SDFSD
SDFSD
SDFSD
Warning
Hazard statements
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P273 Avoid release to the environment.
P280 Wear protective gloves and eye protection/face protection.
P391 Collect spillage.
Hazard components for labelling
Poly(oxy-1,2-ethanediyl), a,a'-[(1-
methylethylidene)di-4,1-phenylene]bis[whydroxy-, polymer with 1,3-
diisocyanatomethylbenzene, 2-propenoate
(ester) 3,5,5-trimethylhexanoate (ester)
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
2-Propenoic acid, reaction products with pentaerythritol
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Glycerol, propoxylated, esters with acrylic acid
Supplemental hazard information
not applicable
2.3. Other hazards
This product does not contain a substance that has endocrine disrupting properties with respect to humans as no
components meets the criteria.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
Following ingestion
If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm.
Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
alcohol resistant foam, carbon dioxide fire blanket, Powder, spray mist, (water)
Unsuitable extinguishing media
strong water jet
5.2. Special hazards arising from the substance or mixture
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device. Cool closed containers that are near the source of the fire. Do
not allow water used to extinguish fire to enter drains, ground or waterways.
Additional information
No data available
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see section 13). Clean using cleansing
agents. Do not use solvents.
6.4. Reference to other sections
Observe protective provisions (see section 7 and 8).
SECTION 7: Handling and storage
Persons with a history of skin sensitisation problems should not be employed in any process in which this product is used.
7.1. Precautions for safe handling
Advices on safe handling
Use only in well-ventilated areas. Keep away from heat sources, sparks and open flames. Avoid contact with skin, eyes and
clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When using
do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure - no
pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal
protection and safety regulations.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks.
Hints on joint storage
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Protect
from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
only for authorised persons. Store carefully closed containers upright to prevent any leaks. Keep only in the original
container.
7.3. Specific end use(s)
Observe technical data sheet.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limit values
not applicable
DNEL:
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
DNEL long-term dermal (systemic), Workers: 1,7 mg/kg
DNEL long-term inhalative (systemic), Workers: 2,35 mg/m³
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
DNEL long-term dermal (systemic), Workers: 33 mg/kg
DNEL long-term inhalative (systemic), Workers: 1,17 mg/m³
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
DNEL long-term dermal (systemic), Workers: 2,1 mg/kg
DNEL long-term inhalative (systemic), Workers: 7,4 mg/m³
ethoxylated bisphenol A diacrylate
EC No. 613-584-2 / CAS No. 64401-02-1
DNEL long-term dermal (systemic), Workers: 7 mg/kg
DNEL long-term inhalative (systemic), Workers: 12,32 mg/m³
PNEC:
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Index No. 607-249-00-X / EC No. 256-032-2 / CAS No. 42978-66-5
PNEC aquatic, freshwater: 0,005 mg/L
PNEC aquatic, marine water: 0,0005 mg/L
PNEC aquatic, intermittent release: 0,046 mg/L
PNEC sediment, freshwater: 0,487 mg/kg
PNEC sediment, marine water: 0,049 mg/kg
PNEC, soil: 0,095 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
EC No. 500-130-2 / CAS No. 55818-57-0
PNEC aquatic, freshwater: 0,025 mg/L
PNEC aquatic, marine water: 0,003 mg/L
PNEC sediment, freshwater: 8,96 mg/kg
PNEC sediment, marine water: 0,896 mg/kg
PNEC, soil: 1,78 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
Glycerol, propoxylated, esters with acrylic acid
EC No. 500-114-5 / CAS No. 52408-84-1
PNEC aquatic, freshwater: 0,0057 mg/L
PNEC aquatic, marine water: 0,0006 mg/L
PNEC sediment, freshwater: 0,078 mg/kg
PNEC sediment, marine water: 0,0078 mg/kg
PNEC, soil: 0,0122 mg/kg
PNEC sewage treatment plant (STP): 10 mg/L
2-Propenoic acid, reaction products with pentaerythritol
EC No. 629-850-6 / CAS No. 1245638-61-2
PNEC aquatic, freshwater: 0,0032 mg/L
PNEC aquatic, marine water: 0,0003 mg/L
PNEC sediment, freshwater: 1,73 mg/kg
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
silicone acrylate
oral, LD50, Rat: > 2000 mg/kg
ethoxylated bisphenol A diacrylate
oral, LD50, Rat: > 2000 mg/kg
Method: OECD 423
dermal, LD50, Rat: > 2000 mg/kg
Method: OECD 402
Skin corrosion/irritation; Serious eye damage/eye irritation
Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation
May cause an allergic skin reaction.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Based on available data, the classification criteria are not met.
STOT-single exposure; STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Practical experience/human evidence
The fractions of acrylic resin in the preparation have an irritant effect. Prolonged or repeated contact with the preparation can
lead to irritations of mucous membranes and of skin such as redness, formation of blebs, dermatitis, etc.. Cases of allergic
skin reactions have been observed. Liquid splashes can lead to irritations of the eyes. Inhaling of drolets in the air or aerosols
may lead to irritations of the respiratory tract . Ingestion may cause nausea, weakness and affect the central nervous system.
Overall assessment on CMR properties
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.
11.2. Information on other hazards
Endocrine disrupting properties
This product does not contain a substance that has endocrine disrupting properties with respect to humans as no
components meets the criteria.
SECTION 12: Ecological information
Classification according to Regulation (EC) No 1272/2008 [CLP]
Do not allow to enter into surface water or drains.
