Wat 31

Sec: JR_*CO-SC Date: 03-01-21
Time: 3 Hrs Max. Marks: 180
03-01-21_JR.IIT STAR CO-SUPER CHAINA _Jee-ADV_WAT-31_SYLLABUS

PHYSICS: PRESENT WEEK (80%): Waves & Sound: Introduction to wave
motion,classifications, equation of Progressive plane waves and
pulses,Transverse waves on stretched strings- velocity, power
transmitted, Energy (Exclude superposition, reflection & transmission
of waves, standing waves on string, sound waves)
PREVIOUS WEEK (20%): Heat Transfer : Heat conduction in one
dimension; Elementary concepts of convection and radiation; Newton’s
law of cooling, Blackbody radiation: absorptive and emissive powers;
Kirchhoff’s law; Wien’s displacement law, Stefan’s law.
CHEMISTRY: PRESENT WEEK (80%): Alkenes: Preparation, Mechanism of

Elimination reactions (E1, E2, E1CB) (Including Hoffman elimination
and pyrolysis of ester)
PREVIOUS WEEK (20%): Preparation of alkanes from different
compounds, Alkane preparation,Physical properties of alkanes ,
reactions of alkanes, Mechanism of Free radical Substitution
MATHEMATICS: PRESENT WEEK (80%): Family of Circles,Angle between two

Circles,Common chord, Chord whose midpoint is given,Direct,
Transverse, Pair of tangents
PREVIOUS WEEK (20%): CIRCLE: Equation of Circles (Various
forms),Secant, Tangent, Normal, Chord of Circle,Chord of Contact
Narayana IIT Academy 03-01-21_Jr.IIT_*CO-SC _JEE-ADV_WAT-31_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 10) Questions with Multiple Correct Choice 3 0 10 30
Sec – II(Q.N : 11 – 20) Questions with Integer Answer Type 3 0 10 30
Total 20 60
CHEMISTRY:
Total 20 60
MATHS:
Total 20 60
Jr.IIT_*CO SC Page 2
PHYSICS Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct.
1. A transverse sinusoidal wave moves along a string in the positive x direction. In figure
(I) displacement of particle at P as a function of time is given and in figure (II) at a
particular time t, the snap shot of wave is shown:
A) speed of particle P is 2 cm / sec

B) speed of particle P is 3 cm / sec
C) wave speed is 1 cm / sec
D) wave speed is 2 cm / sec
2. A photo graph of a progressive wave moving in a taut rope has been shown. A particle
P (shown in figure) is moving upward.
A) Wave is moving in positive x-direction

B) Wave is moving in negative x-direction
C) Phase at point A is greater than the phase at B
D) Phase at point B is greater than the phase at point A
3. The wave function of a triangular wave pulse is given at time
t = 0 sec as:
 a
 mx for 0  x 
2

 a
y  m  x  a  for  x  a
 2
 0 every where else


The wave pulse is moving in the +X direction in a string having tension T and mass
per unit length  . The total energy present with the wave pulse is
m2Ta
A) Potential energy of wave pulse is
2
B) Kinetic energy of wave pulse is m 2Ta
m2Ta
C) Total energy of wave pulse is
2
D) Total energy of wave pulse is m 2Ta
T
4. A snap shot of a progressive wave at t  is given with a time period T. As shown in
6
 2 
figure. Then check the following options  Here,T   (symbols have their usual
  
meaning)
 
A) Equation of wave if it goes towards positive x-axis y1  Asin  kx   t  
 2
B) Equation of wave if it goes towards positive x-axis y1  Asin  kx   t 
 
