (systemic), Workers: 1,7 mg/kg
DNEL long-term inhalative (systemic), Workers: 2,35 mg/m³
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
DNEL long-term dermal (systemic), Workers: 33 mg/kg
DNEL long-term inhalative (systemic), Workers: 1,17 mg/m³
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
DNEL long-term dermal (systemic), Workers: 2,1 mg/kg
DNEL long-term inhalative (systemic), Workers: 7,4 mg/m³
ethoxylated bisphenol A diacrylate
EC No. 613-584-2 / CAS No. 64401-02-1
DNEL long-term dermal (systemic), Workers: 7 mg/kg
DNEL long-term inhalative (systemic), Workers: 12,32 mg/m³
PNEC:
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
PNEC aquatic, freshwater: 0,005 mg/L
PNEC aquatic, marine water: 0,0005 mg/L
PNEC aquatic, intermittent release: 0,046 mg/L
PNEC sediment, freshwater: 0,487 mg/kg
PNEC sediment, marine water: 0,049 mg/kg
PNEC, soil: 0,095 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
PNEC aquatic, freshwater: 0,025 mg/L
PNEC aquatic, marine water: 0,003 mg/L
PNEC sediment, freshwater: 8,96 mg/kg
PNEC sediment, marine water: 0,896 mg/kg
PNEC, soil: 1,78 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
PNEC aquatic, freshwater: 0,0057 mg/L
PNEC aquatic, marine water: 0,0006 mg/L
PNEC sediment, freshwater: 0,078 mg/kg
PNEC sediment, marine water: 0,0078 mg/kg
PNEC, soil: 0,0122 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
2-Propenoic acid, reaction products with pentaerythritol
EC No. 629-850-6 / CAS No. 1245638-61-2
PNEC aquatic, freshwater: 0,0032 mg/L
PNEC aquatic, marine water: 0,0003 mg/L
PNEC sediment, freshwater: 1,73 mg/kg
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 5 / 10

PNEC sediment, marine water: 0,173 mg/kg


PNEC, soil: 0,34 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
ethoxylated bisphenol A diacrylate
EC No. 613-584-2 / CAS No. 64401-02-1
PNEC aquatic, freshwater: 0,006 mg/L
PNEC aquatic, marine water: 0,001 mg/L
PNEC aquatic, intermittent release: 0,06 mg/L
PNEC sediment, freshwater: 0,6216 mg/kg
PNEC sediment, marine water: 0,0622 mg/kg
PNEC, soil: 0,1208 mg/kg
PNEC sewage treatment plant (STP): 1,43 mg/L
8.2. Exposure controls
Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and
solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.
Personal protection equipment
Respiratory protection
If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection
must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection
apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number.
This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter
(i.e. type A1 according to standard EN 14387) is used.
Hand protection
For prolonged or repeated handling the following glove material must be used: Nitrile rubber, NR
Thickness of the glove material: > 0,56 mm; Breakthrough time: > 480 min.
Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove
manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended
glove articles EN ISO 374
Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
Eye/face protection
Wear closely fitting protective glasses in case of splashes.
Body protection
Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.
Protective measures
After contact clean skin thoroughly with water and soap or use appropriate cleanser.
Environmental exposure controls
Do not allow to enter into surface water or drains. See section 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Physical state: Liquid


Colour: colourless
Odour: characteristic
Odour threshold: No data available
Melting point/freezing point: not applicable
Initial boiling point and boiling range: not applicable
Flammability: not determined
Lower and upper explosion limit:
Lower explosion limit: No data available
Upper explosion limit: No data available
Flash point: > 100 °C
Method: DIN 53213
Auto-ignition temperature: not determined
Decomposition temperature: not determined
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 6 / 10

pH at 20 °C: not applicable


Kinematic viscosity (40°C): not determined
Viscosity at 20 °C: 12000 mPa* s
Method: DIN 53019
Solubility(ies):
Water solubility at 20 °C: insoluble
Partition coefficient: n-octanol/water: see section 12
Vapour pressure at 20 °C: not determined
Density and/or relative density:
Density at 20 °C: 1,12 g/cm³
Relative vapour density: not determined
particle characteristics: not applicable
9.2. Other information
solvent content:
Organic solvents: 0,0 weight-%
Solvent separation test: < 3 weight-% (ADR/RID)
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
section 7.
10.3. Possibility of hazardous reactions
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
10.4. Conditions to avoid
This preparation contains material instable under the following conditions: Heat, strong ultraviolet radiation. An exotherm
polymerization of the product may thereby be caused. Avoid unintended contact with it. Hazardous decomposition byproducts
may form with exposure to high temperatures.
10.5. Incompatible materials
not applicable
10.6. Hazardous decomposition products
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
oral, LD50, Rat: > 2000 mg/kg
dermal, LD50, Rabbit: > 2000 mg/kg
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
oral, LD50, Rat: > 2000 mg/kg
Method: OECD 401
dermal, LD50, Rat: > 2000 mg/kg
Glycerol, propoxylated, esters with acrylic acid
oral, LD50, Rat: > 2000 mg/kg
Method: OECD 401
dermal, LD50, Rabbit: > 2000 mg/kg
Method: OECD 402
2-Propenoic acid, reaction products with pentaerythritol
oral, LD50, Rat 540 - 1350 mg/kg
dermal, LD50, Rabbit: > 2000 mg/kg
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 7 / 10

