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Ancment 638232159769852432

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Test Name: 23IIT1-INTG-BPCH-Batch 2-MN-01S

PHYSICS, CHEMISTRY AND MATHEMATICS


Class I IIT-JEE Achiever (Integrated) 2023-24 (BPCH) (Batch-2) Max. Marks 300
Solution to Test – 01 (Main) Duration 3 Hours
Date 24-06-2023
PART - I: PHYSICS
Multiple choice questions with one correct alternative

1. A vector is not changed if


(A) it is rotated through an arbitrary angle (B) it is multiplied by an arbitrary scalar
(C) it is cross multiplied by a unit vector (D) it is displaced parallel to itself
Ans (D)
2. If 0.5iˆ + 0.8jˆ + ckˆ is a unit vector, then the value of c is
(A) 0.11 (B) 0.22 (C) 0.33 (D) 0.89
Ans (A)
a = 0.5iˆ + 0.8jˆ + ckˆ
a = a12 + a 22 + a 32
a1 = 0.5, a 2 = 0.8, a 3 = c
 (0.5)2 + (0.8)2 + c2 = 1  0.25 + 0.64 + c2 = 1  c2 = 0.11  c = 0.11

3. If the resultant of two forces ( A + B) and ( A − B) is A 2 + B2 , then the angle between these forces is
 (A2 − B2 )  −1  (A + B ) 
2 2
(A) cos−1  − 2  (B) cos  − 
 A + B2   A2 − B2 
 (A 2 + B2 )  −1  2(A + B ) 
2 2
(C) cos −1  − 2 
(D) cos  − 
 2(A − B ) 
2
 A2 − B2 
Ans (C)
Let A + B = C
A−B=D
Angle between C and D = 
Angle between A and B = 
2 2
A 2 + B2 = C + D + 2CDcos 
= (A2 + B2 + 2ABcos ) + (A2 + B2 − 2ABcos ) + 2(A2 − B2 )cos 
A2 + B2 = 2A2 + 2B2 + 2(A2 − B2)cos 
1 A 2 + B2
cos  = −
2 A 2 − B2
 −(A 2 + B2 ) 
 = cos −1  2 
 2(A − B ) 
2

4. If f(x) = x cos x. Find f (x)


(A) −x cos x + 2sin x (B) −2cos x − xsin x (C) −x cos x − 2sin x (D) −2cosx + x sin x
Ans (C)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

Using product rule,


d d(x)
f (x) = x (cos x) + cos x   −xsin x + cos x
dx dx
d(− x sin x + cos x)
f (x) =
dx
d d d
= − x (sin x) + sin x (− x) + (cos x)
dx dx dx
= −x cos x − sin x − sin x
= −x cos x − 2 sin x
5. Given that P + Q + R = 0 . Two out of the three vectors are equal in magnitude. The magnitude of the
third vector is 2 times that of the other two. Which of the following can be the angles between these
vectors?
(A) 90, 135, 135 (B) 45, 45, 90 (C) 30, 60, 90 (D) 45, 90, 135
Ans (A)
Assume magnitude of P, Q, R be a, a , 2a respectively
P+Q+R =0
P and Q are opposite to R
R = a 2 + a 2 + 2a(a cos )
2a = 2a 2 + 2a 2 cos   cos  = 0   = 90
P and Q are equal in magnitude so angle will be 45 each
R will make angle (180 − 45) = 135 with P and Q
So, angle between vector ( P, Q ) , ( Q, R ) and ( R, P ) are 90, 135, 135.

6. The velocity v of a particle is given by the equation v = 6t 2 − 6t3 where v is in ms−1, t is the instant of
time in second while 6 and 6 are suitable dimensional constant. At what value of t will the velocity be
maximum and minimum? Determine these maximum and minimum values of the velocity.
9 8 9 8
(A) , 0 (B) , 0 (C) 0, (D) 0,
8 9 8 9
Ans (A)
v = 6t2 − 6t3
dv
= 12t − 8t 3
dt
dv
= 0 (for value of t, v is minimum or maximum)
dt
2
12t − 8t3 = 0  t = 0, sec
3
2
d v
= 12 − 36t
dt 2
d2 v
= 12  0
dt 2 t =0
So, t = 0 is a print of minima

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1I(I)(BPCH)(B2)2324PCMT01S(M)

d2v 2
2
= 12 − 36  = −12  0
dt t = 2 sec 3
3

2
So, t = sec is a point of maxima
3
Hence, the minimum value of v is 0 ms−1 at t = 0
4 8 8 16 8  2 
The maximum value of v is = 6  − 6   −  ms−1  t = sec 
9 27 3 9 9  3 
7. If P = 4iˆ − 2jˆ + 6kˆ and Q = ˆi − 2jˆ − 3kˆ , then the angle which P + Q makes with x-axis is
 3   4   5   12 
(A) cos −1   (B) cos −1   (C) cos −1   (D) cos −1  
 50   50   50   50 
Ans (C)
P = 4iˆ − 2jˆ + 6kˆ and Q = ˆi − 2jˆ − 3kˆ
P + Q = 5iˆ − 4jˆ + 3kˆ
Angle made by a vector with x-axis is
x component
cos  =
Magnitude of vector
5 5
cos  = =
5 +4 +3
2 2 2
50
 5 
 = cos −1  
 50 

