Designation: B386 − 03 (Reapproved 2011)

Standard Specification for

Molybdenum and Molybdenum Alloy Plate,
Sheet, Strip, and Foil1
This standard is issued under the fixed designation B386; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 3.1.2 sheet, n—any product 0.187 in. (4.75 mm) or less in
1.1 This specification covers unalloyed molybdenum and thickness, to a minimum of 0.005 in. (0.13 mm) in thickness.
molybdenum alloy plate, sheet, strip, and foil as follows: 3.1.2.1 standard grade, n—sheet ordered without additional
1.1.1 Molybdenum 360—Unalloyed vacuum arc-cast mo- requirements imposed for applications which require drawing
lybdenum. to make a product.
1.1.2 Molybdenum 361—Unalloyed powder metallurgy mo- 3.1.2.2 drawing grade, n—sheet having thickness between
lybdenum. 0.015 in. (0.38 mm) and 0.060 in. (1.52 mm), intended for
1.1.3 Molybdenum Alloy 363—Vacuum arc-cast molybde- applications which require drawing of the sheet ot make a
num-0.5 % titanium-0.1 % zirconium (TZM) alloy. product.
1.1.4 Molybdenum Alloy 364—Powder metallurgy molyb- 3.1.3 strip, n—any product 0.187 in. (4.75 mm) or less in
denum-0.5 % titanium-0.1 % zirconium (TZM) alloy. thickness and less than 5 in. (127 mm) in width.
1.1.5 Molybdenum 365—Unalloyed vacuum arc-cast
molybdenum, low carbon. 3.1.4 foil, n—any product less than 0.005 in. (0.13 mm) in
1.1.6 Molybdenum Alloy 366—Vacuum arc-cast molybde- thickness.
num-30 % tungsten alloy.
1.1.7 Drawing Grade—A drawing grade is defined, which 4. Ordering Information
may be specified as a separate requirement by the purchaser. 4.1 Orders for material under this specification shall include
1.2 The values stated in inch-pound units are to be regarded the following information as applicable:
as standard. The values given in parentheses are mathematical 4.1.1 Material number and temper designation (Section 1
conversions to SI units that are provided for information only and Table 1),
and are not considered standard. 4.1.2 Product form and grade (Section 3),
4.1.3 Chemical requirements (Table 2 and Table 3),
2. Referenced Documents 4.1.4 Mechanical requirements (Section 7 and Table 1),
2.1 ASTM Standards:2 4.1.5 Softening temperature (Section 8),
E8 Test Methods for Tension Testing of Metallic Materials 4.1.6 Tolerances (Section 9, Table 4 and Fig. 1),
E345 Test Methods of Tension Testing of Metallic Foil 4.1.7 Workmanship and quality level requirements (Section
E643 Test Method for Ball Punch Deformation of Metallic 10),
Sheet Material 4.1.8 Packaging (Section 16),
4.1.9 Marking (Section 15),
3. Terminology 4.1.10 Certification and reports (Section 14), and
4.1.11 Disposition of rejected material (Section 13).
3.1 Definitions of Terms Specific to This Standard:
3.1.1 plate, n—any product 3⁄16 in. or more in thickness.
5. Materials and Manufacture
5.1 The various molybdenum mill products covered by this
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This specification is under the jurisdiction of ASTM Committee B10 on specification shall be formed with the conventional extrusion,
Reactive and Refractory Metals and Alloys and is the direct responsibility of forging, or rolling equipment normally found in primary
Subcommittee B10.04 on Molybdenum and Tungsten.
