VIBRANT ACADEMY ORGANIC CHEMISTRY

Class Test-6
(India) Private Limited Target IIT JEE 2024
CLASS : XII (MEGA)

Topic : Reaction of Alkene (Ozonolysis) Hydrocarbon

Single Choice Questions :
1. Ozonolysis gas used is
(A) O2
(B) O3

2. In ozonolysis of alkene and alkyne undergo

(A) Oxidation
(B) Reduction

3. In ozonolysis reaction alkene is

(A) Nucleophile
(B) Electrophile

4. In ozonolysis reaction ozone is

(A) Electrophile
(B) Nucleophile

5. Reaction of ozone with alkene at very low temp give

(A) Molozonide
(B) ozonide

6. Reaction of ozone with cis 2 butene give molozonide which is

(A) Racemic
(B) Meso

7. Reaction of trans-2-butene with ozone give molozonide which is

(A) Meso
(B) Racemic

8. Number of ozonide formed when ethene undergo ozonolysis

(A) 1
(B) 2

9. Number of ozonide formed when propene undergo ozonolysis

(A) 2 (B) 4 (C) 6

10. Number of ozonide formed when but -2-ene undergo ozonolysis

(A) 1 (B) 2 (C) 3

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11. Number of product obtained are

H H
(1) O3
(2) (CH3)2S

(A) 1 (B) 2 (C) 3

12. Which of above is reductive ozonolysis ?

H CH2CH3 reductive H H3CH2C

workup C O
C C C O+
(1) + O3
H H H H

H CH3 reductive H H3C

workup
C C C O+ C O
(2) + O3
H CH3 H H3C

H3C C3H7 reductive H3C C3H7

workup C O
C C C O+
(3) + O3
H C3H7
H C3H7

O
CH3 reductive
workup C CH3
(4) + O3 H3C C
CH3 CH2

(A) All (B) None

13. Major product is

COOH
COOH

Phthalic acid
COOH
N2
COOH

N
Cinchomeronic acid

(A) Upper (B) Lower

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14. Number of molozonide in abve reaction

O
+ O3 O O

O
O O

(A) 1 (B) 2

15. Above step is

O
O C
C C
C
O O O
O Ozonide

(A) Addition step

(B) Substitution step

16. Intermediate of ozonolysis is

(A) Zwitterion ion
(B) Ketone

17. Product is

O
O
O O
O Zn + Water
O
O

O
O

(A) Glycol (B) Glyoxal

18. Which alkene on ozonolysis give formaldehyde

(A) 1-butene
(B) 2-butene

19. Benzene on ozonolysis give

(A) 1 product
(B) 3 products

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20. Number of product obtained are

O
O
Ozonolysis O O
Reductive (s)-2-methylsuccinaldehyde IV

O I O

O
O

IV
(s)-2-methylsuccinaldehyde
II

(A) 1 (B) 3 (C) 4

21. Above conversation can be done by

+2 CH3CHO
21

O
19 20

(A) Reductive ozonolysis

(B) Oxidative ozonolysis

22. Product of above reaction are

H R H
C O
O O
O
C O
R H
H
(A) Aldehyde (B) Acid

23. Other then A and B how many reactants are possible

(A) 0 (B) 1

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24. Above mechanism is of

O
O
1 3 O O O O
R R
4 1 3 1 3
2 R R R R R
R R
2 4
R 2
R
4
R
[3+2] molozonide
very unstable

O
- O O O
O O O O R
1 3
R
4
1 3
 3
R
2
O R
R R 2
1
2 4 R 4 R Staudinger
R R R R ozonide

S
O O
O O S 1 3
1 3 R R
R R R
3
O O+O
1 O 4
R R
2 R
2 O R
4
R
2 4
R R
(A) Reductive ozonolysis
(B) Oxidative ozonolysis

25. Number of chiral product obtained are

CH3 H

CH3—CHCH—C—CHCH—C—CHCH—CH

H CH3
(A) 0 (B) 1

Video solution by M S Chouhan (MSC sir)

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