2zdz
8. Evaluate:  3
z2 + 1
2 2 3
3 2 2 2 3 2
(A) (z + 1) 3 + c (B) (z + 1) 3 + c (C) (z + 1) 2 + c (D) none of (A), (B) & (C)
2 3 2
Ans (A)
2
43 −
1
3 2 3 2
Let 4 = z2 + 1, dy = 2zdz =  4 du = + c = 4 3 + c = (z 2 + 1) 3 + c
3
2 2 2
3

9. Let A = ( ˆi + ˆj) and B = ( 2iˆ − ˆj) . The magnitude of a coplanar vector C such that A  C = B  C = A  B , is
given by
10 5 20 9
(A) (B) (C) (D)
9 9 9 12
Ans (B)
A = ( ˆi + ˆj) and B = ( 2iˆ − ˆj)
A  B = ( ˆi + ˆj)  ( 2iˆ − ˆj) = 1
A C = BC = A B =1
A C = x + y =1  (i)
B  C = 2x − y = 1  (ii)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

2 1
x= , y=
3 3
2 2
 2 1 5
C =   +  =
 3  3 9

10. The value of sin 75 is


3 +1 3 +1 3 +1 3 −1
(A) (B) (C) (D)
2 2 2 4 4
Ans (B)
sin 75 = sin(45 + 30)
sin(A + B) = sin A cos B + cos A sin B
sin 75 = sin 45 cos 30 + cos 45 sin 30
1 3 1 1 3 +1
=  + + =
2 2 2 2 2 2
th th
2 3
11. If a car covers of the total distance with v1 speed and distance with v2, then average speed is
5 5
1 v1 + v 2 2v1v 2 5v1v 2
(A) v1v 2 (B) (C) (D)
2 2 v1 + v 2 3v1 + 2v 2
Ans (D)
Let total distance travelled by cos = x
2x 3x
Total time taken to cover whole distance is t = 5 + 5
v1 v 2
Total distance
Average speed =
Total time
x x 5v1v 2
= =
t 2x 3x 3v1 + 2v 2
5 + 5
v1 v 2

12. Body A starts from rest with an acceleration a1. After 2s another body B starts from rest with an
acceleration a2. If they travel equal distances in 5s after the start of A, the ratio a1 : a2 will be equal to
(A) 9 : 25 (B) 5 : 7 (C) 5 : 9 (D) 7 : 9
Ans (C)
Initial speed, u = 0
Distance covered in nth second after starting from rest.
1
S = (2n − 1)
2
For A: n = 5
a 9
SA = 1 (2  5 − 1) = a1
2 2
For B: n = 3
a 5
SB = 2 (2  3 − 1) = a 2
2 2

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1I(I)(BPCH)(B2)2324PCMT01S(M)

SA = SB
9 5
a1 = a 2
2 2
a1 : a 2 = 5 : 9
13. If a = v , at t = 0 if its velocity is v0. Find time in which velocity becomes zero
(A) 2 v 0 ( 3 − 1) (B) 2 v 0 ( 2 + 1) (C) 2 v 0 ( 3 + 1) (D) 2 v 0 ( 2 − 1)
Ans (D)
t = 0, v = v0
t = t, v = 2v0
a= v
dy
= v
dt
dv = vdt
t 2v0
dv
 dt =
0

v0
v

t = 2 v v0 = 2 v0 ( 2 − 1)
2v0

14. Mark the correct statements


(A) The magnitude of the velocity of a particle is equal to its speed.
(B) The magnitude of average velocity in an interval is equal to its average speed in that interval.
(C) It is possible to have a situation in which the speed of a particle is always zero but the average speed
is not zero.
(D) It is possible to have a situation in which the speed of the particle is never zero but the average speed
in an interval is zero.
Ans (A)
15. The graph of displacement v/s time is

Its corresponding velocity-time graph will be

(A) (B) (C) (D)

Ans (A)
16. The displacement-time graph for two particles A and B are straight lines inclined at angles of 30° and
60° with the time axis. The ratio of velocities of vA : vB is
(A) 1 : 2 (B) 1: 3 (C) 3 :1 (D) 1 : 3
Ans (D)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

dv
Slope of x-t graph = v =
dt
vA : vB = slopeA : slopeB
1
= tan 30 : tan 60 = : 3 =1:3
3

17. B1, B2 and B3 are three balloons ascending with velocities v, 2v and 3v respectively. If a bomb is
dropped from each when they are at same height, then
(A) Bomb from B1 reaches ground first (B) Bomb from B2 reaches ground first
(C) Bomb from B3 reaches ground first (D) They reach the ground simultaneously
Ans (A)
Bomb B1 will have less velocity upward on dropping, so it will reach ground first.
18. In the displacement-time graph of a moving particle is shown, the instantaneous velocity of the particle
is negative at the point
x
D