silicone acrylate
oral, LD50, Rat: > 2000 mg/kg
ethoxylated bisphenol A diacrylate
oral, LD50, Rat: > 2000 mg/kg
Method: OECD 423
dermal, LD50, Rat: > 2000 mg/kg
Method: OECD 402
Skin corrosion/irritation; Serious eye damage/eye irritation
Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation
May cause an allergic skin reaction.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Based on available data, the classification criteria are not met.
STOT-single exposure; STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Practical experience/human evidence
The fractions of acrylic resin in the preparation have an irritant effect. Prolonged or repeated contact with the preparation can
lead to irritations of mucous membranes and of skin such as redness, formation of blebs, dermatitis, etc.. Cases of allergic
skin reactions have been observed. Liquid splashes can lead to irritations of the eyes. Inhaling of drolets in the air or aerosols
may lead to irritations of the respiratory tract . Ingestion may cause nausea, weakness and affect the central nervous system.
Overall assessment on CMR properties
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.
11.2. Information on other hazards
Endocrine disrupting properties
This product does not contain a substance that has endocrine disrupting properties with respect to humans as no
components meets the criteria.
SECTION 12: Ecological information
Classification according to Regulation (EC) No 1272/2008 [CLP]
Do not allow to enter into surface water or drains.
12.1. Toxicity
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Fish toxicity, LC50, Leuciscus idus (golden orfe) 4,6 - 10 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: 89 mg/L (48 h)
Algae toxicity, ErC50, Desmodesmus subspicatus: 69,5 mg/L (72 h)
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Fish toxicity, LC50, Danio rerio (zebrafish): > 100 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: > 100 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Selenastrum capricornutum: 105 mg/L (72 h)
Method: OECD 201
Glycerol, propoxylated, esters with acrylic acid
Fish toxicity, LC50, Danio rerio (zebrafish): 5,74 mg/L (96 h)
Method: OECD 203
Daphnia toxicity, EC50, Daphnia magna: 91,4 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Desmodesmus subspicatus: 12,2 mg/L (72 h)
2-Propenoic acid, reaction products with pentaerythritol
Fish toxicity, LC50, Cyprinus carpio (Common Carp): 3,2 mg/L (96 h)
Method: OECD 203
Daphnia toxicity, EC50, Daphnia magna: 13 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: 12 mg/L (96 h)
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 8 / 10

silicone acrylate
Fish toxicity, LC50, Oryzias latipes: 55,1 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: > 100 mg/L (48 h)
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: > 69,2 mg/L (72 h)
ethoxylated bisphenol A diacrylate
Fish toxicity, LC50, Oncorhynchus mykiss (Rainbow trout): > 100 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 6 mg/L (48 h)
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: > 100 mg/L (96 h)
Long-term Ecotoxicity
Toxic to aquatic life with long lasting effects.
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Fish toxicity, NOEC, Pimephales promelas (fathead minnow): 0,25 mg/L (33 d)
Daphnia toxicity, NOEC, Daphnia magna: 0,51 mg/L (21 d)
12.2. Persistence and degradability
Toxicological data are not available.
12.3. Bioaccumulative potential
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Partition coefficient: n-octanol/water: 2,77
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Partition coefficient: n-octanol/water: 1,6 - 3,8
Method: OECD 117
Glycerol, propoxylated, esters with acrylic acid
Partition coefficient: n-octanol/water: 2,52
Method: OECD 107
2-Propenoic acid, reaction products with pentaerythritol
Partition coefficient: n-octanol/water: 1,95 - 3,11
ethoxylated bisphenol A diacrylate
Partition coefficient: n-octanol/water: 3,66 - 4,16
Bioconcentration factor (BCF)
ethoxylated bisphenol A diacrylate
Bioconcentration factor (BCF): 6,46 - 6,92
12.4. Mobility in soil
Toxicological data are not available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Endocrine disrupting properties
No information available.
12.7. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Appropriate disposal / Product
Recommendation
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste
disposal according to directive 2008/98/EC, covering waste and dangerous waste.
List of proposed waste codes/waste designations in accordance with EWC
080111* waste paint and varnish containing organic solvents or
other dangerous substances
*Hazardous waste according to Directive 2008/98/EC (waste framework directive).
Appropriate disposal / Package
Recommendation
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 9 / 10