Current edition approved June 1, 2011. Published June 2011. Originally ferrous and nonferrous plants. The ingot metal for Molybde-
approved in 1991. Last previous edition approved in 2003 as B386 – 03. DOI: num 360 and 365 and Molybdenum Alloys 363 and 366 is
10.1520/B0386-03R11. vacuum arc-melted in furnaces of a type suitable for reactive,
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
refractory metals and for Molybdenum 361 and Molybdenum
Standards volume information, refer to the standard’s Document Summary page on Alloy 364, the metal is consolidated by powder metallurgy
the ASTM website. methods.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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 B386 − 03 (2011)
TABLE 1 Mechanical Requirements
Yield Elonga-
TensileB Strength tion in 2 Minimum
Temper Strength,
Type Thickness, in. (mm) 0.2 % Offset, in. or 50 Bend Ra-
ConditionA min, ksi
(MPa) min, mm, min, dius
ksi (MPa) %
to 0.001 (0.025) 115 (795) 95 (655) 1 ...
over 0.001 to 0.002 (0.025 to 0.05) 115 (795) 95 (655) 2 ...
over 0.002 to 0.003 (0.05 to 0.075) 115 (795) 95 (655) 3 ...
over 0.003 to 0.004 (0.075 to 0.1) 115 (795) 95 (655) 4 ...
0.005 to 0.010 (0.13 to 0.25) 110 (760) 90 (620) 5 2tC
over 0.010 to 0.020 (0.25 to 0.5) 110 (760) 90 (620) 6 2t
SR
360, 361, 365 over 0.020 to 0.060 (0.5 to 1.5) 105 (725) 85 (585) 10 2t
over 0.060 to 0.100 (1.5 to 2.5) 100 (690) 80 (550) 14 2t
over 0.100 to 0.187 (2.5 to 4.75) 100 (690) 80 (550) 18 2t
3⁄16 to 1⁄2 (4.75 to 12.7) 100 (690) 80 (550) 10 ...
over 1⁄2 to 1 (12.7 to 25.4) 95 (655) 80 (550) 2D ...
over 1 to 11⁄2 (25.4 to 38) 95 (655) 80 (550) 1D ...
363, 364 SR 0.010 to 0.025 (0.25 to 0.635) 120 (830) 100 (690) 6 2t
over 0.025 to 0.060 (0.635 to 1.5) 120 (830) 100 (690) 7 2t
over 0.060 to 0.090 (1.5 to 2.3) 120 (830) 100 (690) 9 ...
over 0.090 to 0.187 (2.3 to 4.75) 120 (830) 100 (690) 10 ...
3⁄16 to 1⁄2 (4.75 to 12.7) 120 (830) 100 (690) 10 ...
over 1⁄2 to 1 (12.7 to 25.4) 110 (760) 95 (655) 10 ...
over 1 to 11⁄2 (25.4 to 38) 100 (690) 85 (585) 8 ...
360 RX 3 16
⁄ to 11⁄2 (4.75 to 38) 55 (380) 25 (170) 20 ...
363, 364 RX 3 16
⁄ to 11⁄2 (4.75 to 38) 75 (515) 45 (310) 10 ...
A
SR = stress-relieved. RX = essentially fully recrystallized.
B
Both longitudinal and transverse tests between 65 and 85°F (18 and 29°C).
C
Material thickness = t.
D
Transverse elongation variable due to cross rolling limitations.
TABLE 2 Chemical Requirements
Composition,%
Element Material Number
360 361 363 364 365 366
C 0.030 max 0.010 max 0.010–0.030 0.010–0.040 0.010 max 0.030 max
O, maxA 0.0015 0.0070 0.0030 0.030 0.0015 0.0025
N, maxA 0.002 0.002 0.002 0.002 0.002 0.002
Fe, max 0.010 0.010 0.010 0.010 0.010 0.010
Ni, max 0.002 0.005 0.002 0.005 0.002 0.002
Si, max 0.010 0.010 0.010 0.005 0.010 0.010
Ti ... ... 0.40–0.55 0.40–0.55 ... ...
W ... ... ... ... ... 27–33
Zr ... ... 0.06–0.12 0.06–0.12 ... ...
Mo balance balance balance balance balance balance
A
Pending approved methods of analysis, deviations from these limits alone shall not be cause for rejection.
6. Chemical Composition 6.2.3 The manufacturer shall not ship material that is
6.1 The molybdenum and molybdenum alloy ingots and outside the limits specified in Table 2 for the applicable type,
billets for conversion to finished products covered by this with the exception of oxygen and nitrogen, whose percentage
specification shall conform to the requirements of the chemical may vary with the method of fabrication.
composition prescribed in Table 2. 6.2.4 Check analysis limits shall be as specified in Table 3.