E F
C
t
(A) C (B) D (C) E (D) F
Ans (C)
19. A body is thrown vertically upwards. Which one of the following graphs correctly represent the velocity
vs time?

v v v
v
(A) (B) (C) (D)
t t t

t
Ans (D)
20. All the graphs below are intended to represent the same motion. One of them does it incorrectly. Pick it
up.
Position Velocity

(A) time (B) time

Velocity distance

position time
(C) (D)

Ans (D)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

Numerical problems

21. A force is inclined at 60° to the horizontal. If its rectangular component in the horizontal direction is
50 N, then magnitude of the force in the vertical direction is
Ans 87
F = Fx = 50 N
F cos  = 60
50
F= = 2(50) = 100 N
cos60
3
Fy = F sin  = F sin 60 = 100 sin 60  100 = 50 3
2
Fy = 87 N

22. If A and B are two vectors such that A + B = A − B the angle between vectors A and B is , then
n
the value of n is _____
Ans 2
Let us assume angle between A and B be 
Resultant of A + B : R 1 = A 2 + B2 + 2ABcos 
Resultant of A − B : R 2 = A 2 + B2 − 2ABcos 
Given: R1 = R2
A 2 + B2 + 2ABcos  = A 2 + B2 − 2ABcos 
 4AB cos  = 0  cos  = 0   = 90

23. Let a, b and c be three vector such that a + b + c = 0 , if a = 3, b = 4 and c = 5 , then find the value of
(a  b + b  c + c  a )
Ans 25
a+b+c=0
a + b = −c
a  c + b  c = −c  c
a  c + b  c = −c 2  (i)
Similarly, a + c = b
a  b + c  b = −b 2  (ii)
Again, b + c = −a
b  a + c  a = −a 2  (iii)
By adding equation (i), (ii) and (iii)
2 ( a  b + b  c + c  a ) = − ( a 2 + b2 + c2 )
1
( a  b + b  c + c  a ) = (32 + 42 + 52 ) = 25
2
1
24. If A and B denote the sides of a parallelogram and its area is AB (A and B are the magnitude of
2
A and B respectively), the angle between A and B is
Ans 30

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1I(I)(BPCH)(B2)2324PCMT01S(M)

Area of parallelogram is A  B = ABsin 


1
ABsin  = AB
2
1
sin  =   = 30
2
25. An athlete completes one round of a circular track of radius is 1.5 m in 40 seconds. What will be his
displacement at the end of 2 minutes 20 seconds?
Ans 3
Total time duration = 2 min 20 sec = 140 sec
Completed, 1 round in 40 sec
140
In 140 sec, he will cover = = 3.5 sec
40
Total displacement = Total displacement in 3 complete round + displacement in 0.5 round
= 0 + diameter of circular track = 0 + 2R = 2R  2  1.5 = 3 m
26. Calculate the area of the parallelogram when adjacent sides are given by the vectors A = ˆi + 2jˆ + 3kˆ and
B = 2iˆ − 3jˆ + kˆ (Round off to the nearest integer)
Ans 14
ˆi ˆj kˆ
AB = 1 2 3 = ˆi(2 + 9) + ˆj(6 − 1) + k(
ˆ −3 − 4)  11iˆ + 5jˆ − 7kˆ
2 −3 1
A  B = 112 + 52 + (−7)2 = 195 sq.unit

27. A body falls from rest in the gravitational field of the earth. The distance travelled in the fifth second of
its motion is _____ (g = 10 ms−2)
Ans 45
u=0
g
h n = (2n − 1)
2
10
h 5th = (2  5 − 1) = 45 m
2
28. A driver takes 0.20 sec to apply the breaks. If he is driving a car at a speed of 54 km hr −1 and the brakes
cause a deceleration 7.5 ms−2. Find the distance travelled by the car after he sees the need to put the
brakes on.
Ans 15
5
Speed = 54  = 15 ms −1
18
From t = 0 to t = 0.20 sec
S = 15  0.2 = 3m
u 2 15  15
Stopping distance = = = 15 m
2a 26

29. A stone is thrown vertically upward with an initial speed u from the top of a tower, reaches the ground
with a speed 3u. The height of the tower is ____ (u = 10 ms−1)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

Ans 40
Initial velocity = u
Final velocity = v = 3u
Acceleration = g
v2 − u2 = 2gh
(3u)2 − u2 = 2gh
9u 2 − u 2
h=
2g
4u 2
h=
g

30. Two trains 120 m and 80 m in length are running in opposite directions with velocities 42 km h−1 and
30 km h−1. In what time they will completely cross each other.
Ans 10
5
Relative velocity of train w.r.t the other = 42 − (−3) = 72 km h −1  = 20 ms −1
18
Total distance to be covered by each train to cross other train = 120 + 80 = 200 m
200
Time taken to cross = = 10 sec
20

PART - II: CHEMISTRY


Multiple choice questions with one correct alternative

31. A photon of light of wavelength 6000 Å has energy E. The wavelength of photon of a light which has
energy or photon 4E is
(A) 1500 Å (B) 1800 Å (C) 2000 Å (D) 2400 Å
Ans (A)
 E  E 
E   1 = 1 , 1 = 2 (E 2 = 4E1 )   2 = 1500 Å
 E 2  2 4E1 6000