C) Equation of wave if it goes towards negative x-axis y 2  Asin  kx   t  
 6
 
D) Equation of wave if it goes towards negative x-axis y 2  Asin  kx   t  
 6
5. A uniform rope of length 12m and mass 3kg hangs vertically from a rigid support. A
block of mass 1 kg is attached to the free end of the rope. A transverse pulse of
wavelength 0.08m is produced at the lower end of the rope, then:
A) Wavelength of pulse when it reaches the top is 0.08 m
B) Wavelength of pulse when it reaches the top is 0.16 m
C) Frequency of wave pulse changes when it reaches the top.
D) Frequency of wave pulse does not change when it reaches the top.
0.1C3
6. The wave function for the wave pulse is y  x, t   with C = 4cm at x = 0
C2   x  vt 
2
the displacement y  x,t  is observed to decrease from its maximum value to half of its
maximum value in time t  2  103 s .
A) y(x, t) represents the motion of travelling pulse moving along positive X direction.
B) y(x, t) does not represent the motion of a travelling pulse
C) Speed of wave pulse is 20 m/s
D) Speed of wave pulse is 10 m/s
7. One end of a string of length L is tied to the ceiling of a lift accelerating upwards with
an acceleration 2g. The other end of the string is free. The linear mass density of the
string varies linearly from 0 to  from bottom to top.
A) The velocity of the wave in the string will be 3g/4 everywhere
B) The acceleration of the wave on the string will be 3g/4 everywhere
C) The time taken by a pulse to reach from bottom to top will be 8L / 3g
D) The time taken by a pulse to reach from bottom to top will be 4L / 3g

8. A “hot reservoir” at 100.0 °C is connected to a “cold reservoir” at 0°C via two
separate rods each of length 10cm which are insulated perfectly on their sides as
shown in the figure(i). Rod A is made of steel, has a cross sectional area of 4.0 cm2.
Rod B is made of copper. Take thermal conductivities of steel and copper respectively
as 50 W m–1K–1 and 400 W m–1K–1. The areas are such that in figure (i) rate of heat
flow through both rods are equal. Mark the correct statement(s):
A) The cross-sectional area of the copper rod is 0.5 cm2
B) In figure (i) the time it takes for a total of 1.0 × 103 J of heat to flow from the hot to
the cold reservoir via the steel rod is 50 sec
C) In figure (ii) suppose the two rods of above specifications were welded end to end
and the free ends connected to the reservoirs. The rate of flow of heat from hot to cold
reservoirs in this situation is 15J/sec.
D) In figure (ii) suppose the two rods of above specifications were welded end to end
and the free ends connected to the reservoirs. The rate of flow of heat from hot to cold
reservoirs in this situation is 10J/sec.
9. The two ends of a uniform rod (thermal conductivity K) are maintained at different but
dT
constant temperature. The temperature gradient at any point on the rod is in steady
d
state. The heat flow per unit time per unit cross-section of the rod is I. Which
statement is/are correct?
dT
A) is the same for all points on the rod
d
B) I will increase as we move from higher to lower temperature
dT
C) I  K
d
D) In steady state the temperature gradient is zero at the ends of the rods.
10. A spherical object which behaves as a blackbody is raised to the temperature T0 and
placed in an environment, initially at 0°C. While the object cools from T0 in an
interval of time t   , the environment rises to the temperature t0 °C during the same
dT
time. The average rate of cooling of the object and the average net heat loss Q
dt
 dT
of the object during the time interval 0  t  are given by   A and Q   A
4 dt
3 dT
respectively while the same quantities during the interval  t   are   B and
4 dt
Q  B . Read the following statements about this system and choose correct
statement(s).
A)  A   B ,  A   B B)  A   B ,  A   B

C) The Newton’s law of cooling will be more accurate near t  than near
2
t  0 or t  
D) The rate of cooling decreases with time at first, reaches a minimum and then
increases with time
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
11. A heavy mass is hanging from ceiling as shown, both wires are identical. A pulse is
produced in both the strings simultaneously at the point of contact with mass. If it
reaches the ceiling in 3 3  103 sec for string on the right, in what time will it reach
the ceiling for the left string (in 10–3 sec?)
12. The kinetic energy of pulse travelling in a taut string is  0.03  n  mJ . Find the value of
n. (Given Tension (T) = 10N and   0.1kg / m )
13. In the given figure, a string of linear mass density 3×10–2 kg/m and length L = 1m, is
stretched by a force F   3  kt  N, where k is a constant and t is time in sec. At the
time t = 0, a pulse is generated at the end P of the string. Find the value of k/10 (in
N/s) if the value of force becomes zero as the pulse reaches point Q.
14. A cylindrical rod with one end in a steam chamber and other end in ice causes melting
of 0.1 gm of ice/sec. If the rod is replaced with another rod of half the length and
double the radius of first and thermal conductivity of second rod is ¼ that of first, if
the rate of ice melting is x gm/s. Find the value of 15x.
15. Two highly conducting shells A and B have radius R and 2R and are concentric.
Temperature of A is maintained at 2T0 and the arrangement is kept in an enclosure of
temperature T0 as shown. In steady state the temperature of B is T0 n , find n
(assume a =1 for shell B)
16. The equation of a vibrating string, fixed at both ends, is given by