6.2 Check Analysis: 7. Mechanical Properties
6.2.1 Check analysis is an analysis made by the purchaser or
the manufacturer of the metal after it has been processed into 7.1 Material supplied under this specification shall conform
finished mill forms, and is either for the purpose of verifying to the mechanical property requirements given in Table 1,
the composition of a heat or lot or to determine variations in the when tested in the transverse direction to final working at test
composition within a heat or lot. temperatures between 65 and 85°F (18 and 29°C).
6.2.2 Check analysis tolerances do not broaden the specified 7.2 Tension test specimens shall be prepared and tested in
heat analysis requirements but cover variations between labo- accordance with Test Methods E8 or E345 for foil. Tensile
ratories in the measurement of chemical content. properties shall be determined using a strain rate of 0.002 to
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 B386 − 03 (2011)
TABLE 3 Permissible Variations in Check Analysis 9.4 Flatness tolerances on molybdenum and molybdenum
Check Permissible alloy flat products shall be as follows:
Analysis Variations
Material No. Flatness
Limits, in Check
max or range, % Analysis, % Deviation,
Thickness, in. (mm) max, %
C 360, 363, 364, 366, 0.010–0.040 ±0.005
361, 365 0.010 ±0.002 0.005 to 0.187 (0.13 to 4.75) 4
OA 361 0.0070 +10 % relative 3⁄16 to 1⁄2 (4.75 to 12.7) 5
360, 363, 365, 366 0.0030 +10 % relative Over 1⁄2 to 1 (over 12.7 to 25.4) 8
364 0.030 +10 % relative Over 1 to 11⁄2 (over 25.4 to 38) 8
NA 361, 364, 365 0.0020 +0.0005
360, 363, 366 0.0010 +0.0005 9.4.1 Determine flatness deviation as follows: (Fig. 1)
Fe 360, 361, 363, 364, 365, 366 0.010 +0.001
Ni 360, 361, 363, 364, 365, 366 0.005 +0.0005 Flatness deviation, % 5 ~ H/L ! 3 100 (1)
Si 360, 361, 363, 364, 365, 366 0.010 +0.002
Ti 363, 364 0.40–0.55 ±0.05 where:
W 366 27.0–33.0 ±1.0 H = maximum vertical distance between a flat reference
Zr 363, 364 0.06–0.12 ±0.02
surface and the lower surface of the flat product, and
A A
See Table 2, Footnote L = minimum horizontal distance between the highest point
of the flat product where H is determined, and the point
of contact of the lower surface of the flat product with
a flat reference surface.
0.005 in./in.·min (or mm/mm·min) through 0.6 % offset and
0.02 to 0.05 in/in·min (or mm/mm·min) to fracture. 10. Workmanship, Finish, and Appearance
7.3 For sheet and strip, the bend test specimens shall 10.1 Molybdenum and molybdenum alloy plate, sheet, strip,
withstand being bent at a temperature between 65 and 85°F (18 and foil shall be free of injurious external and internal
and 29°C) through an angle of 90° or more without fracture. imperfections of a nature that will interfere with the purpose
The bend shall be made on a radius equal to that shown in for which it is intended.
Table 3 for the applicable type. The bend test specimen shall be 10.2 Material may be supplied with as rolled, as cleaned, as
at least 0.5 in. (12.7 mm) wide and deburred. The speed of the machined, or as ground finish.
ram shall be 5 to 10 in. (127 to 254 mm)/min. 10.3 The manufacturer shall be permitted to remove surface
7.4 For sheet ordered as drawing grade, ball punch defor- imperfections provided such removal does not reduce the
mation tests shall be performed in accordance with Test dimensions below the minimum permitted by the tolerances for
Method E643. Drawing grade sheet shall meet the require- that dimension.
ments of Fig. 2.