32. The specific charge of a proton is 9.6  107 C kg−1, then for an -particle it will be
(A) 2.4  107 C kg−1 (B) 4.8  107 C kg−1 (C) 19.2  107 C kg−1 (D) 38.4  107 C kg−1
Ans (B)
1 2
Use the ratio for e/m of proton   and -particle  
1 4

33. Which of the following pairs is an example of isotones?


39 41 40 36 38 37 38 40
(A) 19 K, 20 Ca (B) 19 K, 16 S (C) 18 Ar, 17 Cl (D) 17 Cl, 20 Ca
Ans (C)
Same number of neutrons = 20
34. According to Bohr’s atomic model, the radius of the orbit is directly proportional to
(A) n2 (B) 1/n2 (C) 1/n (D) n
Ans (A)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

35. An electron revolving around H-nucleus in the ground state absorbs 10.2 eV energy. Its angular
momentum increases by
h h 2h h
(A) (B) (C) (D)
2   4
Ans (A)
 1 1  1 1 
E = (13.6 eV )  Z2  2 − 2   E = (13.6 eV )  12  2 − 2   n 2 = 2
 n1 n 2   1 n2 
 h   h  h
Now, change in angular momentum =  2  − 1  =
 2    2  2
−3.4 eV n=2
10.2 eV
−13.6 eV n=1

36. The IUPAC name for the following compound is


CH3
H3 C CH

CH3
CH2

(A) 3-methyl-4-(3-methylprop-1-enyl)-1-heptyne (B) 3,5-dimethy1-4-propylhept-6-en-1-yne


(C) 3-methyl-4-(1-methylprop-2-ynyl)-1-heptene (D) 3, 5-dimethyl-4-propylhept-1-en-6-yne
Ans (D)
CH3 7
H3C 4
CH
5
6
3
2 CH3
CH2
1

37. Thomson’s model of the atom as an intimate mixture of negative and positive particles is negated by
(A) de-Broglie’s prediction of wave properties for a stream of electrons
(B) Heisenberg’s principle that there is an uncertainty of position and/or momentum for small particles
such as electrons
(C) Rutherford’s experiments with large angle scattering of alpha particles by a gold foil
(D) Millikan’s oil drop experiment which can determine the e/m ratio of charged particles
Ans (C)
38. The work function () of some metals is listed below. The number of metals which will show
photoelectric effect when light of 300 nm wavelength falls on the metal is
Metal Li Na K Mg Cu Ag Fe Pt W
 (eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75
(A) 1 (B) 2 (C) 3 (D) 4
Ans (D)
hc 1240
E= = = 4.13 eV
 300
If E  , then photoelectric effect occurs. N = 5

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1I(I)(BPCH)(B2)2324PCMT01S(M)

39. The atomic number of hydrogen-like ion having the wavelength difference between the first line of
Balmer and Lyman series equal to 59.3 nm is
(A) 2 (B) 3 (C) 4 (D) 1
Ans (B)
1 1
3 − 2 = 59.3 nm or − = 59.3 nm  Z = 3
 1 1 1 1 
RZ2  2 − 2  RZ2  2 − 2 
2 3  1 2 

40. A transition for H-atom from second to first orbit has the same wavelength as from nth orbit to second
orbit for He+ ion. The value of n is 
(A) 2 (B) 3 (C) 4 (D) 6
Ans (C)
H(2 → 1), He+(n → 2)
1 1
=
 H  He+
1 1  1 1 
R H (1)2  −  = R H (2)2  − 2 
1 4  4 n 
3 1 1  3 4
= 4  − 2   =1− 2
4 4 n  4 n
4 3 4 1
= 1 −  2 =  n2 = 16  n = 4
n2 4 n 4
41. The e/m ratio of a particle of charge 2 unit and mass 4 amu is
(A) 4.8  107 C kg−1 (B) 0.5 C kg−1 (C) 4.8  104 C kg−1 (D) 8  10−20 C kg−1
Ans (A)
CH3

42. The IUPAC name of is

(A) 3-methylcyclohexene (B) 1-methylcyclohex-2-ene


(C) 1-methylcyclohexene (D) 1-methylcyclohex-5-ene
Ans (A)

43. The IUPAC name of the compound CH3 CH2 CH CONH2 is


CH3
(A) 2-ethylbutanamide (B) 2-methylbutanamide
(C) 1-amino-2-methylpropanone (D) 2-methylbutanamine
Ans (B)
OH
44. The IUPAC name of the compound

(A) 5-ethyl-6-methylcyclohex-2-enol (B) 3-ethyl-2-methylcyclohex-5-enol


(C) 5-ethyl-3-hydroxy-4-methylcyclohexene (D) 4-ethyl-6-hydroxy-5-methylcyclohexene
Ans (A)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