 x 
y  (3 mm) sin   sin(400t)
 15 
Where x is the distance (in cm) measured from one end of the string, t is the time (in
seconds), and y gives the displacement. The speed of transverse waves along the string
equals 12u m/s, find u.
17. A uniform rope with length L  1m and mass m  200g and  is held at one end and
whirled in a horizontal circle with angular velocity  rad / s . You can ignore the force
of gravity on the rope. The time required for a transverse wave to travel from one end

of the rope to the other is sec, then value of n is
n
18. A simple harmonic wave of amplitude 2mm is travelling along positive x-axis. At a
given instant, displacement for two different particles on the wave is 1 mm and
2mm along positive Y direction. If wave length of wave is 48 mm then find
minimum separation between positions of the particles (in mm)
19. A plane elastic wave    e  x cos  t  kx  , where  ,  ,  and k are constants,
propagates in a homogeneous medium. Find the phase difference between the
oscillations in radian at the points where the particles’ displacement amplitudes differ
by   1.0%, if   0.042 m1 and the wavelength is   50cm
20. An ant sitting on a string can pull the string with a maximum force up to three times of
10
its own weight. A sine wave of amplitude A  2 m in vertical plane is generated in

the string. Find the minimum time period of oscillations of string in second so that ant
will not fall from the string. (Neglect the variation of tension in the string due to
weight of the ant, g  10m/ s2 )
CHEMISTRY Max Marks:60
SECTION-I
21. Identify reaction/s that correctly match with their products
A)
B)
C)
D)
22. Select the correct statement/s
A) Syn-elimination is preferred in the reactions when elimination reactions proceed

through 5 or 6 membered cyclic transition state.
B) Syn-elimination reaction is possible when the trans-arrangement of leaving groups is

not possible.
C) E-2 reaction shows primary kinetic Isotopic effect.
D) All stereospecific reactions are necessarily stereo selective but stereo selective
reactions are not necessarily stereospecific reactions.
23. Which of following will give syn-elimination on heating?
A) CH 3CH 2CH 2  OCOCH 3 B)
C) D)
24. Which of the following are correct for given reaction?
A)
B)
C) The reaction is thermal elimination reaction

D) The reaction is E1 reaction
25. Which alkene is/are formed in given reaction.
CH 3 (CH 2 )6 CH 2OH 
H 3 PO4
 Alkene/s

A) octene-1 B) octene-2 C) octene-3 D) octene-4

26. Select the impurities which can be added in Isomerisation reaction of alkane.
A) Alkyl halide B) Alkenes C) H 2 D) O2
27. Select correct option for this reaction:
A) Total 2 alkene are produced
B) It follows E2 mechanism
C) 2 fractions are obtained on fractional distillation of organic products
D) Me3COK will give same major product as KOH
28. Alkyl halides, out of the given, gives only 3 alkenes (including stereoisomers) on
dehydrohalogenation with alcoholic KOH is-
A) B)
C) D)
29. Which alkene/s are not formed in product?
A) B)
C) D)
30. Select which reaction/s is correct with major product given?
A)
B)
C)
D)
SECTION-II
(both inclusive).
31. Calculate total number of alkene products when 2-chloro-2-cyclobutyl hexane react
with alcoholic KOH and heat.
32. How many alkyl chlorides will produce isooctane on treatment with NaBH 4 ?
33. Find the total number of alpha-H in major alkene?
34. How many chloro derivatives are possible for ethane?
35. Find the number of of alkyl chloride which on reaction with alcoholic KOH, heat gives
Following compound as major product-
R  Cl 
alc. KOH
heat