SECTION 14: Transport information


14.1. UN number or ID number
UN 3082
14.2. UN proper shipping name
Land transport (ADR/RID): Environmentally hazardous substance, liquid, n.o.s.
(Poly(oxy-1,2-ethanediyl), a,a'-[(1-methylethylidene)di-4,1-p
henylene]bis[whydroxy-, polymer with 1,3-diisocyanatomethylb enzene,
2-propenoate(ester) 3,5,5-trimethylhexanoate (ester))
Sea transport (IMDG): ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Poly(oxy-1,2-ethanediyl), a,a'-[(1-methylethylidene)di-4,1-p
henylene]bis[whydroxy-, polymer with 1,3-diisocyanatomethylb enzene,
2-propenoate(ester) 3,5,5-trimethylhexanoate (ester))
Air transport (ICAO-TI / IATA-DGR): Environmentally hazardous substance, liquid, n.o.s.
(Poly(oxy-1,2-ethanediyl), a,a'-[(1-methylethylidene)di-4,1-p
henylene]bis[whydroxy-, polymer with 1,3-diisocyanatomethylb enzene,
2-propenoate(ester) 3,5,5-trimethylhexanoate (ester))
14.3. Transport hazard class(es)
9
14.4. Packing group
III
14.5. Environmental hazards
Land transport (ADR/RID) UMWELTGEFÄHRDEND
Marine pollutant p / Poly(oxy-1,2-ethanediyl),
a,a'-[(1-methylethylidene)di-4,1-phenylene]bis[whydroxy-, polymer with
1,3-diisocyanatomethylb
14.6. Special precautions for user
Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in
case of an accident or leakage.
Advices on safe handling: see parts 6 - 8
Further information

Land transport (ADR/RID)


Tunnel restriction code -

in packages <= 5 litres Kein Gut der Klasse 9


Sea transport (IMDG)
EmS-No. F-A, S-F
in packages <= 5 litres not restricted 2.10.2.7
Air transport (ICAO-TI / IATA-DGR)
in packages <= 5 litres Not Restricted, as per Special Provision A197
14.7. Maritime transport in bulk according to IMO instruments
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
Directive 2010/75/EU on industrial emissions [Industrial Emissions Directive]
VOC-value (in g/L): 0,024
National regulations
Restrictions of occupation
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juveniles according to the 'juvenile work protection guideline' (94/33/EC).
15.2. Chemical Safety Assessment
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878

Article No.: O10506 UV-Varnish O10506 Dual Effect


Print date: 07.05.2024 423290 GE
Version: 15.0 Issue date: 03.11.2023 Page 10 / 10

Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Full text of classification in section 3:
Skin Sens. 1B / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 2 / H411 Hazardous to the aquatic environment Toxic to aquatic life with long lasting effects.
Eye Irrit. 2 / H319 Serious eye damage/eye irritation Causes serious eye irritation.
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
STOT SE 3 / H335 STOT-single exposure May cause respiratory irritation.
Skin Irrit. 2 / H315 Skin corrosion/irritation Causes skin irritation.
Acute Tox. 4 / H302 Acute toxicity (oral) Harmful if swallowed.
Eye Dam. 1 / H318 Serious eye damage/eye irritation Causes serious eye damage.
Classification procedure
Classification for mixtures and used evaluation method according to regulation (EC) No 1272/2008 [CLP]
Skin Sens. 1 Respiratory or skin sensitisation Calculation method.
Aquatic Chronic 2 Hazardous to the aquatic environment Calculation method.
Abbreviations and acronyms
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
OEL Occupational Exposure Limit Value
BLV Biological Limit Value
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging
CMR Carcinogenic, Mutagenic and Reprotoxic
DIN German Institute for Standardization / German industrial standard
DNEL Derived No-Effect Level
EAKV European Waste Catalogue Directive
EC Effective Concentration
EC European Community
EN European Standard
IATA-DGR International Air Transport Association – Dangerous Goods Regulations
IBC Code International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk
ICAO-TI International Civil Aviation Organization Technical Instructions for the Safe Transport of Dangerous
Goods by Air
IMDG Code International Maritime Code for Dangerous Goods
ISO International Organization for Standardization
LC Lethal Concentration
LD Lethal Dose
MARPOL Maritime Pollution: The International Convention for the Prevention of Pollution from Ships
OECD Organisation for Economic Cooperation and Development
PBT persistent, bioaccumulative, toxic
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
UN United Nations
VOC Volatile Organic Compounds
vPvB very persistent and very bioaccumulative
Further information
Classification according to Regulation (EC) No 1272/2008 [CLP]

The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations.Without written approval, the product must not be used for purposes different from those mentioned in section
1.It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and
regulations.The details in this safety data sheet describe the safety requirements of our product and are not to be regarded
as guaranteed attributes of the product.

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