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    DPP For Jee Daily Practice Problems CH 1: Some Basic Concepts of Chemistry Solutions

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    The document contains 25 chemistry problems related to stoichiometry, empirical and molecular formula determination, and gas laws. It provides the questions, relevant data, and the answers. The problems cover various concepts in chemistry including moles, molar mass, percent composition, and chemical reactions.

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    DPP For Jee Daily Practice Problems CH 1: Some Basic Concepts of Chemistry Solutions

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    The document contains 25 chemistry problems related to stoichiometry, empirical and molecular formula determination, and gas laws. It provides the questions, relevant data, and the answers. The problems cover various concepts in chemistry including moles, molar mass, percent composition, and chemical reactions.

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    The document contains 25 chemistry problems related to stoichiometry, empirical and molecular formula determination, and gas laws. It provides the questions, relevant data, and the answers. The problems cover various concepts in chemistry including moles, molar mass, percent composition, and chemical reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    14 views8 pages

    DPP For Jee Daily Practice Problems CH 1: Some Basic Concepts of Chemistry Solutions

    Uploaded by

    hcvy7zbjs6
    The document contains 25 chemistry problems related to stoichiometry, empirical and molecular formula determination, and gas laws. It provides the questions, relevant data, and the answers. The problems cover various concepts in chemistry including moles, molar mass, percent composition, and chemical reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 8

    DPP FOR JEE

    DAILY PRACTICE PROBLEMS


    CH 1: SOME BASIC CONCEPTS OF CHEMISTRY
    SOLUTIONS
    1. (c)
    According to law of conservation of mass "mass is neither created nor
    destroyed during a chemical change"
    ∴ Mass of the reactants = Mass of products x + 4.9 = 6 +
    1.825
    or x = 2.925 g

    2. (b) Moles of urea present in 100 ml of sol.=

    [ M = Moles of solute present in 1L of solution]


    3. (d) Relative atomic mass =

    or

    Now if we use 1/6 in place of 1/12 the formula becomes

    ∴ .
    4. (d) 1 Mole of Mg3(PO4)2 contains 8 mole of oxygen atoms
    ∴ 8 mole of oxygen atoms ≡ 1 mole of Mg3(PO4)2​ mole of
    Mg3(PO4)2
    0.25 mole of oxygen atom mole of Mg3(PO4)2

    mole of Mg3 (PO4)2

    5. (b) From
    V1 =

    6. (d) Weight of Iron in 67200 =

    Number of atoms of Iron =

    7. (a) 2Al(s) + 6HCl(aq) 2Al3+(aq) + 6Cl– (aq) + 3H2(g)


    6 moles of HCl produces = 3 moles of H2 = 3 × 22.4 L of H2 at
    S.T.P
    1 mole of HCl produces = L of H2 at S.T.P = 11.2 L of

    H2 at STP
    8. (a) 95% H2SO4 by weight means 100g H2SO4 solution contains 95g
    H2SO4 by mass.
    Molar mass of H2SO4 = 98g mol–1

    Moles in 95g = = 0.969 mole

    Volume of 100g = 54.52 cm3 = 54.52

    × 10–3 L

    9. (c) 50 mL of 16.9% solution of AgNO3

    = 8.45 g of Ag NO3

    nmole = = 0.0497 moles

    50 ml of 5.8% solution of NaCl contain


    NaCl =

    nNaCl = = 0.0495 moles

    AgNO3 + NaCl → AgCl↓ + Na + Cl


    1 mole 1 mole 1 mole
    ∴ 0.049 mole 0.049 mole 0.049 mole of AgCl
    n=

    w = (nAgCl) × Molecular Mass


    = (0.049) × (107.8 + 35.5)
    = 7.02 g
    10. (b) Number of valence electrons in a ion = 1
    Now, 1 mol or 42 g of has = 6.023 × 1023 ions
    So, 42 g of has 6.023 × 4 × 1023 valence e–

    1 g of has valence e–

    4.2 g of has valence e– i.e.,

    0.1 NA valence e–.


    11. (c) 74.75% of chlorine means 74.75g chlorine is present in 100g of
    metal chloride.
    Weight of metal = 100g – 74.75g = 25.25g
    Equivalent weight = 12