36. Total number of 1, 2- shift’s during formation of major product is:
37.
x 1
Find the value of where x is the total number of   H in all possible alkenes are
2
formed in reaction.
38. How many product(s) corresponding to the molecular formula C9H16 formed in
following reaction-
39. Find the D.B.U of the product
40. Find the number of alkyl chloride which on reaction with alcoholic KOH, heat gives
following compound as the only product –
[X ] 
alc KOH
Heat

monochloride
MATHEMATICS Max Marks:60
SECTION-I
2
41. Given a circle of radius 3 and a point P outside the circle such that APB  , where
3
A and B are points of tangency from P to the circle. Line joining P and center O of the
circle cut the circle at C and D (Where C is near to point P), which of the following
statement(s) is/are correct.
9 3
A) Area of triangle ABC  Area of triangle ABD is
2
3 3
B) Area of triangle ABC  Area of triangle ABD is
2
C) Circum radius of triangle PAB is 3

D) Circum radius of triangle PAB is 2 3
42. Let t1 , t2 , t3 be the lengths of tangents from a point P to the circles x 2  y 2  a 2 ,
x 2  y 2  2ax , x 2  y 2  2ay respectively. If t14  t22t32  a 4 , then the locus of P is
A) x  y  0 B) x  y  0
C) x 2  y 2  ax  ay  0 D) x 2  y 2  ax  ay  0
43. If secants are drawn through P  2, 1 to the circle x 2  y 2  2 x  0 meeting it at A and B
and Q lies on AB segment then
A) Locus of Q such that PA, PQ, PB are in H.P is 3 x  y  2  0
B) Locus of Q such that PA, PQ, PB are in A.P is x 2  y 2  x  y  2  0
C) Locus of Q such that PA, PQ, PB are in G.P is x 2  y 2  4 x  2 y  4  0
D) If ‘a’ is least and ‘b’ is greatest and a  PQ  b then G.M of ‘a’ and ‘b’ is 3
44. Three circles whose radii are 1, 2 and 3 units and having centres at A, B and C
respectively touch each other (Pair-wise) externally at D, E and F respectively then
which of the following is/are correct
A) Circum radius of DFE is 1 B) Circum centre of ABC is 1/2 units from E
8
C) Length of DE  D) B is the orthocentre of ABC
5
45. Three circles of same radius ‘r’ and drawn so that each one touches the other two
externally. The radius of the circle which touches all the three circles is
A)  3  2 3  B)  2  2  C)  2  3  D)  2  3 
r r r r
3 2 3 3
46. Circles of radii 3 and 4 intersect orthogonally. The area common to the two circles is
4 4
A) 8  12  7 tan 1 B) 8  12  7 tan 1
3 3
3 9 3
C) 8  12  7 tan 1 D)  12  7 tan 1
4 2 4
47. The locus of points of intersection of the tangents to x 2  y 2  a 2 at the extremities of a

chord of circle x 2  y 2  a 2 which touches the circle x 2  y 2  2ax  0 is/are
A) y 2  a  a  2 x  B) x 2  a  a  2 y  C) x 2  y 2   x  a  D) x 2  y 2   y  a 
2 2
48. Two chords are drawn from the point P  h, k  on the circle x 2  y 2  hx  ky . If the y-axis
divides both the chords in the ratio 2 : 3, then which of the following may be correct?
A) k 2  15h 2 B) 15k 2  h 2 C) h 2  15k 2 D) k 2  5h 2
49. Let x, y be real variable satisfying the x 2  y 2  8 x  10 y  40  0 . Let
a  max  x  2    y  3 and b  min  x  2    y  3 , then

2 2 2 2
A) a  b  18 B) a  b  4 2 C) a  b  4 2 D) ab  73
Point M moved on the circle  x  4    y  8   20 . Then it broke away from it and

2 2
50.
moving along a tangent to the circle, cuts the x-axis at the point  2, 0  . The
coordinates of a point on the circle at which the moving point broke away is:
A)   ,  B)   , 
3 46 2 44
C)  6, 4  D)  3,5
 5 5   5 5 
SECTION-II
(both inclusive).
51. Equation of a straight line meeting the circle x 2  y 2  100 in two points, each point is at
a distance of 4 units from the point 8, 6  on the circle, is ax  by  46  0 where a, b  N
then a  b is equal to
52. Given the family of lines, a  2 x  y  4   b  x  2 y  3  0 , among the lines, of the family,
the number of lines situated at a distance of 10 from the point M  2, 3 is
53. A chord of the circle x 2  y 2  4 x  6 y  0 passing through origin subtends an angle

