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Lipids

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LIPIDS

LIPIDS
• Lipids are organic substances that include
fats and fat-like substances, such as
phospholipids, wax, steroid, and
sphingolipids.
• Lipids are generally hydrophobic substance
and insoluble in water but soluble in
organic solvents, like benzene, ether, and
chloroform
• The general formula CH3(CH2)nCOOH.
Functions of Lipids
• Solvent for fat-soluble vitamins and
hormones.
• Prevents water loss from skin surface.
• Essential parts of cell structures such as
cell membranes.
• Insulating material to prevent heat loss
and protection against extreme cold.
• Source and storage of energy.
TYPES OF LIPIDS
1. Triglycerides
2. Phospholipids
3. Steroids
4. Waxes
5. Sphingolipids
Building Blocks of Lipids
Fatty Acids
✓ Organic acid (chain of carbons
with hydrogens attached) that has
an acid group at one end & a
methyl group at the other end

Copyright 2005 Wadsworth Group, a division of Thomson Learning


TRIGLYCERIDES
✓ Triglycerides – Fats & Oils
1. Predominate form of fat in foods
and major storage form of fat in
the body
2. Structure – composed of 3 fatty
acids + glycerol
Fatty Acids & Triglycerides
✓ glycerol + 3 fatty acids → triglyceride + H2O

An ester bond connects the glycerol and the


fatty acids.
TYPES OF FATTY ACIDS
▪ Saturated fatty acid – carbon chains
filled with hydrogen atoms (no C=C
double bonds)
1. Saturated fat – triglyceride
containing 3 saturated fatty
acids, such as animal fats
(butter, lard) & tropical oils
(palm, coconut)
2. Appear solid at room temperature
FATTY ACIDS
▪ Unsaturated fatty acid – carbon chains lack some
hydrogens (>1 C=C double bond)
1. Monounsaturated fat – triglyceride containing fatty
acids with 1 double bond; i.e. canola & olive oil
2. Polyunsaturated fat- triglycerides
containing a high % of fatty acids with
>2 double bonds; i.e. corn, safflower, soybean,
sunflower oils and fish;
3. Appear liquid at room temperature
4. Mainly found in plant and are healthier source of fats.
PHOSPHOLIPIDS
✓ Phospholipids – similar
to triglycerides in structure
except only 2 fatty acids +
choline
Phospholipids in foods:
Lecithin, egg yolks, soybeans,
wheat germ, peanuts
Lecithin

Copyright 2005 Wadsworth Group, a division of Thomson Learning


Phospholipids
1. Functions: part of cell
membranes and acts as
an emulsifier (helps
keep fats in solution)
2. Not a dietary essential;
made by the liver
Phospholipids

Copyright 2005 Wadsworth Group, a division of Thomson Learning


STEROIDS
▪ Important part of:
1. Sex hormones – testosterone
2. Vitamin D
3. Bile (aids fat digestion)
4. Cholesterol – in foods and
made by the liver; dietary
sources include egg yolks,
liver, meats, dairy products
Wax
• Important components for many
organisms, such as cuticle covering the
surface of leaves and stems of plants
• Protective coverings on the skin and fur of
some animals.
Sphingolipids
• Found in brain, lungs, and nerve tissues
• Serve as surfactants that help reduce
tension on the lungs to maintain the right
shape.
Fat Digestion
✓ Hydrolysis
✓ Triglycerides →
monoglycerides, fatty acids,
glycerol

Copyright 2005 Wadsworth Group, a division of Thomson Learning


Fat Digestion

Copyright 2005 Wadsworth Group, a division of Thomson Learning


Health Effects of Fats
✓ Excess fat intake contributes to many diseases
including:
1. Obesity
2. Diabetes
3. Cancer
4. Heart disease
▪ How?
1. High fat diets = high kcal diets
2. High saturated fat intake raises
blood cholesterol
3. High fat intakes may promote cancer

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