6 OH
5 1
4 2
3

45. The IUPAC name of O is


N

(A) N-ethyl-2-isopropyl-N-methylbutanamide
(B) N-ethyl-N-methyl-2-ethyl-3-methylbutanamide
(C) N-ethyl-N-methylamino-2-ethyl-3-methylbutanone
(D) N-ethyl-2(1-methylethyl)-N-methylbutanamide
Ans (B)

3 2
4
O 1
N

46. The electrons, identified by quantum numbers n and l (i) n = 4, l = 1 (ii) n = 4, l = 0 (iii) n = 3, l = 2 and
(iv) n = 3, l = 1 can be placed in order of increasing energy, from the lowest to highest, as
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii)
(C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
Ans (A)
(Hint: smaller the value of “n + l” value lesser the energy of the subshell
47. The radius of which of the following orbit is same as that of the first Bohr’s orbit of hydrogen atom?
(A) He+ (n = 2) (B) Li2+(n = 3) (C) Li2+ (n = 2) (D) Be3+(n = 2)
Ans (D)
r = n2(0.529)/Z Å
Be3+ (n = 2), Z = 4 gives r = 0.529 Å
48. An electron is not allowed in that orbit for which the angular momentum is equal to
h 1.5h 1.7h 2.5h
(A) (B) (C) (D)
   
Ans (C)
nh
mvr =
2
n = 1, 2, 3 …
49. What is the IUPAC name of the given compound?

(A) 3-Methylene-4-methyl-5-heptene (B) 2-Ethyl-3-methyl-1-hexen-4-yne


(C) 5-Methylene-5-ethyl-4-methyl-2-heptyne (D) 5-Ethyl-4-methyl-2-hexyn-5-ene

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1I(I)(BPCH)(B2)2324PCMT01S(M)

Ans (B)
Conceptual
50. Select the correct IUPAC name of the following compound
BrCH 2 CHCOCH 2 CH 2 CH 3
|
CONH 2
(A) 2-bromomethyl-3-oxohexanamide (B) 1-bromo-2-amido-3-oxohexane
(C) 1-bromo-2-amido-n-propyl ketone (D) 3-bromo-2-propyl propenamide
Ans (A)

Numerical problems
51. At what minimum atomic number would a transition from first excited state to ground state energy level
result in the emission of electromagnetic radiations with  = 3.0  10–8 m? (RH = 109678 cm−1)
Ans 2
1 1 1  1 3 4
= Z2 R H  2 − 2   −8
= Z2  1.09678  107    Z2 = 4
 1 2  3  10 4
−8
3  10  1.09678  107  3
Atomic number, Z = 2
52. The maximum number of electrons that can have principal quantum number, n = 3 and spin quantum
1
number ms = − is
2
Ans 9
Total no. of electrons with (n = 3) = 2n2 = 18
1
Half of these electrons will have ms = −
2
53. Number of lines in visible region when an electron returns from 5th orbit to ground state in H-spectrum is
Ans 3
Visible lines belong to Balmer series, n1 = 2
So, the transitions will be from 5 to 4, 5 to 3 and 5 to 2
54. Total number of nodal planes and spherical nodes present in 5g orbital is
Ans 4
Number of nodal planes = l = 4 for a g orbital
Number of nodal surfaces = n − l − 1
=5−4−1
=0
 Total number of planes and surfaces = 4 + 0 = 4
Alternatively, total number of nodes = n − 1
=5−1=4
55. How many unpaired electrons are present in Co3+ ion?
Ans 4
Atomic number of Co is 27, outer shell configuration is 4s23d7 and in Co3+ ion it is 3d6, hence, it will
have 4 unpaired electrons

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1I(I)(BPCH)(B2)2324PCMT01S(M)

56. How many of the following names are correct according to IUPAC system of nomenclature?
(1) Pent-3-yne (2) Hexa-1,6-diene (3) 4-methyl hexa-1,5-diyne
(4) 3-ethyl-hex-3-ene (5) 1-methoxy ethan-2-ol, (6) 4,4,5-trimethyl hex-1-yne
(7) 1,2-dihydroxy ethane (8) Pent-4-en-1-yne
Ans 2
Conceptual: (4th and 6th)
57. In the given compound position of ‘yne’ is at
CHCCH(CH3)C(CH3)2CH=CH2
Ans 5
Double bond gets priority
58. Number of possible spectral lines which may be emitted in the Brackett series in hydrogen atom, if
electron in the 9th excited state returns to ground state are
Ans 6
59. The number of photons of light having a wavelength 4000 Å are necessary to provide 1.00 J of energy is
2  10x, then the value of x is
Ans 18
hc 6.62  10−34  3  108
Energy of one photon = = = 4.9655
 4000  10−10
1.00
Number of photons = −19
= 2.01 1018
4.965  10
60. How many orbitals of the following have magnetic quantum number value is zero
4s, 3pz, 1s, 2pz, 3d x 2 − y2 , 3d xy ,3d z2 , 4f z3 2s, 4p z
Ans 7
4s, 1s, 2pz, 3d z2 , 4f z3 2s,4pz

