طرق تقدير معدلات التآكل
طرق تقدير معدلات التآكل
طرق تقدير معدلات التآكل
א
א
- ١٥ -
אא ١٦١ א
א אאאא
אE١ J٣F
K אאאאא
E אאFאאא
אא
אאאאאא
אאאאאאאKא
אE אאFאאאא
אאאKאאאא
Kא
WאאE٢ J٣F
אאא،אאא
Kא א،אא
אאKאאאאא
WאאאאאKאאא
- ٢٩ -
אא ١٦١ א
א אאאא
אאאאא
Kא،E١ J٣Fא
- ٣٠ -
אא ١٦١ א
א אאאא
KאאE١ J٣F
WאאE٣ J٣F
אאא
Kאאאאאאא
،א אאא
،א،K(Corrosion rates)א
٠{٤٤ JZ،١{٦٧ JZE◦ FאEFאא
אאאאאאאKE
אKאא
K א،אאאא
אא،אאאא،
Kא
(Corrosion current)אאאא
אאא
אאא،אא
Kאאאא
Wאאאאא
- ٣١ -
אא ١٦١ א
א אאאא
= K I t∆m
W
tאא Z ∆m
EFא = I
EFא Z t
٩٦٥٠٠CאאDאא Z K
אאאFאא
(Polarization אאא
אE Fא
،curves)
אK
אאאאEF
א،אאא
، J١ J٣אF
א،
E
Ecorr
Icorr
KאאE١ J٣F
- ٣٢ -
אא ١٦١ א
א אאאא
،אאא
א
J٣אF(Mixed corrosion potential)אא א
– אאאE J١
א
،–،א
KאאאEאFא
אא،א
אאאאאא(Concentration polarization)
،אאאאאEא…א،אF
אאאא(Activation polarization)אא
( Linear polarization אא،אאא
אאא(Resistance polarization)אאresistance )
Kאאא
W( Linear polarization resistance )אא
،אאאא
אKאאאא
٢٠±אאאא
KE٥ J٣FאאאאKא
Wאאא
- ٣٣ -
אא ١٦١ א
א אאאא
אE٣ J٣Fא،βc،βa
K
אא אK אאE٢ J٣Fא
W
אאאאאא
Wאאא
We: is the electrochemical equivalent = molecular wt./no. of electrons involved
in the anodic reaction;
d: is the density of the tested material (g/cm3);.
Icorr: corrosion current (µA/m2).
- ٣٤ -
אא ١٦١ א
א אאאא
KאאE٢ J٣F
KאאE٢ J٣F
- ٣٥ -
אא ١٦١ א
א אאאא
KאאאE٣ J٣F
WאאE٤ J٣F
אאאאאא
אאאK אאאאא
אאאאא
Kאאא
(Electrical resistance probes)אאאא
KE٤ J٣Fא
- ٣٦ -
אא ١٦١ א
א אאאא
KאאE٤ J٣F
Wאאאאאא
R = ρL/A
ρ : resistivity, L: length and A: cross-sectional area of the conductor.
אאאאא
א،אאאאאאא
KE٣ J٣Fאא
KאאאאE٣ J٣F
א א
١
٥ J٣
١٠ א
- ٣٧ -