12.1. Toxicity
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Fish toxicity, LC50, Leuciscus idus (golden orfe) 4,6 - 10 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: 89 mg/L (48 h)
Algae toxicity, ErC50, Desmodesmus subspicatus: 69,5 mg/L (72 h)
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Fish toxicity, LC50, Danio rerio (zebrafish): > 100 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: > 100 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Selenastrum capricornutum: 105 mg/L (72 h)
Method: OECD 201
Glycerol, propoxylated, esters with acrylic acid
Fish toxicity, LC50, Danio rerio (zebrafish): 5,74 mg/L (96 h)
Method: OECD 203
Daphnia toxicity, EC50, Daphnia magna: 91,4 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Desmodesmus subspicatus: 12,2 mg/L (72 h)
2-Propenoic acid, reaction products with pentaerythritol
Fish toxicity, LC50, Cyprinus carpio (Common Carp): 3,2 mg/L (96 h)
Method: OECD 203
Daphnia toxicity, EC50, Daphnia magna: 13 mg/L (48 h)
Method: OECD 202
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: 12 mg/L (96 h)
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
silicone acrylate
Fish toxicity, LC50, Oryzias latipes: 55,1 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna: > 100 mg/L (48 h)
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: > 69,2 mg/L (72 h)
ethoxylated bisphenol A diacrylate
Fish toxicity, LC50, Oncorhynchus mykiss (Rainbow trout): > 100 mg/L (96 h)
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 6 mg/L (48 h)
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: > 100 mg/L (96 h)
Long-term Ecotoxicity
Toxic to aquatic life with long lasting effects.
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Fish toxicity, NOEC, Pimephales promelas (fathead minnow): 0,25 mg/L (33 d)
Daphnia toxicity, NOEC, Daphnia magna: 0,51 mg/L (21 d)
12.2. Persistence and degradability
Toxicological data are not available.
12.3. Bioaccumulative potential
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
Partition coefficient: n-octanol/water: 2,77
4,4'-(1-methylethylidene)bisphenol, polymer with (chloromethyl)oxirane, acrylate
Partition coefficient: n-octanol/water: 1,6 - 3,8
Method: OECD 117
Glycerol, propoxylated, esters with acrylic acid
Partition coefficient: n-octanol/water: 2,52
Method: OECD 107
2-Propenoic acid, reaction products with pentaerythritol
Partition coefficient: n-octanol/water: 1,95 - 3,11
ethoxylated bisphenol A diacrylate
Partition coefficient: n-octanol/water: 3,66 - 4,16
Bioconcentration factor (BCF)
ethoxylated bisphenol A diacrylate
Bioconcentration factor (BCF): 6,46 - 6,92
12.4. Mobility in soil
Toxicological data are not available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Endocrine disrupting properties
No information available.
12.7. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Appropriate disposal / Product
Recommendation
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste
disposal according to directive 2008/98/EC, covering waste and dangerous waste.
List of proposed waste codes/waste designations in accordance with EWC
080111* waste paint and varnish containing organic solvents or
other dangerous substances
*Hazardous waste according to Directive 2008/98/EC (waste framework directive).
Appropriate disposal / Package
Recommendation
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2020/878
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Full text of classification in section 3:
Skin Sens. 1B / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Aquatic Chronic 2 / H411 Hazardous to the aquatic environment Toxic to aquatic life with long lasting effects.
Eye Irrit. 2 / H319 Serious eye damage/eye irritation Causes serious eye irritation.
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
STOT SE 3 / H335 STOT-single exposure May cause respiratory irritation.
Skin Irrit. 2 / H315 Skin corrosion/irritation Causes skin irritation.
Acute Tox. 4 / H302 Acute toxicity (oral) Harmful if swallowed.
Eye Dam. 1 / H318 Serious eye damage/eye irritation Causes serious eye damage.
Classification procedure
Classification for mixtures and used evaluation method according to regulation (EC) No 1272/2008 [CLP]
Skin Sens. 1 Respiratory or skin sensitisation Calculation method.
Aquatic Chronic 2 Hazardous to the aquatic environment Calculation method.
Abbreviations and acronyms
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
OEL Occupational Exposure Limit Value
BLV Biological Limit Value
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging
CMR Carcinogenic, Mutagenic and Reprotoxic
DIN German Institute for Standardization / German industrial standard
DNEL Derived No-Effect Level
EAKV European Waste Catalogue Directive
EC Effective Concentration
EC European Community
EN European Standard
IATA-DGR International Air Transport Association – Dangerous Goods Regulations
IBC Code International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk
ICAO-TI International Civil Aviation Organization Technical Instructions for the Safe Transport of Dangerous
Goods by Air
IMDG Code International Maritime Code for Dangerous Goods
ISO International Organization for Standardization
LC Lethal Concentration
LD Lethal Dose
MARPOL Maritime Pollution: The International Convention for the Prevention of Pollution from Ships
OECD Organisation for Economic Cooperation and Development
PBT persistent, bioaccumulative, toxic
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
UN United Nations
VOC Volatile Organic Compounds
vPvB very persistent and very bioaccumulative
Further information
Classification according to Regulation (EC) No 1272/2008 [CLP]
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations.Without written approval, the product must not be used for purposes different from those mentioned in section
1.It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules and
regulations.The details in this safety data sheet describe the safety requirements of our product and are not to be regarded
as guaranteed attributes of the product.