PART - III: MATHEMATICS


Multiple choice questions with one correct alternative
50 n
61. Let Xi = Yi = T , where each Xi contains 10 elements and each Yi, contains 5 elements. If each
i =1 i =1
element of the set T is an element of exactly 20 of sets Xi' and exactly 6 of sets Yi' , then n is equal to
(A) 15 (B) 50 (C) 45 (D) 30
Ans (D)
50 n
Xi = Yi = T ⸪ n(Xi) = 10, n(Yi) = 5
i =1 i =1
50 n
500 5n
So, Xi = 500  Yi = 5n  =  n = 30
i =1 i =1 20 6
62. Let S = {1, 2, 3, …, 100}. The number of non-empty subset A of S such that the product of elements in
A is even is
(A) 2100 − 1 (B) 250 (250 – 1) (C) 250 − 1 (D) 250 + 1
Ans (B)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

⸪ Product of two even number is always even, product of two odd numbers is always odd and product of
odd and even numbers is always even.
⸫ Number of required subsets = Total number of subsets − Total number of subsets having only odd
numbers
= 2100 − 250 = 250 (250 − 1)
63. Two newspapers A and B are published in a city. It is known that 25% of the city population reads
A and 20% reads B while 8% reads both A and B. Further, 30% of those who read A but not B look into
advertisements and 40% of those who read B but not A also look into advertisements, while 50% of
those who read both A and B look into advertisements. Then the percentage of the population who look
into advertisements is
(A) 13.9 (B) 12.8 (C) 13 (D) 13.5
Ans (A)

% of people who reads A only = 25 − 8 = 17%


% of people who read B only = 20 − 8 = 12%
% of people from A only who read advertisement = 17 × 0.3 = 5.1%
% of people from B only who read advertisement =12 × 0.4 = 4.8%
% of people from A and B both who read advertisement = 8 × 0.5 = 4%
⸫ Total % of people who read advertisement = 5.1 + 4.8 + 4 =13.9%
64. For real numbers x and y, xRy if and only if x − y + 3 is an irrational number. Then the relation R is
(A) Reflexive but neither symmetric nor transitive
(B) Symmetric and reflexive but not transitive
(C) Transitive and reflexive but not symmetric
(D) Equivalence
Ans (A)
x  R, xRx as x − x + 3 = 3 is an irrational number.
Hence R is a reflexive relation. ( 3, 1)  R as 3 − 1 + 3 = 2 3 − 1 is an irrational number, whereas
(1, 3 )  R as 1 − 3 + 3 = 1 which is a rational number. Hence R is not a symmetric relation.
( 3, 3, 4 ) , ( 4, 4 3 )  R but ( 3 3,4 3 )  R as 3 3 − 4 3 + 3 = 0 is a rational number.

65. If R is a relation on the set A = {1, 2, 3} be defined by R = {(2, 3)}, then R is


(A) Transitive but not antisymmetric relation
(B) An equivalence and antisymmetric relation
(C) transitive and antisymmetric relation
(D) neither transitive nor antisymmetric relation
Ans (C)
Given relation is transitive and antisymmetric relation (by definition)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

66. If R is a relation on set of natural numbers and aRb if a > b, then R is


(A) Reflexive and transitive but not antisymmetric relation
(B) Antisymmetric and reflexive but not transitive relation
(C) Antisymmetric and transitive but not reflexive relation
(D) transitive, but neither antisymmetric nor reflexive relation
Ans (C)
x  N, (x, x)  R, as x > x is not possible, hence R is not a reflexive relation.
If x > y, (x, y)  R, and x ≠ y and (y, x)  R, hence R is an antisymmetric relation.
x > y and y > z implies x > z, hence R is a transitive relation
67. If A and B are any two sets, X denotes complement of set X, then [B  (B − A)] =
(A) A (B) A − B (C) B − A (D) B
Ans (D)
[B  (B − A)] = [B  (B  A)] = [B  (B  A)] = B
68. If A, B and C are any three sets, X denotes complement of set X, then the set
[A  B  C)  (A  B  C)  C] is equal to
(A) B − C (B) C − B (C) B − C (D) C − B
Ans (C)
[A  B  C)  (A  B  C)  C] = [(A  B  C)  (A  B  C)  C]−
= [(A  A)  (B  C)]  C = [  (B  C)]  C
= (B  C)  C = (B  C)  (C  C) = B − C

69. If observations in a data are multiplied by a positive constant, then there is change in scale of data and if
these observations are added by a constant then there is shifting of origin,  denotes standard deviation
of given data, then
(A)  is dependent of any change in origin but independent of change in scale
(B)  is independent of any change in origin and of change in scale
(C)  is dependent of any change in origin and of change in scale
(D)  is independent of any change in origin but dependent of change in scale
Ans (D)
If given observations are xi, where i = 1, 2, 3, … n, and when it is transformed to yi, given by
yi = axi + b, then y = ax. So, standard deviation is dependent on change of scale but independent of
change in origin.
70. If the mean deviation about median for the number 3, 5, 7, 2k, 12, 16, 21, 24 arranged in the ascending
order, is 6 then the median is
(A) 11.5 (B) 10.5 (C) 12 (D) 11
Ans (D)
2k + 12
Median = =k+6
2
⸫ Mean deviation about median
k + 3 + k + 1 + k − 1 + 6 − k + k − 6 + k − 9 + k − 15 + k − 18
= =6
8

