CHEMISTERY Chap1
CHEMISTERY Chap1
CHEMISTERY Chap1
Liquids
There are many different liquids such as;
water, oil, fruit juice, and many others.
The particles in liquids are arranged in a
random way, and are close together, touching
many of their neighbours. There are some
gaps, but liquids cannot usually be compressed
or squashed.
The particles of a liquid have enough energy
to break free of some of the forces of attraction
between the particles. So particles in liquids
can move around and can move over each
other, allowing liquids to flow and be poured.
Gases
There are lots of different gases, such as the
air we breathe or the helium used to fill
balloons.
The particles in gases are widely spaced and
randomly arranged, meaning they can be
easily compressed or squashed.
The particles in a gas have enough energy to
overcome the forces of attraction between the
particles, so are free to move in any direction.
They move quickly in straight lines, colliding
with each other and the walls of their
container.
Variables
Scientific investigations often involve things that
can be changed, known as variables. Scientists
often want to find out if changing one variable will
make a difference to another variable.
Solids, liquids and gases change state when they
are heated or cooled.
Processes such as evaporation and boiling change
the state of substances.
A particle model can be used to show how solids,
liquids and gases change state.
Changes of state
When an ice cube is heated, it melts, and if the
liquid water continues to be heated it will
eventually boil.Melting and boiling are changes of
state, and they can occur in reverse too if a
substance is cooled down.
Heating up and cooling down
Substances can change state when they are heated
or cooled.
Heating up
Melting - When a solid is heated, it absorbs
energy and it melts, turning into a liquid.
Boiling - If the liquid is heated, it absorbs
more energy and it boils, turning into a gas.
These changes absorb energy from the
surroundings so they are endothermic.
Evaporating is when a liquid turns into a gas
slowly, at temperatures that are below
its boiling point. Puddles dry up because
they evaporate – they don’t boil.
Cooling down
Condensing - If a gas is cooled, it transfers
energy to the surroundings, and turns into a
liquid.
Freezing - If the liquid is cooled, it transfers
energy to the surroundings, and turns into a
solid.
These changes transfer energy to the
surroundings so they are exothermic.
Image caption,
Water changing state
Ice
Some solids change directly into a gas without
becoming a liquid first. This process is called
sublimation.
Solid carbon dioxide is often called dry ice. It must
be kept inside well insulated containers because
when its temperature rises above -78 °C
it sublimes, or sublimates, into carbon dioxide gas.
This process is endothermic, so it can be used to
keep other substances cold.
Dry ice must be handled carefully because it can
cause frostbite if touched, which means it will
freeze skin and body tissues. Dry ice can also be
used to create artificial fog in theatres.
Pressure in gases is caused by
particles colliding with the walls of the container.
Gas pressure is increased when the temperature
increases or the volume of the container decreases.
What happens to the pressure of a gas if the
temperature is increased? The gas pressure
increases. If a gas is heated, its particles move
around more quickly. They hit the walls of their
container harder and more often, which increases
the pressureAs the particles of a gas collide with
the walls of their container, they exert a force on
these walls.
Gas pressure is the name given to the force exerted
by gas particles colliding with the wall of their
container.
Pressure is force exerted over an area.
Gas pressure is the force exerted by a gas on a
specific area.
A car tyre contains gas under pressure. This means
that there are more air particles pushing on the
inside of the tyre than on the outside of the tyre.
Hyd
rogen is the first element listed in the periodic table. We use
the symbol H for hydrogen. It is an explosive gas which burns
with a very clear ‘squeaky pop’ when a burning splint is
inserted into a test tube containing it.
Helium is the second element in the periodic table, and has the
symbol He. Helium is also a gas, but is very different from
hydrogen because it doesn’t take part in any chemical
reactions. Helium is used for party balloons because it is
lighter than air.
The first 94 chemical elements, up to plutonium, occur
naturally on Earth and elsewhere in the universe. The heaviest
elements are made by humans using nuclear reactions, but
these elements cannot be seen in this version of the periodic
table.
Where are the metal elements found on the periodic table?
To the left and in the middle.
Particle diagrams - elements
Particle diagrams can be used to show the atoms of elements.
All of the atoms in a particle diagram must be the same colour
and size.
A particle diagram can represent a solid element, a liquid
element or a gaseous element.
1. A solid element
The particles are close together and arranged in a regular way.
2. A liquid element
The particles are close together and arranged in a random
way.
3. A gaseous element
The particles are far apart and arranged in a random way.
Molecules
Some non-metal elements are made from atoms which are
bonded into clusters called molecules.
For example, oxygen is a gaseous element made from
molecules.
Figure caption,
Compounds
A compound is a substance that contains atoms of two or more
different elements.
The elements are chemically bonded together in a
specific ratio of atoms.
The formula of a compound shows how many atoms of each
element are bonded together.
The formula is made up of symbols and numbers.
The numbers are written as subscript, which means they are
smaller than the symbol, and slightly lower down. For
example, the formula for water is H₂O.