7
tan 1   at the point where the circle meets positive y-axis, then the equation of chord
4
belongs to the pair of lines 3x 2  5 xy  2 y 2  x  ky  0 , where ‘k’ is equal to
54. Let AB be any chord of the circle x 2  y 2  2 x  6 y  6  0 which subtends right angle at
the point (2,4), then the locus of midpoint of AB is x 2  y 2  ax  by  7  0 where a  b 
55. If ABCD is a square of unit side, four circles of unit radius are described with centres

A, B, C, D, then the area common to the four circles is a   c , where a, b, c  N
b
a  b  c 
4
then
a4  b  c 
3
56. If ‘  ’ is the angle between the circles passing through   , 2  ,  2 ,   and touching x-
axis, then the locus of the point from which pair of tangents are drawn to the circle
x 2  y 2  2 x  2 y  7  0 which includes the angle ‘  ’ is x 2  y 2  2 x  2 y  k  0 . Find
number of positive integral divisors of ‘k’
Given circles C1 :  x  1 x  2    y  1  y    0 , C2 :  x  1 x  3   y  1  y    0 ,

1 1
57.
 2  3
 1  1
C3 :  x  2  x  3   y    y    0 . Let their points of intersection form ABC , then
 2  3
   is equal to _ (where   abscissa of centroid of ABC ,   ordinate of
orthocentre of ABC )
58. Let C1  x 2  y 2  169  0 and C2  x 2  y 2  24 x  32 y  111  0 . Let AB be their common
chord. Maximum area of ABC , if ‘C’ lies on minor arc AB, is equal to 12 a . Find
greatest prime divisor of a
59. A circle is drawn through the point of intersection of A and B of the curve
2 x 2  3 y  5 x  8  0 and the line y  7 x  0 , the length of tangent drawn from
origin to the circle is equal to
60. Circles of radii 36 and 9 touches externally. The radius of the circle which touches the
two circles externally and also their common tangent is ___

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Sec: JR_*CO-SC Date: 03-01-21

Time: 3 Hrs Max. Marks: 180

03-01-21_JR.IIT STAR CO-SUPER CHAINA _Jee-ADV_WAT-31_SYLLABUS

CHEMISTRY: PRESENT WEEK (80%): Alkenes: Preparation, Mechanism of

MATHEMATICS: PRESENT WEEK (80%): Family of Circles,Angle between two

A) speed of particle P is 2 cm / sec

A) Wave is moving in positive x-direction

D) The time taken by a pulse to reach from bottom to top will be 4L / 3g

A) The cross-sectional area of the copper rod is 0.5 cm2

B) I will increase as we move from higher to lower temperature

16. The equation of a vibrating string, fixed at both ends, is given by

22. Select the correct statement/s

A) Syn-elimination is preferred in the reactions when elimination reactions proceed

B) Syn-elimination reaction is possible when the trans-arrangement of leaving groups is

C) E-2 reaction shows primary kinetic Isotopic effect.

A) CH 3CH 2CH 2  OCOCH 3 B)

24. Which of the following are correct for given reaction?

C) The reaction is thermal elimination reaction

A) octene-1 B) octene-2 C) octene-3 D) octene-4

29. Which alkene/s are not formed in product?

34. How many chloro derivatives are possible for ethane?

Following compound as major product-

36. Total number of 1, 2- shift’s during formation of major product is:

39. Find the D.B.U of the product

C) Circum radius of triangle PAB is 3

A) Circum radius of DFE is 1 B) Circum centre of ABC is 1/2 units from E

47. The locus of points of intersection of the tangents to x 2  y 2  a 2 at the extremities of a

A) k 2  15h 2 B) 15k 2  h 2 C) h 2  15k 2 D) k 2  5h 2

49. Let x, y be real variable satisfying the x 2  y 2  8 x  10 y  40  0 . Let

a  max  x  2    y  3 and b  min  x  2    y  3 , then

Point M moved on the circle  x  4    y  8   20 . Then it broke away from it and

the number of lines situated at a distance of 10 from the point M  2, 3 is

53. A chord of the circle x 2  y 2  4 x  6 y  0 passing through origin subtends an angle

belongs to the pair of lines 3x 2  5 xy  2 y 2  x  ky  0 , where ‘k’ is equal to

Given circles C1 :  x  1 x  2    y  1  y    0 , C2 :  x  1 x  3   y  1  y    0 ,

origin to the circle is equal to

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