16
1I(I)(BPCH)(B2)2324PCMT01S(M)

58 − 2k  7 
 =6   k  6
8  2 
 k = 5, Median = 11
24 194
71. Let the mean and the variance of 5 observations x1, x2, x3, x4, x5 be and respectively. If the
5 25
7
mean and variance of the first 4 observations are and a respectively, then (4a + x5) is equal to
2
(A) 13 (B) 15 (C) 17 (D) 18
Ans (B)
 xi = 24  x = 25
x=
5 5
 i
2 =
 xi2 −  24 2  192   x 2 = 154
 5 
i
5 25
x1 + x2 + x3 + x4 = 14  x5 = 10
x 2 + x 22 + x 32 + x 24 49
2 = 1 − =a
4 4
x12 + x 22 + x32 + x 24 = 4a + 49  x52 = 154 − 4a − 49
5
 100 = 105 − 4a  4a = 5  a =
4
⸫ 4a + x5 = 5 + 10 = 15
72. If A = {1, 2, 3, 4, 5}, then which of the following is true
(A) A  A =  (B) A  A =  (C) A  A = A (D) A   = 
Ans (C)
9
73. The mean and variance of the data 4, 5, 6, 6, 7, 8, x, y where x < y are 6 and respectively. Then
4
x4 + y2 is equal to
(A) 162 (B) 320 (C) 674 (D) 420
Ans (B)
9
Given mean and variance are 6 and rest
4
4+5+6+6+7+8+ x + y
Mean x = =6
8
 x + y = 48 – 36 = 12 … (i)
1 9
Take variance = ( 4 − 6 ) + ( 5 − 6 ) + ( 6 − 6 ) + ( 6 − 6 ) + ( 7 − 6 ) + (8 − 6 ) + ( x − 6 ) + ( y − 6 )  =
 2 2 2 2 2 2

8 4
1 81
= 8z + x 2 + y 2  =
8 4
 x + y = 162 – 80
2 2

 x2 + y2 = 80 … (ii)
Subtract (i) from (ii) ⸫ x = 4; y = 8
Now, x4 + y2 = 256 + 64 = 320

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1I(I)(BPCH)(B2)2324PCMT01S(M)

74. The mean of the numbers a, b, 8, 5, 10 is 6 and their variance is 6.8. If M is the mean deviation of the
numbers about the mean, then 25 M is equal to
(A) 60 (B) 55 (C) 50 (D) 45
Ans (A)
5

(x − x)
2
i
Since, Variance is  2 = i =1
and given mean = 6
n
a + b + 8 + 5 + 10
= 6  a + b = 7 and b = 7 – a
5
( a − 62 ) + ( b − 6 )2 + (8 − 6 )2 + ( 5 − 6 )2 + (10 − 6 )2
6.8 =
5
34 = (a – 6) + (7 – a – 6) + 4 + 1 + 18
2 2

a2 – 7a + 12 = 0  a = 4 or a = 3
a=4 a=3
b=3 b=4
5

x i −x
a − 6 + b − 6 + 8 − 6 + 5 − 6 + 10 − 6
M= i =1
 M=
n 5
When a = 3, b = 4 when a = 4, b = 3
3 + 2 + 2 +1+ 4 2 + 3 + 2 +1+ 7
M= M=
5 5
12 12
M= M=
5 5
12
⸫ 25M = 25  = 60
5
75. If R is a relation on the set A = {1, 2, 3, 4, 5} be defined by R = {(4, 5), (2, 2)}, then R is
(A) Transitive but not antisymmetric relation
(B) An equivalence and antisymmetric relation
(C) transitive and antisymmetric relation
(D) neither transitive nor antisymmetric relation
Ans (C)
Given relation is transitive and antisymmetric relation (by definition)
76. If A and B are two finite sets such that A  B = , then n(A  B) =
(A) n(A) + n(B) (B) n(A) + n(B) + n(A  B)
(C) n(A) + n(B) − n(A  B) (D) n(A) n(B)
Ans (A)
77. If A and B are any two finite sets then n(A) + n(B) is equal to
(A) n(A  B) (B) n(A  B)
(C) n(A  B) + n(A  B) (D) n(A  B) − n(A  B)
Ans (C)
We have n(A  B) = n(A) + n(B) − n(A  B)  n(A) + n(B) = n(A  B) + n(A  B)

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1I(I)(BPCH)(B2)2324PCMT01S(M)

78. Which of the following is (A – B)  (B – A)


(A) (A  B) – (A – B) (B) (A  B)  (A  B)
(C) (A  B) – (A  B) (D) (A – B)  (B – A)
Ans (C)
(A – B)  (B – A) = (A  B) – (A  B)
A–B B–A