11. Sampling
8. Softening Temperature 11.1 Care shall be exercised to ensure that the sample
8.1 If specified, the material supplied under this specifica- selected for testing is representative of the material and form
tion shall have mechanical properties not lower than those and is not contaminated by the sampling procedure.
shown in Table 1 after reheating in a protective atmosphere to
the following temperatures for a period of 30 min. 12. Methods of Chemical Analysis
Alloy Type °F °C 12.1 The chemical composition enumerated in this specifi-
cation shall in case of disagreement, be determined in accor-
360 1650 900
dance with the methods approved for referee purposes by
361 1650 900
363 2100 1150 ASTM. Where such methods are not available, methods of
364 2100 1150 analysis as mutually agreed upon by the manufacturer and the
365 1650 900
366 1900 1040
purchaser shall be employed.
13. Rejection
9. Permissible Variations in Dimensions
13.1 Material not conforming to this specification or to
9.1 Thickness tolerances on molybdenum and molybdenum
authorized modifications shall be subject to rejection. Unless
alloy material covered by this specification shall be as specified
otherwise specified, rejected material may be returned to the
in Table 4.
manufacturer at the manufacturer’s expense unless the pur-
9.2 Width tolerances shall be as agreed upon between the chaser receives, within 4 weeks of notice of rejection, other
manufacturer and the purchaser. In general, shearing tolerance instructions for disposition.
will be 61⁄16 in. (61.6 mm) and slitting tolerance will be 61⁄32
in. (60.8 mm). 14. Certification
9.3 Length and camber tolerances shall be as agreed upon 14.1 If requested, the manufacturer shall supply at least
between the manufacturer and the purchaser. In general, length three copies of a report of the chemical analysis of each heat
and camber tolerances will show a maximum deviation of 61⁄16 (Types 360, 363, 365, and 366) or powder metallurgy product
in. (1.6 mm) per foot length. from the powder lot (Types 361 and 364) represented in the
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 B386 − 03 (2011)
TABLE 4 Permissible Thickness Variations of Plate, Sheet, Strip and Foil
Thickness Tolerance,A in.
Specified Width, in. (mm) Specified Thickness, in. (mm) (mm)
12 (305) and under 0.005 to 0.010 (0.13 to 0.25), incl ±0.001 (±0.0254)
over 0.010 to 0.020 (0.25 to 0.51), incl ±0.002 (±0.0508)
over 0.020 (0.51) ±10 %
Over 12 to 24 (305 to 610), incl over 0.010 to 0.025 (0.25 to 0.64), incl ±0.0025 (±0.0635)
over 0.025 (0.64) ±10 %
Over 24 to 30 (610 to 762), incl over 0.016 to 0.030 (0.41 to 0.76), incl ±0.003 (±0.0762)
over 0.030 (0.76) ±10 %
Over 30 to 48 (762 to 1219), incl 0.040 (1.02) and over ±10 %
0.1875 (4.762) and over ±10 %
A
Tolerances for foil shall be as agreed upon between producer and purchaser.
FIG. 1 Plate and Sheet Flatness Tolerances
temper condition, nominal thickness, and quantity and number
of items covered by the shipment.
15. Product Marking
15.1 Unless otherwise specified, each plate, sheet, or strip
shall be legibly and conspicuously marked or tagged with the
number of this specification, material type and temper
condition, heat or lot number, manufacturer’s identification,
and the nominal thickness gage in inches. All markings must
withstand ordinary handling and shall be capable of removal
with standard cleaning solvents.
15.2 Coiled sheet, strip, and foil shall be similarly marked at
the outside end of each coil.
16. Packaging and Package Marking
FIG. 2 Ball Punch Deformation Requirements for Drawing Grade 16.1 Unless otherwise specified, material purchased under
Sheet this specification must be packaged by box or other suitable
protective containers and shall be so marked as to indicate the
shipment, and reports of the result of tests of each size of each nature of any special handling required.
heat or powder lot to determine properties required in Sections
7 and 8. 17. Keywords
14.2 The report shall include the purchase order number, 17.1 drawing grade sheet; foil; molybdenum; molybdenum
heat or powder lot number, this specification number, type and alloy; plate; sheet; strip
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 B386 − 03 (2011)
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