Examples
Oxygen molecules
A molecule is made up of 2 or more atoms. These can be the
same type or different.
To break
apart the elements in a compound, a chemical reaction must
take place, for example, electrolysis or thermal
decomposition. However, when elements make a mixture,
then through a physical process such as filtration or
crystallisation, it is possible to separate them.
Compounds are not found on the periodic table. For example,
water isn’t on the periodic table because it is a compound, not
an element. Water is made from the element hydrogen bonded
to the element oxygen.
Particle diagrams - compounds
A particle diagram for a compound will show more than one
type of atom.
For example:
H₂O
Water molecules are made up of two elements - hydrogen
(white atoms) and oxygen (red atoms).
Water molecules are made up of two elements - hydrogen
(white atoms) and oxygen (red atoms).
Water has a specific ratio of two hydrogen atoms to one
oxygen atom.
CO₂
Carbon dioxide molecules are made up of two elements -
carbon (black atoms) and oxygen (red atoms).
Carbon dioxide has a specific ratio is one carbon atom to two
oxygen atoms.
Non-metals
Compounds made from non-metal elements that are bonded
together usually form molecules.
Compounds including both a metal element and a non-metal
element bonded together do not form molecules.
Their diagrams look quite different, this is called a lattice.
If this 3D particle diagram for sodium chloride was shown on
a large scale, it would show the same number of metal sodium
atoms (grey) as chlorine atoms (green), because the formula
is NaCl.
Image caption,
A carbon atom
Diamond
Graphite
The atoms in graphite are arranged in layers that slide over each
other. This makes graphite slippery. It is sometimes used instead of
oil to lubricate locks. Graphite is the only non-metal element that
conducts electricity.
Graphene
Scientists are still working out how we could use it, but in the
future it could be used to make better gloves, sportswear and
medical devices.
Mixtures
A mixture is formed when two or more elements or
compounds are present without being chemically bonded
together.
The substances which have been mixed are not present in
specific amounts or ratios like they are in a compound, e.g.
two hydrogen atoms for each oxygen atom in water. They can
be in any combination, e.g. for a mixture of sand and water
you could have any amount of sand with any amount of water.
In a mixture, the two ingredients can be separated using
physical processes, without chemical reactions. This is
because they are not chemically bonded together.
Here are some examples:
A mixture of sand and water can be separated
using filtration.
A solution of salt and water can be separated
using crystallisation or distillation.
A mixture of iron filings and sulfur powder can be
separated using a magnet.
Particle diagrams - mixtures
A particle diagram of a mixture can include atoms and
molecules, but they are not bonded together.
Image caption,
A water molecule
Water is made of molecules. Each water molecule is made
from two hydrogen atoms chemically bonded to one oxygen
atom. This means that the chemical formula of water is H₂O.
Carbon dioxide is made of molecules of a carbon atom
bonded to two oxygen atoms (CO₂).
Drawing atoms and molecules
Atoms can be drawn as circles. But all the atoms of an
element need to look exactly the same.
When drawing a diagram of molecules made from the atoms
of more than one element, different sizes and colours can
show the different elements.
There are no rules for the colours of the atoms when drawing
them.
They can be any colour
Examples
Figure caption,
Water molecules
Water (H₂O) molecules contain one oxygen atom and two
hydrogen atoms.
Here, the oxygen atom is red and the hydrogen atoms are
white.
Figure caption,
Ethanol molecules
Ethanol is a much larger molecule made of three types of
atoms. Its formula is CH₃CH₂OH.
Here, the oxygen atom is red, carbon is black and hydrogen is
white.
Image caption,
A ball-and-stick model of methane
Molecules can be drawn in different ways. In this diagram of
methane (CH₄) the chemical bond between atoms is shown as
a stick.
One molecule of the compound methane is made from one
carbon atom and four hydrogen atoms.
These are carbon dioxide molecules. Can you work out
what elements the different coloured circles are?
The black circles are carbon atoms and the red ones are
oxygen. Carbon dioxide molecules contain one carbon
atom and two oxygen atoms. The formula for carbon
dioxide is written as CO₂.
Single element molecules
Some molecules are made from one type of atom. This means
the molecule is an element.
Oxygen is a non-metal element and is found naturally as a
molecule. Each one is made up of two oxygen atoms that are
strongly bonded together.
At room temperature oxygen is a gas.
Figure caption,
An oxygen molecule
ELEMENTS
An element is a substance that cannot be broken down into any other
substance. Every element is made up of its own type of atom. This is
why the chemical elements are all very different from each other.
Everything in the universe contains the atoms of at least one or more
element.
The periodic table lists all the known elements and groups together
those with similar properties.
What is an element?
An element is a substance that cannot be broken down into
any other substance. There are about 100 elements, each with
its own type of atom. Everything in the universe contains the
atoms of at least one or more elements.
The periodic table lists all the known elements, grouping
together those with similar properties. Most elements
are metals, which are shiny and conduct electricity well.
Metals include gold, aluminium and iron which are all solid at
room temperature.
Mercury is the only metal that is liquid at room temperature.