79. If A = {1, 2}, B = {2, 4, 5}, then A  (A  B) is


(A) {(1, 2), (2, 2)} (B) {(2, 1) (2, 2)} (C) {(1, 4) (4, 1)} (D) {(1, 5) (5, 1)}
Ans (A)
A  (A  B) = {1, 2}  {2} = {(1, 2), (2, 2)}
80. The standard deviation of x + 1, x + 2, x + 3, x + 8, x + 7 and x + 9 is
58 29 58 29
(A) (B) (C) (D)
6 6 6 6
Ans (A)
x + 1, x + 2, x + 3, x + 8, x + 7, x + 9  1, 2, 3, 8, 7, 9
30
x= = 5 and  x i2 = 208
6
 xi2 208 208 − 150 58
= − (x)2 = − (5)2 = =
n 6 6 6

Numerical problems

81. Let A = {1, 2, 3, 4, 5, 6, 7} and B = (3, 6, 7, 9}. Then the number of elements in the set
{C  A : C  B ≠ } is 8, then value of  is ____
Ans 14
Given sets are A= {1, 2, 3, 4, 5, 6, 7} and B = {3, 6, 7, 9}
Total subset of A = 27 = 128
Here, C  B =  when set C contains the element 1, 2, 4, 5.
⸫ S = {C  A; C  B ≠ }
Total number of elements = Total − (C  B = ) = 128 − 24 = 112
82. Set A has m elements and set B has n elements. If the total number of subsets of A is 112 more than the
total number of subsets of B, then the value of mn is ________
Ans 28
2m = 112 + 2n  2m – 2n = 112
 2n (2m − n − 1) = 24 (23 – 1)
⸫ m = 7, n = 4  mn = 28
83. Let X = {n  N : 1 ≤ n ≤ 50}. If A = {n  X: n is a multiple of 2} and B = (n  X : n is a multiple of 7},
then the number of elements in the smallest subset of X containing both A and B is _____

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1I(I)(BPCH)(B2)2324PCMT01S(M)

Ans 29
From the given conditions
n(A) = 25, n(B) = 7 and n(A  B) = 3
n(A  B) = n(A) + n(B) − n(A  B) = 25 + 7 – 3 = 29
84. Let the mean and the variance of 20 observations x1, x2, … x20 be 15 and 9, respectively. For   R, if
the mean of (x1 + )2, (x2 + )2, …, (x20 + )2 is 178, then the square of the maximum value of  is equal
to ______
Ans 4
 x i = 15  20 = 300
x 2
i
− (15) = 9 
2
x 2
i = 234  20 = 4680
20
 ( xi +  )
2

= 178   ( x i +  ) = 3560
2

20
  x i2 + 2 x i +    = 3560
4680 + 600  − 202 = 3560  2 + 30 + 56 = 0
 ( + 28)( − 2) = 0   = −2, −28
Square of maximum value of  is 4
85. The mean and variance of 10 observation were calculated as 15 and 15 respectively by a student who
took by mistake 25 instead of 15 for one observation. Then the correct standard deviation is _______
Ans 2
Given n = 10, x = 15

2 = 15  x =
 xi = 15 and  =  xi2 − ( x )2 = 15
10 10
10 9 9 9
 x i = 150   x i + 25 = 150 
i =1
x
i =1
i = 125   x i + 15 = 140
i =1

140
Actual mean = = 14 = x new
10
9
x i2 + 252 − 152 9 9


i =1 10
= 15  
i =1
x 2
i + 625 = 2400  
i =1
xi2 = 1775

+ 152 = 2000 = (  x i2 )original


9
 x
i =1
2
i

( x ) 2
i original − ( x new )
2
2000
 2
original = = − 142 = 200 − 196 = 4
10 10
(S.D)original = 6 = 2
86. If A = , then the number of elements in the power set of A is
Ans 1
Power set of a given set is always non empty for   P(A) for every set A
Thus if A = , then P(A) has one element i.e., 
87. If n(A) = 10, n(B) = 6 and n(C) = 5 for three disjoint sets A, B and C, then n(A  B  C) =
Ans 21

20
1I(I)(BPCH)(B2)2324PCMT01S(M)

As A, B, C are disjoint sets, therefore, n(A  B  C) = n(A) + n(B) + n(C)


88. If the coefficient of variation, and mean of a certain data are 30 and 60 respectively., then the variance of
the data is k2, then k equal to
Ans 18

C.V = 30, x = 60 and C.V =  100
x
 variance = (18) = 324
2

89. The following information relates to a sample of size 60 : x2 = 18000, x = 960. The variance is
Ans 44
Given, x2 = 18000, x = 960, n = 60
2 2
x 2  x  18000  960 
Now, variance = −  = −  = 300 − 256 = 44
n  n  60  60 

90. The standard deviation of 105, 120 125, 130, 110, 115 and 135 is
Ans 10
105, 120, 125, 130, 110, 115, 135
Subtracting 125 from each observation we get −20, −5, 0, 5, −15, −10, 10
−35
x= = −5 ,  x i2 = 875
7
 xi2 875
 = − (x)2 = − (−5)2 = 125 − 25 = 100 = 10
n 7

***

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