    Valency of metal

    ∴ Formula of compound = MCl4


    12. (d) Q 18 gm, H2O contains = 2 gm H
    ∴ 0.72 gm H2O contains
    =

    Q 44 gm CO2 contains = 12 gm C
    ∴ 3.08 gm CO2 contains
    =

    ∴C:H=

    = 0.07 : 0.08 = 7 : 8
    ∴ Empirical formula = C7H8
    13. (a)

    Na2CO3 + NaHCO3 + NaCl + HCl

    (excess)

    Thus, on complete reaction with HCl, 1kg of washing soda will evolve 9
    mol of CO2.
    14. (a) 2.6 has two significant figures.
    0.260 has three significant figures.
    0.002600 has four significant figures.
    2.6000 has five significant figures.
    15. (b) Given
    mass of solute (w) = 120 g
    mass of solvent (w) = 1000 g
    Mol. mass of solute = 60 g
    density of solution = 1.12 g/ ml
    From the given data,
    Mass of solution = 1000 + 120 = 1120 g
    or

    Volume of solution or = 1 litre

    Now molarity (M) = =

    16. (d) In an unknown compounds containing N and H


    given % of H = 12.5%
    ∴ % of N = 100 – 12.5 = 87.5%

    2 × vapour density = Mol. wt = mol wt. = 16 × 2 = 32.


    Molecular formula = n × empirical formula mass
    =2

    ∴ Molecular formula of the compound will be = (NH2)2 = N2H4

    17. (a)

    18. (b) The required equation is

    nascent
    oxygen

    [O] required for 1 mol. of Fe(C2O4) is 1.5, 5 [O] are obtained from 2
    moles of KMnO4
    1.5 [O] will be obtained from
    = moles of KMnO4.

    19. (a)
    a 3a

    (3 – a) 4 (3 – a)
    But, 3a + 4 (3 – a) = 10
    a = 2 (Propane ) and 3 – 2 = 1 (Butane )
    20. (c)
    Element % Relative no. ofSimplest ratio of
    atoms atoms
    C 49.3 49.3/12 = 4.1 4.1/2.74 = 1.5
    1.5 × 2 = 3
    H 6.84 6.84/1 = 6.84 6.84/2.74 = 2.5
    = 2.5 × 2= 5
    O 43.86 43.86/16 = 2.74 2.74/2.74 = 1
    1 × 2 =2
    Empirical formula = C3H5O2
    Empirical formula mass
    = (3 × 12) + (5 × 1) + (2 × 16) = 36 + 5 + 32 = 73
    Molecular mass = 2 × Vapour density
    = 2 × 73 = 146
    n= = 146/73 = 2

    Molecular formula = Empirical formula × 2


    = (C3H5O2) × 2 = C6H10O4
    21. (1.67) No. of moles =
    No. of moles in 200 mg =

    = 4.5 × 10–3 moles


    No. of moles in 1022 molecules
    = = 1.67 moles

    No. of moles left = (4.5 – 1.67) × 10–3 = 2.88 × 10–3


    22. (67.2)

    or

    Now, since 10.8 gm boron requires hydrogen


    = at N.T.P

    hence 21.6 gm boron requires hydrogen


    at N.T. P.

    23. (1.22) Since molarity of solution is 3.60 M. It means 3.6 moles of


    H2SO4 is present in its 1 litre solution.
    Mass of 3.6 moles of H2SO4
    = Moles × Molecular mass
    = 3.6 × 98 g = 352.8 g
    1000 ml solution has 352.8 g of H2SO4
    Given that 29 g of H2SO4 is present in = 100 g of solution
    352.8 g of H2SO4 is present in

    = g of solution

    = 1216 g of solution
    Density = = = 1.216 g/mL = 1.22 g/mL

    24. (30)

    Moles of =
    = 0.01 0.05 moles of CO
    Weight of CO = 0.05 × 28 = 1.4 g;
    Weight of = 2 – 1.4 = 0.6 g

    Hence % of = × 100 = 30%

    25. (9.6)C2H4 + 3 O2 2CO2 + 2H2O


    28 g 96 g
    28 g of C2H4 undergo complete combustion by
    = 96 g of O2
    ∴ 2.8 kg of C2H4 undergo complete combustion by
    = 9.6 kg of O2.

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